Abstract: Enzymatic saccharification of biomass for reducing
sugar production is one of the crucial processes in biofuel production
through biochemical conversion. In this study, enzymatic
saccharification of dilute potassium hydroxide (KOH) pre-treated
Tetraselmis suecica biomass was carried out by using cellulase
enzyme obtained from Trichoderma longibrachiatum. Initially, the
pre-treatment conditions were optimised by changing alkali reagent
concentration, retention time for reaction, and temperature. The T.
suecica biomass after pre-treatment was also characterized using
Fourier Transform Infrared Spectra and Scanning Electron
Microscope. These analyses revealed that the functional group such
as acetyl and hydroxyl groups, structure and surface of T. suecica
biomass were changed through pre-treatment, which is favourable for
enzymatic saccharification process. Comparison of enzymatic
saccharification of untreated and pre-treated microalgal biomass
indicated that higher level of reducing sugar can be obtained from
pre-treated T. suecica. Enzymatic saccharification of pre-treated T.
suecica biomass was optimised by changing temperature, pH, and
enzyme concentration to solid ratio ([E]/[S]). Highest conversion of
carbohydrate into reducing sugar of 95% amounted to reducing sugar
yield of 20 (wt%) from pre-treated T. suecica was obtained from
saccharification, at temperature: 40°C, pH: 4.5 and [E]/[S] of 0.1
after 72 h of incubation. Hydrolysate obtained from enzymatic
saccharification of pretreated T. suecica biomass was further
fermented into biobutanol using Clostridium saccharoperbutyliticum
as biocatalyst. The results from this study demonstrate a positive
prospect of application of dilute alkaline pre-treatment to enhance
enzymatic saccharification and biobutanol production from
microalgal biomass.
Abstract: Solid fuel transient burning behavior under oxidizer
gas flow is numerically investigated. It is done using analysis of the
regression rate responses to the imposed sudden and oscillatory
variation at inflow properties. The conjugate problem is considered
by simultaneous solution of flow and solid phase governing
equations to compute the fuel regression rate. The advection
upstream splitting method is used as flow computational scheme in
finite volume method. The ignition phase is completely simulated to
obtain the exact initial condition for response analysis. The results
show that the transient burning effects which lead to the combustion
instabilities and intermittent extinctions could be observed in solid
fuels as the solid propellants.
Abstract: This paper looks into detailed investigation of
thermal-hydraulic characteristics of the flow field in a fuel rod
model, especially near the spacer. The area investigate represents a
source of information on the velocity flow field, vortex, and on the
amount of heat transfer into the coolant all of which are critical for
the design and improvement of the fuel rod in nuclear power plants.
The flow field investigation uses three-dimensional Computational
Fluid Dynamics (CFD) with the Reynolds stresses turbulence model
(RSM). The fuel rod model incorporates a vertical annular channel
where three different shapes of spacers are used; each spacer shape is
addressed individually. These spacers are mutually compared in
consideration of heat transfer capabilities between the coolant and
the fuel rod model. The results are complemented with the calculated
heat transfer coefficient in the location of the spacer and along the
stainless-steel pipe.
Abstract: This paper describes a method to measure and
compensate a 4 axes ultra-precision machine tool that generates micro
patterns on the large surfaces. The grooving machine is usually used
for making a micro mold for many electrical parts such as a light guide
plate for LCD and fuel cells. The ultra precision machine tool has three
linear axes and one rotational table. Shaping is usually used to
generate micro patterns. In the case of 50 μm pitch and 25 μm height
pyramid pattern machining with a 90° wedge angle bite, one of linear
axis is used for long stroke motion for high cutting speed and other
linear axis are used for feeding. The triangular patterns can be
generated with many times of long stroke of one axis. Then 90°
rotation of work piece is needed to make pyramid patterns with
superposition of machined two triangular patterns.
To make a two dimensional positioning error, straightness of two
axes in out of plane, squareness between the each axis are important.
Positioning errors, straightness and squarness were measured by laser
interferometer system. Those were compensated and confirmed by
ISO230-6. One of difficult problem to measure the error motions is
squareness or parallelism of axis between the rotational table and
linear axis. It was investigated by simultaneous moving of rotary table
and XY axes. This compensation method is introduced in this paper.
