Abstract: loss of feedwater accident is one of the frequently sever accidents in steam boiler facilities. It threatens the system structural integrity and generates serious hazards and economic loses. The safety analysis of the thermal installations, based extensively on the numeric simulation. The simulation analysis using realistic computer codes like Relap5/Mod3.2 will help understand steam boiler thermal-hydraulic behavior during normal and abnormal conditions. In this study, we are interested on the evaluation of the radiant steam boiler assessment and response to loss-of-feedwater accident. Pressure, temperature and flow rate profiles are presented in various steam boiler system components. The obtained results demonstrate the importance and capability of the Relap5/Mod3.2 code in the thermal-hydraulic analysis of the steam boiler facilities.
Abstract: Dill (Anethum graveolens L.) is a popular herb used in
many regions, including Baltic countries. Dill is widely used for
flavoring foods and beverages due to its pleasant spicy aroma. The
aim of this work was to determine the best blanching method for
processing of dill prior to microwave vacuum drying based on
sensory properties, color and volatile compounds in dried product.
Two blanching mediums were used – water and steam, and for part of
samples microwave pretreatment was additionally used. Evaluation of
dried dill volatile aroma compounds, color changes and sensory
attributes was performed. Results showed that blanching significantly
influences the quality of dried dill. After evaluation of volatile aroma
compounds, color and sensory properties of microwave vacuum dried
dill, as the best method for dill pretreatment was established
blanching at 90 °C for 30 s.
Abstract: This work presents the hydrogen production from
steam gasification of palm kernel shell (PKS) at 700 oC in the
presence of 5% Ni/BEA and 5% Fe/BEA as catalysts. The steam
gasification was performed in two-staged reactors to evaluate the
effect of calcinations temperature and the steam to biomass ratio on
the product gas composition. The catalytic activity of Ni/BEA
catalyst decreases with increasing calcinations temperatures from 500
to 700 oC. The highest H2 concentration is produced by Fe/BEA
(600) with more than 71 vol%. The catalytic activity of the catalysts
tested is found to correspond to its physicochemical properties. The
optimum range for steam to biomass ratio if found to be between 2 to
4. Excess steam content results in temperature drop in the gasifier
which is undesirable for the gasification reactions.
Abstract: Cogeneration may be defined as a system which
contains electricity production and regain of the thermo value of
exhaust gases simultaneously. The examination is based on the data-s
of an active cogeneration plant. This study, it is aimed to determine
which component of the system should be revised first to raise the
efficiency and decrease the loss of exergy. For this purpose, second
law analysis of thermodynamics is applied to each component due to
consider the effects of environmental conditions and take the quality
of energy into consideration as well as the quantity of it. The exergy
balance equations are produced and exergy loss is calculated for each
component. 44,44 % loss of exergy in heat exchanger, 29,59 % in
combustion chamber, 18,68 % in steam boiler, 5,25 % in gas turbine
and 2,03 % in compressor is calculated.
Abstract: The paper investigates parallel channel instabilities of
natural circulation boiling water reactor. A thermal-hydraulic model
is developed to simulate two-phase flow behavior in the natural circulation boiling water reactor (NCBWR) with the incorporation of
ex-core components and recirculation loop such as steam separator, down-comer, lower-horizontal section and upper-horizontal section
and then, numerical analysis is carried out for parallel channel
instabilities of the reactor undergoing both in-phase and out-of-phase
modes of oscillations. To analyze the relative effect on stability of the reactor due to inclusion of various ex-core components and
recirculation loop, marginal stable point is obtained at a particular inlet enthalpy of the reactor core without the inclusion of ex-core
components and recirculation loop and then with the inclusion of the
same. Numerical simulations are also conducted to determine the
relative dominance between two modes of oscillations i.e. in-phase and out-of-phase. Simulations are also carried out when the channels
are subjected to asymmetric power distribution keeping the inlet enthalpy same.
