Abstract: In this study the adsorption of Cu (II) ions from aqueous solutions on synthetic zeolite NaA was evaluated. The effect of solution temperature and the determination of the kinetic parameters of adsorption of Cu(II) from aqueous solution on zeolite NaA is important in understanding the adsorption mechanism. Variables of the system include adsorption time, temperature (293- 328K), initial solution concentration and pH for the system. The sorption kinetics of the copper ions were found to be strongly dependent on pH (the optimum pH 3-5), solute ion concentration and temperature (293 – 328 K). It was found, the pseudo-second-order model was the best choice among all the kinetic models to describe the adsorption behavior of Cu(II) onto ziolite NaA, suggesting that the adsorption mechanism might be a chemisorptions process The activation energy of adsorption (Ea) was determined as Cu(II) 13.5 kJ mol-1. The low value of Ea shows that Cu(II) adsorption process by zeolite NaA may be an activated chemical adsorption. The thermodynamic parameters (ΔG0, ΔH0, and ΔS0) were also determined from the temperature dependence. The results show that the process of adsorption Cu(II) is spontaneous and endothermic process and rise in temperature favors the adsorption.
Abstract: A mathematical model for the hydrodynamic
lubrication of parabolic slider bearings with couple stress lubricants
is presented. A numerical solution for the mathematical model using
finite element scheme is obtained using three nodes isoparametric
quadratic elements. Stiffness integrals obtained from the weak form
of the governing equations were solved using Gauss Quadrature to
obtain a finite number of stiffness matrices. The global system of
equations was obtained for the bearing and solved using Gauss Seidel
iterative scheme. The converged pressure solution was used to obtain
the load capacity of the bearing. Parametric studies were carried out
and it was shown that the effect of couple stresses and profile
parameter are to increase the load carrying capacity of the parabolic
slider bearing. Numerical experiments reveal that the magnitude of
the profile parameter at which maximum load is obtained increases
with decrease in couple stress parameter. The results are presented in
graphical form.
Abstract: Base on extenics theory, the statistical physical and mechanical properties from laboratory experiments are used to evaluate the bearing capacity of lateritic soil foundation. The properties include water content, bulk density, liquid limit, cohesion, and so on. The matter-element and the dependent function are defined. Then the synthesis dependent degree and the final grade index are calculated. The results show that predicted outcomes can be matched with the in-situ test data, and a evaluate grade associate with bearing capacity can be deduced. The results provide guidance to assess and determine the bearing capacity grade of lateritic soil foundation.
Abstract: The study analyzed the risk and returns of commercial-property in Southwestern Nigeria and selected stocksmarket investment between 2000 and 2009; compared the inflation hedging characteristics and diversification potentials of investing in commercial-property and selected stock- market investment. Primary data were collected on characteristics, rental and capital values of commercial- properties from their property managers through the use of questionnaire. Secondary data on stock prices and dividends on banking, insurance and conglomerates sectors were sourced from the Nigerian Stock Exchange (2000-2009). The result showed that average return on all the selected stock- investments was higher than that of commercial-property. As regards risk, commercial-property indicated lower risk, compared to stocks. Also the stock-investment had better inflation hedging capacity than commercial-properties; combination of both had diversification potentials. The study concluded that stock-market investment offered attractive higher return than commercial-property although with higher risk and there could be diversification benefits in combining commercial-property with stock- investment.
Abstract: This study investigates the roles of knowledge
acquisition, absorptive capacity, and innovation capability in finance
and manufacturing industries. With 362 valid questionnaires from
manufactures and financial industries in Taiwan, we examine the
relationships between absorptive capacity, knowledge acquisition and
innovation capability using a structural equation model. The results
indicate that absorptive capacity is the mediator between knowledge
acquisition and innovation capability, and that knowledge acquisition
has a positive effect on absorptive capacity.
Abstract: In order to implement flexibility as well as survivable
capacities over passive optical network (PON), a new automatic
random fault-recovery mechanism with array-waveguide-grating
based (AWG-based) optical switch (OSW) is presented. Firstly,
wavelength-division-multiplexing and optical code-division
multiple-access (WDM/OCDMA) scheme are configured to meet the
various geographical locations requirement between optical network
unit (ONU) and optical line terminal (OLT). The AWG-base optical
switch is designed and viewed as central star-mesh topology to
prohibit/decrease the duplicated redundant elements such as fiber and
transceiver as well. Hence, by simple monitoring and routing switch
algorithm, random fault-recovery capacity is achieved over
bi-directional (up/downstream) WDM/OCDMA scheme. When error
of distribution fiber (DF) takes place or bit-error-rate (BER) is higher
than 10-9 requirement, the primary/slave AWG-based OSW are
adjusted and controlled dynamically to restore the affected ONU
groups via the other working DFs immediately.
