Abstract: Heavy metals have bad effects on environment and
soils and it can uptake by natural HAP .natural Hap is an inexpensive
material that uptake large amounts of various heavy metals like Zn
(II) .Natural HAP (N-HAP), extracted from bovine cortical bone ash,
is a good choice for substitution of commercial HAP. Several
experiments were done to investigate the sorption capacity of Zn (II)
to N-HAP in various particles sizes, temperatures, initial
concentrations, pH and reaction times. In this study, the sorption of
Zinc ions from a Zn solution onto HAP particles with sizes of 1537.6
nm and 47.6 nm at three initial pH values of 4.50, 6.00 and 7.50 was
studied. The results showed that better performance was obtained
through a 47.6 nm particle size and higher pH values. The
experimental data were analyzed using Langmuir, Freundlich, and
Arrhenius equations for equilibrium, kinetic and thermodynamic
studies. The analysis showed a maximum adsorption capacity of NHAP
as being 1.562 mmol/g at a pH of 7.5 and small particle size.
Kinetically, the prepared N-HAP is a feasible sorbent that retains Zn
(II) ions through a favorable and spontaneous sorption process.
Abstract: To understand the seismic behavior of the offshore
structures, the dynamic interaction of the water-structure-soil should
be assessed. In this regard the role of the water dynamic properties in
magnifying or reducing of the effects of earthquake induced motions
on offshore structures haven't been investigated in precise manner in
available literature. In this paper the sea water level fluctuations
effects on the seismic behavior of a sample of offshore structures has
been investigated by emphasizing on the water-structure interaction
phenomenon. For this purpose a two dimensional finite element
model of offshore structures as well as surrounded water has been
developed using ANSYS software. The effect of soil interaction with
embedded pile foundation has been imposed by using a series of
nonlinear springs in horizontal and vertical directions in soil-piles
contact points. In the model, the earthquake induced motions have
been applied on springs and consequently the motions propagated
upward to the structure and surrounded water. As a result of
numerical study, the horizontal deformations of the offshore deck as
well as internal force and buckling coefficient in structural elements
have been recorded and controlled with and without water presence.
In part of study a parametric study has been accomplished on sea
water level fluctuations and effect of this parameter has been studied
on the aforementioned numerical results.
Abstract: The use of sewage sludge and effluents from
wastewater treatment plants for irrigation of agricultural lands is on
the rise particularly in peri-urban areas of developing countries.
The reuse of nutrients and organic matter in treated wastewater
and sewage sludge via land application is a desirable goal. However,
trace or heavy metals present in sludge pose the risk of human or
phytotoxicity from land application. Long-term use of sewage
sludge, heavy metals can accumulate to phytotoxic levels and results
in reduced plants growth and/or enhanced metal concentrations in
plants, which consumed by animals then enter the food chain. In this
research, the amount of heavy metals was measured in plants
irrigated with wastewater and sludge application. For this purpose,
three pilots were made in a Shush treatment plant in south of Tehran.
Three plants species, spinach, lettuce and radish were selected and
planted in the pilots.First pilot was irrigated just with wastewater of
treatment plant and second pilot was irrigated with wastewater and
sludge application .Third pilot was irrigated with simulated heavy
metals solution equal 50 years of irrigation. The results indicate that
the average of amount of heavy metals Pb, Cd in three plant species
in first pilot were lower than permissible limits .In second pilot,
Cadmium accumulations are high in three species plants and more
than the standard limits. Concentration of Cd , Pb have exceed their
permitted limits in plants in third pilot . It was concluded that the use
of wastewater and sludge application in agricultural lands enriched
soils with heavy metals to concentrations that may pose potential
environmental and health risks in the long-term.
Abstract: The use of contour strips of perennial vegetation with
bio-fuel potential can improve surface water quality by reducing
NO3-N and sediment outflow from cropland to surface water-bodies.
