Abstract: Heavy metal transfer in soil profiles is a major
environmental concern because even slow transport through the soil
may eventually lead to deterioration of groundwater quality. The use
of sewage sludge and effluents from wastewater treatment plants for
irrigation of agricultural lands is on the rise particularly in peri-urban
area of developing countries. In this study soil samples under sludge
application and wastewater irrigation were studied and soil samples
were collected in the soil profiles from the surface to 100 cm in
depth. For this purpose, three plots were made in a treatment plant in
south of Tehran-Iran. First plot was irrigated just with effluent from
wastewater treatment plant, second plot with simulated heavy metals
concentration equal 50 years irrigation and in third plot sewage
sludge and effluent was used. Trace metals concentration (Cd, Cu)
were determined for soil samples. The results indicate movement of
metals was observed, but the most concentration of metals was found
in topsoil samples. The most of Cadmium concentration was
measured in the topsoil of plot 3, 4.5mg/kg and Maximum cadmium
movement was observed in 0-20 cm. The most concentration of
copper was 27.76mg/kg, and maximum percolation in 0-20 cm.
Metals (Cd, Cu) were measured in leached water. Preferential flow
and metal complexation with soluble organic apparently allow
leaching of heavy metals.
Abstract: The management of the health-care wastes is one of
the most important problems in Istanbul, a city with more than 12
million inhabitants, as it is in most of the developing countries.
Negligence in appropriate treatment and final disposal of the healthcare
wastes can lead to adverse impacts to public health and to the
environment. This paper employs a fuzzy multi-criteria group
decision making approach, which is based on the principles of fusion
of fuzzy information, 2-tuple linguistic representation model, and
technique for order preference by similarity to ideal solution
(TOPSIS), to evaluate health-care waste (HCW) treatment
alternatives for Istanbul. The evaluation criteria are determined
employing nominal group technique (NGT), which is a method of
systematically developing a consensus of group opinion. The
employed method is apt to manage information assessed using multigranularity
linguistic information in a decision making problem with
multiple information sources. The decision making framework
employs ordered weighted averaging (OWA) operator that
encompasses several operators as the aggregation operator since it
can implement different aggregation rules by changing the order
weights. The aggregation process is based on the unification of
information by means of fuzzy sets on a basic linguistic term set
(BLTS). Then, the unified information is transformed into linguistic
2-tuples in a way to rectify the problem of loss information of other
fuzzy linguistic approaches.
Abstract: An experiment was performed in the south of
Morocco in order to evaluate the effect of deficit irrigation by treated
wastewater on chickpea production. We applied six irrigation
treatments on a local variety of chickpea by supplying alternatively
50 or 100% of ETm in a completely randomized design.
We found a highly significant difference between treatments in
terms of biomass production. Drought stress during the vegetative
period showed highest yield with 6.5 t/ha which was more than the
yield obtained for the control (4.9 t/ha). The optimal crop stage in
which deficit irrigation can be applied is the vegetative growth stage,
as the crop has a chance to develop its root system, to be able to
cover the plant needs for water and nutrient supply during the rest of
cycle, and non stress conditions during the flowering and seed filling
stages allow the plant to optimize its photosynthesis and carbon
translocation, therefore increase its productivity.
Abstract: To coop with urbanization issues and the economic need for expansion, the city of Jakarta is planning to reclaim more land in the Jakarta Bay. However, the reclamation activities of some islands have barely started and already the developers are facing difficulties in finding sufficient quantities of sand as fill material. When addressing the problem of sand scarcity in the case of Jakarta where, an excess of waste production, an inadequate solid waste management system and a lack of dumping ground pose a major problem, it is hard not to think of the use of waste as alternative fill material. This paper analyses the possibilities of using waste in the land reclamation projects, considering the governmental, social, environmental and economic context of the city. The results identify types of waste that could be used, ways of using those types of waste and implementation conditions for the city of Jakarta.
Abstract: Magnesium wastes are produced by many industrial activities. This waste problem is becoming a future problem for the world. Magnesium borates have many advantages such as; high corrosion resistance, heat resistance, high coefficient of elasticity and can also be used in the production of material against radiation. Addition, magnesium borates have great potential in sectors
including ceramic and detergents industry and superconducting materials.
In this study, using the starting materials of waste magnesium and H3BO3 the hydrothermal method was applied at a moderate
temperature of 70oC. Several mole ratios of waste magnesium to H3BO3 are selected as; 1:2, 1:4, 1:6, 1:8, 1:10. Reaction time was determined as 1 hour. After the synthesis, X-Ray Diffraction (XRD) and Fourier Transform Infrared Spectroscopy (FT-IR) techniques are applied to products. As a result the forms of mcallisterite “Mg2(B6O7(OH)6)2.9(H2O)”, admontite “MgO(B2O3)3.7(H2O)” and magnesium boron hydrate (MgO(B2O3)3.6(H2O)” are obtained.
