Abstract: The effects of irrigation with dairy factory wastewater
on soil properties were investigated at two sites that had received
irrigation for > 60 years. Two adjoining paired sites that had never
received DFE were also sampled as well as another seven fields from
a wider area around the factory. In comparison with paired sites that
had not received effluent, long-term wastewater irrigation resulted in
an increase in pH, EC, extractable P, exchangeable Na and K and
ESP. These changes were related to the use of phosphoric acid,
NaOH and KOH as cleaning agents in the factory. Soil organic C
content was unaffected by DFE irrigation but the size (microbial
biomass C and N) and activity (basal respiration) of the soil
microbial community were increased. These increases were
attributed to regular inputs of soluble C (e.g. lactose) present as milk
residues in the wastewater. Principal component analysis (PCA) of
the soils data from all 11sites confirmed that the main effects of DFE
irrigation were an increase in exchangeable Na, extractable P and
microbial biomass C, an accumulation of soluble salts and a liming
effect. PCA analysis of soil bacterial community structure, using
PCR-DGGE of 16S rDNA fragments, generally separated individual
sites from one another but did not group them according to irrigation
history. Thus, whilst the size and activity of the soil microbial
community were increased, the structure and diversity of the
bacterial community remained unaffected.
Abstract: Since water resources of desert Naein City are very
limited, a approach which saves water resources and meanwhile
meets the needs of the greenspace for water is to use city-s sewage
wastewater. Proper treatment of Naein-s sewage up to the standards
required for green space uses may solve some of the problems of
green space development of the city. The present paper closely
examines available statistics and information associated with city-s
sewage system, and determines complementary stages of sewage
treatment facilities of the city. In the present paper, population, per
capita water use, and required discharge for various greenspace
pieces including different plants are calculated. Moreover, in order to
facilitate the application of water resources, a Crude water
distribution network apart from drinking water distribution network is
designed, and a plan for mixing municipal wells- water with sewage
wastewater in proposed mixing tanks is suggested. Hence, following
greenspace irrigation reform and complementary plan, per capita
greenspace of the city will be increased from current amount of 13.2
square meters to 32 square meters.
Abstract: 17α-ethinylestradiol (EE2) is a recalcitrant micropollutant which is found in small amounts in municipal wastewater. But these small amounts still adversely affect for the reproductive function of aquatic organisms. Evidence in the past suggested that full-scale WWTPs equipped with nitrification process enhanced the removal of EE2 in the municipal wastewater. EE2 has been proven to be able to be transformed by ammonia oxidizing bacteria (AOB) via co-metabolism. This research aims to clarify the EE2 degradation pattern by different consortium of ammonia oxidizing microorganism (AOM) including AOA (ammonia oxidizing archaea) and investigate contribution between the existing ammonia monooxygenase (AMO) and new synthesized AOM. The result showed that AOA or AOB of N. oligotropha cluster in enriched nitrifying activated sludge (NAS) from 2mM and 5mM, commonly found in municipal WWTPs, could degrade EE2 in wastewater via co-metabolism. Moreover, the investigation of the contribution between the existing ammonia monooxygenase (AMO) and new synthesized AOM demonstrated that the new synthesized AMO enzyme may perform ammonia oxidation rather than the existing AMO enzyme or the existing AMO enzyme may has a small amount to oxidize ammonia.
Abstract: In this research, an anaerobic co-digestion using decanter cake from palm oil mill industry to improve the biogas production from frozen seafood wastewater is studied using Continuously Stirred Tank Reactor (CSTR) process. The experiments were conducted in laboratory-scale. The suitable Hydraulic Retention Time (HRT) was observed in CSTR experiments with 24 hours of mixing time using the mechanical mixer. The HRT of CSTR process impacts on the efficiency of biogas production. The best performance for biogas production using CSTR process was the anaerobic codigestion for 20 days of HRT with the maximum methane production rate of 1.86 l/d and the average maximum methane production of 64.6%. The result can be concluded that the decanter cake can improve biogas productivity of frozen seafood wastewater.
