Abstract: In this study, production possibilities of hydrogen and/or methane via SCWG from black grape residues have been investigated. For this aim, grape residues which remain as a byproduct of the wine making process have been used. Since utilization from grape residues is limited due to the high moisture content, supercritical water gasification is the most convenient method. The effect of the gasification temperature and type of catalyst on supercritical water gasification have been investigated. Gasification experiments were performed in a batch autoclave at four different temperatures 300, 400, 500 and 600°C. K2CO3 and Trona (NaHCO3.Na2CO3·2H2O) were used as catalyst. Real biomass types of black grape residues have been successfully gasified and the product gas (hydrogen, methane, carbon dioxide, carbon monoxide and a small amount of ethane and ethylene) were identified by using gas chromatography. A TOC analyzer was used to determine total organic carbon (TOC) content of aqueous phase. The amounts of carboxylic acids, aldehydes, ketones, furfurals and phenols present in the aqueous solutions were analyzed by high performance liquid chromatography. When the temperature increased from 300°C to 600°C, mol% of H2 in gas products increased. The presence of catalysts improves the hydrogen yield. Trona showed gasification activity to be similar to that of K2CO3. It may be concluded that the use of Trona instead of commercially produced catalysts, can be preferably used in the gasification of biomass in supercritical water.
Abstract: The crystallization kinetics and phase transformation
of SiO2.Al2O3.0,56P2O5.1,8CaO.0,56CaF2 glass have been
investigated using differential thermal analysis (DTA), x-ray
diffraction (XRD), and scanning electron microscopy (SEM). Glass
samples were obtained by melting the glass mixture at 14500С/120
min. in platinum crucibles. The mixture were prepared from
chemically pure reagents: SiO2, Al(OH)3, H3PO4, CaCO3 and CaF2.
The non-isothermal kinetics of crystallization was studied by
applying the DTA measurements carried out at various heating rates.
The activation energies of crystallization and viscous flow were
measured as 348,4 kJ.mol–1 and 479,7 kJ.mol–1 respectively. Value of
Avrami parameter n ≈ 3 correspond to a three dimensional of crystal
growth mechanism. The major crystalline phase determined by XRD
analysis was fluorapatite (Ca(PO4)3F) and as the minor phases –
fluormargarite (CaAl2(Al2SiO2)10F2) and vitlokite (Ca9P6O24). The
resulting glass-ceramic has a homogeneous microstructure, composed
of prismatic crystals, evenly distributed in glass phase.
Abstract: This paper presents a system for discovering
association rules from collections of unstructured documents called
EART (Extract Association Rules from Text). The EART system
treats texts only not images or figures. EART discovers association
rules amongst keywords labeling the collection of textual documents.
The main characteristic of EART is that the system integrates XML
technology (to transform unstructured documents into structured
documents) with Information Retrieval scheme (TF-IDF) and Data
Mining technique for association rules extraction. EART depends on
word feature to extract association rules. It consists of four phases:
structure phase, index phase, text mining phase and visualization
phase. Our work depends on the analysis of the keywords in the
extracted association rules through the co-occurrence of the keywords
in one sentence in the original text and the existing of the keywords
in one sentence without co-occurrence. Experiments applied on a
collection of scientific documents selected from MEDLINE that are
related to the outbreak of H5N1 avian influenza virus.
Abstract: Radio frequency identification (RFID) applications have grown rapidly in many industries, especially in indoor location identification. The advantage of using received signal strength indicator (RSSI) values as an indoor location measurement method is a cost-effective approach without installing extra hardware. Because the accuracy of many positioning schemes using RSSI values is limited by interference factors and the environment, thus it is challenging to use RFID location techniques based on integrating positioning algorithm design. This study proposes the location estimation approach and analyzes a scheme relying on RSSI values to minimize location errors. In addition, this paper examines different factors that affect location accuracy by integrating the backpropagation neural network (BPN) with the LANDMARC algorithm in a training phase and an online phase. First, the training phase computes coordinates obtained from the LANDMARC algorithm, which uses RSSI values and the real coordinates of reference tags as training data for constructing an appropriate BPN architecture and training length. Second, in the online phase, the LANDMARC algorithm calculates the coordinates of tracking tags, which are then used as BPN inputs to obtain location estimates. The results show that the proposed scheme can estimate locations more accurately compared to LANDMARC without extra devices.
