Abstract: Liquid-Liquid Equilibrium (LLE) data are measured
for the ternary mixtures of water + 1-butanol + butyl acetate and
quaternary mixtures of water + 1-butanol + butyl acetate + glycerol at
atmospheric pressure at 313.15 K. In addition, isothermal
vapor–liquid–liquid equilibrium (VLLE) data are determined
experimentally at 333.15 K. The region of heterogeneity is found to
increase as the hydrophilic agent (glycerol) is introduced into the
aqueous mixtures. The experimental data are correlated with the
NRTL model. The predicted results from the solution model with the
model parameters determined from the constituent binaries are also
compared with the experimental values.
Abstract: In the present study, the properties of Al-Al2O3
nanocomposite hollow sphere structures were investigated. For this
reason, the Al-based nanocomposite hollow spheres with different
amounts of nano-alumina reinforcement (0-10wt %) and different
ratio of thickness to diameter (t/D: 0.06-0.3) were prepared via a
powder metallurgy method. Then, the effect of mentioned parameters
was studied on physical and quasi static mechanical properties of
their related prepared structures (open/closed cell) such as density,
hardness, strength, and energy absorption. It was found that, as the
t/D ratio increases the relative density, compressive strength and
energy absorption increase. The highest values of strength and energy
absorption were obtained from the specimen with 5 wt. % of
nanoparticle reinforcement, t/D of 0.3 (t=1 mm, D=400μm) as 22.88
MPa and 13.24 MJ/m3, respectively. The moderate specific strength
of prepared composites in the present study showed the good
consistency with the properties of others low carbon steel composite
with similar structure.
Abstract: This paper presents the results obtained by numerical
simulation using the software ANSYS CFX-CFD for the air
pollutants dispersion in the atmosphere coming from the evacuation
of combustion gases resulting from the fuel combustion in an electric
thermal power plant. The model uses the Navier-Stokes equation to
simulate the dispersion of pollutants in the atmosphere. It is
considered as important factors in elaboration of simulation the
atmospheric conditions (pressure, temperature, wind speed, wind
direction), the exhaust velocity of the combustion gases, chimney
height and the obstacles (buildings). Using the air quality monitoring
stations it is measured the concentrations of main pollutants (SO2,
NOx and PM). The pollutants were monitored over a period of 3
months, after that the average concentration are calculated, which is
used by the software. The concentrations are: 8.915 μg/m3 (NOx),
9.587 μg/m3 (SO2) and 42 μg/m3 (PM). A comparison of test data
with simulation results demonstrated that CFX was able to describe
the dispersion of the pollutant as well the concentration of this
pollutants in the atmosphere.
Abstract: In this paper, analysis of an infinite beam resting on
multilayer tensionless extensible geosynthetic reinforced granular
fill-poor soil system overlying soft soil strata under moving load with
constant velocity is presented. The beam is subjected to a
concentrated load moving with constant velocity. The upper
reinforced granular bed is modeled by a rough membrane embedded
in Pasternak shear layer overlying a series of compressible nonlinear
winkler springs representing the underlying the very poor soil. The
multilayer tensionless extensible geosynthetic layer has been
assumed to deform such that at interface the geosynthetic and the soil
have some deformation. Nonlinear behaviour of granular fill and the
very poor soil has been considered in the analysis by means of
hyperbolic constitutive relationships. Governing differential
equations of the soil foundation system have been obtained and
solved with the help of appropriate boundary conditions. The solution
has been obtained by employing finite difference method by means of
Gauss-Siedal iterative scheme. Detailed parametric study has been
conducted to study the influence of various parameters on the
response of soil–foundation system under consideration by means of
deflection and bending moment in the beam and tension mobilized in
the geosynthetic layer. These parameters include magnitude of
applied load, velocity of load, damping, ultimate resistance of poor
soil and granular fill layer. Range of values of parameters has been
considered as per Indian Railway conditions. This study clearly
observed that the comparisons of multilayer tensionless extensible
geosynthetic reinforcement with poor foundation soil and magnitude
of applied load, relative compressibility of granular fill and ultimate
resistance of poor soil has significant influence on the response of
soil–foundation system.
