Abstract: Polycyclic Aromatic Hydrocarbons (PAHs) are
formed mainly because of incomplete combustion of organic
materials during industrial, domestic activities or natural occurrence.
Their toxicity and contamination of terrestrial and aquatic ecosystem
have been established. However, with limited validity index, previous
research has focused on PAHs isomer pair ratios of variable
physicochemical properties in source identification. The objective of
this investigation was to determine the empirical validity of Pearson
Correlation Coefficient (PCC) and Cluster Analysis (CA) in PAHs
source identification along soil samples of different land uses.
Therefore, 16 PAHs grouped, as Endocrine Disruption Substances
(EDSs) were determined in 10 sample stations in top and sub soils
seasonally. PAHs was determined the use of Varian 300 gas
chromatograph interfaced with flame ionization detector. Instruments
and reagents used are of standard and chromatographic grades
respectively. PCC and CA results showed that the classification of
PAHs along pyrolitic and petrogenic organics used in source
signature is about the predominance PAHs in environmental matrix.
Therefore, the distribution of PAHs in the studied stations revealed
the presence of trace quantities of the vast majority of the sixteen
PAHs, which may ultimately inhabit the actual source signature
authentication. Therefore, factors to be considered when evaluating
possible sources of PAHs could be; type and extent of bacterial
metabolism, transformation products/substrates, and environmental
factors such as salinity, pH, oxygen concentration, nutrients, light
intensity, temperature, co-substrates, and environmental medium are
hereby recommended as factors to be considered when evaluating
possible sources of PAHs.
Abstract: The paper is focused to the evaluation railway tracks
in the Slovakia by using Multi-Criteria method. Evaluation of railway
tracks has important impacts for the assessment of investment in
technical equipment. Evaluation of railway tracks also has an
important impact for the allocation of marshalling yards. Marshalling
yards are in transport model as centers for the operation assigned
catchment area. This model is one of the effective ways to meet the
development strategy of the European Community's railways. By
applying this model in practice, a transport company can guarantee a
higher quality of service and then expect an increase in performance.
The model is also applicable to other rail networks. This model
supplements a theoretical problem of train formation problem of new
ways of looking at evaluation of factors affecting the organization of
wagon flows.
Abstract: The article includes the results and conclusions from
empirical researches that had been done. The research focuses on the
impact of investments made in small and medium-sized enterprises
financed from EU funds on the competitiveness of these companies.
The researches includes financial results in sales revenue and net
income, expenses, and many other new products/services on offer,
higher quality products and services, more modern methods of
production, innovation in management processes, increase in the
number of customers, increase in market share, increase in
profitability of production and provision of services. The main
conclusions are that, companies with direct investments under this
measure shall apply the modern methods of production. The
consequence of this is to increase the quality of our products and
services. Furthermore, both small and medium-sized enterprises have
introduced new products and services. Investments were carried out,
thus enabling better work organization in enterprises. Entrepreneurs
would guarantee higher quality of service, which would result in
better relationships with their customers, what is more, noting the rise
in number of clients. More than half of the companies indicated that
the investments contributed to the increase in market share. Same
thing as for market reach and brand recognition of particular
company. An interesting finding is that, investments in small
enterprises were more effective than medium-sized enterprises.
Abstract: The purpose of the study was to examine lifelong
education for teachers as a tool for achieving effective teaching and
learning. Lifelong education enhances social inclusion, personal
development, citizenship, employability, teaching and learning,
community and the nation. It is imperative that the teacher needs to
update his knowledge regularly to be able to perform optimally, since
he has a major position in the inculcation of desirable elements in
students, and the challenges of lifelong education were also
discussed. Descriptive survey design was adopted for the study. A
simple random sampling technique was used to select 80 teachers as
sample from a population of 105 senior secondary school teachers in
Makurdi Local Government Area of Benue State. A 20-item self
designed questionnaire subjected to expert validation and reliability
was used to collect data. The reliability Alpha coefficient of 0.87 was
established using Cronbach’s Alpha technique, mean scores and
standard deviation were used to answer the 2 research questions
while chi-square was used to analyse data for the 2 null hypotheses,
which states that lifelong education for teachers is not a significant
tool for achieving effective teaching and lifelong education for
teachers does not significantly impact on effective learning. The
findings of the study revealed that, lifelong education for teachers can
be used as a tool for achieving effective teaching and learning, and
the study recommended among others that government, organizations
and individuals should in collaboration put lifelong education
programmes for teachers on the priority list. The paper concluded
that the strategic position of lifelong education for teachers towards
enhanced teaching, learning and the production of quality manpower
in the society makes it imperative for all hands to be on “deck” to
support the programme financially and otherwise.