Abstract: In this investigation, anatase TiO2 thin films were
grown by radio frequency magnetron sputtering on glass substrates at
a high sputtering pressure and room temperature. The anatase films
were then annealed at 300-600 °C in air for a period of 1 hour. To
examine the structure and morphology of the films, X-ray diffraction
(XRD) and atomic force microscopy (AFM) methods were used
respectively. From X-ray diffraction patterns of the TiO2 films, it was
found that the as-deposited film showed some differences compared
with the annealed films and the intensities of the peaks of the
crystalline phase increased with the increase of annealing
temperature. From AFM images, the distinct variations in the
morphology of the thin films were also observed. The optical
constants were characterized using the transmission spectra of the
films obtained by UV-VIS-IR spectrophotometer. Besides, optical
thickness of the film deposited at room temperature was calculated
and cross-checked by taking a cross-sectional image through SEM.
The optical band gaps were evaluated through Tauc model. It was
observed that TiO2 films produced at room temperatures exhibited
high visible transmittance and transmittance decreased slightly with
the increase of annealing temperatures. The films were found to be
crystalline having anatase phase. The refractive index of the films
was found from 2.31-2.35 in the visible range. The extinction
coefficient was nearly zero in the visible range and was found to
increase with annealing temperature. The allowed indirect optical
band gap of the films was estimated to be in the range from 3.39 to
3.42 eV which showed a small variation. The allowed direct band
gap was found to increase from 3.67 to 3.72 eV. The porosity was
also found to decrease at a higher annealing temperature making the
film compact and dense.
Abstract: This paper proposes a copyright protection scheme for color images using secret sharing and wavelet transform. The scheme contains two phases: the share image generation phase and the watermark retrieval phase. In the generation phase, the proposed scheme first converts the image into the YCbCr color space and creates a special sampling plane from the color space. Next, the scheme extracts the features from the sampling plane using the discrete wavelet transform. Then, the scheme employs the features and the watermark to generate a principal share image. In the retrieval phase, an expanded watermark is first reconstructed using the features of the suspect image and the principal share image. Next, the scheme reduces the additional noise to obtain the recovered watermark, which is then verified against the original watermark to examine the copyright. The experimental results show that the proposed scheme can resist several attacks such as JPEG compression, blurring, sharpening, noise addition, and cropping. The accuracy rates are all higher than 97%.
Abstract: Software Reliability is one of the key factors in the software development process. Software Reliability is estimated using reliability models based on Non Homogenous Poisson Process. In most of the literature the Software Reliability is predicted only in testing phase. So it leads to wrong decision-making concept. In this paper, two Software Reliability concepts, testing and operational phase are studied in detail. Using S-Shaped Software Reliability Growth Model (SRGM) and Exponential SRGM, the testing and operational reliability values are obtained. Finally two reliability values are compared and optimal release time is investigated.
Abstract: Considering toxicity of heavy metals and their
accumulation in domestic wastes, immobilization of lead and
cadmium is envisaged inside glass-ceramics. We particularly
focused this work on calcium-rich phases embedded in a
glassy matrix.
Glass-ceramics were synthesized from glasses doped with
12 wt% and 16 wt% of PbO or CdO. They were observed and
analyzed by Electron MicroProbe Analysis (EMPA) and
Analytical Scanning Electron Microscopy (ASEM). Structural
characterization of the samples was performed by powder XRay
Diffraction.
Diopside crystals of CaMgSi2O6 composition are shown to
incorporate significant amounts of cadmium (up to 9 wt% of
CdO). Two new crystalline phases are observed with very
high Cd or Pb contents: about 40 wt% CdO for the cadmiumrich
phase and near 60 wt% PbO for the lead-rich phase. We
present complete chemical and structural characterization of
these phases. They represent a promising way for the
immobilization of toxic elements like Cd or Pb since glass
ceramics are known to propose a “double barrier" protection
(metal-rich crystals embedded in a glass matrix) against metal
release in the environment.
Abstract: This paper presents a numerical analysis of the
seismic behaviour of earth dams. Analysis is conducted for the solid
phase. It may correspond to the response of the dam before water
filling. Analysis is conducted for a simple case which concerns the
elastic response of the dam. Numerical analyses are conducted using
the FLAC3D program. The behaviour of the Shell and core of the
dam and the foundation behaviour is assumed to be elastic. Result
shows the influence of the variation of the shear modulus of the core
and shell on the seismic amplification of the dam. It can be observed
that the variation of the shearing modulus of the core leads to a
moderate increase in the dynamic amplification and the increase in
the shell shearing modulus leads to a significant increase in the
dynamic amplification.