Abstract: This paper applied factor conditions from Porter’s
Diamond Model (1990) to understand the various challenges facing
the AMISA. Factor conditions highlighted in Porter’s model are
grouped into two groups namely, basic and advance factors. Two
AMISA associations representing over 10 000 employees were
interviewed. The largest Clothing, Textiles and Leather (CTL)
apparel retail group was also interviewed with a government
department implementing the industrialization policy were
interviewed. The paper points out that AMISA have basic factor conditions
necessary for competitive advantage in the apparel industries.
However advance factor creation has proven to be a challenge for
AMISA, Higher Education Institutions (HEIs) and government. Poor
infrastructural maintenance has contributed to high manufacturing
costs and poor quick response technologies. The use of Porter’s
Factor Conditions as a tool to analyze the sector’s competitive
advantage challenges and opportunities has increased knowledge
regarding factors that limit the AMISA’s competitiveness. It is
therefore argued that other studies on Porter’s Diamond model
factors like Demand conditions, Firm strategy, structure and rivalry
and Related and supporting industries can be used to analyze the
situation of the AMISA for the purposes of improving competitive
advantage.
Abstract: This paper presents results of the survey regarding the
awareness about HIV/AIDS among HIV-infected individuals. A
questionnaire covering various aspects of HIV-infection was
conducted among 110 HIV-infected individuals who attended the
G.A. Zaharyan Moscow Tuberculosis Clinic, Department for
treatment of TB patients with HIV. The questionnaire included
questions about modes of HIV transmission and preventive measures
against HIV/AIDS, as well as questions about age, gender, education
and employment status. The survey revealed that the respondents in
the whole had a good knowledge regarding modes of HIV
transmission and preventive measures against HIV/AIDS: about
83,6% male respondents and 85,7% female respondents gave an
accurate answers regarding the HIV-infection. However, the
overwhelming majority of the study participants, that is, 88,5% men
and 98% women, was quite ignorant about the risk of acquiring HIV
through saliva and toothbrush of HIV-infected individual. Though
that risk is rather insignificant, it is still biologically possible. And
this gap in knowledge needs to be filled. As the study showed another
point of concern was the fact, that despite the knowledge of HIV
transmission risk through unprotected sex about 40% percent of HIVpositive
men and 25% of HIV-positive women did not insist on using
condoms with their sexual partners. These findings indicate that there
are still some aspects about HIV-infection which needed to be
clarified and explained through more detailed and specific
educational programs.
Abstract: Workflow scheduling is an important part of cloud
computing and based on different criteria it decides cost, execution
time, and performances. A cloud workflow system is a platform
service facilitating automation of distributed applications based on
new cloud infrastructure. An aspect which differentiates cloud
workflow system from others is market-oriented business model, an
innovation which challenges conventional workflow scheduling
strategies. Time and Cost optimization algorithm for scheduling
Hybrid Clouds (TCHC) algorithm decides which resource should be
chartered from public providers is combined with a new De-De
algorithm considering that every instance of single and multiple
workflows work without deadlocks. To offset this, two new concepts
- De-De Dodging Algorithm and Priority Based Decisive Algorithm -
combine with conventional deadlock avoidance issues by proposing
one algorithm that maximizes active (not just allocated) resource use
and reduces Makespan.
Abstract: A novel chromium-free protective coating films based
on a zeolite coating was growing onto a FeCrAlloy metal using in –
situ hydrothermal method. The zeolite film was obtained using in-situ
crystallization process that is capable of coating large surfaces with
complex shape and in confined spaces has been developed. The
zeolite coating offers an advantage of a high mechanical stability and
thermal stability. The physicochemical properties were investigated
using X-ray diffraction (XRD), Electron Microscopy (SEM), Energy
Dispersive X–ray Analysis (EDX) and Thermogravimetric Analysis
(TGA). The transition from oxide-on-alloy wires to hydrothermally
synthesised uniformly zeolite coated surfaces was followed using
SEM and XRD. In addition, the robustness of the prepared coating
was confirmed by subjecting these to thermal cycling (ambient to
550oC).
