Abstract: Offshore oil-spill has become the most emerging problem in the world. In the current paper, a graphene/ZnO/polymer nanocomposite thin film is coated on stainless steel mesh via layer by layer deposition method. The structural characterization of materials is determined by Scanning Electron Microscopy (SEM) and X-ray diffraction (XRD). The total petroleum hydrocarbons (TPHs) and separation efficiency have been measured via gas chromatography – flame ionization detector (GC-FID). TPHs are reduced to 2 ppm and separation efficiency of the nanocomposite coated mesh is reached ≥ 99% for the final sample. The nanocomposite coated mesh acts as a promising candidate for the separation of oil- water mixture.
Abstract: Solar thermal power plants using parabolic trough collectors (PTC) are currently a powerful technology for generating electricity. Most of these solar power plants use thermal oils as heat transfer fluid. The latter is heated in the solar field and transfers the heat absorbed in an oil-water heat exchanger for the production of steam driving the turbines of the power plant. Currently, we are seeking to develop PTCs with direct steam generation (DSG). This process consists of circulating water under pressure in the receiver tube to generate steam directly into the solar loop. This makes it possible to reduce the investment and maintenance costs of the PTCs (the oil-water exchangers are removed) and to avoid the environmental risks associated with the use of thermal oils. The pressure drops in these systems are an important parameter to ensure their proper operation. The determination of these losses is complex because of the presence of the two phases, and most often we limit ourselves to describing them by models using empirical correlations. A comparison of these models with experimental data was performed. Our calculations focused on the evolution of the pressure of the liquid-vapor mixture along the receiver tube of a PTC-DSG for pressure values and inlet flow rates ranging respectively from 3 to 10 MPa, and from 0.4 to 0.6 kg/s. The comparison of the numerical results with experience allows us to demonstrate the validity of some models according to the pressures and the flow rates of entry in the PTC-DSG receiver tube. The analysis of these two parameters’ effects on the evolution of the pressure along the receiving tub, shows that the increase of the inlet pressure and the decrease of the flow rate lead to minimal pressure losses.
Abstract: A coupled two-layer finite volume/finite element
method was proposed for solving dam-break flow problem
over deformable beds. The governing equations consist of the
well-balanced two-layer shallow water equations for the water flow
and a linear elastic model for the bed deformations. Deformations
in the topography can be caused by a brutal localized force or
simply by a class of sliding displacements on the bathymetry.
This deformation in the bed is a source of perturbations, on
the water surface generating water waves which propagate with
different amplitudes and frequencies. Coupling conditions at the
interface are also investigated in the current study and two mesh
procedure is proposed for the transfer of information through the
interface. In the present work a new procedure is implemented at
the soil-water interface using the finite element and two-layer finite
volume meshes with a conservative distribution of the forces at
their intersections. The finite element method employs quadratic
elements in an unstructured triangular mesh and the finite volume
method uses the Rusanove to reconstruct the numerical fluxes. The
numerical coupled method is highly efficient, accurate, well balanced,
and it can handle complex geometries as well as rapidly varying
flows. Numerical results are presented for several test examples of
dam-break flows over deformable beds. Mesh convergence study is
performed for both methods, the overall model provides new insight
into the problems at minimal computational cost.
Abstract: The present work focuses on the investigation of the effect of non-Newtonian behavior on the oil-water stratified flow in a horizontal channel using ANSYS Fluent. Coupled level set and volume of fluid (CLSVOF) has been used to capture the evolving interface assuming unsteady, coaxial flow with constant fluid properties. The diametric variation of oil volume fraction, mixture velocity, total pressure and pressure gradient has been studied. Non-Newtonian behavior of oil has been represented by the power law model in order to investigate the effect of flow behavior index. Stratified flow pattern tends to assume dispersed flow pattern with the change in the behavior of oil to non-Newtonian. The pressure gradient is found to be very much sensitive to the flow behavior index. The findings could be useful in designing the transportation pipe line in petroleum industries.
