Abstract: Geopolymer mortar is produced by alkaline activation of pozzolanic materials such as fly ground granulated blast-furnace slag (GGBFS) and fly ash (FA). Its unique reaction pathway facilitates rapid strength development in comparison with hydration of ordinary Portland cement (OPC). Geopolymer can be fabricated using various types and dosages of alkali-activator, which effectively gives a wider control over the performance of the final product. The present study investigates the effect of types of precursors and curing conditions on the fresh state and strength development characteristics of geopolymers, thereby comparatively exploring the effect of precursors from various sources of origin. The obtained result showed that the setting time and strength development of the specimens with the identical mix proportion but different precursors displayed significant variations.
Abstract: In the present work, metakaolin-based geopolymer including different polymer admixtures was studied. Different types of commercial polymer admixtures VINNAPAS® and polyethylene glycol of different relative molecular weight were used as polymer admixtures. The main objective of this work is to investigate the influence of different types of admixtures on the properties of metakaolin-based geopolymer mortars considering their different dosage. Mechanical properties, such as flexural and compressive strength were experimentally determined. Also, study of the microstructure of selected specimens by using a scanning electron microscope was performed. The results showed that the specimen with addition of 1.5% of VINNAPAS® 7016 F and 10% of polyethylene glycol 400 achieved maximum mechanical properties.
Abstract: Geopolymer (cement-free) concrete is the most promising green alternative to ordinary Portland cement concrete and other cementitious materials. While a range of different geopolymer concretes have been produced, a common feature of these concretes is heat curing treatment which is essential in order to provide sufficient mechanical properties in the early age. However, there are several practical issues with the application of heat curing in large-scale structures. The purpose of this study is to develop cement-free concrete without heat curing treatment. Experimental investigations were carried out in two phases. In the first phase (Phase A), the optimum content of water, polycarboxylate based superplasticizer contents and potassium silicate activator in the mix was determined. In the second stage (Phase B), the effect of ground granulated blast furnace slag (GGBFS) incorporation on the compressive strength of fly ash (FA) and Slag based geopolymer mixtures was evaluated. Setting time and workability were also conducted alongside with compressive tests. The results showed that as the slag content was increased the setting time was reduced while the compressive strength was improved. The obtained compressive strength was in the range of 40-50 MPa for 50% slag replacement mixtures. Furthermore, the results indicated that increment of water and superplasticizer content resulted to retarding of the setting time and slight reduction of the compressive strength. The compressive strength of the examined mixes was considerably increased as potassium silicate content was increased.
Abstract: Fly ash (FA) thanks to the significant presence of SiO2
and Al2O3 as the main components is a potential raw material for
geopolymers production. Mechanical activation is a method for
improving FA reactivity and also the porosity of final mixture; those
parameters can be analysed through sorption properties. They have
direct impact on the durability of fly ash based geopolymer mortars.
In the paper, effect of FA fineness on sorption properties of
geopolymers based on sodium silicate, as well as relationship
between fly ash fineness and apparent density, compressive and
flexural strength of geopolymers are presented. The best results in the
evaluated area reached the sample H1, which contents the highest
portion of particle under 20μm (100% of GFA). The interdependence
of individual tested properties was confirmed for geopolymer
mixtures corresponding to those in the cement based mixtures: higher
is portion of fine particles < 20μm, higher is strength, density and
lower are sorption properties. The compressive strength as well as
sorption parameters of the geopolymer can be reasonably controlled
by grinding process and also ensured by the higher share of fine
particle (to 20μm) in total mass of the material.
Abstract: In the present work, fly ash geopolymer based
composites including polyester (PES) waste were studied. Specimens
of three compositions were prepared: (a) fly ash geopolymer with 5%
PES waste; (b) fly ash geopolymer mortar with 5% PES waste; (c) fly
ash geopolymer mortar with 6.25% PES waste. Compressive and
bending strength measurements, water absorption test and
determination of thermal conductivity coefficient were performed.
The results showed that the addition of sand in a mixture of
geopolymer with 5% PES content led to higher compressive strength,
while it increased water absorption and reduced thermal conductivity
coefficient. The increase of PES addition in geopolymer mortars
resulted in a more dense structure, indicated by the increase of
strength and thermal conductivity and the decrease of water
absorption.
Abstract: Despite of the preponderant role played by cement among the construction materials, it is today considered as a material destructing the environment due to the large quantities of carbon dioxide exhausted during its manufacture. Besides, global warming is now recognized worldwide as the new threat to the humankind against which advanced countries are investigating measures to reduce the current amount of exhausted gases to the half by 2050. Accordingly, efforts to reduce green gases are exerted in all industrial fields. Especially, the cement industry strives to reduce the consumption of cement through the development of alkali-activated geopolymer mortars using industrial byproducts like bottom ash. This study intends to gather basic data on the flowability and strength development characteristics of alkali-activated geopolymer mortar by examining its FT-IT features with respect to the effects and strength of the alkali-activator in order to develop bottom ash-based alkali-activated geopolymer mortar. The results show that the 35:65 mass ratio of sodium hydroxide to sodium silicate is appropriate and that a molarity of 9M for sodium hydroxide is advantageous. The ratio of the alkali-activators to bottom ash is seen to have poor effect on the strength. Moreover, the FT-IR analysis reveals that larger improvement of the strength shifts the peak from 1060 cm–1 (T-O, T=Si or Al) toward shorter wavenumber.
Abstract: This paper presents the findings of an
experimental investigation to study the effect of alkali content
in geopolymer mortar specimens exposed to sulphuric acid.
Geopolymer mortar specimens were manufactured from Class F fly
ash by activation with a mixture of sodium hydroxide and sodium
silicate solution containing 5% to 8% Na2O. Durability of specimens
were assessed by immersing them in 10% sulphuric acid solution and
periodically monitoring surface deterioration and depth of
dealkalization, changes in weight and residual compressive strength
over a period of 24 weeks. Microstructural changes in the specimens
were studied with Scanning electron microscopy (SEM) and EDAX.
Alkali content in the activator solution significantly affects the
durability of fly ash based geopolymer mortars in sulphuric acid.
Specimens manufactured with higher alkali content performed better
than those manufactured with lower alkali content. After 24 weeks in
sulphuric acid, specimen with 8% alkali still recorded a residual
strength as high as 55%.