Abstract: The production and consumption of natural gas is on
the rise throughout the world as a result of its wide availability, ease
of transportation, use and clean-burning characteristics. The chief use
of ethane is in the chemical industry in the production of Ethene
(ethylene) by steam cracking. In this simulation, obtained ethane
recovery percent based on Gas sub-cooled process (GSP) is 99.9 by
mole that is included 32.1% by using de-methanizer column and
67.8% by de-ethanizer tower. The outstanding feature of this process
is the novel split-vapor concept that employs to generate reflux for
de-methanizer column. Remain amount of ethane in export gas cause
rise in gross heating value up to 36.66 MJ/Nm3 in order to use in
industrial and household consumptions.
Abstract: This paper presents the new results of energy plant –
rye and triticale at yellow ripeness and ripe, pre-treatment in high
pressure steam reactor and monosaccharide extraction. There were
investigated the influence of steam pressure (20 to 22 bar), retention
duration (180 to 240 s) and catalytic sulphuric acid concentration
strength (0 to 0.5 %) on the pre-treatment process, contents of
monosaccharides (glucose, arabinose, xylose, mannose) and
undesirable by-compounds (furfural and HMF) in the reactor. The
study has determined that the largest amount of monosaccharides
(37.2 % of glucose, 2.7 % of arabinose, 8.4 % of xylose, and 1.3 %
of mannose) was received in the rye at ripe, the samples of which
were mixed with 0.5 % concentration of catalytic sulphuric acid, and
hydrolysed in the reactor, where the pressure was 20 bar, whereas the
reaction time – 240 s.
Abstract: In this paper, the energy performance of a selected
UHDE Ammonia plant is optimized by conducting heat integration through waste heat recovery and the synthesis of a heat exchange
network (HEN). Minimum hot and cold utility requirements were estimated through IChemE spreadsheet. Supporting simulation was
carried out using HYSYS software. The results showed that there is
no need for heating utility while the required cold utility was found to
be around 268,714 kW. Hence a threshold pinch case was faced. Then, the hot and cold streams were matched appropriately. Also,
waste heat recovered resulted with savings in HP and LP steams of
approximately 51.0% and 99.6%, respectively. An economic analysis
on proposed HEN showed very attractive overall payback period not
exceeding 3 years. In general, a net saving approaching 35% was
achieved in implementing heat optimization of current studied UHDE Ammonia process.
Abstract: As the fossil fuels kept on depleting, intense research in developing hydrogen (H2) as the alternative fuel has been done to cater our tremendous demand for fuel. The potential of H2 as the ultimate clean fuel differs with the fossil fuel that releases significant amounts of carbon dioxide (CO2) into the surrounding and leads to the global warming. The experimental work was carried out to study the production of H2 from palm kernel shell steam gasification at different variables such as heating rate, steam to biomass ratio and adsorbent to biomass ratio. Maximum H2 composition which is 61% (volume basis) was obtained at heating rate of 100oCmin-1, steam/biomass of 2:1 ratio, and adsorbent/biomass of 1:1 ratio. The commercial adsorbent had been modified by utilizing the alcoholwater mixture. Characteristics of both adsorbents were investigated and it is concluded that flowability and floodability of modified CaO is significantly improved.
Abstract: In this article the investigation about installation heat
recovery steam generation (HRSG) on the exhaust of turbo generators of phases 2&3 at South Pars Gas Complex is presented.
The temperature of exhaust gas is approximately 665 degree centigrade, Installation of heat recovery boiler was simulated in
ThermoFlow 17.0.2 software, based on test operation data and the
equipments site operation conditions in Pars exclusive economical energy area, the affect of installation HRSG package on the available
gas turbine and its operation parameters, ambient temperature, the
exhaust temperatures steam flow rate were investigated. Base on the results recommended HRSG package should have the capacity for 98
ton per hour high pressure steam generation this refinery, by use of
exhaust of three gas turbines for each package in operation condition of each refinery at 30 degree centigrade. Besides saving energy this
project will be an Environment-Friendly project. The Payback Period
is estimated approximately 1.8 year, with considering Clean Development Mechanism.
