Abstract: Investigations of the unimolecular decomposition of
vinyl ethyl ether (VEE), vinyl propyl ether (VPE) and vinyl butyl
ether (VBE) have shown that activation of the molecule of a ether
results in formation of a cyclic construction - the transition state (TS),
which may lead to the displacement of the thermodynamic
equilibrium towards the reaction products. The TS is obtained by
applying energy minimization relative to the ground state of an ether
under the program MM2 when taking into account the hydrogen bond
formation between a hydrogen atom of alkyl residue and the extreme
atom of carbon of the vinyl group. The dissociation of TS up to the
products is studied by energy minimization procedure using the
mathematical program Gaussian. The obtained calculation data for
VEE testify that the decomposition of this ether may be conditioned
by hydrogen bond formation for two possible versions: when α- or β-
hydrogen atoms of the ethyl group are bound to carbon atom of the
vinyl group. Applying the same calculation methods to other ethers
(VPE and VBE) it is shown that only in the case of hydrogen bonding
between α-hydrogen atom of the alkyl residue and the extreme atom
of carbon of the vinyl group (αH---C) results in decay of theses
ethers.
Abstract: This paper presents a robust vehicle detection approach using Haar-like feature. It is possible to get a strong edge feature from this Haar-like feature. Therefore it is very effective to remove the shadow of a vehicle on the road. And we can detect the boundary of vehicles accurately. In the paper, the vehicle detection algorithm can be divided into two main steps. One is hypothesis generation, and the other is hypothesis verification. In the first step, it determines vehicle candidates using features such as a shadow, intensity, and vertical edge. And in the second step, it determines whether the candidate is a vehicle or not by using the symmetry of vehicle edge features. In this research, we can get the detection rate over 15 frames per second on our embedded system.
Abstract: The pulp and paper mill effluent is one of the high
polluting effluent amongst the effluents obtained from polluting
industries. All the available methods for treatment of pulp and paper
mill effluent have certain drawbacks. The coagulation is one of the
cheapest process for treatment of various organic effluents. Thus, the
removal of chemical oxygen demand (COD) and colour of paper mill
effluent is studied using coagulation process. The batch coagulation
process was performed using various coagulants like: aluminium
chloride, poly aluminium chloride and copper sulphate. The initial
pH of the effluent (Coagulation pH) has tremendous effect on COD
and colour removal. Poly aluminium chloride (PAC) as coagulant
reduced COD to 84 % and 92 % of colour was removed at an
optimum pH 5 and coagulant dose of 8 ml l-1. With aluminium
chloride at an optimum pH = 4 and coagulant dose of 5 g l-1, 74 %
COD and 86 % colour removal were observed. The results using
copper sulphate as coagulant (a less commercial coagulant) were
encouraging. At an optimum pH 6 and mass loading of 5 g l-1, 76 %
COD reduction and 78 % colour reduction were obtained. It was also
observed that after addition of coagulant, the pH of the effluent
decreases. The decrease in pH was highest for AlCl3, which was
followed by PAC and CuSO4. Significant amount of COD reductions
was obtained by coagulation process. Since the coagulation process
is the first stage for treatment of effluent and some of the coagulant
cations usually remain in the treated effluents. Thus, cation like
copper may be one of the good catalyst for second stage of treatment
process like wet oxidation. The copper has been found to be good
oxidation catalyst then iron and aluminum.
Abstract: The fundamental aim of extended expansion concept is
to achieve higher work done which in turn leads to higher thermal
efficiency. This concept is compatible with the application of
turbocharger and LHR engine. The Low Heat Rejection engine was
developed by coating the piston crown, cylinder head inside with
valves and cylinder liner with partially stabilized zirconia coating of
0.5 mm thickness. Extended expansion in diesel engines is termed as
Miller cycle in which the expansion ratio is increased by reducing the
compression ratio by modifying the inlet cam for late inlet valve
closing. The specific fuel consumption reduces to an appreciable level
and the thermal efficiency of the extended expansion turbocharged
LHR engine is improved.
In this work, a thermodynamic model was formulated and
developed to simulate the LHR based extended expansion
turbocharged direct injection diesel engine. It includes a gas flow
model, a heat transfer model, and a two zone combustion model. Gas
exchange model is modified by incorporating the Miller cycle, by
delaying inlet valve closing timing which had resulted in considerable
improvement in thermal efficiency of turbocharged LHR engines. The
heat transfer model, calculates the convective and radiative heat
transfer between the gas and wall by taking into account of the
combustion chamber surface temperature swings. Using the two-zone
combustion model, the combustion parameters and the chemical
equilibrium compositions were determined. The chemical equilibrium
compositions were used to calculate the Nitric oxide formation rate by
assuming a modified Zeldovich mechanism. The accuracy of this
model is scrutinized against actual test results from the engine. The
factors which affect thermal efficiency and exhaust emissions were
deduced and their influences were discussed. In the final analysis it is
seen that there is an excellent agreement in all of these evaluations.