Abstract: The purpose of this article is to make an approach to
the Security Studies, exposing their theories and concepts to
understand the role that they have had in the interpretation of the
changes and continuities of the world order and their impact on
policies in facing the problems of the 21st century. The aim is to
build a bridge between the security studies as a subfield and the
meaning that has been given to the world order. The idea of epistemic
communities serves as a methodological proposal for the different
programs of research in security studies, showing their influence in
the realities of States, intergovernmental organizations and
transnational forces, moving to implement, perpetuate and project a
vision of the world order.
Abstract: Grains, including oats (Avena sativa L.), have been
recognized functional foods, because provide beneficial effect on the
health of the consumer and decrease the risk of various diseases. Oats
are good source of soluble fibre, essential amino acids, unsaturated
fatty acids, vitamins and minerals. Oat breeders have developed oat
varieties and improved yielding ability potential of oat varieties.
Therefore, the aim of investigation was to analyze the composition of
perspective oat varieties and breeding lines grains grown in different
conditions and evaluate functional properties. In the studied samples
content of protein, starch, β-glucans, total dietetic fibre, composition
of amino acids and vitamin E were determined. The results of
analysis showed that protein content depending of varieties ranged
9.70% to 17.30% total dietary fibre 13.66 g100g-1 to 30.17 g100g-1,
content of β-glucans 2.7 g100g-1 to 3.5 g100g-1, amount of
vitamin E (α-tocopherol) determined from 4 mgkg-1 to 9.9 mgkg-1.
The sums of essential amino acids in oat grain samples were
determined from 31.63 gkg-1 to 54.90 gkg-1. It is concluded that
amino acids composition of husked and naked oats grown in organic
or conventional conditions is close to optimal for human health.
Abstract: This paper presents thermal annealing de-wetting
technique for the preparation of porous metal membrane for Thin
Film Encapsulation (TFE) application. Thermal annealing de-wetting
experimental results reveal that pore size formation in porous metal
membrane depend upon i.e. 1. The substrate at which metal is
deposited, 2. Melting point of metal used for porous metal cap layer
membrane formation, 3. Thickness of metal used for cap layer, 4.
Temperature used for formation of porous metal membrane. In order
to demonstrate this technique, Silver (Ag) was used as a metal for
preparation of porous metal membrane on amorphous silicon (a-Si)
and silicon oxide. The annealing of the silver thin film of various
thicknesses was performed at different temperature. Pores in porous
silver film were analyzed using Scanning Electron Microscope
(SEM). In order to check the usefulness of porous metal film for TFE
application, the porous silver film prepared on amorphous silicon (a-
Si) and silicon oxide was released using XeF2 and VHF, respectively.
Finally, guide line and structures are suggested to use this porous
membrane for robust TFE application.
Abstract: Mobile Adhoc Networks (MANETs) are
infrastructure-less, dynamic network of collections of wireless mobile
nodes communicating with each other without any centralized
authority. A MANET is a mobile device of interconnections through
wireless links, forming a dynamic topology. Routing protocols have a
big role in data transmission across a network. Routing protocols,
two major classifications are unipath and multipath. This study
evaluates performance of an on-demand multipath routing protocol
named Adhoc On-demand Multipath Distance Vector routing
(AOMDV). This study proposes Energy Aware AOMDV (EAAOMDV)
an extension of AOMDV which decreases energy
consumed on a route.
Abstract: Polyaniline is an indispensible component in lightemitting
devices (LEDs), televisions, cellular telephones, automotive,
corrosion-resistant coatings, actuators etc. The electrical conductivity
properties was found be increased by introduction of metal nano
particles. In the present study, an attempt has been made to utilize
platinum nano particles to achieve the improved electrical properties.