Abstract: The purpose of this work was to study the effect of the
irrigation using waste water with various electric conductivities (T(0,92ds/m), EC3 (3ds/m) and EC6 (6ds/m) on three varieties of
quinoa cultivated in a field south of Morocco. The follow up of the evolution of the chemical and agronomic parameters throughout the
culture made it possible to determine the responses to the saline stress in arid conditions. Results showed that the salinity caused the
depression of plant-s height, and reduced the fresh and dry weight in
the different parts of the three varieties plants. The increase of the irrigation water EC didn-t affect the yield for the varieties. Thus,
quinoa resisted to salinity and proved a behavior of a facultative halophyte crop. In fact, the cultivation of this using treated wastewater is feasible especially in arid areas for a sustainable use of
water resources.
Abstract: In this study, aerobic digestion of tannery industry
wastewater was carried out using mixed culture obtained from
common effluent treatment plant treating tannery wastewater. The
effect of pH, temperature, inoculum concentration, agitation speed
and initial substrate concentration on the reduction of organic matters
were found. The optimum conditions for COD reduction was found
to be pH - 7 (60%), temperature - 30ÔùªC (61%), inoculum
concentration - 2% (61%), agitation speed - 150rpm (65%) and initial
substrate concentration - 1560 mg COD/L (74%). Kinetics studies
were carried by using Monod model, First order, Diffusional model
and Singh model. From the results it was found that the Monod
model suits well for the degradation of tannery wastewater using
mixed microbial consortium.
Abstract: Different agricultural waste peels were assessed for
their suitability to be used as primary substrates for the
bioremediation of free cyanide (CN-) by a cyanide-degrading fungus
Aspergillus awamori isolated from cyanide containing wastewater.
The bioremediated CN- concentration were in the range of 36 to 110
mg CN-/L, with Orange (C. sinensis) > Carrot (D. carota) > Onion
(A. cepa) > Apple (M. pumila), being chosen as suitable substrates
for large scale CN- degradation processes due to: 1) the high
concentration of bioremediated CN-, 2) total reduced sugars released
into solution to sustain the biocatalyst, and 3) minimal residual NH4-
N concentration after fermentation. The bioremediation rate constants
(k) were 0.017h-1 (0h < t < 24h), with improved bioremediation rates
(0.02189h-1) observed after 24h. The averaged nitrilase activity was
~10 U/L.
Abstract: Anaerobic treatment has many advantages over other
biological method particularly when used to treat complex
wastewater such as petroleum refinery wastewater. In this study two
Up-flow Anaerobic Sludge Blanket (UASB) reactors were operated
in parallel to treat six volumetric organic loads (0.58, 1.21, 0.89,
2.34, 1.47 and 4.14 kg COD/m3·d) to evaluate the chemical oxygen
demand (COD) removal efficiency. The reactors were continuously
adapting to the changing of operation condition with increase in the
removal efficiency or slight decrease until the last load which was
more than two times the load, at which the reactor stressed and the
removal efficiency decreased to 75% with effluent concentration of
1746 mg COD/L. Other parameters were also monitored such as pH,
alkalinity, volatile fatty acid and gas production rate. The UASB
reactor was suitable to treat petroleum refinery wastewater and the
highest COD removal rate was 83% at 1215 kg/m3·d with COD
concentration about 356 mg/L in the effluent.
Abstract: “Garbage enzyme", a fermentation product of kitchen waste, water and brown sugar, is claimed in the media as a multipurpose solution for household and agricultural uses. This study assesses the effects of dilutions (5% to 75%) of garbage enzyme in reducing pollutants in domestic wastewater. The pH of the garbage enzyme was found to be 3.5, BOD concentration about 150 mg/L. Test results showed that the garbage enzyme raised the wastewater-s BOD in proportion to its dilution due to its high organic content. For mixtures with more than 10% garbage enzyme, its pH remained acidic after the 5-day digestion period. However, it seems that ammonia nitrogen and phosphorus could be removed by the addition of the garbage enzyme. The most economic solution for removal of ammonia nitrogen and phosphorus was found to be 9%. Further tests are required to understand the removal mechanisms of the ammonia nitrogen and phosphorus.
