Abstract: The increased number of automobiles in recent years
has resulted in great demand for fossil fuel. This has led to the
development of automobile by using alternative fuels which include
gaseous fuels, biofuels and vegetables oils as fuel. Energy from
biomass and more specific bio-diesel is one of the opportunities that
could cover the future demand of fossil fuel shortage. Biomass in the
form of cashew nut shell represents a new energy source and
abundant source of energy in India. The bio-fuel is derived from
cashew nut shell oil and its blend with diesel are promising
alternative fuel for diesel engine. In this work the pyrolysis Cashew
Nut Shell Liquid (CNSL)-Diesel Blends (CDB) was used to run the
Direct Injection (DI) diesel engine. The experiments were conducted
with various blends of CNSL and Diesel namely B20, B40, B60, B80
and B100. The results are compared with neat diesel operation. The
brake thermal efficiency was decreased for blends of CNSL and
Diesel except the lower blends of B20. The brake thermal efficiency
of B20 is nearly closer to that of diesel fuel. Also the emission level
of the all CNSL and Diesel blends was increased compared to neat
diesel. The higher viscosity and lower volatility of CNSL leads to
poor mixture formation and hence lower brake thermal efficiency and
higher emission levels. The higher emission level can be reduced by
adding suitable additives and oxygenates with CNSL and Diesel
blends.
Abstract: In very narrow pathways, the speed of sound propagation and the phase of sound waves change due to the air viscosity. We have developed a new finite element method (FEM) that includes the effects of air viscosity for modeling a narrow sound pathway. This method is developed as an extension of the existing FEM for porous sound-absorbing materials. The numerical calculation results for several three-dimensional slit models using the proposed FEM are validated against existing calculation methods.
Abstract: The state of melt viscosity in injection process is significantly influenced by the setting parameters due to that the shear rate of injection process is higher than other processes. How to determine plastic melt viscosity during injection process is important to understand the influence of setting parameters on the melt viscosity. An apparatus named as pressure sensor bushing (PSB) module that is used to evaluate the melt viscosity during injection process is developed in this work. The formulations to coupling melt viscosity with fill time and injection pressure are derived and then the melt viscosity is determined. A test mold is prepared to evaluate the accuracy on viscosity calculations between the PSB module and the conventional approaches. The influence of melt viscosity on the tensile strength of molded part is proposed to study the consistency of injection quality.
Abstract: The paper presents a one-dimensional transient
mathematical model of thermal oil-water two-phase emulsion flows
in pipes. The set of the mass, momentum and enthalpy conservation
equations for the continuous fluid and droplet phases are solved. Two
friction correlations for the continuous fluid phase to wall friction are
accounted for in the model and tested. The aerodynamic drag force
between the continuous fluid phase and droplets is modeled, too. The
density and viscosity of both phases are assumed to be constant due
to adiabatic experimental conditions. The proposed mathematical
model is validated on the experimental measurements of oil-water
emulsion flows in horizontal pipe [1,2]. Numerical analysis on
single- and two-phase oil-water flows in a pipe is presented in the
paper. The continuous oil flow having water droplets is simulated.
Predictions, which are performed by using the presented model, show
excellent agreement with the experimental data if the water fraction is
equal or less than 10%. Disagreement between simulations and
measurements is increased if the water fraction is larger than 10%.
Abstract: An adaptive Helmholtz resonator was designed and
adapted to hydraulics. The resonator was controlled by open- and
closed-loop controls so that 20 dB attenuation of the peak-to-peak
value of the pulsating pressure was maintained. The closed-loop
control was noted to be better, albeit it was slower because of its low
pressure and temperature variation, which caused variation in the
effective bulk modulus of the hydraulic system. Low-pressure
hydraulics contains air, which affects the stiffness of the hydraulics,
and temperature variation changes the viscosity of the oil. Thus, an
open-loop control loses its efficiency if a condition such as
temperature or the amount of air changes after calibration. The
instability of the low-pressure hydraulic system reduced the
operational frequency range of the Helmholtz resonator when
compared with the results of an analytical model.
Different dampers for hydraulics are presented. Then analytical
models of a hydraulic pipe and a hydraulic pipe with a Helmholtz
resonator are presented. The analytical models are based on the wave
equation of sound pressure. Finally, control methods and the results
of experiments are presented.