Abstract: In this paper, we present an innovative scheme of
blindly extracting message bits from an image distorted by an attack.
Support Vector Machine (SVM) is used to nonlinearly classify the
bits of the embedded message. Traditionally, a hard decoder is used
with the assumption that the underlying modeling of the Discrete
Cosine Transform (DCT) coefficients does not appreciably change.
In case of an attack, the distribution of the image coefficients is
heavily altered. The distribution of the sufficient statistics at the
receiving end corresponding to the antipodal signals overlap and a
simple hard decoder fails to classify them properly. We are
considering message retrieval of antipodal signal as a binary
classification problem. Machine learning techniques like SVM is
used to retrieve the message, when certain specific class of attacks is
most probable. In order to validate SVM based decoding scheme, we
have taken Gaussian noise as a test case. We generate a data set using
125 images and 25 different keys. Polynomial kernel of SVM has
achieved 100 percent accuracy on test data.
Abstract: In the article there have been revealed the properties
of designing the research teaching the military masters and in the context it has been offered the program of mastering by the masters
military men the methodology of research work, in the course of practical teaching activity there has been considered the developed
and approbated model of organization of the process of mastering by the masters the methodology of research work. As a whole, the research direction of master preparation leaves its
sign to the content of education, forms of organization of educational
process, scientific work of masters. In this connection the offered in
the article properties of organization of research teaching and a model
of organization of mastering by the masters military men the methodology of research work can be taken into account when
designing the content of master preparation.
Abstract: The selection for plantation of a particular type of
mustard plant depending on its productivity (pod yield) at the stage
of maturity. The growth of mustard plant dependent on some
parameters of that plant, these are shoot length, number of leaves,
number of roots and roots length etc. As the plant is growing, some
leaves may be fall down and some new leaves may come, so it can
not gives the idea to develop the relationship with the seeds weight at
mature stage of that plant. It is not possible to find the number of
roots and root length of mustard plant at growing stage that will be
harmful of this plant as roots goes deeper to deeper inside the land.
Only the value of shoot length which increases in course of time can
be measured at different time instances. Weather parameters are
maximum and minimum humidity, rain fall, maximum and minimum
temperature may effect the growth of the plant. The parameters of
pollution, water, soil, distance and crop management may be
dominant factors of growth of plant and its productivity. Considering
all parameters, the growth of the plant is very uncertain, fuzzy
environment can be considered for the prediction of shoot length at
maturity of the plant. Fuzzification plays a greater role for
fuzzification of data, which is based on certain membership
functions. Here an effort has been made to fuzzify the original data
based on gaussian function, triangular function, s-function,
Trapezoidal and L –function. After that all fuzzified data are
defuzzified to get normal form. Finally the error analysis
(calculation of forecasting error and average error) indicates the
membership function appropriate for fuzzification of data and use to
predict the shoot length at maturity. The result is also verified using
residual (Absolute Residual, Maximum of Absolute Residual, Mean
Absolute Residual, Mean of Mean Absolute Residual, Median of
Absolute Residual and Standard Deviation) analysis.
Abstract: Image compression is one of the most important
applications Digital Image Processing. Advanced medical imaging
requires storage of large quantities of digitized clinical data. Due to
the constrained bandwidth and storage capacity, however, a medical
image must be compressed before transmission and storage. There
are two types of compression methods, lossless and lossy. In Lossless
compression method the original image is retrieved without any
distortion. In lossy compression method, the reconstructed images
contain some distortion. Direct Cosine Transform (DCT) and Fractal
Image Compression (FIC) are types of lossy compression methods.
This work shows that lossy compression methods can be chosen for
medical image compression without significant degradation of the
image quality. In this work DCT and Fractal Compression using
Partitioned Iterated Function Systems (PIFS) are applied on different
modalities of images like CT Scan, Ultrasound, Angiogram, X-ray
and mammogram. Approximately 20 images are considered in each
modality and the average values of compression ratio and Peak
Signal to Noise Ratio (PSNR) are computed and studied. The quality
of the reconstructed image is arrived by the PSNR values. Based on
the results it can be concluded that the DCT has higher PSNR values
and FIC has higher compression ratio. Hence in medical image
compression, DCT can be used wherever picture quality is preferred
and FIC is used wherever compression of images for storage and
transmission is the priority, without loosing picture quality
diagnostically.