Abstract: An important goal of parboiling is a decrease of rice broken percentage and at the beginning Selected paddy of variety of rice Tarom and soaked at three different temperatures 45 Cº, 65 Cº and 80 Cº orderly for 5 hours, 4 hours and 1.5 hours to moisture of 40 % and then in steaming stage to operate these action two steaming methods are selected steaming under pressure condition and steaming in atmosphere pressure and In the first method after exerting air, the steam pressure is increase to 1 Kg/Cm2 which is done in two different duration times of 2.5 and 5 minutes and in second method used of three times of 5,10 and 15 minutes and dry to 8% moisture and decreases of rice broken percentage at best condition in variety of Tarom of 37.2 % to 7.3 % and increases yield percentage at best condition in variety of Tarom of 69.4 % to 75.93 % and bran percentage decreased in variety of Tarom of 9.53 % to 2.2-3.2 % and this issue cause increases yield percentage in rice and use of This method is very significant for our country because broken percentage of rice in our country is 23-33 %.
Abstract: Two-interconnected fluidized bed systems are widely used in various processes such as Fisher-Tropsch, hot gas desulfurization, CO2 capture-regeneration with dry sorbent, chemical-looping combustion, sorption enhanced steam methane reforming, chemical-looping hydrogen generation system, and so on. However, most of two-interconnected fluidized beds systems require riser and/or pneumatic transport line for solid conveying and loopseals or seal-pots for gas sealing, recirculation of solids to the riser, and maintaining of pressure balance. The riser (transport bed) is operated at the high velocity fluidization condition and residence times of gas and solid in the riser are very short. If the reaction rate of catalyst or sorbent is slow, the riser can not ensure sufficient contact time between gas and solid and we have to use two bubbling beds for each reaction to ensure sufficient contact time. In this case, additional riser must be installed for solid circulation. Consequently, conventional two-interconnected fluidized bed systems are very complex, large, and difficult to operate. To solve these problems, a novel two-interconnected fluidized bed system has been developed. This system has two bubbling beds, solid injection nozzles, solid conveying lines, and downcomers. In this study, effects of operating variables on solid circulation rate, gas leakage between two beds have been investigated in a cold mode two-interconnected fluidized bed system. Moreover, long-term operation of continuous solid circulation up to 60 hours has been performed to check feasibility of stable operation.
Abstract: In process control applications, above 90% of the
controllers are of PID type. This paper proposed a robust PI
controller with fractional-order integrator. The PI parameters were
obtained using classical Ziegler-Nichols rules but enhanced with the
application of error filter cascaded to the fractional-order PI. The
controller was applied on steam temperature process that was
described by FOPDT transfer function. The process can be classified
as lag dominating process with very small relative dead-time. The
proposed control scheme was compared with other PI controller
tuned using Ziegler-Nichols and AMIGO rules. Other PI controller
with fractional-order integrator known as F-MIGO was also
considered. All the controllers were subjected to set point change and
load disturbance tests. The performance was measured using Integral
of Squared Error (ISE) and Integral of Control Signal (ICO). The
proposed controller produced best performance for all the tests with
the least ISE index.
Abstract: In this study, oxidative steam reforming of methanol (OSRM) over a Au/CeO2–Fe2O3 catalyst prepared by a depositionprecipitation (DP) method was studied to produce hydrogen in order to feed a Proton Exchange Membrane Fuel Cell (PEMFC). The support (CeO2, Fe2O3, and CeO2–Fe2O3) were prepared by precipitation and co-precipitation methods. The impact of the support composition on the catalytic performance was studied by varying the Ce/(Ce+Fe) atomic ratio, it was found that the 1%Au/CF(0.25) calcined at 300 °C exhibited the highest catalytic activity in the whole temperature studied. In addition, the effect of Au content was investigated and 3%Au/CF(0.25) exhibited the highest activity under the optimum condition in the temperature range of 200 °C to 400 °C. The catalysts were characterized by various techniques: XRD, TPR, XRF, and UV-vis.
Abstract: Bond Graph as a unified multidisciplinary tool is widely
used not only for dynamic modelling but also for Fault Detection and
Isolation because of its structural and causal proprieties. A binary
Fault Signature Matrix is systematically generated but to make the
final binary decision is not always feasible because of the problems
revealed by such method. The purpose of this paper is introducing a
methodology for the improvement of the classical binary method of
decision-making, so that the unknown and identical failure signatures
can be treated to improve the robustness. This approach consists of
associating the evaluated residuals and the components reliability data
to build a Hybrid Bayesian Network. This network is used in two
distinct inference procedures: one for the continuous part and the
other for the discrete part. The continuous nodes of the network are
the prior probabilities of the components failures, which are used by
the inference procedure on the discrete part to compute the posterior
probabilities of the failures. The developed methodology is applied
to a real steam generator pilot process.
