Abstract: Polycyclic aromatic hydrocarbons (PAHs) are formed
during the pyrolysis of scrap tyres to produce tyre pyrolytic oil
(TPO). Due to carcinogenic, mutagenic, and toxic properties PAHs
are priority pollutants. Hence it is essential to remove PAHs from
TPO before utilising TPO as a petroleum fuel alternative (to run the
engine). Agricultural wastes have promising future to be utilized as
biosorbent due to their cost effectiveness, abundant availability, high
biosorption capacity and renewability. Various low cost adsorbents
were prepared from natural sources. Uptake of PAHs present in tyre
pyrolytic oil was investigated using various low-cost adsorbents of
natural origin including sawdust (shisham), coconut fiber, neem bark,
chitin, activated charcoal. Adsorption experiments of different PAHs
viz. naphthalene, acenaphthalene, biphenyl and anthracene have been
carried out at ambient temperature (25°C) and at pH 7. It was
observed that for any given PAH, the adsorption capacity increases
with the lignin content. Freundlich constant Kf and 1/n have been
evaluated and it was found that the adsorption isotherms of PAHs
were in agreement with a Freundlich model, while the uptake
capacity of PAHs followed the order: activated charcoal> saw dust
(shisham) > coconut fiber > chitin. The partition coefficients in
acetone-water, and the adsorption constants at equilibrium, could be
linearly correlated with octanol–water partition coefficients. It is
observed that natural adsorbents are good alternative for PAHs
removal. Sawdust of Dalbergia sissoo, a by-product of sawmills was
found to be a promising adsorbent for the removal of PAHs present in
TPO. It is observed that adsorbents studied were comparable to those
of some conventional adsorbents.
Abstract: Freeze concentration freezes or crystallises the water
molecules out as ice crystals and leaves behind a highly concentrated
solution. In conventional suspension freeze concentration where ice
crystals formed as a suspension in the mother liquor, separation of
ice is difficult. The size of the ice crystals is still very limited which
will require usage of scraped surface heat exchangers, which is very
expensive and accounted for approximately 30% of the capital cost.
This research is conducted using a newer method of freeze
concentration, which is progressive freeze concentration. Ice crystals
were formed as a layer on the designed heat exchanger surface. In
this particular research, a helical structured copper crystallisation
chamber was designed and fabricated. The effect of two operating
conditions on the performance of the newly designed crystallisation
chamber was investigated, which are circulation flowrate and coolant
temperature. The performance of the design was evaluated by the
effective partition constant, K, calculated from the volume and
concentration of the solid and liquid phase. The system was also
monitored by a data acquisition tool in order to see the temperature
profile throughout the process. On completing the experimental
work, it was found that higher flowrate resulted in a lower K, which
translated into high efficiency. The efficiency is the highest at 1000
ml/min. It was also found that the process gives the highest
efficiency at a coolant temperature of -6 °C.
Abstract: Human amniotic membrane (HAM) is a useful
biological material for the reconstruction of damaged ocular surface.
The processing and preservation of HAM is critical to prevent the
patients undergoing amniotic membrane transplant (AMT) from cross
infections. For HAM preparation human placenta is obtained after an
elective cesarean delivery. Before collection, the donor is screened
for seronegativity of HCV, Hbs Ag, HIV and Syphilis. After
collection, placenta is washed in balanced salt solution (BSS) in
sterile environment. Amniotic membrane is then separated from the
placenta as well as chorion while keeping the preparation in BSS.
Scrapping of HAM is then carried out manually until all the debris is
removed and clear transparent membrane is acquired. Nitrocellulose
membrane filters are then placed on the stromal side of HAM, cut
around the edges with little membrane folded towards other side
making it easy to separate during surgery. HAM is finally stored in
solution of glycerine and Dulbecco-s Modified Eagle Medium
(DMEM) in 1:1 ratio containing antibiotics. The capped borosil vials
containing HAM are kept at -80°C until use. This vial is thawed to
room temperature and opened under sterile operation theatre
conditions at the time of surgery.
Abstract: Ambiguities in effects of earthquake on various
structures in all earthquake codes would necessitate more study and
research concerning influential factors on dynamic behavior.
Previous studies which were done on different features in different
buildings play a major role in the type of response a structure makes
to lateral vibrations. Diagnosing each of these irregularities can help
structure designers in choosing appropriate setbacks for decreasing
possible damages. Therefore vertical setback is one of the irregularity
factors in the height of the building where can be seen in skyscrapers
and hotels. Previous researches reveal notable changes in the place of
these setbacks showing dynamic response of the structure.
