Abstract: Superabsorbent polymers received much attention and
are used in many fields because of their superior characters to
traditional absorbents, e.g., sponge and cotton. So, it is very
important but challenging to prepare highly and fast-swelling
superabsorbents. A reliable, efficient and low-cost technique for
removing heavy metal ions from wastewater is the adsorption using
bio-adsorbents obtained from biological materials, such as
polysaccharides-based hydrogels superabsorbents. In this study, novel multi-functional superabsorbent composites
type semi-interpenetrating polymer networks (Semi-IPNs) were
prepared via graft polymerization of acrylamide onto chitosan
backbone in presence of gelatin, CTS-g-PAAm/Ge, using potassium
persulfate and N,N’-methylene bisacrylamide as initiator and
crosslinker, respectively. These hydrogels were also partially
hydrolyzed to achieve superabsorbents with ampholytic properties
and uppermost swelling capacity. The formation of the grafted
network was evidenced by Fourier Transform Infrared Spectroscopy
(ATR-FTIR) and Thermogravimetric Analysis (TGA). The porous
structures were observed by Scanning Electron Microscope (SEM).
From TGA analysis, it was concluded that the incorporation of the Ge
in the CTS-g-PAAm network has marginally affected its thermal
stability. The effect of gelatin content on the swelling capacities of
these superabsorbent composites was examined in various media
(distilled water, saline and pH-solutions). The water absorbency was
enhanced by adding Ge in the network, where the optimum value was
reached at 2 wt. % of Ge. Their hydrolysis has not only greatly
optimized their absorption capacity but also improved the swelling
kinetic.These materials have also showed reswelling ability. We
believe that these super-absorbing materials would be very effective
for the adsorption of harmful metal ions from wastewater.
Abstract: This paper describes a novel sensor device, a pressure
pulse wave meter, which uses a bidirectional condenser microphone.
The microphone work as a microphone as well as a sensor with high
gain over a wide frequency range; they are also highly reliable and
economic. Currently aging is becoming a serious social issue in Japan causing
increased medical expenses in the country. Hence, it is important for
elderly citizens to check health condition at home, and to care the
health conditions through daily monitoring. Given this circumstances,
we developed a novel pressure pulse wave meter based on a
bidirectional condenser microphone: this device is used as a measuring
instrument of health conditions.
Abstract: Despite the advances made in various new
technologies, application of these technologies for agriculture still
remains a formidable task, as it involves integration of diverse
domains for monitoring the different process involved in agricultural
management. Advances in ambient intelligence technology represents
one of the most powerful technology for increasing the yield of
agricultural crops and to mitigate the impact of water scarcity,
climatic change and methods for managing pests, weeds and diseases.
This paper proposes a GPS-assisted, machine to machine solutions
that combine information collected by multiple sensors for the
automated management of paddy crops. To maintain the economic
viability of paddy cultivation, the various techniques used in
agriculture are discussed and a novel system which uses ambient
intelligence technique is proposed in this paper. The ambient
intelligence based agricultural system gives a great scope.
Abstract: Present work deals with the possible use of fertigation
in agriculture and its impact on the availability of mineral nitrogen
(Nmin) in topsoil and subsoil horizons. The aim of the present study is
to demonstrate the effect of the organic matter presence in fertigation
on microbial transformation and availability of mineral nitrogen
forms. The main investigation reason is the potential use of pretreated
waste water, as a source of organic carbon (Corg) and residual
nutrients (Nmin) for fertigation. Laboratory experiment has been
conducted to demonstrate the effect of the arable land fertilization
method on the Nmin availability in different depths of the soil with
the usage of model experimental containers filled with soil from
topsoil and podsoil horizons that were taken from the precise area.
Tufted hairgrass (Deschampsia caespitosa) has been chosen as a
model plant. The water source protection zone Brezova nad Svitavou
has been a research area where significant underground reservoirs of
drinking water of the highest quality are located. From the second
half of the last century local sources of drinking water show
nitrogenous compounds increase that get here almost only from
arable lands. Therefore, an attention of the following text focuses on
the fate of mineral nitrogen in the complex plant-soil. Research
results show that the fertigation application with Corg in a
combination with mineral fertilizer can reduce the amount of Nmin
leached from topsoil horizon of agricultural soils. In addition, some
plants biomass production reduces may occur.