Abstract: Addition of an oily waste to a co-composting process of dairy cow manure with food waste, and the influence in the final product was evaluated. Three static composting piles with different substrates concentrations were assessed. Sawdust was also added to all composting piles to attain 60%, humidity at the beginning of the process. In pile 1, the co-substrates were the solid-phase of dairy cow manure, food waste and sawdust as bulking agent. In piles 2 and 3 there was an extra input of oily waste of 7 and 11% of the total volume, respectively, corresponding to 18 and 28% in dry weight. The results showed that the co-composting process was feasible even at the highest fat content. Another positive effect due to the oily waste addition was the requirement of extra humidity, due to the hydrophobic properties of this specific waste, which may imply reduced need of a bulking agent. Moreover, this study shows that composting can be a feasible way of adding value to fatty wastes. The three final composts presented very similar and suitable properties for land application.
Abstract: The international society focuses on the environment
protection and natural energy sources control for the global
cooperation against weather change and sustainable growth. The study
presents the overview of the water shortage status and the necessity of wastewater reuse facility in military facilities and for the possibility of
the introduction, compares the economics by means of cost-benefit
analysis. The military features such as the number of users of military barracks and the water use were surveyed by the design principles by
facility types, the application method of wastewater reuse facility was selected, the feed water, its application and the volume of reuse volume were defined and the expectation was estimated, confirming
the possibility of introducing a wastewater reuse possibility by means of cost-benefit analysis.
Abstract: Ever since industrial revolution began, our ecosystem
has changed. And indeed, the negatives outweigh the positives.
Industrial waste usually released into all kinds of body of water, such
as river or sea. Tempeh waste is one example of waste that carries
many hazardous and unwanted substances that will affect the
surrounding environment. Tempeh is a popular fermented food in
Asia which is rich in nutrients and active substances. Tempeh liquid
waste- in particular- can cause an air pollution, and if penetrates
through the soil, it will contaminates ground-water, making it
unavailable for the water to be consumed. Moreover, bacteria will
thrive within the polluted water, which often responsible for causing
many kinds of diseases. The treatment used for this chemical waste is
biological treatment such as constructed wetland and activated
sludge. These kinds of treatment are able to reduce both physical and
chemical parameters altogether such as temperature, TSS, pH, BOD,
COD, NH3-N, NO3-N, and PO4-P. These treatments are implemented
before the waste is released into the water. The result is a
comparation between constructed wetland and activated sludge,
along with determining which method is better suited to reduce the
physical and chemical subtances of the waste.
Abstract: An overview of the important aspects of managing
and controlling industrial effluent discharges to public sewers namely
sampling, characterization, quantification and legislative controls has
been presented. The findings have been validated by means of a case
study covering three industrial sectors namely, tanning, textile
finishing and food processing industries. Industrial effluents
discharges were found to be best monitored by systematic and
automatic sampling and quantified using water meter readings
corrected for evaporative and consumptive losses. Based on the
treatment processes employed in the public owned treatment works
and the chemical oxygen demand and biochemical oxygen demand
levels obtained, the effluent from all the three industrial sectors
studied were found to lie in the toxic zone. Thus, physico-chemical
treatment of these effluents is required to bring them into the
biodegradable zone. KL values (quoted to base e) were greater than
0.50 day-1 compared to 0.39 day-1 for typical municipality
wastewater.
Abstract: The integration between technology of remote
sensing, information from the data of digital image, and modeling
technology for the simulation of water quality will provide easiness
during the observation on the quality of water changes on the river
surface. For example, Ciliwung River which is contaminated with
non-point source pollutant from household wastes, particularly on its
downstream. This fact informed that the quality of water in this river
is getting worse. The land use for settlements and housing ranges
between 62.84% - 81.26% on the downstream of Ciliwung River,
give a significant picture in seeing factors that affected the water
quality of Ciliwung River.
Abstract: Statistics Canada stated that the wastewater treatment
facilities in most provinces are aging and passes 63% of their useful
life in 2007 the highest ratio among public infrastructure assets.
Currently, there is no standard condition rating system for wastewater
treatment plants that give a specific rating index that describe the
physical integrity of different infrastructure elements in the treatment
plant and its environmental performance. The main objective of this
study is to develop a condition-rating index for wastewater treatment
plants mainly activated sludge systems. The proposed WWTP CRI, is
based on dividing the treatment plant into its three treatment phases;
primary phase, secondary phase and the tertiary phase. The
condition-rating index will reflect the infrastructures state for each
phase, mainly tanks, pipes, blowers and pumps.
