Abstract: Spent petroleum catalyst from Korean petrochemical
industry contains trace amount of metals such as Ni, V and Mo.
Therefore an attempt was made to recover those trace metal using
bioleaching process. Different leaching parameters such as Fe(II)
concentration, pulp density, pH, temperature and particle size of
spent catalyst particle were studied to evaluate their effects on the
leaching efficiency. All the three metal ions like Ni, V and Mo
followed dual kinetics, i.e., initial faster followed by slower rate. The
percentage of leaching efficiency of Ni and V were higher than Mo.
The leaching process followed a diffusion controlled model and the
product layer was observed to be impervious due to formation of
ammonium jarosite (NH4)Fe3(SO4)2(OH)6. In addition, the lower
leaching efficiency of Mo was observed due to a hydrophobic coating
of elemental sulfur over Mo matrix in the spent catalyst.
Abstract: The square-lattice Ising model is the simplest system
showing phase transitions (the transition between the paramagnetic
phase and the ferromagnetic phase and the transition between the
paramagnetic phase and the antiferromagnetic phase) and critical
phenomena at finite temperatures. The exact solution of the squarelattice
Ising model with free boundary conditions is not known for
systems of arbitrary size. For the first time, the exact solution of
the Ising model on the square lattice with free boundary
conditions is obtained after classifying all )
spin configurations with the microcanonical transfer matrix. Also, the
phase transitions and critical phenomena of the square-lattice Ising
model are discussed using the exact solution on the square
lattice with free boundary conditions.
Abstract: The aim of the study was to identify seat belt wearing
factor among road users in Malaysia. Evidence-based approach
through in-depth crash investigation was utilised to determine the
intended objectives. The objective was scoped into crashes
investigated by Malaysian Institute of Road Safety Research
(MIROS) involving passenger vehicles within 2007 and 2010. Crash
information of a total of 99 crash cases involving 240 vehicles and
864 occupants were obtained during the study period. Statistical test
and logistic regression analysis have been performed. Results of the
analysis revealed that gender, seat position and age were associated
with seat belt wearing compliance in Malaysia. Males are 97.6%
more likely to wear seat belt compared to females (95% CI 1.317 to
2.964). By seat position, the finding indicates that frontal occupants
were 82 times more likely to be wearing seat belt (95% CI 30.199 to
225.342) as compared to rear occupants. It is also important to note
that the odds of seat belt wearing increased by about 2.64% (95% CI
1.0176 to 1.0353) for every one year increase in age. This study is
essential in understanding the Malaysian tendency in belting up
while being occupied in a vehicle. The factors highlighted in this
study should be emphasized in road safety education in order to
increase seat belt wearing rate in this country and ultimately in
preventing deaths due to road crashes.
Abstract: Clustering large populations is an important problem
when the data contain noise and different shapes. A good clustering
algorithm or approach should be efficient enough to detect clusters
sensitively. Besides space complexity, time complexity also gains
importance as the size grows. Using hierarchies we developed a new
algorithm to split attributes according to the values they have and
choosing the dimension for splitting so as to divide the database
roughly into equal parts as much as possible. At each node we
calculate some certain descriptive statistical features of the data
which reside and by pruning we generate the natural clusters with a
complexity of O(n).
Abstract: A new algorithm called Character-Comparison to Character-Access (CCCA) is developed to test the effect of both: 1) converting character-comparison and number-comparison into character-access and 2) the starting point of checking on the performance of the checking operation in string searching. An experiment is performed using both English text and DNA text with different sizes. The results are compared with five algorithms, namely, Naive, BM, Inf_Suf_Pref, Raita, and Cycle. With the CCCA algorithm, the results suggest that the evaluation criteria of the average number of total comparisons are improved up to 35%. Furthermore, the results suggest that the clock time required by the other algorithms is improved in range from 22.13% to 42.33% by the new CCCA algorithm.
