Abstract: Here, we have shown the reaction of [Cr(ArN(CH2)3NAr)2Cl2] (1) where (Ar = 2,6-Pri
2C6H3) and in presence of NaCp (2) (Cp= C5H5 = cyclopentadien), with a center
coordination η5 interaction between Cp as co-ligand and chromium
metal center, for optimization we used density functional theory
(DFT), under methods, explicitly including electrons correlations, for
the final calculations as MB3LYP (Becke) (Lee–Yang–Parr) level of
theory we used to obtain more exact results. This complex was
calculated as electronic energy for molecular system, because the
calculation accounting all electrons correlations interactions. The
optimised of [Cr(ArN(CH2)3NAr)2(η5-Cp)] (Ar = 2,6-Pri2C6H3 and Cp = C5H5) was found to be thermally stable. By using Dewar-Chatt-Duncanson model, as a basis of the molecular orbital (MO) analysis
and showed the highest occupied molecular orbital (HOMO) and
lowest occupied molecular orbital LUMO.
Abstract: The ferrites ZnFe2O4, CdFe2O4 and CuFe2O4 are
synthesized in laboratory conditions using ceramic technology. Their
homogeneity and structure are proven by X-Ray diffraction analysis
and Mössbauer spectroscopy. The synthesized ferrites are subjected
to strong acid and high temperature leaching with solutions of H2SO4,
HCl and HNO3. The results indicate that the highest degree of
leaching of Zn, Cd and Cu from the ferrites is achieved by use of
HCl. The charging of five zinc sulfide concentrates was optimized using
the criterion of minimal amount of zinc ferrite produced when
roasting the concentrates in a fluidized bed. The results obtained are
interpreted in terms of the hydrometallurgical zinc production and
maximum recovery of zinc, copper and cadmium from initial zinc
concentrates after their roasting.
Abstract: The present explanatory study concerns with the
relation between Diabetes Mellitus and Food Balance in the Kingdom
of Saudi Arabia during 2005-2010, using published data. Results illustrated that Saudi citizen daily protein consumption
(DPC) during 2005-2007 (g/capita/day) is higher than the average
global consumption level of protein with 15.27%, daily fat
consumption (DFC) with 24.56% and daily energy consumption
(DEC) with 16.93% and increases than recommended level by
International Nutrition Organizations (INO) with 56% for protein,
60.49% for fat and 27.37% for energy. On the other hand, DPC per
capita in Saudi Arabia decreased during the period 2008-2010 from
88.3 to 82.36 gram/ day. Moreover, DFC per capita in Saudi Arabia
decreased during the period 2008-2010 from 3247.90 to 3176.43
Cal/capita/ day, and daily energy consumption (DEC) of Saudi
citizen increases than world consumption with 16.93%, whereas
increases with 27.37% than INO. Despite this, DPC, DFC and DEC
per capita in Saudi Arabia still higher than world mean. On the other
side, results illustrated that the number of diabetic patients in Saudi
Arabia during the same period (2005-2010). The curve of diabetic
patient’s number in Saudi Arabia during 2005-2010 is regular
ascending with increasing level ranged between 7.10% in 2005 and
12.44% in 2010. It is essential to devise Saudi National programs to educate the
public about the relation of food balances and diabetes so it could be
avoided, and provide citizens with healthy dietary balances tables.
Abstract: Rapid population growth, urbanization and
industrialization are known as the most important factors of
environment problems. Elimination and management of solid wastes
are also within the most important environment problems. One of the
main problems in solid waste management is the selection of the best
site for elimination of solid wastes. Lately, Geographical Information
System (GIS) has been used for easing selection of landfill area. GIS
has the ability of imitating necessary economic, environmental and
political limitations. They play an important role for the site selection
of landfill area as a decision support tool. In this study; map layers will be studied for minimum effect of
environmental, social and cultural factors and maximum effect for
engineering/economic factors for site selection of landfill areas and
using GIS for a decision support mechanism in solid waste landfill
areas site selection will be presented in Aksaray/Turkey city,
Güzelyurt district practice.
Abstract: Evolution strategy (ES) is a well-known instance of evolutionary algorithms, and there have been many studies on ES. In this paper, the author proposes an extended ES for solving fuzzy-valued optimization problems. In the proposed ES, genotype values are not real numbers but fuzzy numbers. Evolutionary processes in the ES are extended so that it can handle genotype instances with fuzzy numbers. In this study, the proposed method is experimentally applied to the evolution of neural networks with fuzzy weights and biases. Results reveal that fuzzy neural networks evolved using the proposed ES with fuzzy genotype values can model hidden target fuzzy functions even though no training data are explicitly provided. Next, the proposed method is evaluated in terms of variations in specifying fuzzy numbers as genotype values. One of the mostly adopted fuzzy numbers is a symmetric triangular one that can be specified by its lower and upper bounds (LU) or its center and width (CW). Experimental results revealed that the LU model contributed better to the fuzzy ES than the CW model, which indicates that the LU model should be adopted in future applications of the proposed method.