Abstract: In this study, it is investigated the stability boundary of
Functionally Graded (FG) panel under the heats and supersonic
airflows. Material properties are assumed to be temperature
dependent, and a simple power law distribution is taken. First-order
shear deformation theory (FSDT) of plate is applied to model the
panel, and the von-Karman strain- displacement relations are
adopted to consider the geometric nonlinearity due to large
deformation. Further, the first-order piston theory is used to model the
supersonic aerodynamic load acting on a panel and Rayleigh damping
coefficient is used to present the structural damping. In order to find a
critical value of the speed, linear flutter analysis of FG panels is
performed. Numerical results are compared with the previous works,
and present results for the temperature dependent material are
discussed in detail for stability boundary of the panel with various
volume fractions, and aerodynamic pressures.
Abstract: This paper presents a new heuristic algorithm for the classical symmetric traveling salesman problem (TSP). The idea of the algorithm is to cut a TSP tour into overlapped blocks and then each block is improved separately. It is conjectured that the chance of improving a good solution by moving a node to a position far away from its original one is small. By doing intensive search in each block, it is possible to further improve a TSP tour that cannot be improved by other local search methods. To test the performance of the proposed algorithm, computational experiments are carried out based on benchmark problem instances. The computational results show that algorithm proposed in this paper is efficient for solving the TSPs.
Abstract: In this paper, a class of impulsive BAM fuzzy cellular neural networks with distributed delays and reaction-diffusion terms is formulated and investigated. By employing the delay differential inequality and inequality technique developed by Xu et al., some sufficient conditions ensuring the existence, uniqueness and global exponential stability of equilibrium point for impulsive BAM fuzzy cellular neural networks with distributed delays and reaction-diffusion terms are obtained. In particular, the estimate of the exponential convergence rate is also provided, which depends on system parameters, diffusion effect and impulsive disturbed intention. It is believed that these results are significant and useful for the design and applications of BAM fuzzy cellular neural networks. An example is given to show the effectiveness of the results obtained here.
Abstract: The research was set up on chernozem soil at the Látókép AGTC MÉK research area of the University of Debrecen in Hungary. We examined the yield, the yield production per 1kg NPK fertilizer and the water and nutrient utilization of hybrid PR37N01 and PR37M81 in 2013. We found that PR37N01 produced the most yield at the level of N120+P (17,476kg ha-1) while PR37M81 reached the highest yield at level N150+PK (16,754kg ha-1). Studies related to yield production per 1kg NPK indicated that the best results were achieved at level N30+PK compared to the control treatment. Yield production per 1kg NPK was17.6kg kg-1 by P37N01 and 44.2kg kg-1 by PR37M81. By comparing the water utilization of hybrids we found that the worst water utilization results were reached in the control treatment (PR37N01: 26.2kg mm-1, PR37M81: 19.5kg mm-1). The best water utilization values were produced at level N120+PK in the case of hybrid PR37N01 (32.1kg mm-1) and at N150+PK in the case of hybrid PR37M81 (30.8kg mm-1). We established the values of the nutrient reaction and the fertilizer optimum of hybrids. We discovered a strong relationship between the amount of fertilizer applied and the yield produced (r2= 0.8228–0.9515). The best nutrient response was induced by hybrid PR37N01, while the weakest results were reached by hybrid PR37M81.
Abstract: Electromagnetic flow meter by measuring the varying of magnetic flux, which is related to the velocity of conductive flow, can measure the rate of fluids very carefully and precisely. Electromagnetic flow meter operation is based on famous Faraday's second Law. In these equipments, the constant magnetostatic field is produced by electromagnet (winding around the tube) outside of pipe and inducting voltage that is due to conductive liquid flow is measured by electrodes located on two end side of the pipe wall. In this research, we consider to 2-dimensional mathematical model that can be solved by numerical finite difference (FD) solution approach to calculate induction potential between electrodes. The fundamental concept to design the electromagnetic flow meter, exciting winding and simulations are come out by using MATLAB and PDE-Tool software. In the last stage, simulations results will be shown for improvement and accuracy of technical provision.
Abstract: In this era of technology, fueled by the pervasive usage of the internet, security is a prime concern. The number of new attacks by the so-called “bots", which are automated programs, is increasing at an alarming rate. They are most likely to attack online registration systems. Technology, called “CAPTCHA" (Completely Automated Public Turing test to tell Computers and Humans Apart) do exist, which can differentiate between automated programs and humans and prevent replay attacks. Traditionally CAPTCHA-s have been implemented with the challenge involved in recognizing textual images and reproducing the same. We propose an approach where the visual challenge has to be read out from which randomly selected keywords are used to verify the correctness of spoken text and in turn detect the presence of human. This is supplemented with a speaker recognition system which can identify the speaker also. Thus, this framework fulfills both the objectives – it can determine whether the user is a human or not and if it is a human, it can verify its identity.