Abstract: Fixed-bed slow pyrolysis experiments of rice husk
have been conducted to determine the effect of pyrolysis
temperature, heating rate, particle size and reactor length on the
pyrolysis product yields. Pyrolysis experiments were performed at
pyrolysis temperature between 400 and 600°C with a constant
heating rate of 60°C/min and particle sizes of 0.60-1.18 mm. The
optimum process conditions for maximum liquid yield from the rice
husk pyrolysis in a fixed bed reactor were also identified. The highest
liquid yield was obtained at a pyrolysis temperature of 500°C,
particle size of
1.18-1.80 mm, with a heating rate of 60°C/min in a 300 mm length
reactor. The obtained yield of, liquid, gas and solid were found be in
the range of 22.57-31.78 %, 27.75-42.26 % and 34.17-42.52 % (all
weight basics) respectively at different pyrolysis conditions. The
results indicate that the effects of pyrolysis temperature and particle
size on the pyrolysis yield are more significant than that of heating
rate and reactor length. The functional groups and chemical
compositions present in the liquid obtained at optimum conditions
were identified by Fourier Transform-Infrared (FT-IR) spectroscopy
and Gas Chromatography/ Mass Spectroscopy (GC/MS) analysis
respectively.
Abstract: A specially designed flat plate was mounted vertically
over the axial line in the wind tunnel of the Aerospace Department of
the Pusan National University. The plate is 2 m long, 0.8 m high and 8
cm thick. The measurements were performed in velocity range from
15 to 60 m/s. A sand paper turbulizer was placed close to the plate nose
to provide fully developed turbulent boundary layer over the most part
of the plate. Strain balances were mounted in the trailing part of the
plate to measure the skin friction drag over removable insertions of
0.55×0.25m2 size. A set of the insertions was designed and
manufactured: 3mm thick polished metal surface and three compliant
surfaces. The compliant surfaces were manufactured of a silicone
rubber Silastic® S2 (Dow Corning company). To modify the
viscoelastic properties of the rubber, its composition was varied: 90%
of the rubber + 10% catalyst (standard), 92.5% + 7.5% (weak), 85% +
15% (strong). Modulus of elasticity and the loss tangent were
measured accurately for these materials in the frequency range from
40 Hz to 3 KHz using the unique proposed technique.
Abstract: Determination of nano particle size is substantial since
the nano particle size exerts a significant effect on various properties
of nano materials. Accordingly, proposing non-destructive, accurate
and rapid techniques for this aim is of high interest. There are some
conventional techniques to investigate the morphology and grain size
of nano particles such as scanning electron microscopy (SEM),
atomic force microscopy (AFM) and X-ray diffractometry (XRD).
Vibrational spectroscopy is utilized to characterize different
compounds and applied for evaluation of the average particle size
based on relationship between particle size and near infrared spectra
[1,4] , but it has never been applied in quantitative morphological
analysis of nano materials. So far, the potential application of nearinfrared
(NIR) spectroscopy with its ability in rapid analysis of
powdered materials with minimal sample preparation, has been
suggested for particle size determination of powdered
pharmaceuticals. The relationship between particle size and diffuse
reflectance (DR) spectra in near infrared region has been applied to
introduce a method for estimation of particle size. Back propagation
artificial neural network (BP-ANN) as a nonlinear model was applied
to estimate average particle size based on near infrared diffuse
reflectance spectra. Thirty five different nano TiO2 samples with
different particle size were analyzed by DR-FTNIR spectrometry and
the obtained data were processed by BP- ANN.
Abstract: The Japanese integrative approach to social systems
can be observed in supply chain management as well as in the
relationship between public and private sectors. Both the Lean
Production System and the Developmental State Model are
characterized by efforts towards the achievement of mutual goals,
resulting in initiatives for capacity building which emphasize the
system level. In Brazil, although organizations undertake efforts to
build capabilities at the individual and organizational levels, the
system level is being neglected. Fieldwork data confirmed the findings
of other studies in terms of the lack of integration in supply chain
management in the Brazilian automobile industry. Moreover, due to
the absence of an active role of the Brazilian state in its relationship
with the private sector, automakers are not fully exploiting the
opportunities in the domestic and regional markets. For promoting a
higher level of economic growth as well as to increase the degree of
spill-over of technologies and techniques, a more integrative approach
is needed.
Abstract: How to effectively allocate system resource to process
the Client request by Gateway servers is a challenging problem. In
this paper, we propose an improved scheme for autonomous
performance of Gateway servers under highly dynamic traffic loads.
We devise a methodology to calculate Queue Length and Waiting
Time utilizing Gateway Server information to reduce response time
variance in presence of bursty traffic. The most widespread
contemplation is performance, because Gateway Servers must offer
cost-effective and high-availability services in the elongated period,
thus they have to be scaled to meet the expected load. Performance
measurements can be the base for performance modeling and
prediction. With the help of performance models, the performance
metrics (like buffer estimation, waiting time) can be determined at
the development process. This paper describes the possible queue
models those can be applied in the estimation of queue length to
estimate the final value of the memory size. Both simulation and
experimental studies using synthesized workloads and analysis of
real-world Gateway Servers demonstrate the effectiveness of the
proposed system.