Abstract: This paper presents a recognition system for isolated
words like robot commands. It’s carried out by Time Delay Neural
Networks; TDNN. To teleoperate a robot for specific tasks as turn,
close, etc… In industrial environment and taking into account the
noise coming from the machine. The choice of TDNN is based on its
generalization in terms of accuracy, in more it acts as a filter that
allows the passage of certain desirable frequency characteristics of
speech; the goal is to determine the parameters of this filter for
making an adaptable system to the variability of speech signal and to
noise especially, for this the back propagation technique was used in
learning phase. The approach was applied on commands pronounced
in two languages separately: The French and Arabic. The results for
two test bases of 300 spoken words for each one are 87%, 97.6% in
neutral environment and 77.67%, 92.67% when the white Gaussian
noisy was added with a SNR of 35 dB.
Abstract: The current practice of determination of moisture diffusivity of building materials under laboratory conditions is predominantly aimed at the absorption phase. The main reason is the simplicity of the inverse analysis of measured moisture profiles. However, the liquid moisture transport may exhibit significant hysteresis. Thus, the moisture diffusivity should be different in the absorption (wetting) and desorption (drying) phase. In order to bring computer simulations of hygrothermal performance of building materials closer to the reality, it is then necessary to find new methods for inverse analysis which could be used in the desorption phase as well. In this paper we present genetic algorithm as a possible method of solution of the inverse problem of moisture transport in desorption phase. Its application is demonstrated for AAC as a typical building material.
Abstract: Composting is the process in which municipal solid
waste (MSW) and other organic waste materials such as biosolids
and manures are decomposed through the action of bacteria and other
microorganisms into a stable granular material which, applied to
land, as soil conditioner. Microorganisms, especially those that are
able to degrade polymeric organic material have a key role in speed
up this process. The aim of this study has been established to
isolation of microorganisms with high ability to production
extracellular enzymes for degradation of natural polymers that are
exists in MSW for decreasing time of degradation phase. Our
experimental study for isolation designed in two phases: in first
phase we isolated degrading microorganism with selected media that
consist a special natural polymer such as cellulose, starch, lipids and
etc as sole source of carbon. In second phase we selected
microorganism that had high degrading enzyme production with
enzymatic assay for seed production. However, our findings in pilot
scale have indicated that usage of this microbial consortium had high
efficiency for decreasing degradation phase.
Abstract: Two indica varieties, IR36 and ‘Suweon 258’ (“S”)
are middle-heading in southern Japan. 36U, also middle-heading, is
an isogenic line of IR36 carrying Ur1 (Undulate rachis-1) gene.
However, late-heading plants segregated in the F2 population from
the F1 of S × 36U, and so did in the following generations. The
concerning lateness gene is designated as Ex. From the F8 generation,
isogenic-line pair of early-heading and late-heading lines, denoted by
“E” (ex/ex) and “L” (Ex/Ex), were developed. Genetic analyses of
heading time were conducted, using F1s and F2s among L, E, S and
36U. The following inferences were drawn from the experimental
results: 1) L, and both of E and 36U harbor Ex and ex, respectively;
2) Besides Ex, S harbors an inhibitor gene to it, i.e. I-Ex which is a
novel finding of the present study. 3) Ex is a dominant allele at the
E1 locus.
Abstract: Urbanization and related anthropogenic modifications
cause extent of habitat fragmentation and directly lead to decline of
local biodiversity. Conservation biologists advocate corridor creation
as one approach to rescue biodiversity. Here we examine the utility of
roads as corridors in preserving plant diversity by investigating
roadside vegetation in Yellow River Delta (YRD), China. We
examined the spatio-temporal distribution pattern of plant species
richness, diversity and composition along roadside. The results
suggest that roads, as dispersal conduits, increase occurrence
probability of new settlers to a new area, meanwhile, roads accumulate
the greater propagule pressure and favourable survival condition
during operation phase. As a result, more species, including native and
alien plants, non- halophyte and halophyte species, threatened and
cosmopolitic species, were found prosperous at roadside. Roadside
may be a refuge for more species, and the pattern of vegetation
distribution is affected by road age and the distance from road verge.