Abstract: Numerical studies have been carried out using a two
dimensional code to examine the influence of pressure / thrust
transient of solid propellant rockets at liftoff. This code solves
unsteady Reynolds-averaged thin-layer Navier–Stokes equations by
an implicit LU-factorization time-integration method. The results
from the parametric study indicate that when the port is narrow there
is a possibility of increase in pressure / thrust-rise rate due to
relatively high flame spread rate. Parametric studies further reveal
that flame spread rate can be altered by altering the propellant
properties, igniter jet characteristics and nozzle closure burst pressure
without altering the grain configuration and/or the mission
demanding thrust transient. We observed that when the igniter
turbulent intensity is relatively low the vehicle could liftoff early due
to the early flow choking of the rocket nozzle. We concluded that the
high pressurization-rate has structural implications at liftoff in
addition to transient burning effect. Therefore prudent selection of the
port geometry and the igniter, for meeting the mission requirements,
within the given envelop are meaningful objectives for any designer
for the smooth liftoff of solid propellant rockets.
Abstract: Now a days, a significant part of commercial and governmental organisations like museums, cultural organizations, libraries, commercial enterprises, etc. invest intensively in new technologies for image digitization, digital libraries, image archiving and retrieval. Hence image authorization, authentication and security has become prime need. In this paper, we present a semi-fragile watermarking scheme for color images. The method converts the host image into YIQ color space followed by application of orthogonal dual domains of DCT and DWT transforms. The DCT helps to separate relevant from irrelevant image content to generate silent image features. DWT has excellent spatial localisation to help aid in spatial tamper characterisation. Thus image adaptive watermark is generated based of image features which allows the sharp detection of microscopic changes to locate modifications in the image. Further, the scheme utilises the multipurpose watermark consisting of soft authenticator watermark and chrominance watermark. Which has been proved fragile to some predefined processing like intentinal fabrication of the image or forgery and robust to other incidental attacks caused in the communication channel.
Abstract: the reliability analysis of the medical equipments can
help to increase the availability and the efficiency of the systems. In
this manuscript we present a simple method of decomposition that
could be easily applied on the complex medical systems. Using this
method we can easily calculate the effect of the subsystems or
components on the reliability of the overall system. Furthermore, to
investigate the effect of subsystems or components on system
performance, we perform a numerical study varying every time the
worst reliability of subsystem or component with another which has
higher reliability. It can also be useful to engineers and designers of
medical equipment, who wishes to optimize the complex systems.
Abstract: Economic freedoms, most emphasized issue in the recent years, are considered to affect economic growth and performance via institutional structure. In this context, a model that includes Turkey and Middle East Countries, and where the effects of economic freedom on growth are examined, was formed. For the groups of countries determined, in the study carried out by using the dataset belonging the period of 2004 - 2009, between economic freedoms and growth, a negative relationship was observed as group. In the sense of individual effects, it was identified that there was a positive relationship in terms of some Middle East Countries and Turkey.
Abstract: The volume of XML data exchange is explosively
increasing, and the need for efficient mechanisms of XML data
management is vital. Many XML storage models have been proposed
for storing XML DTD-independent documents in relational database
systems. Benchmarking is the best way to highlight pros and cons of
different approaches. In this study, we use a common benchmarking
scheme, known as XMark to compare the most cited and newly
proposed DTD-independent methods in terms of logical reads,
physical I/O, CPU time and duration. We show the effect of Label
Path, extracting values and storing in another table and type of join
needed for each method-s query answering.
Abstract: Multiple criteria decision making (MCDM) is an approach to ranking the solutions and finding the best one when two or more solutions are provided. In this study, MCDM approach is proposed to select the most suitable scheduling rule of robotic flexible assembly cells (RFACs). Two MCDM approaches, Analytic Hierarchy Process (AHP) and Technique for Order Preference by Similarity to Ideal Solution (TOPSIS) are proposed for solving the scheduling rule selection problem. The AHP method is employed to determine the weights of the evaluation criteria, while the TOPSIS method is employed to obtain final ranking order of scheduling rules. Four criteria are used to evaluate the scheduling rules. Also, four scheduling policies of RFAC are examined to choose the most appropriate one for this purpose. A numerical example illustrates applications of the suggested methodology. The results show that the methodology is practical and works in RFAC settings.