Abstract: Treatment of tar-containing wastewater is necessary
for the successful operation of biomass gasification plants (BGPs). In
the present study, tar-containing wastewater was treated using lime
and alum for the removal of in-organics, followed by adsorption on
powdered activated carbon (PAC) for the removal of organics. Limealum
experiments were performed in a jar apparatus and activated
carbon studies were performed in an orbital shaker. At optimum
concentrations, both lime and alum individually proved to be capable
of removing color, total suspended solids (TSS) and total dissolved
solids (TDS), but in both cases, pH adjustment had to be carried out
after treatment. The combination of lime and alum at the dose ratio
of 0.8:0.8 g/L was found to be optimum for the removal of inorganics.
The removal efficiency achieved at optimum
concentrations were 78.6, 62.0, 62.5 and 52.8% for color, alkalinity,
TSS and TDS, respectively. The major advantages of the lime-alum
combination were observed to be as follows: no requirement of pH
adjustment before and after treatment and good settleability of
sludge. Coagulation-precipitation followed by adsorption on PAC
resulted in 92.3% chemical oxygen demand (COD) removal and
100% phenol removal at equilibrium. Ammonia removal efficiency
was found to be 11.7% during coagulation-flocculation and 36.2%
during adsorption on PAC. Adsorption of organics on PAC in terms
of COD and phenol followed Freundlich isotherm with Kf = 0.55 &
18.47 mg/g and n = 1.01 & 1.45, respectively. This technology may
prove to be one of the fastest and most techno-economically feasible
methods for the treatment of tar-containing wastewater generated
from BGPs.
Abstract: The study aimed to investigate characteristics of
vegetative tissue for taxonomic purpose and possibly trend of waste
application in industry. Stems and branches of 15 species in Solanum
found in Thailand were prepared for fiber and examined by light
microscopy. Microstructural characteristic data of fiber i.e. fiber
length and width, fiber lumen diameter and fiber cell wall thickness
were recorded. The longest average fiber cell length (>3.9 mm.) were
obtained in S. lycopersicum L. and S. tuberosum L. Fiber cells from
S. lycopersicum also revealed the widest average diameter of whole
cell and its lumen at >45.5 μm and >29 μm respectively. However
fiber cells with thickest wall of > 9.6 μm were belonged to the
ornamental tree species, S. wrightii Benth. The results showed that
the slenderness ratio, Runkel ratio, and flexibility coefficient, with
potentially suitable for feedstock in paper industry fell in 4 exotic
species, i.e. Solanumamericanum L., S. lycopersicum, S.
seaforthianum Andr., and S. tuberosum L
Abstract: In this study, the theoretical relationship between pressure and density was investigated on cylindrical hollow fuel briquettes produced of a mixture of fibrous biomass material using a screw press without any chemical binder. The fuel briquettes were made of biomass and other waste material such as spent coffee beans, mielie husks, saw dust and coal fines under pressures of 0.878-2.2 Mega Pascals (MPa). The material was densified into briquettes of outer diameter of 100mm, inner diameter of 35mm and 50mm long. It was observed that manual screw compression action produces briquettes of relatively low density as compared to the ones made using hydraulic compression action. The pressure and density relationship was obtained in the form of power law and compare well with other cylindrical solid briquettes made using hydraulic compression action. The produced briquettes have a dry density of 989 kg/m3 and contain 26.30% fixed carbon, 39.34% volatile matter, 10.9% moisture and 10.46% ash as per dry proximate analysis. The bomb calorimeter tests have shown the briquettes yielding a gross calorific value of 18.9MJ/kg.
Abstract: Freeze concentration freezes or crystallises the water
molecules out as ice crystals and leaves behind a highly concentrated
solution. In conventional suspension freeze concentration where ice
crystals formed as a suspension in the mother liquor, separation of
ice is difficult. The size of the ice crystals is still very limited which
will require usage of scraped surface heat exchangers, which is very
expensive and accounted for approximately 30% of the capital cost.