Abstract: A teeming set of doctors that graduated from various
universities within and outside Nigeria with the hope of practicing in
the country, has their hope shattered because of poor financing, lack
of medical equipments and a very weak healthcare systems. Such
hydra headed challenges, allows room for quackery which
increasingly contributes to the cause of mortality in Nigeria. With a
view of reversing the challenges of healthcare delivery and financing
in Nigeria, African Health Market for Equity (AHME), a project
funded by the Bill and Melinda Gates foundation [With contribution
from Department For International Development (DFID)] and
currently implemented in three African Countries (Nigeria, Kenya
and Ghana) over a Five (5) year period supports the healthcare sector
via Medical credit fund (MCF). The study examines the impact of
credit policy and medical credit funding on Nigerian health market.
Ordinary least square analysis, correlation and granger causality tests
were employed to measure the extent to which the Nigerian
healthcare market has been influenced. Medical credit fund
significantly and positively influenced average monthly turnover of
private healthcare providers and Commercial bank’s lending rate had
a weak relationship with access to credit/approved loans (13.46%).
The programme has so far made 13.91% progress, which is very
poor, considering the minimum targeted private health care providers
(437.6) and expected number of loan approvals (180.4) for the two
years. Medical credit policy in Nigeria should be revised to include
private healthcare providers in rural area for more positive impact
and increased returns. Good brand advert and sensitization of the
programme to stakeholders and health pressure group, and an
extension of the programme beyond five years is necessary to better
address the issues raised in the study.
Abstract: The effect of carbon nanofibers (CNFs) on the
electrical properties of Poly(vinylidene fluoride-hexafluoropropylene)
(P(VdF-HFP)) based gel polymer electrolytes has been investigated
in the present work. The length and diameter ranges of CNFs used in
the present work are 5-50 μm and 200-600 nm respectively. The
nanocomposite gel polymer electrolytes have been synthesized by
solution casting technique with varying CNFs content in terms of
weight percentage. Electrochemical impedance analysis demonstrates
that the reinforcement of carbon nanofibers significantly enhances the
ionic conductivity of the polymer electrolyte. The decrease of
crystallinity of P(VdF-HFP) due the addition of CNFs has been
confirmed by X-ray diffraction (XRD). The interaction of CNFs with
various constituents of nanocomposite gel polymer electrolytes has
been assessed by Fourier Transform Infrared (FTIR) spectroscopy.
Moreover CNFs added gel polymer electrolytes offer superior
thermal stability as compared to that of CNFs free electrolytes as
confirmed by Thermogravimetric analysis (TGA).
Abstract: As per the statistical data, the Doubly-fed Induction
Generator (DFIG) based wind turbine with variable speed and
variable pitch control is the most common wind turbine in the
growing wind market. This machine is usually used on the grid
connected wind energy conversion system to satisfy grid code
requirements such as grid stability, Fault Ride Through (FRT), power
quality improvement, grid synchronization and power control etc.
Though the requirements are not fulfilled directly by the machine, the
control strategy is used in both the stator as well as rotor side along
with power electronic converters to fulfil the requirements stated
above. To satisfy the grid code requirements of wind turbine, usually
grid side converter is playing a major role. So in order to improve the
operation capacity of wind turbine under critical situation, the
intensive study of both machine side converter control and grid side
converter control is necessary In this paper DFIG is modeled using
power components as variables and the performance of the DFIG
system is analysed under grid voltage fluctuations. The voltage
fluctuations are made by lowering and raising the voltage values in
the utility grid intentionally for the purpose of simulation keeping in
view of different grid disturbances.