Abstract: The mixed oxide nuclear fuel (MOX) of U and Pu contains several percent of fission products and minor actinides, such as neptunium, americium and curium. It is important to determine accurately the decay heat from Curium isotopes as they contribute significantly in the MOX fuel. This heat generation can cause samples to melt very quickly if excessive quantities of curium are present. In the present paper, we introduce a new approach that can predict the decay heat from curium isotopes. This work is a part of the project funded by King Abdulaziz City of Science and Technology (KASCT), Long-Term Comprehensive National Plan for Science, Technology and Innovations, and take place in King Abdulaziz University (KAU), Saudi Arabia. The approach is based on the numerical solution of coupled linear differential equations that describe decays and buildups of many nuclides to calculate the decay heat produced after shutdown. Results show the consistency and reliability of the approach applied.
Abstract: Thermal behavior of fuel channel under loss of coolant accident (LOCA) is a major concern for nuclear reactor safety. LOCA along with failure of emergency cooling water system (ECC) may leads to mechanical deformations like sagging and ballooning. In order to understand the phenomenon an experiment has been carried out using 19 pin fuel element simulator. Main purpose of the experiment was to trace temperature profiles over the pressure tube, calandria tube and clad tubes of Indian Pressurized Heavy Water Reactor (IPHWR) under symmetrical and asymmetrical heat-up conditions. For simulating the fully voided scenario, symmetrical heating of pressure was carried out by injecting 13.2 KW (2 % of nominal power) to all the 19 pins and the temperatures of pressure tube, calandria tube and clad tubes were measured. During symmetrical heating the sagging of fuel channel was initiated at 460 °C and the highest temperature attained by PT was 650 °C . The decay heat from clad tubes was dissipated to moderator mainly by radiation and natural convection. The highest temperature of 680 °C was observed over the outer ring of clad tubes of fuel simulator. Again, to simulate partially voided condition, asymmetrical heating of pressure was carried out by supplying 8.0 kW power to upper 8 pins of fuel simulator and temperature profiles were measured. Along the circumference of pressure tube (PT) the highest temperature difference of 320 °C was observed, which highlights the magnitude of thermal stresses under partially voided conditions.
Abstract: This paper presents a 24 watts SEPIC converter design
and control using microprocessor. SEPIC converter has advantages of
a wide input range and miniaturization caused by the low stress at
elements. There is also an advantage that the input and output are
isolated in MOSFET-off state. This paper presents the PID control
through the SEPIC converter transfer function using a DSP and the
protective circuit for fuel cell from the over-current and
inverse-voltage by using the characteristic of SEPIC converter. Then it
derives them through the experiments.
Abstract: Hydrogenated biodiesel is one of the most promising
renewable fuels. It has many advantages over conventional biodiesel,
including higher cetane number, higher heating value, lower
viscosity, and lower corrosiveness due to its absence of oxygen.
From previous work, Pd/TiO2 gave high conversion and selectivity in
hydrogenated biodiesel. In this work, the effect of biomass feedstocks
(i.e. beef fat, chicken fat, pork fat, and jatropha oil) on the production
of hydrogenated biodiesel over Pd/TiO2 has been studied. Biomass
feedstocks were analyzed by ICP-OES (inductively coupled plasma
optical emission spectrometry) to identify the content of impurities
(i.e. P, K, Ca, Na, and Mg). The deoxygenation catalyst, Pd/TiO2,
was prepared by incipient wetness impregnation (IWI) and tested in a
continuous flow packed-bed reactor at 500 psig, 325°C, H2/feed
molar ratio of 30, and LHSV of 4 h-1 for its catalytic activity and
selectivity in hydrodeoxygenation. All feedstocks gave high
selectivity in diesel specification range hydrocarbons and the main
hydrocarbons were n-pentadecane (n-C15) and n-heptadecane (n-
C17), resulting from the decarbonylation/decarboxylation reaction.
Intermediates such as oleic acid, stearic acid, palmitic acid, and esters
were also detected in minor amount. The conversion of triglycerides
in jatropha oil is higher than those of chicken fat, pork fat, and beef
fat, respectively. The higher concentration of metal impurities in
feedstock, the lower conversion of feedstock.
Abstract: This study describes the preparation of a novel proton
conducting membranes based on bacterial cellulose (BC) modified by
grafting of 2-acrylamido-2-methyl-1 -propanesulfonic acid (AMPS)
through UV-induced graft polymerization. These AMPS-g-BC
membranes have been characterized by various techniques including
FTIR, SEM and TGA, to find their successful grafting of AMPS on
BC, surface morphology and thermal stability, respectively. Physical
properties of AMPS-g-BC membranes have been assessed in terms of
Lamda value( λ ), ion exchange capacity(IEC) and proton
conductivity. The relationship between degree of grafting and AMPS
concentration used for grafting has been determined by weight gain
method. An optimum proton conductivity equal to 2.89x10-2 S cm-1
and IEC value equal to 1.79 mmol g-1 have been obtained when 20
wt% AMPS concentration is used for grafting (i.e. the corresponding
membrane is notated as AMPS20-g-BC).