Abstract: The measured soil suction values when related to water content is called suction-water content relationship (SWR) or soil-water characteristic curve (SWCC) and forms the basis of unsaturated soil behavior assessment. The SWCC can be measured or predicted based on soil index properties such as grain-size distribution and plasticity index. In this paper, the SWCC of clean and contaminated clayey soil classified as clay with low plasticity (CL) are presented. Laboratory studies were conducted on virgin (disturbed-uncontaminated soil collected from vicinity of Tehran oil refinery) soil and soil samples simulated to varying degrees of contamination with crude oil (i.e., 3, 6, and 9% by dry weight of soil) to compare the results before and after contamination. Laboratory tests were conducted using a device which is capable of measuring volume change and pore pressures. The soil matric suction at the ends of samples controlled by using the axis translation technique. The results show that contamination with crude oil facilitates the movement of water and reduces the soil suction.
Abstract: Formulation of a low oil-water ratio drilling mud with vegetable oil continuous phase without adversely affecting the mud rheology and stability has been a major challenge. A low oil-water ratio is beneficial in producing low fluid loss which is essential for wellbore stability. This study examined the possibility of 50/50 oil-water ratio invert emulsion drilling mud using a vegetable oil continuous phase. Jatropha oil was used as continuous phase. 12 ml of egg yolk which was separated from the albumen was added as the primary emulsifier additive. The rheological, stability and filtration properties were examined. The plastic viscosity and yield point were found to be 36cp and 17 Ib/100 ft2 respectively. The electrical stability at 48.9ºC was 353v and the 30 minutes fluid loss was 6ml. The results compared favourably with a similar formulation using 70/30 oil - water ratio giving plastic viscosity of 31cp, yield point of 17 Ib/100 ft2, electrical stability value of 480v and 12ml for the 30 minutes fluid loss. This study indicates that with a good mud composition using guided empiricism, 50/50 oil-water ratio invert emulsion drilling mud is feasible with a vegetable oil continuous phase. The choice of egg yolk as emulsifier additive is for compatibility with the vegetable oil and environmental concern. The high water content with no fluid loss additive will also minimise the cost of mud formulation.
Abstract: Production fluids are transported from the platform to
tankers or process facilities through transfer pipelines. Water being
one of the heavier phases tends to settle at the bottom of pipelines
especially at low flow velocities and this has adverse consequences
for pipeline integrity. On restart after a shutdown, this could result in
corrosion and issues for process equipment, thus the need to have the
heavier liquid dispersed into the flowing lighter fluid. This study
looked at the flow regime of low water cut and low flow velocity oil
and water flow using conductive film thickness probes in a large
diameter 4-inch pipe to obtain oil and water interface height and the
interface structural velocity. A wide range of 0.1–1.0 m/s oil and
water mixture velocities was investigated for 0.5–5% water cut. Two
fluid model predictions were used to compare with the experimental
results.
Abstract: Characterization of the engineering behavior of
unsaturated soil is dependent on the soil-water characteristic curve
(SWCC), a graphical representation of the relationship between water
content or degree of saturation and soil suction. A reasonable
description of the SWCC is thus important for the accurate prediction
of unsaturated soil parameters. The measurement procedures for
determining the SWCC, however, are difficult, expensive, and timeconsuming.
During the past few decades, researchers have laid a
major focus on developing empirical equations for predicting the
SWCC, with a large number of empirical models suggested. One of
the most crucial questions is how precisely existing equations can
represent the SWCC. As different models have different ranges of
capability, it is essential to evaluate the precision of the SWCC
models used for each particular soil type for better SWCC estimation.
It is expected that better estimation of SWCC would be achieved via
a thorough statistical analysis of its distribution within a particular
soil class. With this in view, a statistical analysis was conducted in
order to evaluate the reliability of the SWCC prediction models
against laboratory measurement. Optimization techniques were used
to obtain the best-fit of the model parameters in four forms of SWCC
equation, using laboratory data for relatively coarse-textured (i.e.,
sandy) soil. The four most prominent SWCCs were evaluated and
computed for each sample. The result shows that the Brooks and
Corey model is the most consistent in describing the SWCC for sand
soil type. The Brooks and Corey model prediction also exhibit
compatibility with samples ranging from low to high soil water
content in which subjected to the samples that evaluated in this study.
