Abstract: The main purpose of this article is to provide a comprehensive review of various physical and chemical processes for electronic waste (e-waste) recycling, their advantages and shortfalls towards achieving a cleaner process of waste utilization, with especial attention towards extraction of metallic values. Current status and future perspectives of waste printed circuit boards (PCBs) recycling are described. E-waste characterization, dismantling/ disassembly methods, liberation and classification processes, composition determination techniques are covered. Manual selective dismantling and metal-nonmetal liberation at – 150 µm at two step crushing are found to be the best. After size reduction, mainly physical separation/concentration processes employing gravity, electrostatic, magnetic separators, froth floatation etc., which are commonly used in mineral processing, have been critically reviewed here for separation of metals and non-metals, along with useful utilizations of the non-metallic materials. The recovery of metals from e-waste material after physical separation through pyrometallurgical, hydrometallurgical or biohydrometallurgical routes is also discussed along with purification and refining and some suitable flowsheets are also given. It seems that hydrometallurgical route will be a key player in the base and precious metals recoveries from e-waste. E-waste recycling will be a very important sector in the near future from economic and environmental perspectives.
Abstract: In this paper, a reverse supply chain network is investigated for a decision making. This decision is surrounded by complex flows of returned products, due to the increasing quantity, the type of returned products and the variety of recovery option products (reuse, recycling, and refurbishment). The most important problem in the reverse logistic network (RLN) is to orient returned products to the suitable type of recovery option. However, returned products orientations from collect sources to the recovery disposition have not well considered in performance model. In this study, we propose a performance model for designing a network configuration on reverse logistics. Conceptual and analytical models are developed with taking into account operational, economic and environmental factors on designing network.
Abstract: This paper proposes a cost-effective private grid using Object-based Grid Architecture (OGA). In OGA, the data process privacy and inter communication are increased through an object- oriented concept. The limitation of the existing grid is that the user can enter or leave the grid at any time without schedule and dedicated resource. To overcome these limitations, cost-effective private grid and appropriate algorithms are proposed. In this, each system contains two platforms such as grid and local platforms. The grid manager service running in local personal computer can act as grid resource. When the system is on, it is intimated to the Monitoring and Information System (MIS) and details are maintained in Resource Object Table (ROT). The MIS is responsible to select the resource where the file or the replica should be stored. The resource storage is done within virtual single private grid nodes using random object addressing to prevent stolen attack. If any grid resource goes down, then the resource ID will be removed from the ROT, and resource recovery is efficiently managed by the replicas. This random addressing technique makes the grid storage a single storage and the user views the entire grid network as a single system.
Abstract: Different knitted structures and knitted parameters play a vital role in the stretch and recovery management of compression sportswear in addition to the materials use to generate this stretch and recovery behavior of the fabric. The present work was planned to predict the different performance indicators of a compression sportswear fabric with some ground parameters i.e. base yarn stitch length (polyester as base yarn and spandex as plating yarn involve to make a compression fabric) and linear density of the spandex which is a key material of any sportswear fabric. The prediction models were generated by response surface method for performance indicators such as stretch & recovery percentage, compression generated by the garment on body, total elongation on application of high power force and load generated on certain percentage extension in fabric. Certain physical properties of the fabric were also modeled using these two parameters.