Abstract: The rapid growth of multimedia technology demands
the secure and efficient access to information. This fast growing lose
the confidence of unauthorized duplication. Henceforth the protection
of multimedia content is becoming more important. Watermarking
solves the issue of unlawful copy of advanced data. In this paper,
blind video watermarking technique has been proposed. A luminance
layer of selected frames is interlaced into two even and odd rows of
an image, further it is deinterlaced and equalizes the coefficients of
the two shares. Color watermark is split into different blocks, and the
pieces of block are concealed in one of the share under the wavelet
transform. Stack the two images into a single image by introducing
interlaced even and odd rows in the two shares. Finally, chrominance
bands are concatenated with the watermarked luminance band. The
safeguard level of the secret information is high, and it is
undetectable. Results show that the quality of the video is not
changed also yields the better PSNR values.
Abstract: This paper proposes a linear model for optimizing
domestic energy consumption in Romania. The particularity of the
model is that it is putting in competition both tangible technologies
and thermal insulation projects with different financing modes.
The model is optimizing the energy system by minimizing the
global discounted cost in household sector, by integrating residential
lighting, space heating, hot water, combined space heating – hot
water, as well as space cooling, in a monolithic model. Another
demand sector included is the passenger transport.
This paper focuses on space heating part, analyzing technical and
economic issues related to investment decisions to envelope and
insulate buildings, in order to minimize energy consumption.
Abstract: This paper presents results of compressive strength,
capillary water absorption, and density tests conducted on concrete
containing recycled aggregate (RCA) which is obtained from
structural waste generated by the construction industry in Turkey. In
the experiments, 0%, 15%, 30%, 45% and 60% of the normal
(natural) coarse aggregate was replaced by the recycled aggregate.
Maximum aggregate particle sizes were selected as 16 mm, 22,4 mm
and 31,5 mm; and 0,06%, 0,13% and 0,20% of air-entraining agent
(AEA) were used in mixtures. Fly ash and superplasticizer were used
as a mineral and chemical admixture, respectively. The same type
(CEM I 42.5) and constant dosage of cement were used in the study.
Water/cement ratio was kept constant as 0.53 for all mixture. It was
concluded that capillary water absorption, compressive strength, and
density of concrete decreased with increasing RCA ratio. Increasing
in maximum aggregate particle size and amount of AEA also affect
the properties of concrete significantly.
Abstract: Waste Load Allocation (WLA) strategies usually
intend to find economic policies for water resource management.
Water quality trading (WQT) is an approach that uses discharge
permit market to reduce total environmental protection costs. This
primarily requires assigning discharge limits known as total
maximum daily loads (TMDLs). These are determined by monitoring
organizations with respect to the receiving water quality and
remediation capabilities. The purpose of this study is to compare two
approaches of TMDL assignment for WQT policy in small catchment
area of Haraz River, in north of Iran. At first, TMDLs are assigned
uniformly for the whole point sources to keep the concentrations of
BOD and dissolved oxygen (DO) at the standard level at checkpoint
(terminus point). This was simply simulated and controlled by
Qual2kw software. In the second scenario, TMDLs are assigned
using multi objective particle swarm optimization (MOPSO) method
in which the environmental violation at river basin and total treatment
costs are minimized simultaneously. In both scenarios, the equity
index and the WLA based on trading discharge permits (TDP) are
calculated. The comparative results showed that using economically
optimized TMDLs (2nd scenario) has slightly more cost savings rather
than uniform TMDL approach (1st scenario). The former annually
costs about 1 M$ while the latter is 1.15 M$. WQT can decrease
these annual costs to 0.9 and 1.1 M$, respectively. In other word,
these approaches may save 35 and 45% economically in comparison
with command and control policy. It means that using multi objective
decision support systems (DSS) may find more economical WLA,
however its outcome is not necessarily significant in comparison with
uniform TMDLs. This may be due to the similar impact factors of
dischargers in small catchments. Conversely, using uniform TMDLs
for WQT brings more equity that makes stakeholders not feel that
much envious of difference between TMDL and WQT allocation. In
addition, for this case, determination of TMDLs uniformly would be
much easier for monitoring. Consequently, uniform TMDL for TDP
market is recommended as a sustainable approach. However,
economical TMDLs can be used for larger watersheds.
Abstract: Psyllium gum alone and in combination with
sunflower oil was investigated as a possible alternative edible coating
for improvement of quality and shelf life of fresh-cut papaya.
