Abstract: Propylene self-metathesis to ethylene and butene was
studied over WOx/SiO2 catalysts at 450oC and atmospheric pressure.
The WOx/SiO2 catalysts were prepared by incipient wetness
impregnation of ammonium metatungstate aqueous solution. It was
found that, adding nano-sized extra supports (SiO2 and TiO2) by
physical mixing with the WOx/SiO2 enhanced propylene conversion.
The UV-Vis and FT-Raman results revealed that WOx could migrate
from the original silica support to the extra support, leading to a
better dispersion of WOx. The ICP-OES results also indicate that
WOx existed on the extra support. Coke formation was investigated
on the catalysts after 10 h time-on-stream by TPO. However, adding
nano-sized extra supports led to higher coke formation which may be
related to acidity as characterized by NH3-TPD.
Abstract: This paper presents a model for a modified T-junction
device for microspheres generation. The numerical model is
developed using a commercial software package: COMSOL
Multiphysics. In order to test the accuracy of the numerical model,
multiple variables, such as the flow rate of cross-flow, fluid properties,
structure, and geometry of the microdevice are applied. The results
from the model are compared with the experimental results in the
diameter of the microsphere generated. The comparison shows a good
agreement. Therefore the model is useful in further optimization of the
device and feedback control of microsphere generation if any.
Abstract: The quality and condition of perishable products
delivered to the market and their subsequent selling prices are
directly affected by the care taken during harvesting and handling.
Mechanical injury, in fact, occurs at all stages, from pre-harvest
operations through post-harvest handling, packing and transport to
the market. The main implications of this damage are the reduction of
the product’s quality and economical losses related to the shelf life
diminution. For most perishable products, the shelf life is relatively
short and it is typically dictated by microbial growth related to the
application of dynamic and static loads during transportation. This
paper presents the correlation between vibration levels and
microbiological growth on strawberries and woodland strawberries
and detects the presence of volatile organic compounds (VOC) in
order to develop an intelligent logistic unit capable of monitoring
VOCs using a specific sensor system. Fresh fruits were exposed to
vibrations by means of a vibrating table in a temperature-controlled
environment. Microbiological analyses were conducted on samples,
taken at different positions along the column of the crates. The values
obtained were compared with control samples not exposed to
vibrations and the results show that different positions along the
column influence the development of bacteria, yeasts and filamentous
fungi.
Abstract: Alone with fast urbanization in world, traffic control
became a big issue in urban construction. Having an efficient and
reliable traffic control system is crucial to macro-traffic control.
Traffic signal is used to manage conflicting requirement by allocating
different sets of mutually compatible traffic movement during distinct
time interval. Many approaches have been made proposed to solve
this discrete stochastic problem. Recognizing the need to minimize
right-of-way impacts while efficiently handling the anticipated high
traffic volumes, the proposed alternative system gives effective
design. This model allows for increased traffic capacity and reduces
delays by eliminating a step in maneuvering through the freeway
interchange. The concept proposed in this paper involves
construction of bridges and ramps at intersection of four roads to
control the vehicular congestion and to prevent traffic breakdown.
Abstract: The main objective of this paper is to provide a new
methodology for road safety assessment in Oman through the
development of suitable accident prediction models. GLM technique
with Poisson or NBR using SAS package was carried out to develop
these models. The paper utilized the accidents data of 31 un-signalized
T-intersections during three years. Five goodness-of-fit
measures were used to assess the overall quality of the developed
models. Two types of models were developed separately; the flow-based
models including only traffic exposure functions, and the full
models containing both exposure functions and other significant
geometry and traffic variables.
The results show that, traffic exposure functions produced much
better fit to the accident data. The most effective geometric variables
were major-road mean speed, minor-road 85th percentile speed,
major-road lane width, distance to the nearest junction, and right-turn
curb radius.
The developed models can be used for intersection treatment or
upgrading and specify the appropriate design parameters of T-intersections.
Finally, the models presented in this thesis reflect the intersection
conditions in Oman and could represent the typical conditions in
several countries in the middle east area, especially gulf countries.