Abstract: Climate change remains a challenging matter for the human and the built environment in the 21st century, where the need to consider adaptation to climate change in the development process is paramount. However, there remains a lack of information regarding how we should prepare responses to this issue, such as through developing organized and sophisticated tools enabling the adaptation process. This study aims to build a systematic framework approach to investigate the potentials that Neighborhood Sustainability Assessment tools (NSA) might offer in enabling both the analysis of the emerging adaptive capacity to climate change. The analysis of the framework presented in this paper aims to discuss this issue in three main phases. The first part attempts to link sustainability and climate change, in the context of adaptive capacity. It is argued that in deciding to promote sustainability in the context of climate change, both the resilience and vulnerability processes become central. However, there is still a gap in the current literature regarding how the sustainable development process can respond to climate change. As well as how the resilience of practical strategies might be evaluated. It is suggested that the integration of the sustainability assessment processes with both the resilience thinking process, and vulnerability might provide important components for addressing the adaptive capacity to climate change. A critical review of existing literature is presented illustrating the current lack of work in this field, integrating these three concepts in the context of addressing the adaptive capacity to climate change. The second part aims to identify the most appropriate scale at which to address the built environment for the climate change adaptation. It is suggested that the neighborhood scale can be considered as more suitable than either the building or urban scales. It then presents the example of NSAs, and discusses the need to explore their potential role in promoting the adaptive capacity to climate change. The third part of the framework presents a comparison among three example NSAs, BREEAM Communities, LEED-ND, and CASBEE-UD. These three tools have been selected as the most developed and comprehensive assessment tools that are currently available for the neighborhood scale. This study concludes that NSAs are likely to present the basis for an organized framework to address the practical process for analyzing and yet promoting Adaptive Capacity to Climate Change. It is further argued that vulnerability (exposure & sensitivity) and resilience (Interdependence & Recovery) form essential aspects to be addressed in the future assessment of NSA’s capability to adapt to both short and long term climate change impacts. Finally, it is acknowledged that further work is now required to understand impact assessment in terms of the range of physical sectors (Water, Energy, Transportation, Building, Land Use and Ecosystems), Actor and stakeholder engagement as well as a detailed evaluation of the NSA indicators, together with a barriers diagnosis process.
Abstract: Heavy metals have a damaging impact for the environment, animals and humans due to their extreme toxicity and removing them from wastewaters is a very important and interesting task in the field of water pollution control. Biosorption is a relatively new method for treatment of wastewaters and recovery of heavy metals. In this study, a continuous fixed bed study was carried out by using Bacillus thuringiensis as a biosorbent for the removal of Cu and Mn ions from Sarcheshmeh Acid Mine Drainage (AMD). The effect of operating parameters such as flow rate and bed height on the sorption characteristics of B. thuringiensis was investigated at pH 6.0 for each metal ion. The experimental results showed that the breakthrough time decreased with increasing flow rate and decreasing bed height. The data also indicated that the equilibrium uptake of both metals increased with decreasing flow rate and increasing bed height. BDST, Thomas, and Yoon–Nelson models were applied to experimental data to predict the breakthrough curves. All models were found suitable for describing the whole dynamic behavior of the column with respect to flow rate and bed height. In order to regenerate the adsorbent, an elution step was carried out with 1 M HCl and five adsorption-desorption cycles were carried out in continuous manner.
Abstract: Experiments were performed to investigate the effects of roughness on the reattachment and redevelopment regions over a 12 mm forward facing step (FFS) in an open channel flow. The experiments were performed over an upstream smooth wall and a smooth FFS, an upstream wall coated with sandpaper 36 grit and a smooth FFS and an upstream rough wall produced from sandpaper 36 grit and a FFS coated with sandpaper 36 grit. To investigate only the wall roughness effects, Reynolds number, Froude number, aspect ratio and blockage ratio were kept constant. Upstream profiles showed reduced streamwise mean velocities close to the rough wall compared to the smooth wall, but the turbulence level was increased by upstream wall roughness. The reattachment length for the smooth-smooth wall experiment was 1.78h; however, when it is replaced with rough-smooth wall the reattachment length decreased to 1.53h. It was observed that the upstream roughness increased the physical size of contours of maximum turbulence level; however, the downstream roughness decreased both the size and magnitude of contours in the vicinity of the leading edge of the step. Quadrant analysis was performed to investigate the dominant Reynolds shear stress contribution in the recirculation region. The Reynolds shear stress and turbulent kinetic energy profiles after the reattachment showed slower recovery compared to the streamwise mean velocity, however all the profiles fairly collapse on their corresponding upstream profiles at x/h = 60. It was concluded that to obtain a complete collapse several more streamwise distances would be required.