It also has economic benefits of producing ethanol. In this study,
The Soil and Water Assessment Tool (SWAT) model was applied to
a watershed in Iowa, USA to examine the effectiveness of contour
strips of switch grass in reducing the NO3-N outflows from crop
fields to rivers or lakes. Numerical experiments were conducted to
identify potential subbasins in the watershed that have high water
quality impact, and to examine the effects of strip size on NO3-N
reduction under various meteorological conditions, i.e. dry, average
and wet years. Useful information was obtained for the evaluation of
economic feasibility of growing switch grass for bio-fuel in contour
strips. The results can assist in cost-benefit analysis and decisionmaking
in best management practices for environmental protection.
Abstract: Researchers have long had trouble in measurement of
Exchangeable Sodium Ratio (ESR) at salt-affected soils. this
parameter are often determined using laborious and time consuming
laboratory tests, but it may be more appropriate and economical to
develop a method which uses a more simple soil salinity index. The
aim of this study was to determine the relationship between
exchangeable sodium ratio (ESR) and sodium adsorption ratio (SAR)
in some salt-affected soils of Khuzestan plain. To this purpose, two
experimental areas (S1, S2) of Khuzestan province-IRAN were
selected and four treatments with three replications by series of
double rings were applied. The treatments were included 25cm,
50cm, 75cm and 100cm water application. The statistical results of
the study indicated that in order to predict soil ESR based on soil
SAR the linear regression model ESR=0.2048+0.0066 SAR
(R2=0.53) & ESR=0.0564+0.0171 SAR (R2=0.76) can be
recommended in Pilot S1 and S2 respectively.
Abstract: 15 strains of oil-destructing microorganisms were
isolated from oil polluted soil of Western Kazakhstan. Strains 2-A
and 41-3 with the highest oil-destructing activities were chosen from
them. It was shown that these strains oxidized n-alkanes very well,
but isoalkanes, isoparaffin, cycloparaffin and heavy aromatic
compounds were destructed very slowly. These both strains were
tested as preparations for bioremediation of oil-polluted soil in model
and field experiments. The degree of utilizing of soil oil by this
preparation was 79-84 % in field experiments.
Abstract: Considering the serious health hazards of air pollutants from automobiles, the present study was aimed to estimate the genotoxic/tumor inducing potential of three soil samples collected from junctions of Bus stand (BS), Crystal (CT) and Railway station (RS) of Amritsar, Punjab (India) using Allium cepa root chromosomal aberration assay (AlRCAA) and potato disc tumor assay (PDTA). The genotoxic potential in AlRCAA was 41.27% and 41.26% for BS; 37.89% and 43.38% for RS and 33.76% and 37.83% for CT during in situ and root dip treatments, respectively. The maximum number of tumors were induced in RS sample (64) followed by BS (21) and CT (9) during PDTA. The physicochemical parameters of soil sample were also studied and the concentration of lead was found to be 95.21 mg/Kg in RS, 35.30 mg/Kg in BS and 24.59 mg/Kg in CT samples.
Abstract: This paper explores oil prices changes impact on energy policy of Kazakhstan in 2001-2009. It involves the role of oil income to the economic development, process of diversification of internal and external energy policy of Kazakhstan, and the changes in oil law towards subsoil users.
Abstract: High building constructions are increasing in south
beaches of the Caspian Sea because of tourist attractions and limitation of residential areas. According to saturated alluvial fields transfer of load from high structures to the soil by piles is inevitable.
In spite of most of these piles are under compression forces, tension piles are used in special conditions. Few studies have been conducted
because of the limited use of these piles. Tension capacity of openended pipe piles in full scale was tested in this study. The length of the bored piles was 420 up to 480 cm and all were in 120 cm
diameter. The results of testing 7 piles were compared with the results of relations given by researches.