Abstract: This research work takes a different approach in
the discussion of urban form impacts on transport planning and
auto dependency. Concentrated density represented by effective
density explains auto dependency better than the conventional
density and it is proved to be a realistic density representative for
the urban transportation analysis. Model analysis reveals that
effective density is influenced by the shopping accessibility
index as well as job density factor. It is also combined with the
job access variable to classify four levels of Transport Activity
Centers (TACs) in Okinawa, Japan. Trip attraction capacity and
levels of the newly classified TACs was found agreeable with the
amount of daily trips attracted to each center. The trip attraction
data set was drawn from a 2007 Okinawa personal trip survey.
This research suggests a planning methodology which guides
logical transport supply routes and concentrated local
development schemes.
Abstract: This paper describes an efficient hardware implementation of a new technique for interfacing the data exchange between the microprocessor-based systems and the external devices. This technique, based on the use of software/hardware system and a reduced physical address, enlarges the interfacing capacity of the microprocessor-based systems, uses the Direct Memory Access (DMA) to increases the frequency of the new bus, and improves the speed of data exchange. While using this architecture in microprocessor-based system or in computer, the input of the hardware part of our system will be connected to the bus system, and the output, which is a new bus, will be connected to an external device. The new bus is composed of a data bus, a control bus and an address bus. A Xilinx Integrated Software Environment (ISE) 7.1i has been used for the programmable logic implementation.
Abstract: In this paper the development of a heat exchanger as a
pilot plant for educational purpose is discussed and the use of neural
network for controlling the process is being presented. The aim of the
study is to highlight the need of a specific Pseudo Random Binary
Sequence (PRBS) to excite a process under control. As the neural
network is a data driven technique, the method for data generation
plays an important role. In light of this a careful experimentation
procedure for data generation was crucial task. Heat exchange is a
complex process, which has a capacity and a time lag as process
elements. The proposed system is a typical pipe-in- pipe type heat
exchanger. The complexity of the system demands careful selection,
proper installation and commissioning. The temperature, flow, and
pressure sensors play a vital role in the control performance. The
final control element used is a pneumatically operated control valve.
While carrying out the experimentation on heat exchanger a welldrafted
procedure is followed giving utmost attention towards safety
of the system. The results obtained are encouraging and revealing
the fact that if the process details are known completely as far as
process parameters are concerned and utilities are well stabilized then
feedback systems are suitable, whereas neural network control
paradigm is useful for the processes with nonlinearity and less
knowledge about process. The implementation of NN control
reinforces the concepts of process control and NN control paradigm.
The result also underlined the importance of excitation signal
typically for that process. Data acquisition, processing, and
presentation in a typical format are the most important parameters
while validating the results.
Abstract: In this paper, we observe that developed countries are generally equipped with innovation capabilities and produce major chunk of the world-s knowledge and technology. The contribution of developing countries, on the other hand, is insignificant, and most of them far behind the global technological front. More specifically, we empirically observe that the developing world neither contributes substantially to the world-s scientific publications nor to the R&D activities. They also have lesser “absorptive capacity" and “technological capability", and their “innovation systems" are plagued with many problems. Finally, we argue that these countries can break the shackles and improve their innovation capabilities by pursuing genuine innovation policies on long-term basis with honesty and commitment.
Abstract: The European countries that during the past two
decades based their exchange rate regimes on currency board
arrangement (CBA) are usually analysed from the perspective of
corner solution choice’s stabilisation effects. There is an open
discussion on the positive and negative background of a strict
exchange rate regime choice, although it should be seen as part of the
transition process towards the monetary union membership. The
focus of the paper is on the Baltic countries that after two decades of
a rigid exchange rate arrangement and strongly influenced by global
crisis are finishing their path towards the euro zone. Besides the
stabilising capacity, the CBA is highly vulnerable regime, with
limited developing potential. The rigidity of the exchange rate (and
monetary) system, despite the ensured credibility, do not leave
enough (or any) space for the adjustment and/or active crisis
management. Still, the Baltics are in a process of recovery, with fiscal
consolidation measures combined with (painful and politically
unpopular) measures of internal devaluation. Today, two of them
(Estonia and Latvia) are members of euro zone, fulfilling their
ultimate transition targets, but de facto exchanging one fixed regime
with another.