Abstract: The paper is focused on the operational model for
transport the single wagon consignments on railway network by
using two different models of train formation. The paper gives an
overview of possibilities of improving the quality of transport
services. Paper deals with two models used in problematic of train
formatting - time continuously and time discrete. By applying these
models in practice, the transport company can guarantee a higher
quality of service and expect increasing of transport performance.
The models are also applicable into others transport networks. The
models supplement a theoretical problem of train formation by new
ways of looking to affecting the organization of wagon flows.
Abstract: Introduction: The process to build a better safety
culture, methods of error analysis, and preventive measures, starts
with an understanding of the effects when human factors engineering
refer to remote microscopic diagnosis in surgery and specially in
organ transplantation for the remote evaluation of the grafts. It has
been estimated that even in well-organized transplant systems an
average of 8% to 14% of the grafts (G) that arrive at the recipient
hospitals may be considered as diseased, injured, damaged or
improper for transplantation. Digital microscopy adds information on
a microscopic level about the grafts in Organ Transplant (OT), and
may lead to a change in their management. Such a method will
reduce the possibility that a diseased G, will arrive at the recipient
hospital for implantation. Aim: Ergonomics of Digital Microscopy
(DM) based on virtual slides, on Telemedicine Systems (TS) for
Tele-Pathological (TPE) evaluation of the grafts (G) in organ
transplantation (OT). Material and Methods: By experimental
simulation, the ergonomics of DM for microscopic TPE of Renal
Graft (RG), Liver Graft (LG) and Pancreatic Graft (PG) tissues is
analyzed. In fact, this corresponded to the ergonomics of digital
microscopy for TPE in OT by applying Virtual Slide (VS) system for
graft tissue image capture, for remote diagnoses of possible
microscopic inflammatory and/or neoplastic lesions. Experimentation
included: a. Development of an OTE-TS similar Experimental
Telemedicine System (Exp.-TS), b. Simulation of the integration of
TS with the VS based microscopic TPE of RG, LG and PG applying
DM. Simulation of the DM based TPE was performed by 2
specialists on a total of 238 human Renal Graft (RG), 172 Liver Graft
(LG) and 108 Pancreatic Graft (PG) tissues digital microscopic
images for inflammatory and neoplastic lesions on four electronic
spaces of the four used TS. Results: Statistical analysis of specialist‘s
answers about the ability to diagnose accurately the diseased RG, LG
and PG tissues on the electronic space among four TS (A,B,C,D)
showed that DM on TS for TPE in OT is elaborated perfectly on the
ES of a Desktop, followed by the ES of the applied Exp.-TS. Tablet
and Mobile-Phone ES seem significantly risky for the application of
DM in OT (p
Abstract: The garment manufacturing industry involves
sequential processes that are subjected to uncontrollable variations.
The industry depends on the skill of labour in handling the varieties
of fabrics and accessories, machines, as well as complicated sewing
operation. Due to these reasons, garment manufacturers have created
systems to monitor and to control the quality of the products on a
regular basis by conducting quality approaches to minimize variation.