This research is conducted using a newer method of freeze
concentration, which is progressive freeze concentration. Ice crystals
were formed as a layer on the designed heat exchanger surface. In
this particular research, a helical structured copper crystallisation
chamber was designed and fabricated. The effect of two operating
conditions on the performance of the newly designed crystallisation
chamber was investigated, which are circulation flowrate and coolant
temperature. The performance of the design was evaluated by the
effective partition constant, K, calculated from the volume and
concentration of the solid and liquid phase. The system was also
monitored by a data acquisition tool in order to see the temperature
profile throughout the process. On completing the experimental
work, it was found that higher flowrate resulted in a lower K, which
translated into high efficiency. The efficiency is the highest at 1000
ml/min. It was also found that the process gives the highest
efficiency at a coolant temperature of -6 °C.
Abstract: Preparation of size controlled nano-particles of silver catalyst on carbon substrate from e-waste has been investigated. Chemical route was developed by extraction of the metals available in nitric acid followed by treatment with hydrofluoric acid. Silver metal particles deposited with an average size 4-10 nm. A stabilizer concentration of 10- 40 g/l was used. The average size of the prepared silver decreased with increase of the anode current density. Size uniformity of the silver nano-particles was improved distinctly at higher current density no more than 20mA... Grain size increased with EK time whereby aggregation of particles was observed after 6 h of reaction.. The chemical method involves adsorption of silver nitrate on the carbon substrate. Adsorbed silver ions were directly reduced to metal particles using hydrazine hydrate. Another alternative method is by treatment with ammonia followed by heating the carbon loaded-silver hydroxide at 980°C. The product was characterized with the help of XRD, XRF, ICP, SEM and TEM techniques.
Abstract: The current work focuses on rephrasing the harmful
effects of mercury that is being released from a number of sources.
Most of the sources are from the industrial waste water. Different
techniques of mercury removal have been discussed and a brief
comparison among these has been made. The experimental work has
been conducted for two most widely used methods of mercury
removal and comparison in terms of their efficiency has been made.
Abstract: The presented work is motivated by a French law
regarding nuclear waste management. A new conceptual Accelerator
Driven System (ADS) designed for the Minor Actinides (MA)
transmutation has been assessed by numerical simulation. The
MUltiple Spallation Target (MUST) ADS combines high thermal power (up to 1.4 GWth) and high specific power. A 30 mA and 1
GeV proton beam is divided into three secondary beams transmitted on three liquid lead-bismuth spallation targets. Neutron and thermalhydraulic
simulations have been performed with the code MURE, based on the Monte-Carlo transport code MCNPX. A methodology has been developed to define characteristic of the MUST ADS concept according to a specific transmutation scenario. The reference
scenario is based on a MA flux (neptunium, americium and curium)
providing from European Fast Reactor (EPR) and a plutonium multireprocessing
strategy is accounted for. The MUST ADS reference
concept is a sodium cooled fast reactor. The MA fuel at equilibrium is mixed with MgO inert matrix to limit the core reactivity and
improve the fuel thermal conductivity. The fuel is irradiated over five
years. Five years of cooling and two years for the fuel fabrication are
taken into account. The MUST ADS reference concept burns about 50% of the initial MA inventory during a complete cycle. In term of
mass, up to 570 kg/year are transmuted in one concept. The methodology to design the MUST ADS and to calculate fuel
composition at equilibrium is precisely described in the paper. A detailed fuel evolution analysis is performed and the reference scenario is compared to a scenario where only americium transmutation is performed.
Abstract: In the course of the present work, plain (nonencapsulated)
and microencapsulated polyphenols were produced
using olive mill wastewater (OMW) as raw material, in order to be
used for enrichment of yogurt and dairy products. The OMW was
first clarified by using membrane technology and subsequently the
contained poly-phenols were isolated by adsorption-desorption
technique using selective macro-porous resins and finally recovered
in dry form after been processed by RO membrane technique
followed by freeze drying. Moreover, the polyphenols were
encapsulated in modified starch by freeze drying in order to mask the
color and bitterness effect and improve their functionality. The two
products were used successfully as additives in yogurt preparations
and the produced products were acceptable by the consumers and
presented with certain advantage to the plain yogurt. For the herein
proposed production scheme a patent application was already
submitted.
Abstract: This study was conducted using the data collected at the mouth of Jen-Gen River to investigate and analyze chromium (Cr) contained in the sediments, and to evaluate the accumulation of Cr and the degree of its potential risk. The results show that samples collected at all monitoring stations near the mouth of Jen-Gen River contain 92–567 mg/kg of Cr with average of 366±166 mg/kg. The spatial distribution of Cr reveals that the Cr concentration is relatively high in the river mouth region, and gradually diminishes toward the harbor region. This indicates that upstream industrial and municipal wastewater discharges along the river bank are major sources of pollution. The accumulation factor and potential ecological risk index indicate that the sedimentation at Jen-Gen River mouth has the most serious degree of Cr accumulation and the highest ecological potential risk.