The paper analyses the challenges for the CBA in unstable
environment since the fixed regimes rely on imported stability and
are sensitive to external shocks. With limited monetary instruments,
these countries were oriented to the fiscal policies and used a
combination of internal devaluation and tax policy measures. Despite
their rather quick recovery, our second goal is to analyse the long
term influence that the measures had on the national economy.
Abstract: One of the most common practices for strengthening
the reinforced concrete structures is the application of FRP (Fiber
Reinforce Plastic) sheets to increase the flexural and shear strengths
of the member. The elastic modulus of FRP is considerably higher
than that of concrete. This will result in debonding between the FRP
sheets and concrete surface. With conventional surface preparation of
concrete, the ultimate capacity of the FRP sheets can hardly be
achieved. New methods for preparation of the bonding surface have
shown improvements in reducing the premature debonding of FRP
sheets from concrete surface. The present experimental study focuses
on the application of grooving method to postpone debonding of the
FRP sheets attached to the side faces of concrete beams for shear
strengthening. Comparison has also been made with conventional
surface preparation method. This study clearly shows the efficiency
of grooving method compared to surface preparation method, in
preventing the debonding phenomenon and in increasing the load
carrying capacity of FRP.
Abstract: The main problem is that there is a very low innovation performance in Latvia. Since Latvia is a Member State of European Union, it also shall have to fulfill the set targets and to improve innovative results.Universities are one of the main performers to provide innovative capacity of country. University, industry and government need to cooperate for getting best results.The intellectual property is one of the indicators to determine innovation level in the country or organization, and patents are one of the characteristics of intellectual property.The objective of the article is to determine indicators characterizing innovative environment in Latvia and influence of the development of universities on them.The methods that will be used in the article to achieve the objectives are quantitative and qualitative analysis of the literature, statistical data analysis and graphical analysis methods.
Abstract: Since the actuator capacity is limited, in the real
application of active control systems under sever earthquakes it is
conceivable that the actuators saturate, hence the actuator saturation
should be considered as a constraint in design of optimal controllers.
In this paper optimal design of active controllers for nonlinear
structures by considering actuator saturation, has been studied. The
proposed method for designing optimal controllers is based on
defining an optimization problem which the objective has been to
minimize the maximum displacement of structure when a limited
capacity for actuator has been used. To this end a single degree of
freedom (SDF) structure with a bilinear hysteretic behavior has been
simulated under a white noise ground acceleration of different
amplitudes. Active tendon control mechanism, comprised of prestressed
tendons and an actuator, and extended nonlinear Newmark
method based instantaneous optimal control algorithm have been
used. To achieve the best results, the weights corresponding to
displacement, velocity, acceleration and control force in the
performance index have been optimized by the Distributed Genetic
Algorithm (DGA). Results show the effectiveness of the proposed
method in considering actuator saturation. Also based on the
numerical simulations it can be concluded that the actuator capacity
and the average value of required control force are two important
factors in designing nonlinear controllers which consider the actuator
saturation.
Abstract: An unstructured finite volume numerical model is
presented here for simulating shallow-water flows with wetting and
drying fronts. The model is based on the Green-s theorem in
combination with Chorin-s projection method. A 2nd-order upwind
scheme coupled with a Least Square technique is used to handle
convection terms. An Wetting and drying treatment is used in the
present model to ensures the total mass conservation. To test it-s
capacity and reliability, the present model is used to solve the
Parabolic Bowl problem. We compare our numerical solutions with
the corresponding analytical and existing standard numerical results.
Excellent agreements are found in all the cases.
Abstract: A procedure for the preparation of clarified Pawpaw
Juice was developed. About 750ml Pawpaw pulp was measured into
2 measuring cylinders A & B of capacity 1 litre heated to 400C,
cooled to 200C. 30mls pectinase was added into cylinder A, while
30mls distilled water was added into cylinder B. Enzyme treated
sample (A) was allowed to digest for 5hours after which it was heated
to 900C for 15 minutes to inactivate the enzyme. The heated sample
was cooled and with the aid of a mucillin cloth the pulp was filtered
to obtain the clarified pawpaw juice. The juice was filled into 100ml
plastic bottles, pasteurized at 950C for 45 minutes, cooled and stored
at room temperature. The sample treated with 30mls distilled water
also underwent the same process. Freshly pasteurized sample was
analyzed for specific gravity, titratable acidity, pH, sugars and
ascorbic acid. The remaining sample was then stored for 2 weeks and
the above analyses repeated. There were differences in the results of
the freshly pasteurized samples and stored sample in pH and ascorbic
acid levels, also sample treated with pectinase yielded higher
volumes of juice than that treated with distilled water.