With that, the aim of this research has been to ascertain the quality
approaches deployed by Malaysian garment manufacturers in three
key areas - quality systems and tools; quality control and types of
inspection; as well as sampling procedures chosen for garment
inspection. Besides, the focus of this research was to distinguish the
quality approaches adopted by companies that supplied finished
garments to both domestic and international markets. Feedback from
each company representative has been obtained via online survey,
which comprised of five sections and 44 questions on the
organizational profile and the quality approaches employed in the
garment industry. As a result, the response rate was 31%. The results
revealed that almost all companies have established their own
mechanism of process control by conducting a series of quality
inspections for daily production, either it was formally set up or
otherwise. In addition, quality inspection has been the predominant
quality control activity in the garment manufacturing, while the level
of complexity of these activities was substantially dictated by the
customers. Moreover, AQL-based sampling was utilized by
companies dealing with exports, whilst almost all the companies that
only concentrated on the domestic market were comfortable using
their own sampling procedures for garment inspection. Hence, this
research has provided insights into the implementation of a number
of quality approaches that were perceived as important and useful in
the garment manufacturing sector, which is truly labour-intensive.
Abstract: In this work, repaired crack in 6061- T6 aluminum
plate with composite patches presented, firstly we determine the
displacement, strain and stress, also the first six mode shape of the
plate, secondly we took the same model adding central crack
initiation, which is located in the center of the plate, its seize vary
from 20 mm to 60 mm and we compare the first results with second.
Thirdly we repair various cracks with composite patch (carbon/
epoxy) and for (2 layers, 4 layers). Finally the comparison of stress,
strain, displacement and six first natural frequencies between un-cracked
specimen, crack propagation and composite patch repair.
Abstract: An early diagnosis of bone metastasis is very
important for making a right decision on a subsequent therapy. One
of the most important steps to be taken initially, for developing a new
radiopharmaceutical is the measurement of organ radiation exposure
dose. In this study, the dosimetric studies of a novel agent for
SPECT-imaging of the bone metastasis, 111In-(4-
{[(bis(phosphonomethyl))carbamoyl]methyl}7,10bis(carboxymethyl)
-1,4,7,10-tetraazacyclododec-1-yl) acetic acid (111In-BPAMD)
complex, have been carried out to estimate the dose in human organs
based on the data derived from mice. The radiolabeled complex was
prepared with high radiochemical purity in the optimal conditions.
Biodistribution studies of the complex was investigated in the male
Syrian mice at the selected times after injection (2, 4, 24 and 48 h).
The human absorbed dose estimation of the complex was made based
on data derived from the mice by the radiation absorbed dose
assessment resource (RADAR) method. 111In-BPAMD complex was prepared with high radiochemical
purity >95% (ITLC) and specific activities of 2.85 TBq/mmol. Total
body effective absorbed dose for 111In-BPAMD was 0.205
mSv/MBq. This value is comparable to the other 111In clinically used
complexes. The results show that the dose with respect to the critical
organs is satisfactory within the acceptable range for diagnostic
nuclear medicine procedures. Generally, 111In-BPAMD has
interesting characteristics and it can be considered as a viable agent
for SPECT-imaging of the bone metastasis in the near future.
Abstract: Countryside has been generally recognized and
regarded as a characteristic symbol which presents in human memory
for a long time. As a result of the change of times, because of it is
failure to meet the growing needs of the growing life and mental
decline, the vast rural area began to decline. But their history feature
image which accumulated by the ancient tradition provides people
with the origins of existence on the spiritual level, such as "identity"
and "belonging", makes people closer to the others in the spiritual and
psychological aspects of a common experience about the past, thus the
sense of a lack of culture caused by the losing of memory symbols is
weakened. So, in the modernization process, how to repair its vitality
and transform and planning it in a sustainable way has become a hot
topics in architectural and urban planning. This paper aims to break
the constraints of disciplines, from the perspective of interdiscipline,
using the research methods of systems science to analyze and discuss
the theories and methods of rural form factors, which based on the
viewpoint of memory in psychology. So we can find a right way to
transform the Rural to give full play to the role of the countryside in
the actual use and the shape of history spirits.
