Abstract: A novel thermo-sensitive superabsorbent hydrogel
with salt- and pH-responsiveness properties was obtained by grafting
of mixtures of acrylic acid (AA) and N-isopropylacrylamide
(NIPAM) monomers onto kappa-carrageenan, kC, using ammonium
persulfate (APS) as a free radical initiator in the presence of
methylene bisacrylamide (MBA) as a crosslinker. Infrared
spectroscopy was carried out to confirm the chemical structure of the
hydrogel. Moreover, morphology of the samples was examined by
scanning electron microscopy (SEM). The effect of MBA
concentration and AA/NIPAM weight ratio on the water absorbency
capacity has been investigated. The swelling variations of hydrogels
were explained according to swelling theory based on the hydrogel
chemical structure. The hydrogels exhibited salt-sensitivity and
cation exchange properties. The temperature- and pH-reversibility
properties of the hydrogels make the intelligent polymers as good
candidates for considering as potential carriers for bioactive agents,
e.g. drugs.
Abstract: A large number of chemical, bio-chemical and pollution-control processes use heterogeneous fixed-bed reactors. The use of finite hollow cylindrical catalyst pellets can enhance conversion levels in such reactors. The absence of the pellet core can significantly lower the diffusional resistance associated with the solid phase. This leads to a better utilization of the catalytic material, which is reflected in the higher values for the effectiveness factor, leading ultimately to an enhanced conversion level in the reactor. It is however important to develop a rigorous heterogeneous model for the reactor incorporating the two-dimensional feature of the solid phase owing to the presence of the finite hollow cylindrical catalyst pellet. Presently, heterogeneous models reported in the literature invariably employ one-dimension solid phase models meant for spherical catalyst pellets. The objective of the paper is to present a rigorous model of the fixed-bed reactors containing finite hollow cylindrical catalyst pellets. The reaction kinetics considered here is the widely used Michaelis–Menten kinetics for the liquid-phase bio-chemical reactions. The reaction parameters used here are for the enzymatic degradation of urea. Results indicate that increasing the height to diameter ratio helps to improve the conversion level. On the other hand, decreasing the thickness is apparently not as effective. This could however be explained in terms of the higher void fraction of the bed that causes a smaller amount of the solid phase to be packed in the fixed-bed bio-chemical reactor.
Abstract: Nowadays it is a trend for electronic circuit designers to
integrate all system components on a single-chip. This paper proposed
the design of a single-chip proportional to absolute temperature
(PTAT) sensor including a voltage reference circuit using CEDEC
0.18m CMOS Technology. It is a challenge to design asingle-chip
wide range linear response temperature sensor for many applications.
The channel widths between the compensation transistor and the
reference transistor are critical to design the PTAT temperature sensor
circuit. The designed temperature sensor shows excellent linearity
between -100°C to 200° and the sensitivity is about 0.05mV/°C.
The chip is designed to operate with a single voltage source of 1.6V.
Abstract: The recycling of concrete, bricks and masonry rubble
as concrete aggregates is an important way to contribute to a
sustainable material flow. However, there are still various
uncertainties limiting the widespread use of Recycled Concrete
Aggregates (RCA). The fluctuations in the composition of grade
recycled aggregates and their influence on the properties of fresh and
hardened concrete are of particular concern regarding the use of
RCA. Most of problems occurring while using recycled concrete
aggregates as aggregates are due to higher porosity and hence higher
water absorption, lower mechanical strengths, residual impurities on
the surface of the RCA forming weaker bond between cement paste
and aggregate. So, the reuse of RCA is still limited. Efficient
polymer based treatment is proposed in order to reuse RCA easier.
The silicon-based polymer treatments of RCA were carried out and
were compared. This kind of treatment can improve the properties of
RCA such as the rate of water absorption on treated RCA is
significantly reduced.
Abstract: This study was to investigate the performance of
hybrid solvents blended between primary, secondary, or tertiary
amines and piperazine (PZ) for CO2 removal from flue gas in terms
of CO2 absorption capacity and regeneration efficiency at 90 oC.
Alkanolamines used in this work were monoethanolamine (MEA),
diethanolamine (DEA), and triethanolamine (TEA). The CO2
absorption was experimentally examined under atmospheric pressure
and room temperature. The results show that MEA blend with PZ
provided the maximum CO2 absorption capacity of 0.50 mol
CO2/mol amine while TEA provided the minimum CO2 absorption
capacity of 0.30 mol CO2/mol amine. TEA was easier to regenerate
for both first cycle and second cycle with less loss of absorption
capacity. The regeneration efficiency of TEA was 95.09 and 92.89 %,
for the first and second generation cycles, respectively.