Different concentrations including 0.5, 1 and 1.5 percent of psyllium
gum were used for coating of fresh-cut papaya. In some samples,
refined sunflower oil was used as a lipid component to increase the
effectiveness of coating in terms of water barrier properties. Soya
lecithin was used as an emulsifier in coatings containing oil.
Pretreatment with 1% calcium chloride was given to maintain the
firmness of fresh-cut papaya cubes. 1% psyllium gum coating was
found to yield better results. Further, addition of oil helped to
maintain the quality and acted as a barrier to water vapour, therefore,
minimizing the weight loss.
Abstract: In this study, the feasibility of incorporating ceramic
waste from bricks (perforated brick and double hollow brick) and
extruded polystyrene (XPS) waste, is analysed.
Results show that it is possible to incorporate up to 25% of
ceramic waste and 4% of XPS waste over the weight of gypsum in a
gypsum matrix. Furthermore, with the addition of ceramic waste an
8% of surface hardness increase and a 25% of capillary water
absorption reduction can be obtained. On the other hand, with the
addition of XPS, a 26% reduction of density and a 37% improvement
of thermal conductivity can be obtained.
The obtained results are favorable to use these materials in order to
produce prefabricated gypsum and also as material for interior
cladding walls.
Abstract: Currently, continuous two-phase decanter process
used for olive oil production is the more internationally widespread.
The wastewaters generated from this industry (OMW) are a real
environmental problem because of its high organic load. Among
proposed treatments for these wastewaters, advanced oxidation
technologies (Fenton, ozone, photoFenton, etc.) are the most
favourable. The direct application of these processes is somewhat
expensive. Therefore, the application of a previous stage based on a
flocculation-sedimentation operation is of high importance. In this
research five commercial flocculants (three cationic, and two anionic)
have been used to achieve the separation of phases (liquid clarifiedsludge).
For each flocculant, different concentrations (0-1000 mg/L)
have been studied. In these experiments, sludge volume formed and
the final water quality were determined. The final removal
percentages of total phenols (11.3-25.1%), COD (5.6-20.4%), total
carbon (2.3-26.5%), total organic carbon (1.50-23.8%), total nitrogen
(1.45-24.8%), and turbidity (27.9-61.4%) were determined. The
variation on electric conductivity reduction percentage (1-8%) was
also determined. Finally, the best flocculants with highest removal
percentages have been determined (QG2001 and Flocudex CS49).
Abstract: Mustard leaves are rich in folates, vitamin A, K and
B-complex. Mustard greens are low in calories and fats and rich in
dietary fiber. They are rich in potassium, manganese, iron, copper,
calcium, magnesium and low in sodium. It is very rich in antioxidants
and Phytonutrients. For the optimization of process variables
(moisture content and mustard leave powder), the experiments were
conducted according to central composite Face Centered Composite
design of RSM. The mustard leaves powder was replaced with
composite flour (a combination of rice, chickpea and corn in the ratio
of 70:15:15). The extrudate was extruded in a twin screw extruder at
a barrel temperature of 120°C. The independent variables were
mustard leaves powder (2-10 %) and moisture content (12-20 %).
Responses analyzed were bulk density, water solubility index, water
absorption index, lateral expansion, antioxidant activity, total
phenolic content, and overall acceptability. The optimum conditions
obtained were 7.19 g mustard leaves powder in 100g premix having
16.8% moisture content (w.b).
Abstract: This study aims at developing a novel cold asphalt
concrete binder course mixture by using Ordinary Portland Cement
(OPC) as a replacement for conventional mineral filler (0%-100%)
with new by-product material (LJMU-A2) used as a supplementary
cementitious material. With this purpose, cold asphalt concrete binder
course mixtures with cationic emulsions were studied by means of
stiffness modulus whereas water sensitivity was assessed by
measuring the stiffness modulus ratio before and after sample
conditioning.
The results indicate that a substantial enhancement in the stiffness
modulus and a considerable improvement of water sensitivity
resistance is achieved by adding LJMU-A2 to the cold asphalt
mixtures as a supplementary cementitious material. Moreover, the
addition of LJMU-A2 to those mixtures leads to a stiffness modulus
after 2-day curing compared to that obtained with Portland cement,
which occurs after 7-day curing.
Abstract: Interstitial free steels possess better formability and
have many applications in automotive industries. Forming limit
diagrams (FLDs) indicate the formability of materials which can be
determined by experimental and finite element (FE) simulations.