Abstract: Measurements of capacitance C and dissipation
factor tand of the stator insulation system provide useful information
about internal defects within the insulation. The index k is defined as
the proportionality constant between the changes at high voltage of
capacitance DC and of the dissipation factor Dtand . DC and
Dtand values were highly correlated when small flat defects were
within the insulation and that correlation was lost in the presence of
large narrow defects like electrical treeing. The discrimination
between small and large defects is made resorting to partial discharge
PD phase angle analysis. For the validation of the results, C and tand
measurements were carried out in a 15MVA 4160V steam turbine
turbogenerator placed in a sugar mill. In addition, laboratory test
results obtained by other authors were analyzed jointly. In such
laboratory tests, model coil bars subjected to thermal cycling resulted
highly degraded and DC and Dtand values were not correlated. Thus,
the index k could not be calculated.
Abstract: Dill contains range of phytochemicals, such as vitamin C and polyphenols, which significantly contribute to their total antioxidant activity. The aim of the current research was to determine the best blanching method for processing of dill prior to microwave vacuum drying based on the content of phenolic compounds, vitamin C and free radical scavenging activity. Two blanching mediums were used – water and steam, and for part of the samples microwave pretreatment was additionally used. Evaluation of vitamin C, phenolic contents and scavenging of DPPH˙ radical in dried dill was performed. Blanching had an effect on all tested parameters and the blanching conditions are very important. After evaluation of the results, as the best method for dill pretreatment was established blanching at 90 °C for 30 seconds.
Abstract: Nowadays, desalination of salt water is considered an important industrial process. In many parts of the world, particularly in the gulf countries, the multi-stage flash (MSF) water desalination has an essential contribution in the production of fresh water. In this study, a simple mathematical model is defined to design a MSF desalination system and the feasibility of using the MSF desalination process in proximity of a 42 MW power plant is investigated. This power plant can just provide 10 ton/h superheated steam from low pressure (LP) section of heat recovery steam generator (HRSG) for thermal desalting system. The designed MSF system with gained output ratio (GOR) of 10.3 has 24 flashing stages and can produce 2480 ton/d of fresh water. The expected performance characteristics of the designed MSF desalination plant are determined. In addition, the effect of motive water pressure on the amount of non-condensable gases removed by water jet vacuum pumps is investigated.
Abstract: The paper presents a computational tool developed for
the evaluation of technical and economic advantages of an innovative
cleaning and conditioning technology of fluidized bed steam/oxygen
gasifiers outlet product gas. This technology integrates into a single
unit the steam gasification of biomass and the hot gas cleaning and
conditioning system. Both components of the computational tool,
process flowsheet and economic evaluator, have been developed
under IPSEpro software. The economic model provides information
that can help potential users, especially small and medium size
enterprises acting in the regenerable energy field, to decide the
optimal scale of a plant and to better understand both potentiality and
limits of the system when applied to a wide range of conditions.
Abstract: The steam cracking reactions are always accompanied with the formation of coke which deposits on the walls of the tubular reactors. The investigation has attempted to control catalytic coking by the applying aluminum, zinc and ceramic coating like aluminum-magnesium by thermal spray and pack cementation method. Rate of coke formation during steam cracking of naphtha has been investigated both for uncoated stainless steel (with different alloys) and metal coating constructed with thermal Spray and pack cementation method with metal powders of Aluminum, Aluminum-Magnesium, zinc, silicon, nickel and chromium. The results of the study show that passivating the surface of SS321 with a coating of Aluminum and Aluminum-Magnesium can significantly reduce the rate of coke deposition during naphtha pyrolysis. SEM and EDAX techniques (Philips XL Series) were used to examine the coke deposits formed by the metal-hydrocarbon reactions. Our objective was to separate the different stages by identifying the characteristic morphologies.