Abstract: Lipases are enzymes particularly amenable for
immobilization by entrapment methods, as they can work equally
well in aqueous or non-conventional media and long-time stability of
enzyme activity and enantioselectivity is needed to elaborate more
efficient bioprocesses. The improvement of Pseudomonas
fluorescens (Amano AK) lipase characteristics was investigated by
optimizing the immobilization procedure in hybrid organic-inorganic
matrices using ionic liquids as additives. Ionic liquids containing a
more hydrophobic alkyl group in the cationic moiety are beneficial
for the activity of immobilized lipase. Silanes with alkyl- or aryl
nonhydrolizable groups used as precursors in combination with
tetramethoxysilane could generate composites with higher
enantioselectivity compared to the native enzyme in acylation
reactions of secondary alcohols. The optimal effect on both activity
and enantioselectivity was achieved for the composite made from
octyltrimethoxysilane and tetramethoxysilane at 1:1 molar ratio (60%
increase of total activity following immobilization and enantiomeric
ratio of 30). Ionic liquids also demonstrated valuable properties as
reaction media for the studied reactions, comparable with the usual
organic solvent, hexane.
Abstract: The purpose of this study was to explore the complex
flow structure a novel active-type micromixer that based on concept of
Wankle-type rotor. The characteristics of this micromixer are two
folds; a rapid mixing of reagents in a limited space due to the
generation of multiple vortices and a graduate increment in dynamic
pressure as the mixed reagents is delivered to the output ports.
Present micro-mixer is consisted of a rotor with shape of triangle
column, a blending chamber and several inlet and outlet ports. The
geometry of blending chamber is designed to make the rotor can be
freely internal rotated with a constant eccentricity ratio. When the
shape of the blending chamber and the rotor are fixed, the effects of
rotating speed of rotor and the relative locations of ports on the mixing
efficiency are numerical studied. The governing equations are
unsteady, two-dimensional incompressible Navier-Stokes equation
and the working fluid is the water. The species concentration equation
is also solved to reveal the mass transfer process of reagents in various
regions then to evaluate the mixing efficiency.
The dynamic mesh technique was implemented to model the
dynamic volume shrinkage and expansion of three individual
sub-regions of blending chamber when the rotor conducted a complete
rotating cycle. Six types of ports configuration on the mixing
efficiency are considered in a range of Reynolds number from 10 to
300. The rapid mixing process was accomplished with the multiple
vortex structures within a tiny space due to the equilibrium of shear
force, viscous force and inertial force. Results showed that the highest
mixing efficiency could be attained in the following conditions: two
inlet and two outlet ports configuration, that is an included angle of 60
degrees between two inlets and an included angle of 120 degrees
between inlet and outlet ports when Re=10.
Abstract: Many foreign and Lithuanian scientists, analyzing the
evaluation of the tax system in respect of the burden of taxation,
agree that the latter, in principle, depends on how many individuals
and what units of the residents constitute a household. Therefore, the
aim of scientific research is to substantiate or to deny the significance
of a household, but not a resident, as a statistical unit, during the
evaluation of tax system, to be precise, determination of the value of
the burden of taxation. A performed scientific research revealed that
evaluation of the tax system in respect of a household, but not a
resident, as a statistical unit, allows not only to evaluate the
efficiency of the tax system more objectively, but also to forecast
practicably existing poverty line, burden of taxation, and to
capacitate the initiation of efficient decisions in social and tax fields
creating the environment of existence.
Abstract: The purpose of this study was to evaluate the tissue
composition and carcass muscularity of 32 legs of Ile de France
lambs fed with diets containing sunflower seeds and vitamin E, with
mean body weight of 15 kg, lodged in individual pens at 15 kg and
slaughtered at 32 kg of body weight. The treatments influenced
(P0,05) by the treatments. The
interaction of the sunflower and vitamin E was positive for bone total
weights and intermuscular fat.
Abstract: Ramadan requires individuals to abstain from food and fluid intake between sunrise and sunset; physiological considerations predict that poorer mood, physical performance and mental performance will result. In addition, any difficulties will be worsened because preparations for fasting and recovery from it often mean that nocturnal sleep is decreased in length, and this independently affects mood and performance.