Abstract: In this paper, a Biochemical Methane Potential (BMP)
test provides a measure of the energy production potential from codigestion
between the frozen seafood wastewater and the decanter
cake. The experiments were conducted in laboratory-scale. The
suitable ratio of the frozen seafood wastewater and the decanter cake
was observed in the BMP test. The ratio of the co-digestion between
the frozen seafood wastewater and the decanter cake has impacts on
the biogas production and energy production potential. The best
performance for energy production potential using BMP test
observed from the 180 ml of the frozen seafood wastewater and 10 g
of the decanter cake ratio. This ratio provided the maximum methane
production at 0.351 l CH4/g TCODremoval. The removal efficiencies
are 76.18%, 83.55%, 43.16% and 56.76% at TCOD, SCOD, TS and
VS, respectively. The result can be concluded that the decanter cake
can improve the energy production potential of the frozen seafood
wastewater. The energy provides from co-digestion between frozen
seafood wastewater and decanter cake approximately 19x109
MJ/year in Thailand.
Abstract: Biochemical Oxygen Demand (BOD) is a measure of
the oxygen used in bacteria mediated oxidation of organic substances
in water and wastewater. Theoretically an infinite time is required for
complete biochemical oxidation of organic matter, but the
measurement is made over 5-days at 20 0C or 3-days at 27 0C test
period with or without dilution. Researchers have worked to further
reduce the time of measurement.
The objective of this paper is to review advancement made in
BOD measurement primarily to minimize the time and negate the
measurement difficulties. Survey of literature review in four such
techniques namely BOD-BARTTM, Biosensors, Ferricyanidemediated
approach, luminous bacterial immobilized chip method.
Basic principle, method of determination, data validation and their
advantage and disadvantages have been incorporated of each of the
methods.
In the BOD-BARTTM method the time lag is calculated for the
system to change from oxidative to reductive state. BIOSENSORS
are the biological sensing element with a transducer which produces
a signal proportional to the analyte concentration. Microbial species
has its metabolic deficiencies. Co-immobilization of bacteria using
sol-gel biosensor increases the range of substrate. In ferricyanidemediated
approach, ferricyanide has been used as e-acceptor instead
of oxygen. In Luminous bacterial cells-immobilized chip method,
bacterial bioluminescence which is caused by lux genes was
observed. Physiological responses is measured and correlated to
BOD due to reduction or emission.
There is a scope to further probe into the rapid estimation of BOD.
Abstract: Zeolite A and MCM-41 have extensive applications in basic science, petrochemical science, energy conservation/storage, medicine, chemical sensor, air purification, environmentally benign composite structure and waste remediation. However, the use of zeolite A and MCM-41 in these areas, especially environmental remediation, are restricted due to prohibitive production cost. Efficient recycling of and resource recovery from coal fly ash has been a major topic of current international research interest, aimed at achieving sustainable development of human society from the viewpoints of energy, economy, and environmental strategy. This project reported an original, novel, green and fast methods to produce nano-porous zeolite A and MCM-41 materials from coal fly ash. For zeolite A, this novel production method allows a reduction by half of the total production time while maintaining a high degree of crystallinity of zeolite A which exists in a narrower particle size distribution. For MCM-41, this remarkably green approach, being an environmentally friendly process and reducing generation of toxic waste, can produce pure and long-range ordered MCM-41 materials from coal fly ash. This approach took 24 h at 25 oC to produce 9 g of MCM-41 materials from 30 g of the coal fly ash, which is the shortest time and lowest reaction temperature required to produce pure and ordered MCM-41 materials (having the largest internal surface area) compared to the values reported in the literature. Performance evaluation of the produced zeolite A and MCM-41 materials in wastewater treatment and air pollution control were reported. The residual fly ash was also converted to zeolite Na-P1 which showed good performance in removal of multi-metal ions in wastewater. In wastewater treatment, compared to commercial-grade zeolite A, adsorbents produced from coal fly ash were effective in removing multi heavy metal ions in water and could be an alternative material for treatment of wastewater. In methane emission abatement, the zeolite A (produced from coal fly ash) achieved similar methane removal efficiency compared to the zeolite A prepared from pure chemicals. This report provides the guidance for production of zeolite A and MCM-41 from coal fly ash by a cost-effective approach which opens potential applications of these materials in environmental industry. Finally, environmental and economic aspects of production of zeolite A and MCM-41 from coal fly ash were discussed.