Abstract: In the present work, detailed analysis on flow characteristics of a pair of immiscible liquids through horizontal pipeline is simulated by using ANSYS FLUENT 6.2. Moderately viscous oil and water (viscosity ratio = 107, density ratio = 0.89 and interfacial tension = 0.024 N/m) have been taken as system fluids for the study. Volume of Fluid (VOF) method has been employed by assuming unsteady flow, immiscible liquid pair, constant liquid properties, and co-axial flow. Meshing has been done using GAMBIT. Quadrilateral mesh type has been chosen to account for the surface tension effect more accurately. From the grid independent study, we have selected 47037 number of mesh elements for the entire geometry. Simulation successfully predicts slug, stratified wavy, stratified mixed and annular flow, except dispersion of oil in water, and dispersion of water in oil. Simulation results are validated with horizontal literature data and good conformity is observed. Subsequently, we have simulated the hydrodynamics (viz., velocity profile, area average pressure across a cross section and volume fraction profile along the radius) of stratified wavy and annular flow at different phase velocities. The simulation results show that in the annular flow, total pressure of the mixture decreases with increase in oil velocity due to the fact that pipe cross section is completely wetted with water. Simulated oil volume fraction shows maximum at the centre in core annular flow, whereas, in stratified flow, maximum value appears at upper side of the pipeline. These results are in accord with the actual flow configuration. Our findings could be useful in designing pipeline for transportation of crude oil.
Abstract: The current desire in food and industrial emulsification is the use of natural emulsifiers. Bambara groundnut flour (BGNF) and its starch (BGNS) will serve both emulsifying and nutritional purposes if found suitable. This current study was aimed at investigating the emulsifying properties of BGNF/BGNS. BGNS was extracted from the BGNF. Emulsions were prepared using a wide range of flour-oil-water and starch-oil-water composition as generated through the application of Response Surface (D-optimal) design. Prepared emulsions were investigated for stability to creaming/sedimentation (using the kinetic information from turbiscan) and flocculation/coalescence (by monitoring the droplet diameter growth using optical microscope) over 5 days. The most stable emulsions (one BGNF-stabilized and the other BGNS-stabilized) were determined. The optimal emulsifier/oil composition was 9g/39g for BGNF and 5g/30g for BGNS. The two emulsions had only 30% and 50% growth in oil droplet diameter respectively by day 5, compared to over 3000% in the unstable ones. The BGNF-stabilized emulsions were more stable than the BGNS-stabilized ones. Emulsions were successfully stabilized with BGNF and BGNS.
Abstract: In the present study, computational fluid dynamics
(CFD) simulation has been executed to investigate the transition
boundaries of different flow patterns for moderately viscous oil-water
(viscosity ratio 107, density ratio 0.89 and interfacial tension of 0.032
N/m.) two-phase flow through a horizontal pipeline with internal
diameter and length of 0.025 m and 7.16 m respectively. Volume of
Fluid (VOF) approach including effect of surface tension has been
employed to predict the flow pattern. Geometry and meshing of the
present problem has been drawn using GAMBIT and ANSYS
FLUENT has been used for simulation. A total of 47037 quadrilateral
elements are chosen for the geometry of horizontal pipeline. The
computation has been performed by assuming unsteady flow,
immiscible liquid pair, constant liquid properties, co-axial flow and a
T-junction as entry section. The simulation correctly predicts the
transition boundaries of wavy stratified to stratified mixed flow.
Other transition boundaries are yet to be simulated. Simulated data
has been validated with our own experimental results.
Abstract: This paper made an attempt to investigate the problem associated with enhancement of emulsions of light crude oil-water recovery in an oil field of Algerian Sahara. Measurements were taken through experiments using RheoStress (RS600). Factors such as shear rate, temperature and light oil concentration on the viscosity behavior were considered. Experimental measurements were performed in terms of shear stress–shear rate, yield stress and flow index on mixture of light crude oil–water. The rheological behavior of emulsion showed Non-Newtonian shear thinning behavior (Herschel-Bulkley). The experiments done in the laboratory showed the stability of some water in light crude oil emulsions form during consolidate oil recovery process. To break the emulsion using additives may involve higher cost and could be very expensive. Therefore, further research should be directed to find solution of these problems that have been encountered.