A difficulty of interpretation in many studies is that the observed changes could be due to fasting but also to the decreased length of sleep and altered food and fluid intakes before and after the daytime fasting. These factors were separated in this study, which took place over three separate days and compared the effects of different durations of fasting (4, 8 or 16h) upon a wide variety of measures (including subjective and objective assessments of performance, body composition, dehydration and responses to a short bout of exercise) - but with an unchanged amount of nocturnal sleep, controlled supper the previous evening, controlled intakes at breakfast and daytime naps not being allowed. Many of the negative effects of fasting observed in previous studies were present in this experiment also. These findings indicate that fasting was responsible for many of the changes previously observed, though some effect of sleep loss, particularly if occurring on successive days (as would occur in Ramadan) cannot be excluded.
Abstract: Rapid urbanization, industrialization and population
growth have led to an increase in number of automobiles that cause
air pollution. It is estimated that road traffic contributes 60% of air
pollution in urban areas. A case by case assessment is required to
predict the air quality in urban situations, so as to evolve certain
traffic management measures to maintain the air quality levels with
in the tolerable limits. Calicut city in the state of Kerala, India has
been chosen as the study area. Carbon Monoxide (CO) concentration
was monitored at 15 links in Calicut city and air quality performance
was evaluated over each link. The CO pollutant concentration values
were compared with the National Ambient Air Quality Standards
(NAAQS), and the CO values were predicted by using CALINE4 and
IITLS and Linear regression models. The study has revealed that
linear regression model performs better than the CALINE4 and
IITLS models. The possible association between CO pollutant
concentration and traffic parameters like traffic flow, type of vehicle,
and traffic stream speed was also evaluated.
Abstract: A mathematical model for the Dynamics of Economic
Profit is constructed by proposing a characteristic differential oneform
for this dynamics (analogous to the action in Hamiltonian
dynamics). After processing this form with exterior calculus, a pair of
characteristic differential equations is generated and solved for the
rate of change of profit P as a function of revenue R (t) and cost C (t).
By contracting the characteristic differential one-form with a vortex
vector, the Lagrangian is obtained for the Dynamics of Economic
Profit.
Abstract: For more than 120 years, gold mining formed the
backbone the South Africa-s economy. The consequence of mine
closure was observed in large-scale land degradation and widespread
pollution of surface water and groundwater. This paper investigates
the feasibility of using natural zeolite in removing heavy metals
contaminating the Wonderfonteinspruit Catchment Area (WCA), a
water stream with high levels of heavy metals and radionuclide
pollution. Batch experiments were conducted to study the adsorption
behavior of natural zeolite with respect to Fe2+, Mn2+, Ni2+, and Zn2+.
The data was analysed using the Langmuir and Freudlich isotherms.
Langmuir was found to correlate the adsorption of Fe2+, Mn2+, Ni2+,
and Zn2+ better, with the adsorption capacity of 11.9 mg/g, 1.2 mg/g,
1.3 mg/g, and 14.7 mg/g, respectively. Two kinetic models namely,
pseudo-first order and pseudo second order were also tested to fit the
data. Pseudo-second order equation was found to be the best fit for
the adsorption of heavy metals by natural zeolite. Zeolite
functionalization with humic acid increased its uptake ability.
Abstract: In this paper a stochastic scenario-based model predictive control applied to molten salt storage systems in concentrated solar tower power plant is presented. The main goal of this study is to build up a tool to analyze current and expected future resources for evaluating the weekly power to be advertised on electricity secondary market. This tool will allow plant operator to maximize profits while hedging the impact on the system of stochastic variables such as resources or sunlight shortage.
Solving the problem first requires a mixed logic dynamic modeling of the plant. The two stochastic variables, respectively the sunlight incoming energy and electricity demands from secondary market, are modeled by least square regression. Robustness is achieved by drawing a certain number of random variables realizations and applying the most restrictive one to the system. This scenario approach control technique provides the plant operator a confidence interval containing a given percentage of possible stochastic variable realizations in such a way that robust control is always achieved within its bounds. The results obtained from many trajectory simulations show the existence of a ‘’reliable’’ interval, which experimentally confirms the algorithm robustness.