Abstract: A sequential treatment of ozonation followed by a
Fenton or photo-Fenton process, using black light lamps (365 nm) in
this latter case, has been applied to remove a mixture of
pharmaceutical compounds and the generated by-products both in
ultrapure and secondary treated wastewater. The scientifictechnological
innovation of this study stems from the in situ
generation of hydrogen peroxide from the direct ozonation of
pharmaceuticals, and can later be used in the application of Fenton
and photo-Fenton processes. The compounds selected as models
were sulfamethoxazol and acetaminophen. It should be remarked that
the use of a second process is necessary as a result of the low
mineralization yield reached by the exclusive application of ozone.
Therefore, the influence of the water matrix has been studied in terms
of hydrogen peroxide concentration, individual compound
concentration and total organic carbon removed. Moreover, the
concentration of different iron species in solution has been measured.
Abstract: The concentrations of As, Hg, Co, Cr and Cd were
tested for each soil sample, and their spatial patterns were analyzed
by the semivariogram approach of geostatistics and geographical
information system technology. Multivariate statistic approaches
(principal component analysis and cluster analysis) were used to
identify heavy metal sources and their spatial pattern. Principal
component analysis coupled with correlation between heavy metals
showed that primary inputs of As, Hg and Cd were due to
anthropogenic while, Co, and Cr were associated with pedogenic
factors. Ordinary kriging was carried out to map the spatial patters of
heavy metals. The high pollution sources evaluated was related with
usage of urban and industrial wastewater. The results of this study
helpful for risk assessment of environmental pollution for decision
making for industrial adjustment and remedy soil pollution.
Abstract: A novel sponge submerged membrane bioreactor
(SSMBR) was developed to effectively remove organics and
nutrients from wastewater. Sponge is introduced within the SSMBR
as a medium for the attached growth of biomass. This paper evaluates
the effects of new and acclimatized sponges for dissolved organic
carbon (DOC) removal from wastewater at different mixed liquor
suspended solids- (MLSS) concentration of the sludge. It was
observed in a series of experimental studies that the acclimatized
sponge performed better than the new sponge whilst the optimum
DOC removal could be achieved at 10g/L of MLSS with the
acclimatized sponge. Moreover, the paper analyses the relationships
between the MLSSsponge/MLSSsludge and the DOC removal efficiency
of SSMBR. The results showed a non-linear relationship between the
biomass parameters of the sponge and the sludge, and the DOC
removal efficiency of SSMBR. A second-order polynomial function
could reasonably represent these relationships.
Abstract: The objective of this study is to evaluate the
occurrence of fungi in aerobic and anoxic activated sludge from
membrane bioreactors (MBRs). Thirty-six samples of both aerobic
and anoxic activated sludge were taken from 2 MBR treating
domestic wastewater. Over a period of eight months 2 samples from
each plant were taken per month. The samples were prepared for
count and definition of fungi. The obtained data show that, sixty
species belonging to 27 genera were collected from activated sludge
samples under aerobic and anoxic conditions. Regarding to the fungi
definition, under aerobic condition the Geotrichum was found at
(8.8%) followed by Penicillium (75.0%), Yeasts (65.7%) and
Trichoderma (55.5%), while Yeasts (77.1%) Geotrichum
candidumand Penicillium (61.1%) species were the most prevalent in
anoxic activated sludge. The results indicate that activated sludge is
habitat for growth and sporulation of different groups of fungi, both
saprophytic and pathogenic.