Consequently analyzing 48 models of concrete frames for 3, 6 and 9
stories heights with three different bays in general shape of a surface
decline by height have been constructed in ETABS2000 software,
and then the shape effect of each and every one of these frames in
period scale has been discussed. The result of this study reveals that
not only mass, stiffness and height but also shape of the frame is
influential.
Abstract: In this study, the reduction of Cr(VI) by use of scrap
iron, a cheap and locally available industrial waste, was investigated
in continuous system. The greater scrap iron efficiency observed for
the first two sections of the column filling indicate that most of the
reduction process was carried out in the bottom half of the column
filling. This was ascribed to a constant decrease of Cr(VI)
concentration inside the filling, as the water front passes from the
bottom to the top end of the column. While the bottom section of the
column filling was heavily passivated with secondary mineral phases,
the top section was less affected by the passivation process; therefore
the column filling would likely ensure the reduction of Cr(VI) for
time periods longer than 216 hours. The experimental results indicate
that fixed beds columns packed with scrap iron could be successfully
used for the first step of Cr(VI) polluted wastewater treatment.
However, the mass of scrap iron filling should be carefully estimated
since it significantly affects the Cr(VI) reduction efficiency.
Abstract: Aluminothermic rail welding was from the beginning
a great success because its low price even in 1895 in Germany. This
method is now, widely used all over the world for the railways
construction, maintenance and modernization. Instructions give you
guidelines for preparing papers for conferences or journals.
After 1989, the welding needs of the potentials beneficiaries
(Romanian Railways, Urban Transportation Companies) keep raise
because of the railways maintenance and modernization necessity.
The main materials that determine the Thermit (T) composition
result from manufacturing scraps all over the country. This can help
the environment by consuming these scraps.
The Romanian need for alumino-thermic welding is now by 11300
per year, and in a favourable economical environment, this amount
can reach 30000 units.
This paper tries to show the effect of two types of modifiers
introduced in the T composition on the structure and properties of an
alumino-thermic welding.
Abstract: Uncertainties of a serial production line affect on the
production throughput. The uncertainties cannot be prevented in a
real production line. However the uncertain conditions can be
controlled by a robust prediction model. Thus, a hybrid model
including autoregressive integrated moving average (ARIMA) and
multiple polynomial regression, is proposed to model the nonlinear
relationship of production uncertainties with throughput. The
uncertainties under consideration of this study are demand, breaktime,
scrap, and lead-time. The nonlinear relationship of production
uncertainties with throughput are examined in the form of quadratic
and cubic regression models, where the adjusted R-squared for
quadratic and cubic regressions was 98.3% and 98.2%. We optimized
the multiple quadratic regression (MQR) by considering the time
series trend of the uncertainties using ARIMA model. Finally the
hybrid model of ARIMA and MQR is formulated by better adjusted
R-squared, which is 98.9%.
Abstract: Failure modes and effects analysis (FMEA) is an effective technique for preventing potential problems and actions needed to error cause removal. On the other hand, the oil producing companies paly a critical role in the oil industry of Iran as a developing country out of which, Sepahan Oil Co. has a considerable contribution. The aim of this research is to show how FMEA could be applied and improve the quality of products at Sepahan Oil Co. For this purpose, the four liter production line of the company has been selected for investigation. The findings imply that the application of FMEA has reduced the scraps from 50000 ppm to 5000 ppm and has resulted in a 0.92 percent decrease of the oil waste.
Abstract: Throughput is an important measure of performance of production system. Analyzing and modeling of production throughput is complex in today-s dynamic production systems due to uncertainties of production system. The main reasons are that uncertainties are materialized when the production line faces changes in setup time, machinery break down, lead time of manufacturing, and scraps. Besides, demand changes are fluctuating from time to time for each product type. These uncertainties affect the production performance. This paper proposes Bayesian inference for throughput modeling under five production uncertainties. Bayesian model utilized prior distributions related to previous information about the uncertainties where likelihood distributions are associated to the observed data. Gibbs sampling algorithm as the robust procedure of Monte Carlo Markov chain was employed for sampling unknown parameters and estimating the posterior mean of uncertainties. The Bayesian model was validated with respect to convergence and efficiency of its outputs. The results presented that the proposed Bayesian models were capable to predict the production throughput with accuracy of 98.3%.
Abstract: Recycling of aluminum alloys often decrease fluidity,
consequently influence the castability of the alloy. In this study, the
fluidity of Al-Zn alloys, such as the standard A713 alloy with and
without scrap addition has been investigated. The scrap added was
comprised of contaminated alloy turning chips. Fluidity
measurements were performed with double spiral fluidity test
consisting of gravity casting of double spirals in green sand moulds
with good reproducibility. The influence of recycled alloy on fluidity
has been compared with that of the virgin alloy and the results
showed that the fluidity decreased with the increase in recycled alloy
at minimum pouring temperatures. Interestingly, an appreciable
improvement in the fluidity was observed at maximum pouring
temperature, especially for coated spirals.