Abstract: Background: To compare the thinning patterns of the
ganglion cell-inner plexiform layer (GCIPL) and peripapillary retinal
nerve fiber layer (pRNFL) as measured using Cirrus high-definition
optical coherence tomography (HD-OCT) in patients with visual field
(VF) defects that respect the vertical meridian. Methods: Twenty eyes of eleven patients with VF defects that
respect the vertical meridian were enrolled retrospectively. The
thicknesses of the macular GCIPL and pRNFL were measured using
Cirrus HD-OCT. The 5% and 1% thinning area index (TAI) was
calculated as the proportion of abnormally thin sectors at the 5% and
1% probability level within the area corresponding to the affected VF.
The 5% and 1% TAI were compared between the GCIPL and pRNFL
measurements. Results: The color-coded GCIPL deviation map showed a
characteristic vertical thinning pattern of the GCIPL, which is also
seen in the VF of patients with brain lesions. The 5% and 1% TAI
were significantly higher in the GCIPL measurements than in the
pRNFL measurements (all P < 0.01). Conclusions: Macular GCIPL analysis clearly visualized a
characteristic topographic pattern of retinal ganglion cell (RGC) loss
in patients with VF defects that respect the vertical meridian, unlike
pRNFL measurements. Macular GCIPL measurements provide more
valuable information than pRNFL measurements for detecting the
loss of RGCs in patients with retrograde degeneration of the optic
nerve fibers.
Abstract: Cryosorption pumps are considered safe, quiet, and
ultra-high vacuum production pumps which have their application
from Semiconductor industries to ITER [International Thermonuclear
Experimental Reactor] units. The principle of physisorption of gases
over highly porous materials like activated charcoal at cryogenic
temperatures (below -1500°C) is involved in determining the
pumping speed of gases like Helium, Hydrogen, Argon, and
Nitrogen. This paper aims at providing detailed overview of
development of Cryosorption pump and characterization of different
activated charcoal materials that optimizes the performance of the
pump. Different grades of charcoal were tested in order to determine
the pumping speed of the pump and were compared with
commercially available Varian cryopanel. The results for bare panel,
bare panel with adhesive, cryopanel with pellets, and cryopanel with
granules were obtained and compared. The comparison showed that
cryopanel adhered with small granules gave better pumping speeds
than large sized pellets.
Abstract: Abstract—[Tris (1,10-phenanthroline) lanthanum(III)]
trithiocyanate is a new compound that has shown high ability for
stopping the synthesis of DNA and also acting as a photosensitizer.
Nowadays, the radiation dose assessment resource (RADAR) method
is known as the most common method for absorbed dose calculation.
177Lu was produced by (n, gamma) reaction in a research reactor.
177Lu-PL3 was prepared in the optimized condition. The
radiochemical yield was checked by ITLC method. The
biodistribution of the complex was investigated by intravenously
injection to wild-type rats via their tail veins. In this study, the
absorbed dose of 177Lu-PL3 to human organs was estimated by
RADAR method. 177Lu was prepared with a specific activity of 2.6-3
GBq.mg-1 and radionuclide purity of 99.98 %. Final preparation of
the radiolabelled complex showed high radiochemical purity of >
99%. The results show that liver and spleen have received the highest
absorbed dose of 1.051 and 0.441 mSv/MBq, respectively. The
absorbed dose values for these two dose-limiting tissues suggest
more biological studies special in tumor-bearing animals.
Abstract: The measurement of organ radiation exposure dose is
one of the most important steps to be taken initially, for developing a
new radiopharmaceutical. In this study, the dosimetric studies of a
novel agent for SPECT-imaging of the bone metastasis, 111In-
1,4,7,10-tetraazacyclododecane-1,4,7,10 tetraethylene phosphonic
acid (111In-DOTMP) complex, have been carried out to estimate the
dose in human organs based on the data derived from rats. The
radiolabeled complex was prepared with high radiochemical purity in
the optimal conditions. Biodistribution studies of the complex was
investigated in the male Syrian rats at selected times after injection
(2, 4, 24 and 48 h). The human absorbed dose estimation of the
complex was made based on data derived from the rats by the
radiation absorbed dose assessment resource (RADAR) method.