Abstract: Due to the growth of the urban area towards lands
contaminated with ancient tails, in this work we evaluated if the
leaching with calcium thiosulfate (CaS2O3) for the recovery of silver,
gold and mercury from this soil, also dissolves arsenic, cadmium and
lead; for this, we determined their quantity per each fraction of size
of particle of the soil before and after the dissolution. Half of the soil
samples were leached in the plant Beneficiadora de Jales del Centro,
S. A. de C.V. and the rest of them remained in the laboratory. The
ICP-OES technique was used to determine the amounts of arsenic,
cadmium and lead, in the samples of both lots. The soil samples were
collected in a neighboring area at El Lampotal, Vetagrande,
Zacatecas, México, with an extension of 600 m2 at 22º52' 37.69'' N,
102º25' 11.73'' W. The amount of arsenic, cadmium and lead found
in nonleached soil and for a particle size of 47 μm was 203.72±3.73,
33.63±1.31 and 3480.99±20.4 mg/kg respectively.
Abstract: Protection of slope and embankment from erosion has
become an important issue in Bangladesh. The constructions of
strong structures require large capital, integrated designing, high
maintenance cost. Strong structure methods have negative impact on
the environment and sometimes not function for the design period.
Plantation of vetiver system along the slopes is an alternative
solution. Vetiver not only serves the purpose of slope protection but
also adds green environment reducing pollution. Vetiver is available
in almost all the districts of Bangladesh. This paper presents the
application of vetiver system with geo-jute, for slope protection and
erosion control of embankments and slopes. In-situ shear tests have
been conducted on vetiver rooted soil system to find the shear
strength. The shear strength and effective soil cohesion of vetiver
rooted soil matrix are respectively 2.0 times and 2.1 times higher than
that of the bared soil. Similar trends have been found in direct shear
tests conducted on laboratory reconstituted samples. Field trials have
been conducted in road embankment and slope protection with
vetiver at different sites. During the time of vetiver root growth the
soil protection has been accomplished by geo-jute. As the geo-jute
degrades with time, vetiver roots grow and take over the function of
geo-jutes. Slope stability analyses showed that vegetation increase
the factor of safety significantly.
Abstract: Recent research on seeds of bio-diesel plants like
Jatropha curcas, constituting 40-50% bio-crude oil indicates its
potential as one of the most promising alternatives to conventional
sources of energy. Also, limited studies on utilization of de-oiled cake
have revealed that Jatropha bio-waste has good potential to be used as
organic fertilizers produced via aerobic and anaerobic treatment.
However, their commercial exploitation has not yet been possible. The
present study aims at developing appropriate bio-processes and
formulations utilizing Jatropha seed cake as organic fertilizer, for
improving the growth of Polianthes tuberose L. (Tuberose). Pot
experiments were carried out by growing tuberose plants on soil
treated with composted formulations of Jatropha de-oiled cake, Farm
Yard Manure (FYM) and inorganic fertilizers were also blended in
soil. The treatment was carried out through soil amendment as well as
foliar spray. The growth and morphological parameters were
monitored for entire crop cycle.
The growth Length and number of leaves, spike length, rachis
length, number of bulb per plant and earliness of sprouting of bulb and
yield enhancement were comparable to that achieved under inorganic
fertilizer. Furthermore, performance of inorganic fertilizer also showed
an improvement when blended with composted bio-waste. These
findings would open new avenues for Jatropha based bio-wastes to be
composted and used as organic fertilizers for commercial floriculture.
Abstract: The present study attempted to improve the Mercury
(Hg) sorption capacity of kanuma volcanic ash soil (KVAS) by
impregnating the cupper (Cu). Impregnation was executed by 1 and
5% Cu powder and sorption characterization of optimum Hg
removing Cu impregnated KVAS was performed under different
operational conditions, contact time, solution pH, sorbent dosage and
Hg concentration using the batch operation studies. The 1% Cu
impregnated KVAS pronounced optimum improvement (79%) in
removing Hg from water compare to control. The present
investigation determined the equilibrium state of maximum Hg
adsorption at 6 h contact period. The adsorption revealed a pH
dependent response and pH 3.5 showed maximum sorption capacity
of Hg. Freundlich isotherm model is well fitted with the experimental
data than that of Langmuir isotherm. It can be concluded that the Cu
impregnation improves the Hg sorption capacity of KVAS and 1%
Cu impregnated KVAS could be employed as cost-effective
adsorbent media for treating Hg contaminated water.