Abstract: 17α-ethynylestradiol (EE2) is a synthetic estrogen
used as a key ingredient in an oral contraceptives pill. EE2 is an
endocrine disrupting compound, high in estrogenic potency.
Although EE2 exhibits low degree of biodegradability with common
microorganisms in wastewater treatment plants (WWTPs), this
compound can be biotransformed by ammonia-oxidizing bacteria
(AOB) via a co-metabolism mechanism in WWTPs. This study
aimed to investigate the effect of real wastewater on
biotransformation of EE2 by AOB. A preliminary experiment on the
effect of nitrite and pH levels on abiotic transformation of EE2
suggested that the abiotic transformation occurred at only pH
Abstract: A portable sensor for the analysis of phosphate in
aqueous samples has been developed. The sensor incorporates
microfluidic technology, colorimetric detection, and wireless
communications into a compact and rugged portable device. The
detection method used is the molybdenum yellow method, in which a
phosphate-containing sample is mixed with a reagent containing
ammonium metavanadate and ammonium molybdate in an acidic
medium. A yellow-coloured compound is generated and the
absorption of this compound is measured using a light emitting diode
(LED) light source and a photodiode detector. The absorption is
directly proportional to the phosphate concentration in the original
sample. In this paper we describe the application of this phosphate
sensor to the analysis of wastewater at a municipal wastewater
treatment plant in Co. Kildare, Ireland.
Abstract: In this study, the designed dual stage membrane
bioreactor (MBR) system was conceptualized for the treatment of
cyanide and heavy metals in electroplating wastewater. The design
consisted of a primary treatment stage to reduce the impact of
fluctuations and the secondary treatment stage to remove the residual
cyanide and heavy metal contaminants in the wastewater under
alkaline pH conditions. The primary treatment stage contained
hydrolyzed Citrus sinensis (C. sinensis) pomace and the secondary
treatment stage contained active Aspergillus awamori (A. awamori)
biomass, supplemented solely with C. sinensis pomace extract from
the hydrolysis process. An average of 76.37%, 95.37%, 93.26 and
94.76% and 99.55%, 99.91%, 99.92% and 99.92% degradation
efficiency for total cyanide (T-CN), including the sorption of nickel
(Ni), zinc (Zn) and copper (Cu) were observed after the first and
second treatment stages, respectively. Furthermore, cyanide
conversion by-products degradation was 99.81% and 99.75 for both
formate (CHOO-) and ammonium (NH4
+) after the second treatment
stage. After the first, second and third regeneration cycles of the C.
sinensis pomace in the first treatment stage, Ni, Zn and Cu removal
achieved was 99.13%, 99.12% and 99.04% (first regeneration cycle),
98.94%, 98.92% and 98.41% (second regeneration cycle) and 98.46
%, 98.44% and 97.91% (third regeneration cycle), respectively.
There was relatively insignificant standard deviation detected in all
the measured parameters in the system which indicated
reproducibility of the remediation efficiency in this continuous
system.
Abstract: Biological Ammonia removal (nitrification), the
oxidation of ammonia to nitrate catalyzed by bacteria, is a key part of
global nitrogen cycling. In the first step of nitrification,
chemolithoautotrophic ammonia oxidizer transform ammonia to
nitrite, this subsequently oxidized to nitrate by nitrite oxidizing
bacteria. This process can be affected by several factors. In this study
the effect of influent COD on biological ammonia removal in a
bench-scale biological reactor was investigated. Experiments were
carried out using synthetic wastewater. The initial ammonium
concentration was 25mgNH4
+-N L-1. The effect of COD between
247.55±1.8 and 601.08±3.24mgL-1 on biological ammonia removal
was investigated by varying the COD loading supplied to reactor.
From the results obtained in this study it could be concluded in the
range of 247.55±1.8 to 351.35±2.05mgL-1, there is a direct
relationship between amount of COD and ammonia removal.
However more than 351.35±2.05 up to 601.08±3.24mgL-1 were
found an indirect relationship between them.