Abstract: In this paper dynamics of a vapour bubble generated
due to a local energy input inside a vertical rigid cylinder and in the
absence of buoyancy forces is investigated. Different ratios of the
diameter of the rigid cylinder to the maximum radius of the bubble
are considered. The Boundary Integral Equation Method is employed
for numerical simulation of the problem. Results show that during
the collapse phase of the bubble inside a vertical rigid cylinder, two
liquid micro jets are developed on the top and bottom sides of the
vapour bubble and are directed inward. Results also show that
existence of a deposit rib inside the vertical rigid cylinder slightly
increases the life time of the bubble. It is found that by increasing the
ratio of the cylinder diameter to the maximum radius of the bubble,
the rate of the growth and collapse phases of the bubble increases
and the life time of the bubble decreases.
Abstract: This study realizes an empirical investigation of main factors to develop an accounting career, stereotypes on accountants and accounting and perceptions on future career path for a sample of master students in accounting. The research provides some insight into what master students consider when choosing their future career paths. The most important two reasons chosen by students were “career opportunities" and “future earnings. They see accounting as structured, governed by conformity, requiring skills in working with numbers, monotonous, accurate, more efficient than effective but also absorbing, interesting and involving a certain degree of novelty. Although these students plan to start their careers in a multinational or accounting/audit firm, most of those plan to leave after five years. It resulted that women value more flexibility and time requiring special attention in retention policies practiced by firms.
Abstract: Hydrogenated biodiesel is one of the most promising
renewable fuels. It has many advantages over conventional biodiesel,
including higher cetane number, higher heating value, lower
viscosity, and lower corrosiveness due to its absence of oxygen.
From previous work, Pd/TiO2 gave high conversion and selectivity in
hydrogenated biodiesel. In this work, the effect of biomass feedstocks
(i.e. beef fat, chicken fat, pork fat, and jatropha oil) on the production
of hydrogenated biodiesel over Pd/TiO2 has been studied. Biomass
feedstocks were analyzed by ICP-OES (inductively coupled plasma
optical emission spectrometry) to identify the content of impurities
(i.e. P, K, Ca, Na, and Mg). The deoxygenation catalyst, Pd/TiO2,
was prepared by incipient wetness impregnation (IWI) and tested in a
continuous flow packed-bed reactor at 500 psig, 325°C, H2/feed
molar ratio of 30, and LHSV of 4 h-1 for its catalytic activity and
selectivity in hydrodeoxygenation. All feedstocks gave high
selectivity in diesel specification range hydrocarbons and the main
hydrocarbons were n-pentadecane (n-C15) and n-heptadecane (n-
C17), resulting from the decarbonylation/decarboxylation reaction.
Intermediates such as oleic acid, stearic acid, palmitic acid, and esters
were also detected in minor amount. The conversion of triglycerides
in jatropha oil is higher than those of chicken fat, pork fat, and beef
fat, respectively. The higher concentration of metal impurities in
feedstock, the lower conversion of feedstock.
Abstract: Heterogeneous catalysis is vital for a number of
chemical, refinery and pollution control processes. The use of
catalyst pellets of hollow cylindrical shape provide several distinct
advantages over other common shapes, and can therefore help to
enhance conversion levels in reactors. A better utilization of the
catalytic material is probably most notable of these features due to
the absence of the pellet core, which helps to significantly lower the
effect of the internal transport resistance. This is reflected in the
enhancement of the effectiveness factor. For the case of the first order
irreversible kinetics, a substantial increase in the effectiveness factor
can be obtained by varying shape parameters. Important shape
parameters of a finite hollow cylinder are the ratio of the inside to the
outside radii (κ) and the height to the diameter ratio (γ). A high value
of κ the generally helps to enhance the effectiveness factor. On the
other hand, lower values of the effectiveness factors are obtained
when the dimension of the height and the diameter are comparable.
Thus, the departure of parameter γ from the unity favors higher
effectiveness factor. Since a higher effectiveness factor is a measure
of a greater utilization of the catalytic material, higher conversion
levels can be achieved using the hollow cylindrical pellets possessing
optimized shape parameters.
Abstract: Renewable natural fibres such as oil palm, flax, and
pineapple leaf can be utilized to obtain new high performance
polymer materials. The reuse of waste natural fibres as reinforcement
for polymer is a sustainable option to the environment. However, due
to its high hydroxyl content of cellulose, natural fibres are
susceptible to absorb water that affects the composite mechanical
properties adversely. Research found that Nano materials such as
Nano Silica Carbide (n-SiC) and Nano Clay can be added into the
polymer composite to overcome this problem by enhancing its
mechanical properties in wet condition. The addition of Nano
material improves the tensile and wear properties, flexural stressstrain
behaviour, fracture toughness, and fracture strength of polymer
natural composites in wet and dry conditions.