Abstract: The reduction of hexavalent chromium by scrap iron
was investigated in continuous system, using long-term column
experiments, for aqueous Cr(VI) solutions having low buffering
capacities, over the Cr(VI) concentration range of 5 – 40 mg/L. The
results showed that the initial Cr(VI) concentration significantly
affects the reduction capacity of scrap iron. Maximum reduction
capacity of scrap iron was observed at the beginning of the column
experiments; the lower the Cr(VI) concentration, the greater the
experiment duration with maximum scrap iron reduction capacity.
However, due to passivation of active surface, scrap iron reduction
capacity continuously decreased in time, especially after Cr(VI)
breakthrough. The experimental results showed that highest
reduction capacity recorded until Cr(VI) breakthrough was 22.8 mg
Cr(VI)/g scrap iron, at CI = 5 mg/L, and decreased with increasing
Cr(VI) concentration. In order to assure total reduction of greater
Cr(VI) concentrations for a longer period of time, either the mass of
scrap iron filling, or the hydraulic retention time should be increased.
Abstract: Focusing on the environmental issues, including the reduction of scrap and consumer residuals, along with the benefiting from the economic value during the life cycle of goods/products leads the companies to have an important competitive approach. The aim of this paper is to present a new mixed nonlinear facility locationallocation model in recycling collection networks by considering multi-echelon, multi-suppliers, multi-collection centers and multifacilities in the recycling network. To make an appropriate decision in reality, demands, returns, capacities, costs and distances, are regarded uncertain in our model. For this purpose, a fuzzy mathematical programming-based possibilistic approach is introduced as a solution methodology from the recent literature to solve the proposed mixed-nonlinear programming model (MNLP). The computational experiments are provided to illustrate the applicability of the designed model in a supply chain environment and to help the decision makers to facilitate their analysis.
Abstract: Magnesium wastes and scraps, one of the metal wastes, are produced by many industrial activities, all over the world. Their growing size is becoming a future problem for the world. In this study, the use of magnesium wastes as a raw material in the production of the magnesium borate hydrates are aimed. The method used in the experiments is hydrothermal synthesis. The conditions are set to, waste magnesium to B2O3, 1:3 as a molar ratio. Four different reaction times are studied which are 30, 60, 120 and 240 minutes. For the identification analyses X-Ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FT-IR) and Raman spectroscopy techniques are used. As a result at all the reaction times magnesium borate hydrates are synthesized and the most crystalline forms are obtained at a reaction time of 120 minutes. The overall yields of the production are found between the values of 65-80 %.
Abstract: A seismic isolation pad produced by utilizing the scrap
tire rubber which contains interleaved steel reinforcing cords has been
proposed. The steel cords are expected to function similar to the steel
plates used in conventional laminated rubber bearings. The scrap tire
rubber pad (STRP) isolator is intended to be used in low rise
residential buildings of highly seismic areas of the developing
countries. Experimental investigation was conducted on unbonded
STRP isolators, and test results provided useful information including
stiffness, damping values and an eventual instability of the isolation
unit. Finite element analysis (FE analysis) of STRP isolator was
carried out on properly bonded samples. These types of isolators
provide positive incremental force resisting capacity up to shear strain
level of 155%. This paper briefly discusses the force deformation
behavior of bonded STRP isolators including stability of the isolation
unit.
Abstract: Hexavalent chromium is highly toxic to most living organisms and a known human carcinogen by the inhalation route of exposure. Therefore, treatment of Cr(VI) contaminated wastewater is essential before their discharge to the natural water bodies. Cr(VI) reduction to Cr(III) can be beneficial because a more mobile and more toxic chromium species is converted to a less mobile and less toxic form. Zero-valence-state metals, such as scrap iron, can serve as electron donors for reducing Cr(VI) to Cr(III). The influence of pH on scrap iron capacity to reduce Cr(VI) was investigated in this study. Maximum reduction capacity of scrap iron was observed at the beginning of the column experiments; the lower the pH, the greater the experiment duration with maximum scrap iron reduction capacity. The experimental results showed that highest maximum reduction capacity of scrap iron was 12.5 mg Cr(VI)/g scrap iron, at pH 2.0, and decreased with increasing pH up to 1.9 mg Cr(VI)/g scrap iron at pH = 7.3.