Abstract: An interesting method to produce calcium carbonate is based in a gas-liquid reaction between carbon dioxide and aqueous solutions of calcium hydroxide. The design parameters for gas-liquid phase are flow regime, individual mass transfer, gas-liquid specific interfacial area. Most studies on gas-liquid phase were devoted to the experimental determination of some of these parameters, and more specifically, of the mass transfer coefficient, kLa which depends fundamentally on the superficial gas velocity and on the physical properties of absorption phase. The principle investigation was directed to study the effect of the vibration on the mass transfer coefficient kLa in gas-liquid phase during absorption of CO2 in the in aqueous solution of calcium hydroxide. The vibration with a higher frequency increase the mass transfer coefficient kLa, but vibration with lower frequency didn-t improve it, the mass transfer coefficient kLa increase with increase the superficial gas velocity.
Abstract: In this investigation Salicylic acid, Sulfosalicylic acid
and Acetyl salicylic acid were chosen as a sample for thin layer
chromatography (TLC) on silica gel plates. Bicarbonate buffer at
different pH containing different amounts of boric acid was applied
as mobile phase. Specific interaction of these substances with boric
acid has effect on Rf in thin layer chromatography. Regular and
similar trend was observed in variations of Rf for mentioned
compounds in TLC by altering of percentages of boric acid in mobile
phase in pH range of 8-10. Also effect of organic solvent, mixture of
water/ organic solvent and organic solvent containing boric acid as
mobile phase was studied.
Abstract: Freeways are originally designed to provide high
mobility to road users. However, the increase in population and
vehicle numbers has led to increasing congestions around the world.
Daily recurrent congestion substantially reduces the freeway capacity
when it is most needed. Building new highways and expanding the
existing ones is an expensive solution and impractical in many
situations. Intelligent and vision-based techniques can, however, be
efficient tools in monitoring highways and increasing the capacity of
the existing infrastructures. The crucial step for highway monitoring
is vehicle detection. In this paper, we propose one of such
techniques. The approach is based on artificial neural networks
(ANN) for vehicles detection and counting. The detection process
uses the freeway video images and starts by automatically extracting
the image background from the successive video frames. Once the
background is identified, subsequent frames are used to detect
moving objects through image subtraction. The result is segmented
using Sobel operator for edge detection. The ANN is, then, used in
the detection and counting phase. Applying this technique to the
busiest freeway in Riyadh (King Fahd Road) achieved higher than
98% detection accuracy despite the light intensity changes, the
occlusion situations, and shadows.
Abstract: Arc welding creates a weld pool to realize continuity between pieces of assembly. The thermal history of the weld is dependent on heat transfer and fluid flow in the weld pool. The metallurgical transformation during welding and cooling are modeled in the literature only at solid state neglecting the fluid flow. In the present paper we associate a heat transfer – fluid flow and metallurgical model for the 16MnD5 steel. The metallurgical transformation model is based on Leblond model for the diffusion kinetics and on the Koistinen-Marburger equation for Marteniste transformation. The predicted thermal history and metallurgical transformations are compared to a simulation without fluid phase. This comparison shows the great importance of the fluid flow modeling.
Abstract: The paper presents a technique suitable in robot
vision applications where it is not possible to establish the object position from one view. Usually, one view pose calculation methods
are based on the correspondence of image features established at a
training step and exactly the same image features extracted at the
execution step, for a different object pose. When such a
correspondence is not feasible because of the lack of specific features
a new method is proposed. In the first step the method computes
from two views the 3D pose of feature points. Subsequently, using a
registration algorithm, the set of 3D feature points extracted at the execution phase is aligned with the set of 3D feature points extracted
at the training phase. The result is a Euclidean transform which have
to be used by robot head for reorientation at execution step.
Abstract: Periodic vortex shedding in pulsating flow inside wavy
channel and the effect it has on heat transfer are studied using the
finite volume method. A sinusoidally-varying component is superimposed
on a uniform flow inside a sinusoidal wavy channel and
the effects on the Nusselt number is analyzed. It was found that a
unique optimum value of the pulsation frequency, represented by the
Strouhal number, exists for Reynolds numbers ranging from 125 to
1000. Results suggest that the gain in heat transfer is related to the
process of vortex formation, movement about the troughs of the wavy
channel, and subsequent ejection/destruction through the converging
section. Heat transfer is the highest when the frequencies of the
pulsation and vortex formation approach being in-phase. Analysis of
Strouhal number effect on Nu over a period of pulsation substantiates
the proposed physical mechanism for enhancement. The effect of
changing the amplitude of pulsation is also presented over a period
of pulsation, showing a monotonic increase in heat transfer with
increasing amplitude. The 60% increase in Nusselt number suggests
that sinusoidal fluid pulsation can an effective method for enhancing
heat transfer in laminar, wavy-channel flows.