Abstract: The paper presents an innovative networked radar
system for detection of obstacles in a railway level crossing scenario.
This Monitoring System (MS) is able to detect moving or still
obstacles within the railway level crossing area automatically,
avoiding the need of human presence for surveillance. The MS is also
connected to the National Railway Information and Signaling System
to communicate in real-time the level crossing status. The
architecture is compliant with the highest Safety Integrity Level
(SIL4) of the CENELEC standard. The number of radar sensors used
is configurable at set-up time and depends on how large the level
crossing area can be. At least two sensors are expected and up four
can be used for larger areas. The whole processing chain that
elaborates the output sensor signals, as well as the communication
interface, is fully-digital, was designed in VHDL code and
implemented onto a Xilinx Virtex 6.
Abstract: Increasing prevalence of childhood obesity has
increased the interest in early and late indicators of gaining weight.
Cell blood counts may be indicators of pro-inflammatory states. The
aim was to evaluate associations of hematological parameters,
including hematocrit (HTC), hemoglobin, blood cell counts and their
indices with the degree of obesity in pediatric population. A total of
249; -139 morbidly obese (MO), 82 healthy normal weight (NW) and
28 overweight (OW) children were included into the scope of the
study. WHO BMI-for age percentiles were used to form age- and sexmatched
groups. Informed consent forms and the Ethics Committee
approval were obtained. Anthropometric measurements were
performed. Hematological parameters were determined. Statistical
analyses were performed using SPSS. The degree for statistical
significance was p≤0.05. Significant differences (p=0.000) between
waist-to-hip ratios and head-to- neck ratios (hnrs) of MO and NW
children were detected. A significant difference between hnrs of OW
and MO children (p=0.000) was observed. Red cell distribution width
(RDW) was higher in OW children than NW group (p=0.030). Such
finding couldn’t be detected between MO and NW groups. Increased
RDW was prominent in OW children. The decrease in mean
corpuscular hemoglobin concentration (MCHC) values in MO
children was sharper than the values in OW children (p=0.006 vs
p=0.042) compared to those in NW group. Statistically higher HTC
levels were observed between MO-NW (p=0.014), but none between
OW-NW. Though the cause-effect relationship between obesity and
erythrocyte indices still needs further investigation, alterations in
RDW, HTC, MCHC during obesity may be of significance in the
early life.
Abstract: In the current work, a three-dimensional geometry of a
75% stenosed blood vessel is analyzed. Large eddy simulation (LES)
with the help of a dynamic subgrid scale Smagorinsky model is
applied to model the turbulent pulsatile flow. The geometry, the
transmural pressure and the properties of the blood and the elastic
boundary were based on clinical measurement data. For the flexible
wall model, a thin solid region is constructed around the 75%
stenosed blood vessel. The deformation of this solid region was
modelled as a deforming boundary to reduce the computational cost
of the solid model. Fluid-structure interaction is realized via a twoway
coupling between the blood flow modelled via LES and the
deforming vessel. The information of the flow pressure and the wall
motion was exchanged continually during the cycle by an arbitrary
Lagrangian-Eulerian method. The boundary condition of current time
step depended on previous solutions. The fluctuation of the velocity
in the post-stenotic region was analyzed in the study. The axial
velocity at normalized position Z=0.5 shows a negative value near
the vessel wall. The displacement of the elastic boundary was
concerned in this study. In particular, the wall displacement at the
systole and the diastole were compared. The negative displacement at
the stenosis indicates a collapse at the maximum velocity and the
deceleration phase.
Abstract: The biodegradable family of polymers
polyhydroxyalkanoates is an interesting substitute for convectional
fossil-based plastics. However, the manufacturing and environmental
impacts associated with their production via intracellular bacterial
fermentation are strongly dependent on the raw material used and on
energy consumption during the extraction process, limiting their
potential for commercialization. Industrial wastewater is studied in
this paper as a promising alternative feedstock for waste valorization.
Based on results from laboratory and pilot-scale experiments, a
conceptual process design, techno-economic analysis and life cycle
assessment are developed for the large-scale production of the most
common type of polyhydroxyalkanoate, polyhydroxbutyrate.
