Abstract: Carbon dioxide is one of the major greenhouse gas
(GHG) contributors. It is an obligation of the industry to reduce the
amount of carbon dioxide emission to the acceptable limits.
Tremendous research and studies are reported in the past and still the
quest to find the suitable and economical solution of this problem
needed to be explored in order to develop the most plausible absorber
for carbon dioxide removal. Amino acids can be potential alternate
solvents for carbon dioxide capture from gaseous streams. This is due
to its ability to resist oxidative degradation, low volatility and its
ionic structure. In addition, the introduction of promoter-like
piperazine to amino acid helps to further enhance the solubility. In
this work, the effect of piperazine on thermo physical properties and
solubility of β-Alanine aqueous solutions were studied for various
concentrations. The measured physicochemical properties data was
correlated as a function of temperature using least-squares method
and the correlation parameters are reported together with it respective
standard deviations. The effect of activator piperazine on the CO2
loading performance of selected amino acid under high-pressure
conditions (1bar to 10bar) at temperature range of (30 to 60)oC was
also studied. Solubility of CO2 decreases with increasing temperature
and increases with increasing pressure. Quadratic representation of
solubility using Response Surface Methodology (RSM) shows that
the most important parameter to optimize solubility is system
pressure. The addition of promoter increases the solubility effect of
the solvent.
Abstract: Carbon dioxide is one of the major green house gases.
It is removed from different streams using amine absorption process.
Sterically hindered amines are suggested as good CO2 absorbers.
Solubility of carbon dioxide (CO2) was measured in aqueous
solutions of 2-Amino-2-methyl-1-propanol (AMP) at temperatures 30
oC, 40 oC and 60 oC. The effect of pressure and temperature was
studied over various concentrations of AMP. It has been found that
pressure has positive effect on CO2 solubility where as solubility
decreased with increasing temperature. Absorption performance of
AMP increased with increasing pressure. Solubility of aqueous AMP
was compared with mo-ethanolamine (MEA) and the absorption
capacity of aqueous solutions of AMP was found to be better.