Abstract: Heating is inevitable in any bearing operation. This
leads to not only the thinning of the lubricant but also could lead to a
thermal deformation of the bearing. The present work is an attempt to
analyze the influence of thermal deformation on the thermohydrodynamic
lubrication of infinitely long tilted pad slider rough
bearings. As a consequence of heating the slider is deformed and is
assumed to take a parabolic shape. Also the asperities expand leading
to smaller effective film thickness. Two different types of surface
roughness are considered: longitudinal roughness and transverse
roughness. Christensen-s stochastic approach is used to derive the
Reynolds-type equations. Density and viscosity are considered to be
temperature dependent. The modified Reynolds equation, momentum
equation, continuity equation and energy equation are decoupled and
solved using finite difference method to yield various bearing
characteristics. From the numerical simulations it is observed that the
performance of the bearing is significantly affected by the thermal
distortion of the slider and asperities and even the parallel sliders
seem to carry some load.
Abstract: Reactiondiffusion systems are mathematical models that describe how the concentration of one or more substances distributed in space changes under the influence of local chemical reactions in which the substances are converted into each other, and diffusion which causes the substances to spread out in space. The classical representation of a reaction-diffusion system is given by semi-linear parabolic partial differential equations, whose general form is ÔêétX(x, t) = DΔX(x, t), where X(x, t) is the state vector, D is the matrix of the diffusion coefficients and Δ is the Laplace operator. If the solute move in an homogeneous system in thermal equilibrium, the diffusion coefficients are constants that do not depend on the local concentration of solvent and of solutes and on local temperature of the medium. In this paper a new stochastic reaction-diffusion model in which the diffusion coefficients are function of the local concentration, viscosity and frictional forces of solvent and solute is presented. Such a model provides a more realistic description of the molecular kinetics in non-homogenoeus and highly structured media as the intra- and inter-cellular spaces. The movement of a molecule A from a region i to a region j of the space is described as a first order reaction Ai k- → Aj , where the rate constant k depends on the diffusion coefficient. Representing the diffusional motion as a chemical reaction allows to assimilate a reaction-diffusion system to a pure reaction system and to simulate it with Gillespie-inspired stochastic simulation algorithms. The stochastic time evolution of the system is given by the occurrence of diffusion events and chemical reaction events. At each time step an event (reaction or diffusion) is selected from a probability distribution of waiting times determined by the specific speed of reaction and diffusion events. Redi is the software tool, developed to implement the model of reaction-diffusion kinetics and dynamics. It is a free software, that can be downloaded from http://www.cosbi.eu. To demonstrate the validity of the new reaction-diffusion model, the simulation results of the chaperone-assisted protein folding in cytoplasm obtained with Redi are reported. This case study is redrawing the attention of the scientific community due to current interests on protein aggregation as a potential cause for neurodegenerative diseases.
Abstract: The paper presents a one-dimensional transient
mathematical model of compressible thermal multi-component gas
mixture flows in pipes. The set of the mass, momentum and enthalpy
conservation equations for gas phase is solved. Thermo-physical
properties of multi-component gas mixture are calculated by solving
the Equation of State (EOS) model. The Soave-Redlich-Kwong
(SRK-EOS) model is chosen. Gas mixture viscosity is calculated on
the basis of the Lee-Gonzales-Eakin (LGE) correlation. Numerical
analysis on rapid decompression in conventional dry gases is
performed by using the proposed mathematical model. The model is
validated on measured values of the decompression wave speed in
dry natural gas mixtures. All predictions show excellent agreement
with the experimental data at high and low pressure. The presented
model predicts the decompression in dry natural gas mixtures much
better than GASDECOM and OLGA codes, which are the most
frequently-used codes in oil and gas pipeline transport service.
Abstract: In this paper, we explore the applicability of the Sinc-
Collocation method to a three-dimensional (3D) oceanography model.
The model describes a wind-driven current with depth-dependent
eddy viscosity in the complex-velocity system. In general, the
Sinc-based methods excel over other traditional numerical methods
due to their exponentially decaying errors, rapid convergence and
handling problems in the presence of singularities in end-points.
Together with these advantages, the Sinc-Collocation approach that
we utilize exploits first derivative interpolation, whose integration
is much less sensitive to numerical errors. We bring up several
model problems to prove the accuracy, stability, and computational
efficiency of the method. The approximate solutions determined by
the Sinc-Collocation technique are compared to exact solutions and
those obtained by the Sinc-Galerkin approach in earlier studies. Our
findings indicate that the Sinc-Collocation method outperforms other
Sinc-based methods in past studies.
Abstract: An artificial neural network (ANN) model is
presented for the prediction of kinematic viscosity of binary mixtures
of poly (ethylene glycol) (PEG) in water as a function of temperature,
number-average molecular weight and mass fraction. Kinematic
viscosities data of aqueous solutions for PEG (0.55419×10-6 –
9.875×10-6 m2/s) were obtained from the literature for a wide range
of temperatures (277.15 - 338.15 K), number-average molecular
weight (200 -10000), and mass fraction (0.0 – 1.0). A three layer
feed-forward artificial neural network was employed. This model
predicts the kinematic viscosity with a mean square error (MSE) of
0.281 and the coefficient of determination (R2) of 0.983. The results
show that the kinematic viscosity of binary mixture of PEG in water
could be successfully predicted using an artificial neural network
model.