Abstract: Sclareolide is made from sclareol by oxidiative synthesis and subsequent crystallization, while the crystallization mother liquor still contains 15%~30%wt of sclareolide to be reclaimed. With the reaction material of sclareol is provided as plant extract, many sorts of complex impurities exist in the mother liquor. Due to the difficulty in recycling sclareolide after solvent recovery, it is common practice for the factories to discard the mother liquor, which not only results in loss of sclareolide, but also contributes extra environmental burden. In this paper, a process based on adsorption and elution has been presented for recycling of sclareolide from mother liquor. After pretreatment of the crystallization mother liquor by HZ-845 resin to remove parts of impurities, sclareolide is adsorbed by HZ-816 resin. The HZ-816 resin loaded with sclareolide is then eluted by elution solvent. Finally, the eluent containing sclareolide is concentrated and fed into the crystallization step in the process. By adoption of the recycle from mother liquor, total yield of sclareolide increases from 86% to 90% with a stable purity of the final sclareolide products maintained.
Abstract: An Energetic and exergetic analysis is conducted on a
Steam Turbine Power Plant of an existing Phosphoric Acid Factory.
The heat recovery systems used in different parts of the plant are also
considered in the analysis. Mass, thermal and exergy balances are
established on the main compounds of the factory. A numerical code
is established using EES software to perform the calculations
required for the thermal and exergy plant analysis. The effects of the
key operating parameters such as steam pressure and temperature,
mass flow rate as well as seawater temperature, on the cycle
performances are investigated. A maximum Exergy Loss Rate of about 72% is obtained for the
melters, followed by the condensers, heat exchangers and the pumps.
The heat exchangers used in the phosphoric acid unit present
exergetic efficiencies around 33% while 60% to 72% are obtained for
steam turbines and blower. For the explored ranges of HP steam
temperature and pressure, the exergy efficiencies of steam turbine
generators STGI and STGII increase of about 2.5% and 5.4%
respectively. In the same way optimum HP steam flow rate values,
leading to the maximum exergy efficiencies are defined.
Abstract: Fresh concrete has one of dynamic properties known
as slump. Slump of concrete is design to compatible with placing
method. Due to hydration reaction of cement, the slump of concrete
is loss through time. Therefore, delayed concrete probably get reject
because slump is unacceptable. In order to recover the slump of
delayed concrete the second dose of superplasticizer (naphthalene
based type F) is added into the system, the slump recovery can be
done as long as the concrete is not setting. By adding superplasticizer
as solution for recover unusable slump loss concrete may affects
other concrete properties. Therefore, this paper was observed setting
times and compressive strength of concrete after being re-dose with
chemical admixture type F (superplasticizer, naphthalene based) for
slump recovery. The concrete used in this study was fly ash concrete
with fly ash replacement of 0%, 30% and 50% respectively. Concrete
mix designed for test specimen was prepared with paste content (ratio
of volume of cement to volume of void in the aggregate) of 1.2 and
1.3, water-to-binder ratio (w/b) range of 0.3 to 0.58, initial dose of
superplasticizer (SP) range from 0.5 to 1.6%. The setting times of
concrete were tested both before and after re-dosed with different
amount of second dose and time of dosing. The research was
concluded that addition of second dose of superplasticizer would
increase both initial and final setting times accordingly to dosage of
addition. As for fly ash concrete, the prolongation effect was higher
as the replacement of fly ash increase. The prolongation effect can
reach up to maximum about 4 hours. In case of compressive strength,
the re-dosed concrete has strength fluctuation within acceptable range
of ±10%.
Abstract: This paper aimed to introduce the solution of concrete
slump recovery using chemical admixture type-F (superplasticizer,
naphthalene base) to the practice in order to solve unusable concrete
problem due to concrete loss its slump, especially for those tropical
countries that have faster slump loss rate. In the other hand, randomly
adding superplasticizer into concrete can cause concrete to segregate.
Therefore, this paper also develops the estimation model used to
calculate amount of second dose of superplasticizer need for concrete
slump recovery. Fresh properties of ordinary Portland cement
concrete with volumetric ratio of paste to void between aggregate
(paste content) of 1.1-1.3 with water-cement ratio zone of 0.30 to
0.67 and initial superplasticizer (naphthalene base) of 0.25%-1.6%
were tested for initial slump and slump loss for every 30 minutes for
one and half hour by slump cone test. Those concretes with slump
loss range from 10% to 90% were re-dosed and successfully
recovered back to its initial slump. Slump after re-dosed was tested
by slump cone test. From the result, it has been concluded that, slump
loss was slower for those mix with high initial dose of
superplasticizer due to addition of superplasticizer will disturb
cement hydration. The required second dose of superplasticizer was
affected by two major parameters, which were water-cement ratio
and paste content, where lower water-cement ratio and paste content
cause an increase in require second dose of superplasticizer. The
amount of second dose of superplasticizer is higher as the solid
content within the system is increase, solid can be either from cement
particles or aggregate. The data was analyzed to form an equation use
to estimate the amount of second dosage requirement of
superplasticizer to recovery slump to its original.