111In-DOTMP complex was prepared with high radiochemical purity
of >99% (ITLC). Total body effective absorbed dose for 111In-
DOTMP was 0.061 mSv/MBq. This value is comparable to the other
111In clinically used complexes. The results show that the dose with
respect to the critical organs is satisfactory within the acceptable
range for diagnostic nuclear medicine procedures. Generally, 111In-
DOTMP has interesting characteristics and can be considered as a
viable agent for SPECT-imaging of the bone metastasis in the near
future.
Abstract: Here, we have shown the reaction of [Cr(ArN(CH2)3NAr)2Cl2] (1) where (Ar = 2,6-Pri
2C6H3) and in presence of NaCp (2) (Cp= C5H5 = cyclopentadien), with a center
coordination η5 interaction between Cp as co-ligand and chromium
metal center, for optimization we used density functional theory
(DFT), under methods, explicitly including electrons correlations, for
the final calculations as MB3LYP (Becke) (Lee–Yang–Parr) level of
theory we used to obtain more exact results. This complex was
calculated as electronic energy for molecular system, because the
calculation accounting all electrons correlations interactions. The
optimised of [Cr(ArN(CH2)3NAr)2(η5-Cp)] (Ar = 2,6-Pri2C6H3 and Cp = C5H5) was found to be thermally stable. By using Dewar-Chatt-Duncanson model, as a basis of the molecular orbital (MO) analysis
and showed the highest occupied molecular orbital (HOMO) and
lowest occupied molecular orbital LUMO.
Abstract: Parboiled rice was developed to produce rice, which
has a low glycemic index for diabetics. However, diabetics also have
a chromium (Cr) deficiency. Thus, it is important to fortify rice with
Cr to increase the Cr content. Moreover, parboiled rice becomes
rancid easily and has a musty odor, rendering the rice unfavorable.
Natural herbs such as pandan leaves (Pandanus amaryllifolius
Roxb.), bay leaves (Syzygium polyanthum [Wigh] Walp) and
cinnamon bark powder (Cinnamomon cassia) are commonly added to
food as aroma enhancers. Previous research has shown that these
herbs could improve insulin sensitivity. The purpose of this study
was to evaluate the effect of herbal extract coatings on the cooking
quality and the preference level of chromium fortified - parboiled rice
(CFPR). The rice grain variety used for this experiment was Ciherang
and the fortificant was CrCl3. The three herbal extracts used for
coating the CFPR were cinnamon, pandan and bay leaf, with
concentration variations of 3%, 6%, and 9% (w/w) for each of the
extracts. The samples were analyzed for their alkali spreading value,
cooking time, elongation, water uptake ratio, solid loss, colour and
lightness; and their sensory properties were determined by means of
an organoleptic test. The research showed that coating the CFPR with
pandan and cinnamon extracts at a concentration of 3% each
produced a preferred CFPR. When coated with those herbal extracts
the CFPR had the following cooking quality properties: alkali
spreading value 5 (intermediate gelatinization temperature), cooking
time, 26-27 min, color value, 14.95-15.00, lightness, 42.30 – 44.06,
elongation, 1.53 – 1.54, water uptake ratio , 4.05-4.06, and solid loss,
0.09/100 g – 0.13 g/100 g.
Abstract: Hydrogels are three-dimensional, hydrophilic,
polymeric networks composed of homopolymers or copolymers and
are insoluble in water due to the presence of chemical or physical
cross-links. When hydrogels come in contact with aqueous solutions,
they can effectively sorb and retain the dissolved substances,
depending on the nature of the monomeric units comprising the
hydrogel. For this reason, hydrogels have been proposed in several
studies as water purification agents. At the present work anionic
hydrogels bearing negatively charged –COO- groups were prepared
and investigated. These gels are based on sodium acrylate (ANa),
either homopolymerized (poly(sodiumacrylate), PANa) or
copolymerized (P(DMAM-co-ANa)) with N,N Dimethylacrylamide
(DMAM). The hydrogels were used to extract some model organic
dyes from water. It is found that cationic dyes are strongly sorbed and
retained by the hydrogels, while sorption of anionic dyes was
negligible. In all cases it was found that both maximum sorption
capacity and equilibrium binding constant varied from one dye to the
other depending on the chemical structure of the dye, the presence of
functional chemical groups and the hydrophobic-hydrophilic balance.