Intracellular polyhydroxybutyrate is obtained via fermentation of
microbial community present in industrial wastewater and the
downstream processing is based on chemical digestion with
surfactant and hypochlorite. The economic potential and
environmental performance results help identifying bottlenecks and
best opportunities to scale-up the process prior to industrial
implementation. The outcome of this research indicates that the
fermentation of wastewater towards PHB presents advantages
compared to traditional PHAs production from sugars because the
null environmental burdens and financial costs of the raw material in
the bioplastic production process. Nevertheless, process optimization
is still required to compete with the petrochemicals counterparts.
Abstract: Fixed-geometry hydrodynamic journal bearings are
one of the best supporting systems for several applications of rotating
machinery. Cylindrical journal bearings present excellent loadcarrying
capacity and low manufacturing costs, but they are subjected
to the oil-film instability at high speeds. An attempt of overcoming
this instability problem has been the development of non-circular
journal bearings. This work deals with an analysis of oil-lubricated
elliptical journal bearings using the finite element method. Steadystate
and dynamic performance characteristics of elliptical bearings
are rendered by zeroth- and first-order lubrication equations obtained
through a linearized perturbation method applied on the classical
Reynolds equation. Four-node isoparametric rectangular finite
elements are employed to model the bearing thin film flow. Curves of
elliptical bearing load capacity and dynamic force coefficients are
rendered at several operating conditions. The results presented in this
work demonstrate the influence of the bearing ellipticity on its
performance at different loading conditions.
Abstract: In this paper, we introduced a gradient-based inverse
solver to obtain the missing boundary conditions based on the
readings of internal thermocouples. The results show that the method
is very sensitive to measurement errors, and becomes unstable when
small time steps are used. The artificial neural networks are shown to
be capable of capturing the whole thermal history on the run-out
table, but are not very effective in restoring the detailed behavior of
the boundary conditions. Also, they behave poorly in nonlinear cases
and where the boundary condition profile is different.
GA and PSO are more effective in finding a detailed
representation of the time-varying boundary conditions, as well as in
nonlinear cases. However, their convergence takes longer. A
variation of the basic PSO, called CRPSO, showed the best
performance among the three versions. Also, PSO proved to be
effective in handling noisy data, especially when its performance
parameters were tuned. An increase in the self-confidence parameter
was also found to be effective, as it increased the global search
capabilities of the algorithm. RPSO was the most effective variation
in dealing with noise, closely followed by CRPSO. The latter
variation is recommended for inverse heat conduction problems, as it
combines the efficiency and effectiveness required by these
problems.
Abstract: Long Distance Truck Drivers (LDTDs) have been
found to be a high risk group in the spread of HIV/AIDS globally;
perhaps, due to their high Sexual Risk Behaviours (SRBs).
Interventions for reducing SRBs in trucking population have not been
fully exploited. A quasi-experimental control group pretest-posttest
design was used to assess the efficacy of psycho-education and
behavioural skills training in reducing SRBs among LDTDs. Sixteen
drivers rivers were randomly assigned into either experimental or
control groups using balloting technique. Questionnaire was used as
an instrument for data collection. Repeated measures t-test and
independent t-test were used to test hypotheses. Intervention had
significant effect on the SRBs among LDTDs at post-test (t{7}=
6.01, p
Abstract: In this paper, a direct power control (DPC)
strategies have been investigated in order to control a high
power AC/DC converter with time variable load. This converter
is composed of a three level three phase neutral point clamped
(NPC) converter as rectifier and an H-bridge four quadrant
current control converter. In the high power application,
controller not only must adjust the desire outputs but also
decrease the level of distortions which are injected to the network
from the converter. Regarding to this reason and nonlinearity
of the power electronic converter, the conventional controllers
cannot achieve appropriate responses. In this research, the
precise mathematical analysis has been employed to design the
appropriate controller in order to control the time variable
load. A DPC controller has been proposed and simulated using
Matlab/ Simulink. In order to verify the simulation result, a real
time simulator- OPAL-RT- has been employed. In this paper,
the dynamic response and stability of the high power NPC
with variable load has been investigated and compared with
conventional types using a real time simulator. The results proved
that the DPC controller is more stable and has more precise
outputs in comparison with conventional controller.