Abstract: Medical imaging uses the advantage of digital
technology in imaging and teleradiology. In teleradiology systems
large amount of data is acquired, stored and transmitted. A major
technology that may help to solve the problems associated with the
massive data storage and data transfer capacity is data compression
and decompression. There are many methods of image compression
available. They are classified as lossless and lossy compression
methods. In lossy compression method the decompressed image
contains some distortion. Fractal image compression (FIC) is a lossy
compression method. In fractal image compression an image is
coded as a set of contractive transformations in a complete metric
space. The set of contractive transformations is guaranteed to
produce an approximation to the original image. In this paper FIC is
achieved by PIFS using quadtree partitioning. PIFS is applied on
different images like , Ultrasound, CT Scan, Angiogram, X-ray,
Mammograms. In each modality approximately twenty images are
considered and the average values of compression ratio and PSNR
values are arrived. In this method of fractal encoding, the
parameter, tolerance factor Tmax, is varied from 1 to 10, keeping the
other standard parameters constant. For all modalities of images the
compression ratio and Peak Signal to Noise Ratio (PSNR) are
computed and studied. The quality of the decompressed image is
arrived by PSNR values. From the results it is observed that the
compression ratio increases with the tolerance factor and
mammogram has the highest compression ratio. The quality of the
image is not degraded upto an optimum value of tolerance factor,
Tmax, equal to 8, because of the properties of fractal compression.
Abstract: The remediation of water resources pollution in
developing countries requires the application of alternative
sustainable cheaper and efficient end-of-pipe wastewater treatment
technologies. The feasibility of use of South African cheap and
abundant pine tree (Pinus patula) sawdust for development of lowcost
AC of comparable quality to expensive commercial ACs in the
abatement of water pollution was investigated. AC was developed at
optimized two-stage N2-superheated steam activation conditions in a
fixed bed reactor, and characterized for proximate and ultimate
properties, N2-BET surface area, pore size distribution, SEM, pHPZC
and FTIR. The sawdust pyrolysis activation energy was evaluated by
TGA. Results indicated that the chars prepared at 800oC and 2hrs
were suitable for development of better quality AC at 800oC and 47%
burn-off having BET surface area (1086m2/g), micropore volume
(0.26cm3/g), and mesopore volume (0.43cm3/g) comparable to
expensive commercial ACs, and suitable for water contaminants
removal. The developed AC showed basic surface functionality at
pHPZC at 10.3, and a phenol adsorption capacity that was higher than
that of commercial Norit (RO 0.8) AC. Thus, it is feasible to develop
better quality low-cost AC from (Pinus patula) sawdust using twostage
N2-steam activation in fixed-bed reactor.
Abstract: Educational institutions often implement policies with
the intention of influencing how learning and teaching occur.
Generally, such policies are not as effective as their makers would
like; changing the behavior of third-level teachers proves difficult.
Nevertheless, a policy instituted in 2006 at the Dublin Institute of
Technology has met with success: each newly hired faculty member
must have a post-graduate qualification in “Learning and Teaching"
or successfully complete one within the first two years of
employment. The intention is to build teachers- knowledge about
student-centered pedagogies and their capacity to implement them.
As a result of this policy (and associated programs that support it),
positive outcomes are readily apparent. Individual teachers who have
completed the programs have implemented significant change at the
course and program levels. This paper introduces the policy,
identifies outcomes in relation to existing theory, describes research
underway, and pinpoints areas where organizational learning has
occurred.
Abstract: The scientific perspective, the practice area of physical education and sports activities improve power capacity in all its forms of expression, being a generator of the research topics. Today theories that strength training athletes and slow down development progress will affect the strength and flexibility are discredited. On the other hand there are sectors and / or samples whose results are sports of the way higher manifestation of power as a result of the composition of the force and velocity, being based in this respect on the systematic and continuous development of both bio-motric capacities said. Training of force for children was and is controversial. Teama de accidentări sau a stopării premature a procesului de creştere a făcut ca în trecut copiii să fie ţinuţi departe de lucrul cu diferite greutăţi.Fear of injury or premature stop the growth process in the past made the children to be kept away from working with different weights. Recent studies have shown that the risk of accidents is relatively small and the strength training can help prevent them. For example, most accidents occur at the level of athletics ligaments and tendons. From this point of view, it can be said that a progressive intervention of force training, optimal design, will help enhancing their process, such as athlete much better prepared to meet training requests and competitions. Preparation of force provides a solid basis for further phases in the highest performance.