Polyaniline and Pt-polyaniline composite are synthesized by
electrochemical routes. X-ray diffractometer confirms the amorphous
nature of polyaniline. The Bragg’s diffraction peaks correspond to
platinum nanoparticles in Pt-polyaniline composite and
thermogravimetric analyzer indicates its decomposition at certain
temperature. The Scanning Electron Micrographs of colloidal
platinum nanoparticles were spherical, uniform shape in the
composite. The current-voltage (I-V) characteristics of the PANI and
composites were also studied which indicate a significant decreasing
resistivity than PANI-Platinum after introduction of pt nanoparticles
in the matrix of polyaniline (PANI).
Abstract: The goal of this paper is to present the diagnostic
contribution that the screening instrument, Mini-Mental State
Examination-2: Expanded Version (MMSE-2:EV), brings in
detecting the cognitive impairment or in monitoring the progress of
degenerative disorders. The diagnostic signification is underlined by
the interpretation of the MMSE-2:EV scores, resulted from the test
application to patients with mild and major neurocognitive disorders.
The cases were selected from current practice, in order to cover vast
and significant neurocognitive pathology: mild cognitive impairment,
Alzheimer’s disease, vascular dementia, mixed dementia, Parkinson’s
disease, conversion of the mild cognitive impairment into
Alzheimer’s disease. The MMSE-2:EV version was used: it was
applied one month after the initial assessment, three months after the
first reevaluation and then every six months, alternating the blue and
red forms. Correlated with age and educational level, the raw scores
were converted in T scores and then, with the mean and the standard
deviation, the z scores were calculated. The differences of raw scores
between the evaluations were analyzed from the point of view of
statistic signification, in order to establish the progression in time of
the disease. The results indicated that the psycho-diagnostic approach
for the evaluation of the cognitive impairment with MMSE-2:EV is
safe and the application interval is optimal. In clinical settings with a
large flux of patients, the application of the MMSE-2:EV is a safe
and fast psychodiagnostic solution. The clinicians can draw objective
decisions and for the patients: it does not take too much time and
energy, it does not bother them and it doesn’t force them to travel
frequently.
Abstract: DNA Barcode provides good sources of needed
information to classify living species. The classification problem has
to be supported with reliable methods and algorithms. To analyze
species regions or entire genomes, it becomes necessary to use the
similarity sequence methods. A large set of sequences can be
simultaneously compared using Multiple Sequence Alignment which
is known to be NP-complete. However, all the used methods are still
computationally very expensive and require significant computational
infrastructure. Our goal is to build predictive models that are highly
accurate and interpretable. In fact, our method permits to avoid the
complex problem of form and structure in different classes of
organisms. The empirical data and their classification performances
are compared with other methods. Evenly, in this study, we present
our system which is consisted of three phases. The first one, is called
transformation, is composed of three sub steps; Electron-Ion
Interaction Pseudopotential (EIIP) for the codification of DNA
Barcodes, Fourier Transform and Power Spectrum Signal Processing.
Moreover, the second phase step is an approximation; it is
empowered by the use of Multi Library Wavelet Neural Networks
(MLWNN). Finally, the third one, is called the classification of DNA
Barcodes, is realized by applying the algorithm of hierarchical
classification.
Abstract: In this paper, the specific sound Transmission Loss
(TL) of the Laminated Composite Plate (LCP) with different material
properties in each layer is investigated. The numerical method to
obtain the TL of the LCP is proposed by using elastic plate theory. The
transfer matrix approach is novelty presented for computational
efficiency in solving the numerous layers of dynamic stiffness matrix
(D-matrix) of the LCP. Besides the numerical simulations for
calculating the TL of the LCP, the material properties inverse method
is presented for the design of a laminated composite plate analogous to
a metallic plate with a specified TL. As a result, it demonstrates that
the proposed computational algorithm exhibits high efficiency with a
small number of iterations for achieving the goal. This method can be
effectively employed to design and develop tailor-made materials for
various applications.