Abstract: Nanoemulsions are a class of emulsions with a droplet
size in the range of 50–500 nm and have attracted a great deal of
attention in recent years because it is unique characteristics. The
physicochemical properties of nanoemulsion suggests that it can be
successfully used to recover the residual oil which is trapped in the
fine pore of reservoir rock by capillary forces after primary and
secondary recovery. Oil-in-water nanoemulsion which can be formed
by high-energy emulsification techniques using specific surfactants
can reduce oil-water interfacial tension (IFT) by 3-4 orders of
magnitude. The present work is aimed on characterization of oil-inwater
nanoemulsion in terms of its phase behavior, morphological
studies; interfacial energy; ability to reduce the interfacial tension and
understanding the mechanisms of mobilization and displacement of
entrapped oil blobs by lowering interfacial tension both at the
macroscopic and microscopic level. In order to investigate the
efficiency of oil-water nanoemulsion in enhanced oil recovery
(EOR), experiments were performed to characterize the emulsion in
terms of their physicochemical properties and size distribution of the
dispersed oil droplet in water phase. Synthetic mineral oil and a series
of surfactants were used to prepare oil-in-water emulsions.
Characterization of emulsion shows that it follows pseudo-plastic
behaviour and drop size of dispersed oil phase follows lognormal
distribution. Flooding experiments were also carried out in a
sandpack system to evaluate the effectiveness of the nanoemulsion as
displacing fluid for enhanced oil recovery. Substantial additional
recoveries (more than 25% of original oil in place) over conventional
water flooding were obtained in the present investigation.
Abstract: The characteristics of fluid flow and phase separation
in an oil-water separator were numerically analysed as part of the
work presented herein. Simulations were performed for different
velocities and droplet diameters, and the way this parameters can
influence the separator geometry was studied.
The simulations were carried out using the software package
Fluent 6.2, which is designed for numerical simulation of fluid flow
and mass transfer. The model consisted of a cylindrical horizontal
separator. A tetrahedral mesh was employed in the computational
domain. The condition of two-phase flow was simulated with the
two-fluid model, taking into consideration turbulence effects using
the k-ε model.
The results showed that there is a strong dependency of phase
separation on mixture velocity and droplet diameter. An increase in
mixture velocity will bring about a slow down in phase separation
and as a consequence will require a weir of greater height. An
increase in droplet diameter will produce a better phase separation.
The simulations are in agreement with results reported in literature
and show that CFD can be a useful tool in studying a horizontal oilwater
separator.
Abstract: The paper presents a one-dimensional transient
mathematical model of thermal oil-water two-phase emulsion flows
in pipes. The set of the mass, momentum and enthalpy conservation
equations for the continuous fluid and droplet phases are solved. Two
friction correlations for the continuous fluid phase to wall friction are
accounted for in the model and tested. The aerodynamic drag force
between the continuous fluid phase and droplets is modeled, too. The
density and viscosity of both phases are assumed to be constant due
to adiabatic experimental conditions. The proposed mathematical
model is validated on the experimental measurements of oil-water
emulsion flows in horizontal pipe [1,2]. Numerical analysis on
single- and two-phase oil-water flows in a pipe is presented in the
paper. The continuous oil flow having water droplets is simulated.
Predictions, which are performed by using the presented model, show
excellent agreement with the experimental data if the water fraction is
equal or less than 10%. Disagreement between simulations and
measurements is increased if the water fraction is larger than 10%.
Abstract: The rheological properties of light crude oil and its mixture with water were investigated experimentally. These rheological properties include steady flow behavior, yield stress, transient flow behavior, and viscoelastic behavior. A RheoStress RS600 rheometer was employed in all of the rheological examination tests. The light crude oil exhibits a Newtonian and for emulsion exhibits a non-Newtonian shear thinning behavior over the examined shear rate range of 0.1–120 s-1. In first time, a series of samples of crude oil from the Algerian Sahara has been tested and the results expressed in terms of τ=f(γ) have demonstrated their Newtonian character for the temperature included in [20°C, 70°C]. In second time and at T=20°C, the oil-water emulsions (30%, 50% and 70%) by volume of water), thermodynamically stable, have demonstrated a non-Newtonian rheological behavior that is to say, Herschel-Bulkley and Bingham types. For each type of crude oil-water emulsion, the rheological parameters are calculated by numerical treatment of results.