FLDs were determined experimentally by LDH test, utilizing optical
strain measurement system for measuring the strains in different
width specimens and by FE simulations in Interstitial Free (IF) and
Interstitial Free High Strength (IFHS) steels. In this study, the
experimental and FE simulated FLDs are compared and also the
stress based FLDs were investigated.
Abstract: Remote arid areas of the vast expanses of the African
deserts hold huge subterranean reserves of brackish water resources
waiting for economic development. This work presents design
guidelines as well as initial performance data of new autonomous
solar desalination equipment which could help local communities
produce their own fresh water using solar energy only and, why not,
contribute to transforming desert lands into lush gardens. The output
of solar distillation equipments are typically low and in the range of 3
l/m2/day on the average. This new design with an integrated, water
based, environmentally-friendly solar heat storage system produced 5
l/m2/day in early spring weather. Equipment output during summer
exceeded 9 liters per m2 per day.
Abstract: In this study, breeding biology and induced breeding
of freshwater mud eel, Monopterus cuchia was observed during the
experimental period from February to June, 2013. Breeding biology
of freshwater mud eel, Monopterus cuchia was considered in terms of
gonadosomatic index, length-weight relationship of gonad, ova
diameter and fecundity. The ova diameter was recorded from 0.3 mm
to 4.30 mm and the individual fecundity was recorded from 155 to
1495 while relative fecundity was found from 2.64 to 12.45. The
fecundity related to body weight and length of fish was also
discussed. A peak of GSI was observed 2.14±0.2 in male and 5.1
±1.09 in female. Induced breeding of freshwater mud eel,
Monopterus cuchia was also practiced with different doses of
different inducing agents like pituitary gland (PG), human chorionic
gonadotropin (HCG), Gonadotropin releasing hormone (GnRH) and
Ovuline-a synthetic hormone in different environmental conditions.
However, it was observed that the artificial breeding of freshwater
mud eel, Monopterus cuchia was not yet succeeded through inducing
agents in captive conditions, rather the inducing agent showed
negative impacts on fecundity and ovarian tissues. It was seen that
mature eggs in the oviduct were reduced, absorbed and some eggs
were found in spoiled condition.
Abstract: Mobil Producing Nigeria Unlimited (MPNU), a
subsidiary of ExxonMobil and the highest crude oil & condensate
producer in Nigeria has its operational base and an oil terminal, the
Qua Iboe terminal (QIT) located at Ibeno, Nigeria. Other oil
companies like Network Exploration and Production Nigeria Ltd,
Frontier Oil Ltd; Shell Petroleum Development Company Ltd; Elf
Petroleum Nigeria Ltd and Nigerian Agip Energy, a subsidiary of the
Italian ENI E&P operate onshore, on the continental shelf and in deep
offshore of the Atlantic Ocean, respectively with the coastal waters of
Ibeno, Nigeria as the nearest shoreline. This study was designed to
delineate the oil-polluted sites in Ibeno, Nigeria using
microbiological and physico-chemical characterization of soils,
sediments and ground and surface water samples from the study area.
Results obtained revealed that there have been significant recent
hydrocarbon inputs into this environment as observed from the high
counts of hydrocarbonoclastic microorganisms in excess of 1% at all
the stations sampled. Moreover, high concentrations of THC, BTEX
and heavy metals contents in all the samples analyzed corroborate the
high recent crude oil input into the study area. The results also
showed that the pollution of the different environmental media
sampled were of varying degrees, following the trend: ground water
> surface water > sediments > soils.
Abstract: Land Use Land Cover (LULC) changes due to human
activities and natural causes have become a major environmental
concern. Assessment of temporal remote sensing data provides
information about LULC impacts on environment. Land Surface
Temperature (LST) is one of the important components for modeling
environmental changes in climatological, hydrological, and
agricultural studies. In this study, LULC changes (September 7, 1984
and July 8, 2014) especially in agricultural lands together with
population changes (1985-2014) and LST status were investigated
using remotely sensed and census data in South Marmara Watershed,
Turkey. LULC changes were determined using Landsat TM and
Landsat OLI data acquired in 1984 and 2014 summers. Six-band TM
and OLI images were classified using supervised classification
method to prepare LULC map including five classes including Forest
(F), Grazing Land (G), Agricultural Land (A), Water Surface (W),
Residential Area-Bare Soil (R-B) classes. The LST image was also
derived from thermal bands of the same dates.