Finally, the nonionic hydrogel of the homopolymer poly(N,Ndimethylacrylamide),
PDMAM, was also used for reasons of
comparison.
Abstract: This paper evaluates the accrual based scheduling for
cloud in single and multi-resource system. Numerous organizations
benefit from Cloud computing by hosting their applications. The
cloud model provides needed access to computing with potentially
unlimited resources. Scheduling is tasks and resources mapping to a
certain optimal goal principle. Scheduling, schedules tasks to virtual
machines in accordance with adaptable time, in sequence under
transaction logic constraints. A good scheduling algorithm improves
CPU use, turnaround time, and throughput. In this paper, three realtime
cloud services scheduling algorithm for single resources and
multiple resources are investigated. Experimental results show
Resource matching algorithm performance to be superior for both
single and multi-resource scheduling when compared to benefit first
scheduling, Migration, Checkpoint algorithms.
Abstract: Household waste form a larger proportion of waste
generated across the state, accumulation of organic waste is an
apparent problem and the existing dump sites could be overstress.
Niger state has abundant arable land and water resources thus should
be one of the highest producers of agricultural crops in the country.
However, the major challenge to agricultural sector today is loss of
soil nutrient coupled with high cost of fertilizer. These have
continued to increase the use of fertilizer and decomposed solid waste
for enhance agricultural yield, which have varying effects on the soil
as well a threat to human livelihood. Consequently, vegetable yield
samples from poultry droppings, decomposed household waste
manure, NPK treatments and control from each replication were
subjected to proximate analysis to determine the nutritional and antinutritional
component as well as heavy metal concentration. Data
collected was analyzed using SPSS software and Randomized
complete Block Design means were compared. The result shows that
the treatments do not devoid the concentrations of any nutritional
components while the anti-nutritional analysis proved that NPK had
higher oxalate content than control and organic treats. The
concentration of lead and cadmium are within safe permissible level
while the mercury level exceeded the FAO/WHO maximum
permissible limit for the entire treatments depicts the need for urgent
intervention to minimize mercury levels in soil and manure in order
to mitigate its toxic effect. Thus, eco-agriculture should be widely
accepted and promoted by the stakeholders for soil amendment,
higher yield, strategies for sustainable environmental protection, food
security, poverty eradication, attainment of sustainable development
and healthy livelihood.
Abstract: This study focuses on the hydro-geology and chemical
constituents analysis of Ikogosi Warm Spring waters in South West
Nigeria. Ikogosi warm spring is a global tourist attraction because it
has both warm and cold spring sources. Water samples from the cold
spring, warm spring and the meeting point were collected, analyzed
and the result shows close similarity in temperature, hydrogen iron
concentration (pH), alkalinity, hardness, Calcium, Magnesium,
Sodium, Iron, total dissolved solid and heavy metals. The measured
parameters in the water samples are within World Health
Organisation standards for fresh water. The study of the geology of
the warm spring reveals that the study area is underlain by a group of
slightly migmatised to non-migmatised paraschists and meta-igneous
rocks. Also, concentration levels of selected heavy metals, (Copper,
Cadmium, Zinc, Arsenic and Cromium) were determined in the water
(ppm) samples. Chromium had the highest concentration value of
1.52ppm (an average of 49.67%) and Cadmium had the lowest
concentration with value of 0.15ppm (an average of 4.89%).
Comparison of these results showed that, their mean levels are within
the standard values obtained in Nigeria. It can be concluded that both
warm and spring water are safe for drinking.