Abstract: Multiphase flow transport in porous medium is very common and significant in science and engineering applications. For example, in CO2 Storage and Enhanced Oil Recovery processes, CO2 has to be delivered to the pore spaces in reservoirs and aquifers. CO2 storage and enhance oil recovery are actually displacement processes, in which oil or water is displaced by CO2. This displacement is controlled by pore size, chemical and physical properties of pore surfaces and fluids, and also pore wettability. In this study, a technique was developed to measure the pressure profile for driving gas/liquid to displace water in pores. Through this pressure profile, the impact of pore size on the multiphase flow transport and displacement can be analyzed. The other rig developed can be used to measure the static and dynamic pore wettability and investigate the effects of pore size, surface tension, viscosity and chemical structure of liquids on pore wettability.
Abstract: Attempts to add fibre and polyphenols (PPs) into
popular beverages present challenges related to the properties of
finished products such as smoothies. Consumer acceptability,
viscosity and phenolic composition of smoothies containing high
levels of fruit fibre (2.5-7.5 g per 300 mL serve) and PPs (250-750
mg per 300 mL serve) were examined. The changes in total
extractable PP, vitamin C content, and colour of selected smoothies
over a storage stability trial (4°C, 14 days) were compared. A set of
acidic aqueous model beverages were prepared to further examine
the effect of two different heat treatments on the stability and
extractability of PPs. Results show that overall consumer
acceptability of high fibre and PP smoothies was low, with average
hedonic scores ranging from 3.9 to 6.4 (on a 1-9 scale). Flavour,
texture and overall acceptability decreased as fibre and polyphenol
contents increased, with fibre content exerting a stronger effect.
Higher fibre content resulted in greater viscosity, with an elevated PP
content increasing viscosity only slightly. The presence of fibre also
aided the stability and extractability of PPs after heating. A reduction
of extractable PPs, vitamin C content and colour intensity of
smoothies was observed after a 14-day storage period at 4°C. Two
heat treatments (75°C for 45 min or 85°C for 1 min) that are
normally used for beverage production, did not cause significant
reduction of total extracted PPs. It is clear that high levels of added
fibre and PPs greatly influence the consumer appeal of smoothies,
suggesting the need to develop novel formulation and processing
methods if a satisfactory functional beverage is to be developed
incorporating these ingredients.
Abstract: This study was conducted in order to determine the physical properties and stability of mayonnaise-like emulsions as affected by modified yam starches. Native yam starch was modified via pre-gelatinization and cross-linking phosphorylation procedures. The emulsions (50% oil dispersed phase) were prepared with 0.3% native potato, native yam, pre-gelatinized yam and cross-linking phosphorylation yam starches. The droplet size of surface weighted mean diameter was found to be significantly (p < 0.05) lower in the sample with cross-linking phosphorylation yam starch as compared to other samples. Moreover, the viscosity of the sample with pregelatinized yam starch was observed to be higher than that of other samples. The phase separation stability was low in the freshly prepared and stored (45 days, 5°C) emulsions containing native yam starch. This study thus generally suggested that modified yam starches were more suitable (i.e. better physical properties and stability) to be used as stabilizers in a similar system i.e. light mayonnaises, rather than a native yam starch.
Abstract: The aim of this study was to investigate the effect of blood viscosity on the radial pulse wave. For this, we obtained the radial pulse wave of 15 males with abnormal high hematocrit level and 47 males with normal hematocrit level at the age of thirties and forties. Various variables of the radial pulse wave between two groups were analyzed and compared by Student's T test. There are significant differences in several variables about height, time and area of the pulse wave. The first peak of the radial pulse wave was higher in abnormal high hematocrit group, but the third peak was higher and longer in normal hematocrit group. Our results suggest that the radial pulse wave can be used for diagnosis of high blood viscosity and more clinical application.
Abstract: In this research sodium bicarbonate (NaHCO3) was introduced to generate carbon dioxide gas (CO2) to the existing nitrogen gas (N2) of elastomeric foam, to lower thermal conductivity (K). Various loadings of NaHCO3 (0 to 60 phr) were added into the azodicarbonamide (AZC)-containing compound and its properties were then determined. Two vulcanization methods, i.e., hot air and infrared (IR), were employed and compared in this study. Results revealed that compound viscosity tended to increase slightly with increasing NaHCO3 content but cure time was delayed. The effect of NaHCO3 content on thermal conductivity depended on the vulcanization method. For hot air method, the thermal conductivity was insignificantly changed with increasing NaHCO3 up to 40 phr whereas it tended to decrease gradually for IR method. At higher NaHCO3 content (60 phr), unexpected increase of thermal conductivity was observed. The water absorption was also determined and foam structures were then used to explain the results.