Abstract: Ensuring of continuity of business is basic strategy of
every company. Continuity of organization activities includes
comprehensive procedures that help in solving unexpected situations
of natural and anthropogenic character (for example flood, blaze,
economic situations). Planning of continuity operations is a process
that helps identify critical processes and implement plans for the
security and recovery of key processes. The aim of this article is to
demonstrate application of system approach to managing business
continuity called business continuity management systems in military
issues. This article describes the life cycle of business continuity
management which is based on the established cycle PDCA (Plan-
Do-Check-Act). After this is carried out by activities which are
making by University of Defence during activation of forces and
means of the integrated rescue system in case of emergencies -
accidents at a nuclear power plant in Czech Republic. Activities of
various stages of deployment earmarked forces and resources are
managed and evaluated by using MCMS application (Military
Continuity Management System).
Abstract: Anaerobic digestion is a well-known technique for
sustainable energy recovery from sewage sludge. However, sewage
sludge digestion is restricted due to certain factors. Pre-treatment
methods have been established in various publications as a promising
technique to improve the digestibility of the sewage sludge and to
enhance the biogas generated which can be used for energy recovery.
In this study, continuous flow microwave (MW) pre-treatment with
different intensities were compared by using 5 L semi-continuous
digesters at a hydraulic retention time of 27 days. We focused on the
effects of MW at different intensities on the sludge solubilization,
sludge digestibility, and biogas production of the untreated and MW
pre-treated sludge. The MW pre-treatment demonstrated an increase
in the ratio of soluble chemical oxygen demand to total chemical
oxygen demand (sCOD/tCOD) and volatile fatty acid (VFA)
concentration. Besides that, the total volatile solid (TVS) removal
efficiency and tCOD removal efficiency also increased during the
digestion of the MW pre-treated sewage sludge compared to the
untreated sewage sludge. Furthermore, the biogas yield also
subsequently increases due to the pre-treatment effect. A higher MW
power level and irradiation time generally enhanced the biogas
generation which has potential for sustainable energy recovery from
sewage treatment plant. However, the net energy balance tabulation
shows that the MW pre-treatment leads to negative net energy production.
Abstract: Recovering resources from water purification sludge
(WPS) have been gradually stipulated in environmental protection
laws and regulations in many nations. Hence, reusing the WPS is
becoming an important topic, and recovering alum from WPS is one of
the many practical alternatives. Most previous research efforts have
been conducted on studying the amphoteric characteristic of aluminum
hydroxide for investigating the optimum pH range to dissolve the
Al(III) species from WPS, but it has been lack of reaction kinetics or
mechanisms related discussion. Therefore, in this investigation, water
purification sludge (WPS) solution was broken by ultrasound to make
particle size of reactants smaller, specific surface area larger.
According to the reaction kinetics, these phenomena let the dissolved
aluminum salt quantity increased and the reaction rate go faster.
Abstract: High Performance Liquid Chromatography (HPLC)
method was developed and validated for simultaneous estimation of
6-Gingerol(6G) and 6-Shogaol(6S) in joint pain relief gel containing
ginger extract. The chromatographic separation was achieved by
using C18 column, 150 x 4.6mm i.d., 5μ Luna, mobile phase
containing acetonitrile and water (gradient elution). The flow rate
was 1.0 ml/min and the absorbance was monitored at 282 nm. The
proposed method was validated in terms of the analytical parameters
such as specificity, accuracy, precision, linearity, range, limit of
detection (LOD), limit of quantification (LOQ), and determined
based on the International Conference on Harmonization (ICH)
guidelines. The linearity ranges of 6G and 6S were obtained over 20-
60 and 6-18 μg/ml respectively. Good linearity was observed over the
above-mentioned range with linear regression equation Y= 11016x-
23778 for 6G and Y = 19276x-19604 for 6S (x is concentration of
analytes in μg/ml and Y is peak area). The value of correlation
coefficient was found to be 0.9994 for both markers. The limit of
detection (LOD) and limit of quantification (LOQ) for 6G were
0.8567 and 2.8555 μg/ml and for 6S were 0.3672 and 1.2238 μg/ml
respectively. The recovery range for 6G and 6S were found to be
91.57 to 102.36 % and 84.73 to 92.85 % for all three spiked levels.