Abstract: In India, the quarrel between the budding human
populace and the planet-s unchanging supply of freshwater and
falling water tables has strained attention the reuse of gray water as
an alternative water resource in rural development. This paper
present the finest design of laboratory scale gray water treatment
plant, which is a combination of natural and physical operations such
as primary settling with cascaded water flow, aeration, agitation and
filtration, hence called as hybrid treatment process. The economical
performance of the plant for treatment of bathrooms, basins and
laundries gray water showed in terms of deduction competency of
water pollutants such as COD (83%), TDS (70%), TSS (83%), total
hardness (50%), oil and grease (97%), anions (46%) and cations
(49%). Hence, this technology could be a good alternative to treat
gray water in residential rural area.
Abstract: The effects of down slope steepness on soil splash distribution under a water drop impact have been investigated in this study. The equipment used are the burette to simulate a water drop, a splash cup filled with sandy soil which forms the source area and a splash board to collect the ejected particles. The results found in this study have shown that the apparent mass increased with increasing downslope angle following a linear regression equation with high coefficient of determination. In the same way, the radial soil splash distribution over the distance has been analyzed statistically, and an exponential function was the best fit of the relationship for the different slope angles. The curves and the regressions equations validate the well known FSDF and extend the theory of Van Dijk.
Abstract: A complete spectral representation for the
electromagnetic field of planar multilayered waveguides
inhomogeneously filled with omega media is presented. The problem
of guided electromagnetic propagation is reduced to an eigenvalue
equation related to a 2 ´ 2 matrix differential operator. Using the
concept of adjoint waveguide, general bi-orthogonality relations for
the hybrid modes (either from the discrete or from the continuous
spectrum) are derived. For the special case of homogeneous layers
the linear operator formalism is reduced to a simple 2 ´ 2 coupling
matrix eigenvalue problem. Finally, as an example of application, the
surface and the radiation modes of a grounded omega slab waveguide
are analyzed.
Abstract: The wind resource in the Italian site of Lendinara
(RO) is analyzed through a systematic anemometric campaign
performed on the top of the bell tower, at an altitude of over 100 m
above the ground. Both the average wind speed and the Weibull
distribution are computed. The resulting average wind velocity is in
accordance with the numerical predictions of the Italian Wind Atlas,
confirming the accuracy of the extrapolation of wind data adopted for
the evaluation of wind potential at higher altitudes with respect to the
commonly placed measurement stations.
Abstract: Recently, the advanced technologies that offer high
precision product, relative easy, economical process and also rapid
production are needed to realize the high demand of ultra precision
micro part. In our research, micromanufacturing based on soft
lithography and nanopowder injection molding was investigated. The
silicone metal pattern with ultra thick and high aspect ratio succeeds to
fabricate Polydimethylsiloxane (PDMS) micro mold. The process
followed by nanopowder injection molding (PIM) by a simple vacuum
hot press. The 17-4ph nanopowder with diameter of 100 nm, succeed
to be injected and it forms green sample microbearing with thickness,
microchannel and aspect ratio is 700μm, 60μm and 12, respectively.
Sintering process was done in 1200 C for 2 hours and heating rate
0.83oC/min. Since low powder load (45% PL) was applied to achieve
green sample fabrication, ~15% shrinkage happen in the 86% relative
density. Several improvements should be done to produce high
accuracy and full density sintered part.
Abstract: ISO 9000 is the most popular and widely adopted meta-standard for quality and operational improvements. However, only limited empirical research has been conducted to examine the impact of ISO 9000 on operational performance based on objective and longitudinal data. To reveal any causal relationship between the adoption of ISO 9000 and operational performance, we examined the timing and magnitude of change in time-based performance as a result of ISO 9000 adoption. We analyzed the changes in operating cycle, inventory days, and account receivable days prior and after the implementation of ISO 9000 in 695 publicly listed manufacturing firms. We found that ISO 9000 certified firms shortened their operating cycle time by 5.28 days one year after the implementation of ISO 9000. In the long-run (3 years after certification), certified firms showed continuous improvement in time-based efficiency, and experienced a shorter operating cycle time of 11 days than that of non-certified firms. There was an average of 6.5% improvement in operating cycle time for ISO 9000 certified firms. Both inventory days and account receivable days showed similar significant improvements after the implementation of ISO 9000, too.