Abstract: The running logs of a process hold valuable
information about its executed activity behavior and generated activity
logic structure. Theses informative logs can be extracted, analyzed and
utilized to improve the efficiencies of the process's execution and
conduction. One of the techniques used to accomplish the process
improvement is called as process mining. To mine similar processes is
such an improvement mission in process mining. Rather than directly
mining similar processes using a single comparing coefficient or a
complicate fitness function, this paper presents a simplified heuristic
process mining algorithm with two similarity comparisons that are
able to relatively conform the activity logic sequences (traces) of
mining processes with those of a normalized (regularized) one. The
relative process conformance is to find which of the mining processes
match the required activity sequences and relationships, further for
necessary and sufficient applications of the mined processes to process
improvements. One similarity presented is defined by the relationships
in terms of the number of similar activity sequences existing in
different processes; another similarity expresses the degree of the
similar (identical) activity sequences among the conforming processes.
Since these two similarities are with respect to certain typical behavior
(activity sequences) occurred in an entire process, the common
problems, such as the inappropriateness of an absolute comparison and
the incapability of an intrinsic information elicitation, which are often
appeared in other process conforming techniques, can be solved by the
relative process comparison presented in this paper. To demonstrate
the potentiality of the proposed algorithm, a numerical example is
illustrated.
Abstract: The nickel and gold nanoclusters as supported
catalysts were analyzed by XAS, XRD and XPS in order to
determine their local, global and electronic structure. The present
study has pointed out a strong deformation of the local structure of
the metal, due to its interaction with oxide supports. The average
particle size, the mean squares of the microstrain, the particle size
distribution and microstrain functions of the supported Ni and Au
catalysts were determined by XRD method using Generalized Fermi
Function for the X-ray line profiles approximation. Based on EXAFS
analysis we consider that the local structure of the investigated
systems is strongly distorted concerning the atomic number pairs.
Metal-support interaction is confirmed by the shape changes of the
probability densities of electron transitions: Ni K edge (1s →
continuum and 2p), Au LIII-edge (2p3/2 → continuum, 6s, 6d5/2 and
6d3/2). XPS investigations confirm the metal-support interaction at
their interface.
Abstract: The objectif of the present work is to determinate the
potential of the solar parabolic trough collector (PTC) for use in the
design of a solar thermal power plant in Algeria. The study is based
on a mathematical modeling of the PTC. Heat balance has been
established respectively on the heat transfer fluid (HTF), the absorber
tube and the glass envelop using the principle of energy conservation
at each surface of the HCE cross-sectionn. The modified Euler
method is used to solve the obtained differential equations. At first
the results for typical days of two seasons the thermal behavior of the
HTF, the absorber and the envelope are obtained. Then to determine
the thermal performances of the heat transfer fluid, different oils are
considered and their temperature and heat gain evolutions compared.
Abstract: Three sulphonic acid-doped polyanilines were
synthesized through chemical oxidation at low temperature (0-5 oC)
and potential of these polymers as sensing agent for O2 gas detection
in terms of fluorescence quenching was studied. Sulphuric acid,
dodecylbenzene sulphonic acid (DBSA) and camphor sulphonic acid
(CSA) were used as doping agents. All polymers obtained were dark
green powder. Polymers obtained were characterized by Fourier
transform infrared spectroscopy, ultraviolet-visible absorption
spectroscopy, thermogravimetry analysis, elemental analysis,
differential scanning calorimeter and gel permeation
chromatography. Characterizations carried out showed that polymers
were successfully synthesized with mass recovery for sulphuric aciddoped
polyaniline (SPAN), DBSA-doped polyaniline (DBSA-doped
PANI) and CSA-doped polyaniline (CSA-doped PANI) of 71.40%,
75.00% and 39.96%, respectively. Doping level of SPAN, DBSAdoped
PANI and CSA-doped PANI were 32.86%, 33.13% and
53.96%, respectively as determined based on elemental analysis.
Sensing test was carried out on polymer sample in the form of
solution and film by using fluorescence spectrophotometer. Samples
of polymer solution and polymer film showed positive response
towards O2 exposure. All polymer solutions and films were fully
regenerated by using N2 gas within 1 hour period. Photostability
study showed that all samples of polymer solutions and films were
stable towards light when continuously exposed to xenon lamp for 9
hours. The relative standard deviation (RSD) values for SPAN
solution, DBSA-doped PANI solution and CSA-doped PANI
solution for repeatability were 0.23%, 0.64% and 0.76%,
respectively. Meanwhile RSD values for reproducibility were 2.36%,
6.98% and 1.27%, respectively. Results for SPAN film, DBSAdoped
PANI film and CSA-doped PANI film showed the same
pattern with RSD values for repeatability of 0.52%, 4.05% and
0.90%, respectively. Meanwhile RSD values for reproducibility were
2.91%, 10.05% and 7.42%, respectively. The study on effect of the
flow rate on response time was carried out using 3 different rates
which were 0.25 mL/s, 1.00 mL/s and 2.00 mL/s. Results obtained
showed that the higher the flow rate, the shorter the response time.