Abstract: The arm length, hand length, hand breadth and middle
finger length of 1540 right-handed industrial workers of Haryana
state was used to assess the relationship between the upper limb
dimensions and stature. Initially, the data were analyzed using basic
univariate analysis and independent t-tests; then simple and multiple
linear regression models were used to estimate stature using SPSS
(version 17). There was a positive correlation between upper limb
measurements (hand length, hand breadth, arm length and middle
finger length) and stature (p < 0.01), which was highest for hand
length. The accuracy of stature prediction ranged from ± 54.897 mm
to ± 58.307 mm. The use of multiple regression equations gave better
results than simple regression equations. This study provides new
forensic standards for stature estimation from the upper limb
measurements of male industrial workers of Haryana (India). The
results of this research indicate that stature can be determined using
hand dimensions with accuracy, when only upper limb is available
due to any reasons likewise explosions, train/plane crashes, mutilated
bodies, etc. The regression formula derived in this study will be
useful for anatomists, archaeologists, anthropologists, design
engineers and forensic scientists for fairly prediction of stature using
regression equations.
Abstract: This paper describes an Action Research project
which was undertaken to inform professional practice in order to
develop a newly created Centre for Student Success in the specific
context of transnational medical and nursing education in the Middle
East. The objectives were to enhance the academic performance,
persistence, integration and personal and professional development of
a multinational study body, in particular in relation to pre-clinical
medical students, and to establish a comfortable, friendly and
student-driven environment within an Irish medical university
recently established in Bahrain. The outcomes of the project resulted
in the development of a specific student success ‘signature’ for this
particular transnational higher education context.
Abstract: A three-dimensional numerical model of
thermoelectric generator (TEG) modules attached to a large chimney
plate is proposed and solved numerically using a control volume based
finite difference formulation. The TEG module consists of a
thermoelectric generator, an elliptical pin-fin heat sink, and a cold
plate for water cooling. In the chimney, the temperature of flue gases is
450-650K. Although the TEG hot-side temperature and thus the
electric power output can be increased by inserting an elliptical pin-fin
heat sink into the chimney tunnel to increase the heat transfer area, the
pin fin heat sink would cause extra pumping power at the same time.
The main purpose of this study is to analyze the effects of geometrical
parameters on the electric power output and chimney pressure drop
characteristics. The effects of different operating conditions, including
various inlet velocities (Vin= 1, 3, 5 m/s), inlet temperatures (Tgas = 450,
550, 650K) and different fin height (0 to 150 mm) are discussed in
detail. The predicted numerical data for the power vs. current (P-I)
curve are in good agreement (within 11%) with the experimental data.
Abstract: This study analyzes the innovative orientation of the
Croatian entrepreneurs. Innovative orientation is represented by the
perceived extent to which an entrepreneur’s product or service or
technology is new, and no other businesses offer the same product.
The sample is extracted from the GEM Croatia Adult Population
Survey dataset for the years 2003-2013. We apply descriptive
statistics, t-test, Chi-square test and logistic regression. Findings
indicate that innovative orientations vary with personal, firm, meso
and macro level variables, and between different stages in
entrepreneurship process. Significant predictors are occupation of the
entrepreneurs, size of the firm and export aspiration for both early
stage and established entrepreneurs. In addition, fear of failure,
expecting to start a new business and seeing an entrepreneurial career
as a desirable choice are predictors of innovative orientation among
early stage entrepreneurs.
Abstract: Using the first-principles full-potential linearized
augmented plane wave plus local orbital (FP-LAPW+lo) method
based on density functional theory (DFT), we have investigated the
electronic structure and magnetism of full Heusler alloys Co2ZrGe
and Co2NbB. These compounds are predicted to be half-metallic
ferromagnets (HMFs) with a total magnetic moment of 2.000 B per
formula unit, well consistent with the Slater-Pauling rule.