Abstract: Flour from Mucuna beans (Mucuna pruriens) were
used in producing texturized meat analogue using a single screw
extruder to monitor modifications on the proximate composition and
the functional properties at high moisture level. Response surface
methodology based on Box Behnken design at three levels of barrel
temperature (110, 120, 130°C), screw speed (100,120,140rpm) and
feed moisture (44, 47, 50%) were used in 17 runs. Regression models
describing the effect of variables on the product responses were
obtained. Descriptive profile analyses and consumer acceptability
test were carried out on optimized flavoured extruded meat analogue.
Responses were mostly affected by barrel temperature and moisture
level and to a lesser extent by screw speed. Optimization results
based on desirability concept indicated that a barrel temperature of
120.15°C, feed moisture of 47% and screw speed of 119.19 rpm
would produce meat analogue of preferable proximate composition,
functional and sensory properties which reveals consumers` likeness
for the product.
Abstract: The liberalization and privatization processes have
forced public utility companies to face new competitive challenges,
implementing strategies to gain market share and, at the same time,
keep the old customers. To this end, many companies have carried
out mergers, acquisitions and conglomerations in order to diversify
their business. This paper focuses on companies operating in the free
energy market in Italy. In the last decade, this sector has undergone
profound changes that have radically changed the competitive
scenario and have led companies to implement diversification
strategies of the business. Our work aims to evaluate the economic
and financial performances obtained by energy companies, following
the beginning of the liberalization process, verifying the possible
relationship with the implemented diversification strategies.
Abstract: This work evaluated the effect of temperature on headspace solid-phase microextraction of volatile and furanic compounds in coated fish sticks. The major goal was the analysis of the samples as consumed, to reproduce volatile compounds people feel when consuming those products. Extraction at 37 ºC (the human body temperature) throughout the HS-SPME analysis of volatile and furanic compounds in coated fish was compared with higher extraction temperatures, which are frequently used for this kind of determinations. The profile of volatile compounds found in deepfried (F) and non-fried (NF) coated fish at 37 and 50 ºC was different from that obtained at 80 ºC. Concerning furan and its derivatives, an extra formation of these compounds was observed at higher extraction temperatures. The analysis of volatile and furanic compounds in fish coated sticks simulating the cooking and eating conditions can be reliably carried out setting the headspace absorption temperature at 37 ºC.
Abstract: In this study, we explore the use of information for inventory decision in the healthcare organization (HO). We consider the scenario when the HO can make use of the information collected from some correlated products to enhance its inventory planning. Motivated by our real world observations that HOs adopt RFID and bar-coding system for information collection purpose, we examine the effectiveness of these systems for inventory planning with Bayesian information updating. We derive the optimal ordering decision and study the issue of Pareto improvement in the supply chain. Our analysis demonstrates that RFID system will outperform the bar-coding system when the RFID system installation cost and the tag cost reduce to a level that is comparable with that of the barcoding system. We also show how an appropriately set wholesale pricing contract can achieve Pareto improvement in the HO supply chain.
Abstract: Rapid Prototyping (RP) is a technology that produces models and prototype parts from 3D CAD model data, CT/MRI scan data, and model data created from 3D object digitizing systems. There are several RP process like Stereolithography (SLA), Solid Ground Curing (SGC), Selective Laser Sintering (SLS), Fused Deposition Modeling (FDM), 3D Printing (3DP) among them SLS and FDM RP processes are used to fabricate pattern of custom cranial implant. RP technology is useful in engineering and biomedical application. This is helpful in engineering for product design, tooling and manufacture etc. RP biomedical applications are design and development of medical devices, instruments, prosthetics and implantation; it is also helpful in planning complex surgical operation. The traditional approach limits the full appreciation of various bony structure movements and therefore the custom implants produced are difficult to measure the anatomy of parts and analyze the changes in facial appearances accurately. Cranioplasty surgery is a surgical correction of a defect in cranial bone by implanting a metal or plastic replacement to restore the missing part. This paper aims to do a comparative study on the dimensional error of CAD and SLS RP Models for reconstruction of cranial defect by comparing the virtual CAD with the physical RP model of a cranial defect.