LULC classification results showed that forest areas, agricultural
lands, water surfaces and residential area-bare soils were increased as
65751 ha, 20163 ha, 1924 ha and 20462 ha respectively. In
comparison, a dramatic decrement occurred in grazing land (107985
ha) within three decades. The population increased 29% between
years 1984-2014 in whole study area. Along with the natural causes,
migration also caused this increase since the study area has an
important employment potential. LULC was transformed among the
classes due to the expansion in residential, commercial and industrial
areas as well as political decisions. In the study, results showed that
agricultural lands around the settlement areas transformed to
residential areas in 30 years.
The LST images showed that mean temperatures were ranged
between 26-32°C in 1984 and 27-33°C in 2014. Minimum
temperature of agricultural lands was increased 3°C and reached to
23°C. In contrast, maximum temperature of A class decreased to
41°C from 44°C. Considering temperatures of the 2014 R-B class and
1984 status of same areas, it was seen that mean, min and max
temperatures increased by 2°C.
As a result, the dynamism of population, LULC and LST resulted
in increasing mean and maximum surface temperatures, living
spaces/industrial areas and agricultural lands.
Abstract: Evapotranspiration is one of the most important
components of the hydrological cycle. Evapotranspiration (ETo) is an
important variable in water and energy balances on the earth’s
surface, and knowledge of the distribution of ET is a key factor in
hydrology, climatology, agronomy and ecology studies. Many
researchers have a valid relationship, which is a function of climate
factors, to estimate the potential evapotranspiration presented to the
plant water stress or water loss, prevent. The FAO-Penman method
(PM) had been recommended as a standard method. This method
requires many data and these data are not available in every area of
world. So, other methods should be evaluated for these conditions.
When sufficient or reliable data to solve the PM equation are not
available then Hargreaves equation can be used. The Hargreaves
equation (HG) requires only daily mean, maximum and minimum air
temperature extraterrestrial radiation .In this study, Hargreaves
method (HG) were evaluated in 12 stations in the North West region
of Iran. Results of HG and M.HG methods were compared with
results of PM method. Statistical analysis of this comparison showed
that calibration process has had significant effect on efficiency of
Hargreaves method.
Abstract: Fibre cement plates, often used in construction,
generally are made using quartz as an inert material, cement as a
binder and cellulose as a fibre. This paper, first of all, investigates the
mechanical properties and durability of fibre cement plates when
quartz is both partly and fully replaced with diatomite. Diatomite
does not only have lower density compared to quartz but also has
high pozzolanic activity. The main objective of this paper is the
investigation of the effects of supplementary cementing materials
(SCMs) on the short and long term mechanical properties and
durability characteristics of fibre cement plates prepared using
diatomite. Supplementary cementing materials such as ground
granulated blast furnace slug (GGBS) and fly ash (FA) are used in
this study. Volume proportions of 10, 20, 30 and 40% of GGBS and
FA are used as partial replacement materials to cement. Short and
long term mechanical properties such as compressive and flexural
strengths as well as sorptivity characteristics and mass were
investigated. Consistency and setting time at each replacement levels
of SCMs were also recorded. The effects of using supplementary
cementing materials on the carbonation and sulphate resistance of
fibre cement plates were then experimented. The results, first of all,
show that the use of diatomite as a full or partial replacement to
quartz resulted in a systematic decrease in total mass of the fibre
cement plates. The reduction of mass was largely due to the lower
density and finer particle size of diatomite compared to quartz. The
use of diatomite did not only reduce the mass of these plates but also
increased the compressive strength significantly as a result of its high
pozzolanic activity. The replacement levels of both GGBS and FA
resulted in a systematic decrease in short term compressive strength
with increasing replacement levels. This was essentially expected as
the total rate of hydration is much lower in GGBS and FA than that
of cement. Long term results however, indicated that the compressive
strength of fibre cement plates prepared using both GGBS and FA
increases with time and hence the compressive strength of plates
prepared using SCMs is either equivalent or more than the
compressive strength of plates prepared using cement alone.
Durability characteristics of fibre cement plates prepared using SCMs
were enhanced significantly. Measurements of sopritivty
characteristics were also indicated that the plates prepared using
SCMs has much lower water absorption capacities compared to
plates prepared cement alone. Much higher resistance to carbonation
and sulphate attach were observed with plates prepared using SCMs.
The results presented in this paper show that the use of SCMs does
not only support the production of more sustainable construction
materials but also enhances the mechanical properties and durability
characteristics of fibre cement plates.