Calculations show that both the alloys have an indirect band gaps, in
the minority-spin channel of density of states (DOS), with values of
0.58 eV and 0.47 eV for Co2ZrGe and Co2NbB, respectively.
Analysis of the DOS and magnetic moments indicates that their
magnetism is mainly related to the d-d hybridization between the Co
and Zr (or Nb) atoms. The half-metallicity is found to be relatively
robust against volume changes. In addition, an atom inside molecule
AIM formalism and an electron localization function ELF were also
adopted to study the bonding properties of these compounds, building
a bridge between their electronic and bonding behavior.
As they have a good crystallographic compatibility with the lattice of
semiconductors used industrially and negative calculated cohesive
energies with considerable absolute values these two alloys could be
promising magnetic materials in the spintronic field.
Abstract: In recent years parasitic antenna play major role in
MIMO systems because of their gain and spectral efficiency. In this
paper, single RF chain MIMO transmitter is designed using
reconfigurable parasitic antenna. The Spatial Modulation (SM) is a
recently proposed scheme in MIMO scenario which activates only
one antenna at a time. The SM entirely avoids ICI and IAS, and only
requires a single RF chain at the transmitter. This would switch ON a
single transmit-antenna for data transmission while all the other
antennas are kept silent. The purpose of the parasitic elements is to
change the radiation pattern of the radio waves which is emitted from
the driven element and directing them in one direction and hence
introduces transmit diversity. Diode is connect between the patch and
ground by changing its state (ON and OFF) the parasitic element act
as reflector and director and also capable of steering azimuth and
elevation angle. This can be achieved by changing the input
impedance of each parasitic element through single RF chain. The
switching of diode would select the single parasitic antenna for
spatial modulation. This antenna is expected to achieve maximum
gain with desired efficiency.
Abstract: Morphological interaction of porcine cumulus-oocyte
complexes (pCOCs) was investigated on in vitro condition using
electron microscope (SEM and TEM). The totals of 1,923 oocytes
were round in shape, surrounded by Zona pellucida with layer of
cumulus cells ranging between 59.29-202.14 μm in size. They were
classified into intact-, multi-, partial cumulus cell layer oocyte, and
completely denuded oocyte, at the percentage composition of 22.80%
32.70%, 18.60%, and 25.90 % respectively. The pCOCs classified as
intact- and multi cumulus cell layer oocytes were further culturing at
37°C with 5% CO2, 95% air atmosphere and high humidity for 44 h
in M199 with Earle’s salts supplemented with 10% HTFCS, 2.2
mg/mL NaHCO3, 1 M Hepes, 0.25 mM pyruvate, 15 μg/mL porcine
follicle-stimulating hormone, 1 μg/mL LH, 1μg/mL estradiol with
ethanol, and 50 μg/mL gentamycin sulfate. On electron microscope
study, cumulus cells were found to stick their processes to secrete
substance from the sac-shape end into Zona pellucida of the oocyte
and also communicated with the neighboring cells through their
microvilli on the beginning of incubation period. It is believed that
the cumulus cells communicate with the oocyte by inserting the
microvilli through this gap and embedded in the oocyte cytoplasm
before secreting substance, through the sac-shape end of the
microvilli, to inhibit primary oocyte development at the prophase I.
Morphological changes of the complexes were observed after
culturing for 24-44 h. One hundred percentages of the cumulus layers
were expanded and cumulus cells were peeling off from the oocyte
surface. In addition, the round-shape cumulus cells transformed
themselves into either an elongate shape or a columnar shape, and no
communication between cumulus neighboring cells. After 44 h of
incubation time, diameter of oocytes surrounded by cumulus cells
was larger than 0 h incubation. The effect of hormones in culture
medium is exerted by their receptors present in porcine oocyte. It is
likely that all morphological changes of the complexes after hormone
treatment were to allow maturation of the oocyte. This study
demonstrated that the association of hormones in M199 could
promote porcine follicle activation in 44 h in vitro condition. This
culture system should be useful for studying the regulation of early
follicular growth and development, especially because these follicles represent a large source of oocytes that could be used in vitro for cell
technology.