The RSD values from repeated extractions for 6G and 6S were 3.43
and 3.09% respectively. The validation of developed method on
precision, accuracy, specificity, linearity, and range were also
performed with well-accepted results.
Abstract: In Algeria, the most impressive and most known
prehistoric art is the painted or engraved rock art which is present
with abundance in several regions. The existence of rock art in Great
Kabylia region has been known for over sixty years. The main purpose of this research is to show the dangers facing
these rock paintings and engravings and what are the arrangements
for their protection and recovery. As every vestige destroyed is a part of the world's memory which
disappears, some steps have to be taken in order to protect these
historical and archaeological heritages.
Abstract: The ferrites ZnFe2O4, CdFe2O4 and CuFe2O4 are
synthesized in laboratory conditions using ceramic technology. Their
homogeneity and structure are proven by X-Ray diffraction analysis
and Mössbauer spectroscopy. The synthesized ferrites are subjected
to strong acid and high temperature leaching with solutions of H2SO4,
HCl and HNO3. The results indicate that the highest degree of
leaching of Zn, Cd and Cu from the ferrites is achieved by use of
HCl. The charging of five zinc sulfide concentrates was optimized using
the criterion of minimal amount of zinc ferrite produced when
roasting the concentrates in a fluidized bed. The results obtained are
interpreted in terms of the hydrometallurgical zinc production and
maximum recovery of zinc, copper and cadmium from initial zinc
concentrates after their roasting.
Abstract: The first layer of defense against data loss is the backup
data. This paper implements an agent-based network backup system
used the backup, server-storage and server-backup agent these
tripartite construction, and the snapshot and hierarchical index are
used in the NSBS. It realizes the control command and data flow
separation, balances the system load, thereby improving efficiency of
the system backup and recovery. The test results show the agent-based
network backup system can effectively improve the task-based
concurrency, reasonably allocate network bandwidth, the system
backup performance loss costs smaller and improves data recovery
efficiency by 20%.
Abstract: It has been known that a characteristic
Burst-Suppression (BS) pattern appears in EEG during the early
recovery period following Cardiac Arrest (CA). Here, to explore the
relationship between cortical and subcortical neural activities
underlying BS, extracellular activity in the parietal cortex and the
centromedian nucleus of the thalamus and extradural EEG were
recorded in a rodent CA model. During the BS, the cortical firing rate
is extraordinarily high, and that bursts in EEG correlate to dense spikes
in cortical neurons. Newly observed phenomena are that 1) thalamic
activity reemerges earlier than cortical activity following CA, and 2)
the correlation coefficient of cortical and thalamic activities rises
during BS period. These results would help elucidate the underlying
mechanism of brain recovery after CA injury.
Abstract: Biomass treatment through densification is very suitable and helpful technology before its effective energy recovery. Densification process of biomass is significantly influenced by various technological and material variables, which are ultimately reflected on the final solid biofuels quality. The paper deals with the experimental research of the relationship between technological and material variables during densification of fast-growing trees, roundly fast-growing willows. The main goal of presented experimental research is to determine the relationship between compression pressure and raw material particle size from a final briquettes density point of view. Experimental research was realized by single-axis densification. The impact of particle size with interaction of compression pressure and stabilization time on the quality properties of briquettes was determined. These variables interaction affects the final solid biofuels (briquettes) quality. From briquettes production point of view and from densification machines constructions point of view is very important to know about mutual interaction of these variables on final briquettes quality. The experimental findings presented here are showing the importance of mentioned variables during the densification process.