Abstract: Organochlorine pesticides (OCPs) are known to be
persistent and bioaccumulative toxicants that may cause reproductive
impairments in wildlife as well as human. The current study uses the
snail-eating turtle Malayemys macrocephala, a long-lived animal
commonly distribute in rice field habitat in central part of Thailand,
as a sentinel to monitor OCP contamination in environment. The
nest soil, complete clutch of eggs, and blood of the turtle were
collected from agricultural areas in the Chao Phraya River Basin,
Thailand during the nesting season of 2007-2008. The novel
methods for tissue extraction by an accelerated solvent extractor
(ASE, for egg) and liquid-liquid extraction (for blood) have been
developed. The nineteen OCP residues were analyzed by gas
chromatography with micro-electron captured detector (GC-μECD).
The validated methods have met requirements of the AOAC
standard. The results indicated that significant amounts of OCPs are
still contaminated in nest soil and eggs of the turtle even though the
OCPs had been banned in this area for many years. This suggested
the potential risk to health of wildlife as well as human in the area.
Abstract: Offset Double-Disk Opener (DDO) is a popular
furrow opener in conservation tillage. It has some limitations such as
negative suction to penetrate in the soil, hair pinning and mixing seed
and fertilizer in the slot. Because of importance of separation of seed
and fertilizer in the slot, by adding two horizontal mini disks to DDO
a modified opener was made (MDO) which placed the fertilizer
between and under two rows of seed. To consider performance of
novel opener an indoor comparison test between DDO and MDO was
performed at soil bin. The experiment was conducted with three
working speeds (3, 6 and 8 km h-1), two bulk densities of soil (1.1
and 1.4 Mg m-3) and two levels of residues (1 and 2 ton ha-1). The
experimental design consisted in a (3×2×2) complete randomized
factorial with three replicates for each test. Moisture of seed furrow,
separation of seed and fertilizer, hair pinning and resultant forces
acting on the openers were used as assessing indexes. There was no
significant difference between soil moisture content in slots created
by DDO and MDO at 0-4 cm depth, but at 4-8 cm the in the slot
created by MDO moisture content was higher about 9%. Horizontal
force for both openers increased with increasing speed and soil bulk
density. Vertical force for DDO was negative so it needed additional
weight for penetrating in the soil, but vertical force for MDO was
positive and, which can solve the challenge of penetration in the soil
in DDO. In soft soil with heavy residues some trash was pushed by
DDO into seed furrow (hair pinning) but at MDO seed were placed at
clean groove. Lateral and vertical separation of seed and fertilizer
was performed effectively by MDO (4.5 and 5 cm, respectively)
while DDO put seed and fertilizer close to each other. Overall, the
Modified Offset Double-disks (MDO) had better performance. So by
adapting this opener with no-tillage drillers it would possible to have
higher yield in conservation tillage where the most appropriate
opener is disk type.
Abstract: Principally, plants grown in soilless culture may be
attacked by the same pests and diseases as cultivated traditionally in
soil. The most destructive phytopathogens are fungi, such as
Phythium, Phytophthora and Fusarium, followed by viruses, bacteria
and nematodes. We investigated effect of carbon nanotube filters on
disease management of soilless culture. Tomato seedlings transplant
in plastic pots filled with a soilless media of vermiculite. The crop
irrigated and fertilized using a hydroponic nutrient solution. We used
carbon nanotube filters for nutrient solution disinfection. Our results
show that carbon nanotube filtration significantly reduces pathogens
on tomato plants. Fungal elimination (Fusarium oxysporum and
Pythium spp.) was usually successful at about 96 to 99.9% all over
the cultural season. It is seem that in tomato soilless culture,
nanofiltration constitutes a reliable method that allows control of the
development of diseases caused by pathogenic fungi
Abstract: Small-scale RC models of both piles and tunnel ducts
were produced as mockups of reality and loaded under soil
confinement conditionsto investigate the damage evolution of
structural RC interacting with soil. Experimental verifications usinga
3D nonlinear FE analysis program called COM3D, which was
developed at the University of Tokyo, are introduced. This analysis
has been used in practice for seismic performance assessment of
underground ducts and in-ground LNG storage tanks in consideration
of soil-structure interactionunder static and dynamic loading. Varying
modes of failure of RCpilessubjected to different magnitudes of soil
confinement were successfully reproduced in the proposed small-scale
experiments and numerically simulated as well. Analytical simulation
was applied to RC tunnel mockups under a wide variety of depth and
soil confinement conditions, and reasonable matching was confirmed.