Abstract: We aimed to investigate how can target and optimize
pulmonary delivery distribution by changing physicochemical
characteristics of instilled liquid.Therefore, we created a new liquids
group:
a. eligible for desired distribution within lung because of
assorted physicochemical characteristics
b. capable of being augmented with a broad range of
chemicals inertly
c. no interference on respiratory function
d. compatible with airway surface liquid
We developed forty types of new liquid,were composed of
Carboxymethylcellulose sodium,Glycerin and different types of
Polysorbates.Viscosity was measured using a Programmable
Rheometer and surface tension by KRUSS Tensiometer.We
subsequently examined the liquids and delivery protocols by simple
and branched glass capillary tube models of airways.Eventually,we
explored pulmonary distribution of liquids being augmented with
technetium-99m in mechanically ventilated rabbits.We used a single
head large field of view gamma camera.Kinematic viscosity between
0.265Stokes and 0.289Stokes,density between 1g/cm3 and 1.5g/cm3
and surface tension between 25dyn/cm and 35dyn/cm were the most
acceptable.
Abstract: The hydraulic actuated excavator, being a non-linear
mobile machine, encounters many uncertainties. There are
uncertainties in the hydraulic system in addition to the uncertain
nature of the load. The simulation results obtained in this study show
that there is a need for intelligent control of such machines and in
particular interval type-2 fuzzy controller is most suitable for
minimizing the position error of a typical excavator-s bucket under
load variations. We consider the model parameter uncertainties such
as hydraulic fluid leakage and friction. These are uncertainties which
also depend up on the temperature and alter bulk modulus and
viscosity of the hydraulic fluid. Such uncertainties together with the
load variations cause chattering of the bucket position. The interval
type-2 fuzzy controller effectively eliminates the chattering and
manages to control the end-effecter (bucket) position with positional
error in the order of few millimeters.
Abstract: This paper characterizes the effects of artificial short
term aging in the laboratory on the rheological properties of virgin
80/100 penetration grade asphalt binder. After several years in
service, asphalt mixture started to deteriorate due to aging. Aging is a
complex physico-chemical phenomenon that influences asphalt
binder rheological properties causing a deterioration in asphalt
mixture performance. To ascertain asphalt binder aging effects, the
virgin, artificially aged and extracted asphalt binder were tested via
the Rolling Thin film Oven (RTFO), Dynamic Shear Rheometer
(DSR) and Rotational Viscometer (RV). A comparative study
between laboratory and field aging conditions were also carried out.
The results showed that the specimens conditioned for 85 minutes
inside the RTFO was insufficient to simulate the actual short term
aging caused that took place in the field under Malaysian field
conditions
Abstract: Effect of viscosity of media on kinetic parameters of the coupled enzyme system NADH:FMN-oxidoreductase–luciferase was investigated with addition of organic solvents (glycerol and sucrose), because bioluminescent enzyme systems based on bacterial luciferases offer a unique and general tool for analysis of the many analytes and enzymes in the environment, research and clinical laboratories and other fields. The possibility of stabilization and increase of activity of the coupled enzyme system NADH:FMN-oxidoreductase–luciferase activity in vicious aqueous-organic mixtures have been shown.
Abstract: Hydrogen is an important chemical in many industries
and it is expected to become one of the major fuels for energy
generation in the future. Unfortunately, hydrogen does not exist in its
elemental form in nature and therefore has to be produced from
hydrocarbons, hydrogen-containing compounds or water.
Above its critical point (374.8oC and 22.1MPa), water has lower
density and viscosity, and a higher heat capacity than those of
ambient water. Mass transfer in supercritical water (SCW) is
enhanced due to its increased diffusivity and transport ability. The
reduced dielectric constant makes supercritical water a better solvent
for organic compounds and gases. Hence, due to the aforementioned
desirable properties, there is a growing interest toward studies
regarding the gasification of organic matter containing biomass or
model biomass solutions in supercritical water.
In this study, hydrogen and biofuel production by the catalytic
gasification of 2-Propanol in supercritical conditions of water was
investigated. Pt/Al2O3and Ni/Al2O3were the catalysts used in the
gasification reactions. All of the experiments were performed under a
constant pressure of 25MPa. The effects of five reaction temperatures
(400, 450, 500, 550 and 600°C) and five reaction times (10, 15, 20,
25 and 30 s) on the gasification yield and flammable component
content were investigated.