Abstract: In Supply Chain Management (SCM), strengthening partnerships with suppliers is a significant factor for enhancing competitiveness. Hence, firms increasingly emphasize supplier evaluation processes. Supplier evaluation systems are basically developed in terms of criteria such as quality, cost, delivery, and flexibility. Because there are many variables to be analyzed, this process becomes hard to execute and needs expertise. On this account, this study aims to develop an expert system on supplier evaluation process by designing Artificial Neural Network (ANN) that is supported with Data Envelopment Analysis (DEA). The methods are applied on the data of 24 suppliers, which have longterm relationships with a medium sized company from German Iron and Steel Industry. The data of suppliers consists of variables such as material quality (MQ), discount of amount (DOA), discount of cash (DOC), payment term (PT), delivery time (DT) and annual revenue (AR). Meanwhile, the efficiency that is generated by using DEA is added to the supplier evaluation system in order to use them as system outputs.
Abstract: This research investigates the effects of the opening
shape and location on the structural behavior of reinforced concrete
deep beam with openings, while keeping the opening size unchanged.
The software ANSYS 12.1 is used to handle the nonlinear finite
element analysis. The ultimate strength of reinforced concrete deep
beam with opening obtained by ANSYS 12.1 shows fair agreement
with the experimental results, with a difference of no more than 20%. The present work concludes that the opening location has much more effect on the structural strength than the opening shape. It was
concluded that placing the openings near the upper corners of the
deep beam may double the strength, and the use of a rectangular
narrow opening, with the long sides in the horizontal direction, can save up to 40% of structural strength of the deep beam.
Abstract: Coarse and fine particulate matter were collected at a
residential area at Vashi, Navi Mumbai and the filter samples were
analysed for trace elements using PIXE technique. The trend of
particulate matter showed higher concentrations during winter than
the summer and monsoon concentration levels. High concentrations
of elements related to soil and sea salt were found in PM10 and
PM2.5. Also high levels of zinc and sulphur found in the particulates
of both the size fractions. EF analysis showed enrichment of Cu, Cr
and Mn only in the fine fraction suggesting their origin from
anthropogenic sources. The EF value was observed to be maximum
for As, Pb and Zn in the fine particulates. However, crustal derived
elements showed very low EF values indicating their origin from
soil. The PCA based multivariate studies identified soil, sea salt,
combustion and Se sources as common sources for coarse and
additionally an industrial source has also been identified for fine
particles.
Abstract: Most electrical distribution systems are incurring large
losses as the loads are wide spread, inadequate reactive power
compensation facilities and their improper control. A typical static
VAR compensator consists of capacitor bank in binary sequential
steps operated in conjunction with a thyristor controlled reactor of the
smallest step size. This SVC facilitates stepless control of reactive
power closely matching with load requirements so as to maintain
power factor nearer to unity. This type of SVC-s requiring a
appropriately controlled TCR. This paper deals with an air cored
reactor suitable for distribution transformer of 3phase, 50Hz, Dy11,
11KV/433V, 125 KVA capacity. Air cored reactors are designed,
built, tested and operated in conjunction with capacitor bank in five
binary sequential steps. It is established how the delta connected TCR
minimizes the harmonic components and the operating range for
various electrical quantities as a function of firing angle is
investigated. In particular firing angle v/s line & phase currents, D.C.
components, THD-s, active and reactive powers, odd and even triplen
harmonics, dominant characteristic harmonics are all investigated and
range of firing angle is fixed for satisfactory operation. The harmonic
spectra for phase and line quantities at specified firing angles are
given. In case the TCR is operated within the bound specified in this
paper established through simulation studies are yielding the best
possible operating condition particularly free from all dominant
harmonics.
Abstract: Deoxygenation of beef fat for the production of hydrogenated biodiesel is investigated in a high pressure continuous flow fixed bed reactor over palladium-supported mesoporous titania catalyst synthesized via a combined single-step sol-gel process with surfactant-assisted templating method (SATM). The catalyst possessed a mesoporous charactheristic with high surface area and narrow pore size distribution. The main products of all Pd/TiO2 catalysts are n-heptadecane (n-C17) and n-pentadecane (n-C15) resulting from decarbonylation reaction. Pd/TiO2 catalyst synthesized via a combined single-step sol-gel process with SATM (SSSG) gave higher activity and selectivity to the desired products when compared to IWI/SG-TiO2 and IWI/P25-TiO2, respectively. SSSG catalyst gave the average conversion up to 80-90 % and 80 % for the selectivity in diesel range hydrocarbons. This result may cause by the higher surface area and the ability in dispersion of palladium ion in mesoporous of TiO2 during sol-gel process.