Abstract: In this paper, an automated algorithm to estimate and remove the continuous baseline from measured spectra containing both continuous and discontinuous bands is proposed. The algorithm uses previous information contained in a Continuous Database Spectra (CDBS) to obtain a linear basis, with minimum number of sampled vectors, capable of representing a continuous baseline. The proposed algorithm was tested by using a CDBS of flame spectra where Principal Components Analysis and Non-negative Matrix Factorization were used to obtain linear bases. Thus, the radical emissions of natural gas, oil and bio-oil flames spectra at different combustion conditions were obtained. In order to validate the performance in the baseline estimation process, the Goodness-of-fit Coefficient and the Root Mean-squared Error quality metrics were evaluated between the estimated and the real spectra in absence of discontinuous emission. The achieved results make the proposed method a key element in the development of automatic monitoring processes strategies involving discontinuous spectral bands.
Abstract: Many applications require surface modification and
micro-structuring of polymers. For these purposes is mainly used
ultraviolet (UV) radiation from excimer lamps or excimer lasers.
However, these sources have a decided disadvantage - degrading the
polymer deep inside due to relatively big radiation penetration depth
which may exceed 100 μm. In contrast, extreme ultraviolet (EUV)
radiation is absorbed in a layer approximately 100 nm thick only. In
this work, the radiation from a discharge-plasma EUV source (with
wavelength 46.9 nm) based on a capillary discharge driver is focused
with a spherical Si/Sc multilayer mirror for surface modification of
PMMA sample or thin gold layer (thickness about 40 nm). It was
found that the focused EUV laser beam is capable by one shot to
ablate PMMA or layer of gold, even if the focus is significantly
influenced by astigmatism.
Abstract: The storage of chemical fertilizers in concrete building often leads to durability problems due to chemical attack. The damage of concrete is mostly caused by certain ammonium salts. The main purpose of the research is to investigate the durability properties of concrete being exposed to ammonium nitrate solution. In this investigation, experiments are conducted on concrete type G50 and G60. The leaching process is achieved by the use of 20% concentration solution of ammonium nitrate. The durability properties investigated are water absorption, volume of permeable voids, and sorptivity. Compressive strength, pH value, and degradation depth are measured after a certain period of leaching. A decrease in compressive strength and an increase in porosity are found through the conducted experiments. Apart from that, the experimental data shows that pH value decreases with increased leaching time while the degradation depth of concrete increases with leaching time. By comparing concrete type G50 and G60, concrete type G60 is more resistant to ammonium nitrate attack.
Abstract: This paper investigates experimental studies on
vibration suppression for a cantilever beam using an
Electro-Rheological (ER) sandwich shock absorber. ER fluid (ERF) is a
class of smart materials that can undergo significant reversible changes
immediately in its rheological and mechanical properties under the
influence of an applied electric field. Firstly, an ER sandwich beam is
fabricated by inserting a starch-based ERF into a hollow composite
beam. At the same time, experimental investigations are focused on the
frequency response of the ERF sandwich beam. Second, the ERF
sandwich beam is attached to a cantilever beam to become as a shock
absorber. Finally, a fuzzy semi-active vibration control is designed to
suppress the vibration of the cantilever beam via the ERF sandwich
shock absorber. To check the consistency of the proposed fuzzy
controller, the real-time implementation validated the performance of
the controller.
Abstract: Lanthanide-doped upconversion nanoparticles which can convert near-infrared lights to visible lights have attracted growing interest because of their great potentials in fluorescence imaging. Upconversion fluorescence imaging technique with excitation in the near-infrared (NIR) region has been used for imaging of biological cells and tissues. However, improving the detection sensitivity and decreasing the absorption and scattering in biological tissues are as yet unresolved problems. In this present study, a novel NIR-reflected multispectral imaging system was developed for upconversion fluorescent imaging in small animals. Based on this system, we have obtained the high contrast images without the autofluorescence when biocompatible UCPs were injected near the body surface or deeply into the tissue. Furthermore, we have extracted respective spectra of the upconversion fluorescence and relatively quantify the fluorescence intensity with the multispectral analysis. To our knowledge, this is the first time to analyze and quantify the upconversion fluorescence in the small animal imaging.