Abstract: Among many different methods that are used for
optimizing different engineering problems mathematical (numerical)
optimization techniques are very important because they can easily
be used and are consistent with most of engineering problems. Many
studies and researches are done on stability analysis of three
dimensional (3D) slopes and the relating probable slip surfaces and
determination of factors of safety, but in most of them force
equilibrium equations, as in simplified 2D methods, are considered
only in two directions. In other words for decreasing mathematical
calculations and also for simplifying purposes the force equilibrium
equation in 3rd direction is omitted. This point is considered in just a
few numbers of previous studies and most of them have only given a
factor of safety and they haven-t made enough effort to find the most
probable slip surface. In this study shapes of the slip surfaces are
modeled, and safety factors are calculated considering the force
equilibrium equations in all three directions, and also the moment
equilibrium equation is satisfied in the slip direction, and using
nonlinear programming techniques the shape of the most probable
slip surface is determined. The model which is used in this study is a
3D model that is composed of three upper surfaces which can cover
all defined and probable slip surfaces. In this research the meshing
process is done in a way that all elements are prismatic with
quadrilateral cross sections, and the safety factor is defined on this
quadrilateral surface in the base of the element which is a part of the
whole slip surface. The method that is used in this study to find the
most probable slip surface is the non-linear programming method in
which the objective function that must get optimized is the factor of
safety that is a function of the soil properties and the coordinates of
the nodes on the probable slip surface. The main reason for using
non-linear programming method in this research is its quick
convergence to the desired responses. The final results show a good
compatibility with the previously used classical and 2D methods and
also show a reasonable convergence speed.
Abstract: The measurements of 226Ra, 232Th and 40K using
gamma spectrometry and radon concentration and exhalation rates
measurements using solid state nuclear track (LR-115, Type-II
plastic) detectors are used to asses a first order exposure risk for the
persons residing in Fatehbad and Hissar districts of Western Haryana,
India. The concentration of Radium, Thorium and Potassium in the
soil samples varies from 13.37 Bq m-3 to 24.67 Bq m-3, 34.67 Bq m-3
to 67.34 Bq m-3 and 298.78 Bq m-3 to 405.67 Bq m-3 respectively
with average values of 18.78, 47.35 and 361.57 Bq m-3 respectively.
The radium equivalent activity (Raeq) calculated for the same soil
samples varies from 92.72 Bq m-3 to 140.6 Bq m-3 with an average
value of 111.80 Bq m-3. The values of absorbed dose and annual
effective dose (indoors and outdoors) are found to vary from 44.18
nGy h-1 to 65.23 nGy h-1, 0.22 mSv y-1 to 0.32 mSv y-1 and 0.05 mSv
y-1 to 0.08 mSv y-1 respectively. The radon concentration and
exhalation rates have also been reported. The radium equivalent
activities in all the soil samples were found to be lower than the limit
(370 Bq kg-1) set in the Organization for Economic Cooperation and
Development (OECD) report and the value of Hex in all the samples
is less than unity.
Abstract: The large and small-scale shaking table tests, which
was conducted for investigating damage evolution of piles inside
liquefied soil, are numerically simulated and experimental verified by the3D nonlinear finite element analysis. Damage evolution of
elasto-plastic circular steel piles and reinforced concrete (RC) one with cracking and yield of reinforcement are focused on, and the failure patterns and residual damages are captured by the proposed constitutive models. The superstructure excitation behind quay wall is
reproduced as well.