Abstract: This paper presents a heuristic to solve large size 0-1 Multi constrained Knapsack problem (01MKP) which is NP-hard. Many researchers are used heuristic operator to identify the redundant constraints of Linear Programming Problem before applying the regular procedure to solve it. We use the intercept matrix to identify the zero valued variables of 01MKP which is known as redundant variables. In this heuristic, first the dominance property of the intercept matrix of constraints is exploited to reduce the search space to find the optimal or near optimal solutions of 01MKP, second, we improve the solution by using the pseudo-utility ratio based on surrogate constraint of 01MKP. This heuristic is tested for benchmark problems of sizes upto 2500, taken from literature and the results are compared with optimum solutions. Space and computational complexity of solving 01MKP using this approach are also presented. The encouraging results especially for relatively large size test problems indicate that this heuristic can successfully be used for finding good solutions for highly constrained NP-hard problems.
Abstract: In this paper, we consider the effect of the initial
sample size on the performance of a sequential approach that used
in selecting a good enough simulated system, when the number
of alternatives is very large. We implement a sequential approach
on M=M=1 queuing system under some parameter settings, with a
different choice of the initial sample sizes to explore the impacts on
the performance of this approach. The results show that the choice
of the initial sample size does affect the performance of our selection
approach.
Abstract: A manufacturing inventory model with shortages with
carrying cost, shortage cost, setup cost and demand quantity as
imprecise numbers, instead of real numbers, namely interval number
is considered here. First, a brief survey of the existing works on
comparing and ranking any two interval numbers on the real line
is presented. A common algorithm for the optimum production
quantity (Economic lot-size) per cycle of a single product (so as
to minimize the total average cost) is developed which works well
on interval number optimization under consideration. Finally, the
designed algorithm is illustrated with numerical example.
Abstract: The mechanical quadrature methods for solving the boundary integral equations of the anisotropic Darcy-s equations with Dirichlet conditions in smooth domains are presented. By applying the collectively compact theory, we prove the convergence and stability of approximate solutions. The asymptotic expansions for the error show that the methods converge with the order O (h3), where h is the mesh size. Based on these analysis, extrapolation methods can be introduced to achieve a higher convergence rate O (h5). An a posterior asymptotic error representation is derived in order to construct self-adaptive algorithms. Finally, the numerical experiments show the efficiency of our methods.
Abstract: Bones are dynamic and responsive organs, they
regulate their strength and mass according to the loads which they are subjected. Because, the Wnt/β-catenin pathway has profound
effects on the regulation of bone mass, we hypothesized that mechanical loading of bone cells stimulates Wnt/β-catenin signaling, which results in the generation of new bone mass.
Mechanical loading triggers the secretion of the Wnt molecule, which after binding to transmembrane proteins, causes GSK-3β (Glycogen synthase kinase 3 beta) to cease the phosphorylation of β-catenin. β-catenin accumulation in the cytoplasm, followed by its
transport into the nucleus, binding to transcription factors (TCF/LEF)
that initiate transcription of genes related to bone formation. To test this hypothesis, we used TOPGAL (Tcf Optimal Promoter
β-galactosidase) mice in an experiment in which cyclic loads were
applied to the forearm. TOPGAL mice are reporters for cells effected
by the Wnt/β-catenin signaling pathway. TOPGAL mice are genetically engineered mice in which transcriptional activation of β-
catenin, results in the production of an enzyme, β-galactosidase. The
presence of this enzyme allows us to localize transcriptional
activation of β-catenin to individual cells, thereby, allowing us to quantify the effects that mechanical loading has on the Wnt/β-catenin pathway and new bone formation. The ulnae of loaded TOPGAL
mice were excised and transverse slices along different parts of the
ulnar shaft were assayed for the presence of β-galactosidase.
Our results indicate that loading increases β-catenin transcriptional
activity in regions where this pathway is already primed (i.e. where basal activity is already higher) in a load magnitude dependent
manner. Further experiments are needed to determine the temporal and spatial activation of this signaling in relation to bone formation.