Abstract: Leishmaniasis is the collective name for a number of
diseases caused by protozoan flagellates of the genus Leishmania,
which is transmitted by Phlebotomine sandfly, the disease has diverse
clinical manifestations and found in many areas of the world,
particularly in Africa, Latin America, South and Central Asia, the
Mediterranean basin and the Middle East. This study was done to
assess primary health care physicians’ knowledge (PHP) and attitude
about leishmaniasis and to assess awareness of local inhabitants
about the disease and its vector in four areas in west Alexandria,
Egypt. It is a cross sectional survey that was conducted in four PHC
units in west Alexandria. All physicians currently working in these
units during the study period were invited to participate in the study;
only 20 PHP completed the questionnaire. 60 local inhabitants were
selected randomly from the four areas of the study, 15 from each
area; Data was collected through two different specially designed
questionnaires. Results showed that 11 (55%) percent of the
physicians had satisfactory knowledge; they answered more than 9
(60%) questions out of a total 14 questions about leishmaniasis and
sandfly. On the other hand when attitude of the primary health care
physicians about leishmaniasis was measured, results showed that 17
(85%) had good attitude and 3 (15%) had poor attitude. The second
questionnaire showed that the awareness of local inhabitants about
leishmaniasis and sandfly as a vector of the disease is poor and needs
to be corrected. (90%) of the interviewed inhabitants had not heard
about leishmaniasis, Only 3 (5%) of them said they know sandfly and
its role in transmission of leishmaniasis. Thus we conclude that
knowledge and attitudes of physicians are acceptable. However, there
is, room for improvement and could be done through formal training
courses and distribution of guidelines. In addition to raising the
awareness of primary health care physicians about the importance of
early detection and notification of cases of leishmaniasis, health
education for raising awareness of the public regarding the vector and
the disease is necessary because related studies have demonstrated
that for inhabitants to take enough protective measures against the
vector, they should perceive that it is responsible for causing a
disease.
Abstract: Constructed Wetland (CW) is a reasonable method to
treat wastewater. Current study was carried out to co-treat landfill
leachate and domestic wastewater using a CW system. Typha
domingensis was transplanted to CW, which encloses two substrate
layers of adsorbents named ZELIAC and zeolite. Response surface
methodology and central composite design were employed to
evaluate experimental data. Contact time (h) and leachate-towastewater
mixing ratio (%; v/v) were selected as independent
factors. Phenols and manganese removal were selected as dependent
responses. At optimum contact time (48.7 h) and leachate-towastewater
mixing ratio (20.0%), removal efficiencies of phenols and
manganese removal efficiencies were 90.5%, and 89.4%,
respectively.
Abstract: This paper presents a power control for a Doubly Fed
Induction Generator (DFIG) using in Wind Energy Conversion
System (WECS) connected to the grid. The proposed control strategy
employs two nonlinear controllers, Backstipping (BSC) and slidingmode
controller (SMC) scheme to directly calculate the required
rotor control voltage so as to eliminate the instantaneous errors of
active and reactive powers. In this paper the advantages of BSC and
SMC are presented, the performance and robustness of this two
controller’s strategy are compared between them. First, we present a
model of wind turbine and DFIG machine, then a synthesis of the
controllers and their application in the DFIG power control.
Simulation results on a 1.5MW grid-connected DFIG system are
provided by MATLAB/Simulink.
Abstract: The enormous amount of information stored on the
web increases from one day to the next, exposing the web currently
faced with the inevitable difficulties of research pertinent information
that users really want. The problem today is not limited to expanding
the size of the information highways, but to design a system for
intelligent search. The vast majority of this information is stored in
relational databases, which in turn represent a backend for managing
RDF data of the semantic web. This problem has motivated us to
write this paper in order to establish an effective approach to support
semantic transformation algorithm for SPARQL queries to SQL
queries, more precisely SPARQL SELECT queries; by adopting this
method, the relational database can be questioned easily with
SPARQL queries maintaining the same performance.
Abstract: In this paper, we consider a cognitive relay network
(CRN) in which the primary receiver (PR) is protected by peak
transmit power ¯PST and/or peak interference power Q constraints.
In addition, the interference effect from the primary transmitter (PT)
is considered to show its impact on the performance of the CRN. We
investigate the outage probability (OP) and outage capacity (OC) of
the CRN by deriving closed-form expressions over Rayleigh fading
channel. Results show that both the OP and OC improve by increasing
the cooperative relay nodes as well as when the PT is far away from
the SR.
Abstract: In this study, nuclear magnetic resonance
spectroscopy and nuclear quadrupole resonance spectroscopy
parameters of 14N (Nitrogen in imidazole ring) in N–H…O hydrogen
bonding for Histidine hydrochloride monohydrate were calculated via
density functional theory. We considered a five-molecule model
system of Histidine hydrochloride monohydrate. Also we examined
the trends of environmental effect on hydrogen bonds as well as
cooperativity. The functional used in this research is M06-2X which
is a good functional and the obtained results has shown good
agreement with experimental data. This functional was applied to
calculate the NMR and NQR parameters. Some correlations among
NBO parameters, NMR and NQR parameters have been studied
which have shown the existence of strong correlations among them.
Furthermore, the geometry optimization has been performed using
M062X/6-31++G(d,p) method. In addition, in order to study
cooperativity and changes in structural parameters, along with
increase in cluster size, natural bond orbitals have been employed.