Abstract: This work presents an improved single fiber pull-out
test for fiber/matrix interface characterization. This test has been
used to study the Inter-Facial Shear Strength ‘IFSS’ of hemp fibers
reinforced polypropylene (PP). For this aim, the fiber diameter
has been carefully measured using a tomography inspired method.
The fiber section contour can then be approximated by a circle
or a polygon. The results show that the IFSS is overestimated if
the circular approximation is used. The Influence of the molding
temperature on the IFSS has also been studied. We find that a molding
temperature of 183◦C leads to better interfacial properties. Above or
below this temperature the interface strength is reduced.
Abstract: Biodiesel production from vegetable oil will produce
glycerol as by-product about 10% of the biodiesel production. The
amount of glycerol that was produced needed alternative way to
handling immediately so as to not become the waste that polluted
environment. One of the solutions was to process glycerol to
polyglycidyl nitrate (PGN). PGN is synthesized from glycerol by
three-step reactions i.e. nitration of glycerol, cyclization of 13-
dinitroglycerine and polymerization of glycosyl nitrate. Optimum
condition of nitration of glycerol with nitric acid has not been known.
Thermodynamic feasibility should be done before run experiments in
the laboratory. The aim of this study was to determine the parameters
those affect nitration of glycerol and nitric acid and chose the
operation condition. Many parameters were simulated to verify its
possibility to experiment under conditions which would get the
highest conversion of 1, 3-dinitroglycerine and which was the ideal
condition to get it. The parameters that need to be studied to obtain
the highest conversion of 1, 3-dinitroglycerine were mol ratio of
nitric acid/glycerol, reaction temperature, mol ratio of
glycerol/dichloromethane and pressure. The highest conversion was
obtained in the range of mol ratio of nitric acid /glycerol between 2/1
– 5/1, reaction temperature of 5-25oC and pressure of 1 atm. The
parameters that need to be studied further to obtain the highest
conversion of 1.3 DNG are mol ratio of nitric acid/glycerol and
reaction temperature.
Abstract: The aim of the present study is to detect the chaotic
behavior in monetary economic relevant dynamical system. The
study employs three different forms of Taylor rules: current, forward,
and backward looking. The result suggests the existence of the
chaotic behavior in all three systems. In addition, the results strongly
represent that using expectations in policy rule especially rational
expectation hypothesis can increase complexity of the system and
leads to more chaotic behavior.
Abstract: Superabsorbent polymers received much attention and
are used in many fields because of their superior characters to
traditional absorbents, e.g., sponge and cotton. So, it is very
important but challenging to prepare highly and fast-swelling
superabsorbents. A reliable, efficient and low-cost technique for
removing heavy metal ions from wastewater is the adsorption using
bio-adsorbents obtained from biological materials, such as
polysaccharides-based hydrogels superabsorbents. In this study, novel multi-functional superabsorbent composites
type semi-interpenetrating polymer networks (Semi-IPNs) were
prepared via graft polymerization of acrylamide onto chitosan
backbone in presence of gelatin, CTS-g-PAAm/Ge, using potassium
persulfate and N,N’-methylene bisacrylamide as initiator and
crosslinker, respectively. These hydrogels were also partially
hydrolyzed to achieve superabsorbents with ampholytic properties
and uppermost swelling capacity. The formation of the grafted
network was evidenced by Fourier Transform Infrared Spectroscopy
(ATR-FTIR) and Thermogravimetric Analysis (TGA). The porous
structures were observed by Scanning Electron Microscope (SEM).
From TGA analysis, it was concluded that the incorporation of the Ge
in the CTS-g-PAAm network has marginally affected its thermal
stability. The effect of gelatin content on the swelling capacities of
these superabsorbent composites was examined in various media
(distilled water, saline and pH-solutions). The water absorbency was
enhanced by adding Ge in the network, where the optimum value was
reached at 2 wt. % of Ge. Their hydrolysis has not only greatly
optimized their absorption capacity but also improved the swelling
kinetic.These materials have also showed reswelling ability. We
believe that these super-absorbing materials would be very effective
for the adsorption of harmful metal ions from wastewater.