Abstract: Artificial neural networks have gained a lot of interest
as empirical models for their powerful representational capacity,
multi input and output mapping characteristics. In fact, most feedforward
networks with nonlinear nodal functions have been proved to
be universal approximates. In this paper, we propose a new
supervised method for color image classification based on selforganizing
feature maps (SOFM). This algorithm is based on
competitive learning. The method partitions the input space using
self-organizing feature maps to introduce the concept of local
neighborhoods. Our image classification system entered into RGB
image. Experiments with simulated data showed that separability of
classes increased when increasing training time. In additional, the
result shows proposed algorithms are effective for color image
classification.
Abstract: The goal of this experiment is to evaluate the
effectiveness of different leachate pre-treatment options in terms of
COD and ammonia removal. This research focused on the evaluation
of physical-chemical methods for pre-treatment of leachate that
would be effective and rapid in order to satisfy the requirements of
the sewer discharge by-laws. The four pre-treatment options
evaluated were: air stripping, chemical coagulation, electrocoagulation
and advanced oxidation with sodium ferrate. Chemical
coagulation reported the best COD removal rate at 43%, compared to
18% for both air stripping and electro-coagulation, and 20% for
oxidation with sodium ferrate. On the other hand, air stripping was
far superior to the other treatment options in terms of ammonia
removal with 86%. Oxidation with sodium ferrate reached only 16%,
while chemical coagulation and electro-coagulation removed less
than 10%. When combined, air stripping and chemical coagulation
removed up to 50% COD and 85% ammonia.
Abstract: Due to the resultant leachate from waste
decomposition in landfills has polluter potential hundred times
greater than domestic sewage, this is considered a problem related to
the depreciation of environment requiring pre-disposal treatment.In
seeking to improve this situation, this project proposes the treatment
of landfill leachate using natural fibers intercropped with advanced
oxidation processes. The selected natural fibers were palm, coconut
and banana fiber.These materials give sustainability to the project
because, besides having adsorbent capacity, are often part of waste
discarded. The study was conducted in laboratory scale.In trials, the
effluents were characterized as Chemical Oxygen Demand (COD),
Turbidity and Color. The results indicate that is technically
promising since that there were extremely oxidative conditions, the
use of certain natural fibers in the reduction of pollutants in leachate
have been obtained results of COD removals between 67.9% and
90.9%, Turbidity between 88.0% and 99.7% and Color between
67.4% and 90.4%.The expectation generated is to continue evaluating
the association of efficiency of other natural fibers with other landfill
leachate treatment processes.
Abstract: Implementation of advanced technologies requires
sophisticated instruments that deal with the operation, control,
restoration and protection of rapidly growing power system network
under normal and abnormal conditions. Presently, the applications of
Phasor Measurement Unit (PMU) are widely found in real time
operation, monitoring, controlling and analysis of power system
network as it eliminates the various limitations of supervisory control
and data acquisition system (SCADA) conventionally used in power
system. The use of PMU data is very rapidly increasing its
importance for online and offline analysis. Wide area measurement
system (WAMS) is developed as new technology by use of multiple
PMUs in power system. The present paper proposes a model of
Matlab based PMU using Discrete Fourier Transform (DFT)
algorithm and evaluation of its operation under different
contingencies. In this paper, PMU based two bus system having
WAMS network is presented as a case study.
Abstract: In this paper, we investigated the athermal pressure
behavior of the structural and elastic properties of scheelite BaWO4
phase up to 7 GPa using the ab initio pseudo-potential method. The
calculated lattice parameters pressure relation have been compared
with the experimental values and found to be in good agreement with
these results. Moreover, we present for the first time the investigation
of the elastic properties of this compound using the density functional
perturbation theory (DFPT). It is shown that this phase is
mechanically stable up to 7 GPa after analyzing the calculated elastic
constants. Other relevant quantities such as bulk modulus, pressure
derivative of bulk modulus, shear modulus; Young’s modulus,
Poisson’s ratio, anisotropy factors, Debye temperature and sound
velocity have been calculated. The obtained results, which are
reported for the first time to the best of the author’s knowledge, can
facilitate assessment of possible applications of the title material.
Abstract: It is the worldwide problem that the recycled PVB is
not recycled and it is wildly stored in landfills. However, PVB has
similar chemical properties such as PVC. Moreover, both of these
polymers are plasticized. Therefore, the study of thermal properties
of plasticized PVC and the recycled PVB obtained by recycling of
windshields is carried out. This work has done in order to find nondegradable
processing conditions applicable for both polymers.
Tested PVC contained 38% of plasticizer diisononyl phthalate
(DINP) and PVB was plasticized with 28% of triethylene glycol,
bis(2-ethylhexanoate) (3GO). The thermal and thermo-oxidative
decomposition of both vinyl polymers are compared by calorimetric
analysis and by tensile strength analysis.