Abstract: In recent years Malaysia has included renewable
energy as an alternative fuel to help in diversifying the country-s
energy reliance on oil, natural gas, coal and hydropower with
biomass and solar energy gaining priority. The scope of this paper is
to look at the designing procedures and analysis of a solar thermal
parabolic trough concentrator by simulation utilizing meteorological
data in several parts of Malaysia. Parameters which include the
aperture area, the diameter of the receiver and the working fluid may
be varied to optimize the design. Aperture area is determined by
considering the width and the length of the concentrator whereas the
geometric concentration ratio (CR) is obtained by considering the
width and diameter of the receiver. Three types of working fluid are
investigated. Theoretically, concentration ratios can be very high in
the range of 10 to 40 000 depending on the optical elements used and
continuous tracking of the sun. However, a thorough analysis is
essential as discussed in this paper where optical precision and
thermal analysis must be carried out to evaluate the performance of
the parabolic trough concentrator as the theoretical CR is not the only
factor that should be considered.
Abstract: The mixture formation prior to the ignition process
plays as a key element in the diesel combustion. Parametric studies of
mixture formation and ignition process in various injection parameter
has received considerable attention in potential for reducing
emissions. Purpose of this study is to clarify the effects of injection
pressure on mixture formation and ignition especially during ignition
delay period, which have to be significantly influences throughout the
combustion process and exhaust emissions. This study investigated
the effects of injection pressure on diesel combustion fundamentally
using rapid compression machine. The detail behavior of mixture
formation during ignition delay period was investigated using the
schlieren photography system with a high speed camera. This method
can capture spray evaporation, spray interference, mixture formation
and flame development clearly with real images. Ignition process and
flame development were investigated by direct photography method
using a light sensitive high-speed color digital video camera. The
injection pressure and air motion are important variable that strongly
affect to the fuel evaporation, endothermic and prolysis process
during ignition delay. An increased injection pressure makes spray tip
penetration longer and promotes a greater amount of fuel-air mixing
occurs during ignition delay. A greater quantity of fuel prepared
during ignition delay period thus predominantly promotes more rapid
heat release.
Abstract: Combustion of sprays is of technological importance, but its flame behavior is not fully understood. Furthermore, the multiplicity of dependent variables such as pressure, temperature, equivalence ratio, and droplet sizes complicates the study of spray combustion. Fundamental study on the influence of the presence of liquid droplets has revealed that laminar flames within aerosol mixtures more readily become unstable than for gaseous ones and this increases the practical burning rate. However, fundamental studies on turbulent flames of aerosol mixtures are limited particularly those under near mono-dispersed droplet conditions. In the present work, centrally ignited expanding flames at near atmospheric pressures are employed to quantify the burning rates in gaseous and aerosol flames. Iso-octane-air aerosols are generated by expansion of the gaseous pre-mixture to produce a homogeneously distributed suspension of fuel droplets. The effects of the presence of droplets and turbulence velocity in relation to the burning rates of the flame are also investigated.
Abstract: Fuel cell's system requires regulating circuit for
voltage and current in order to control power in case of connecting to
other generative devices or load. In this paper Fuel cell system and
convertor, which is a multi-variable system, are controlled using
sliding mode method. Use of weighting matrix in design procedure
made it possible to regulate speed of control. Simulation results show
the robustness and accuracy of proposed controller for controlling
desired of outputs.
Abstract: The fuel cost of the motor vehicle operating on its
common route is an important part of the operating cost. Therefore,
the importance of the fuel saving is increasing day by day. One of the
parameters which improve fuel saving is the regulation of driving
characteristics. The number and duration of stop is increased by the
heavy traffic load. It is possible to improve the fuel saving with
regulation of traffic flow and driving characteristics. The researches
show that the regulation of the traffic flow decreases fuel
consumption, but it is not enough to improve fuel saving without the
regulation of driving characteristics. This study analyses the fuel
consumption of two trips of city bus operating on its common route
and determines the effect of traffic density and driving characteristics
on fuel consumption. Finally it offers some suggestions about
regulation of driving characteristics to improve the fuel saving. Fuel
saving is determined according to the results obtained from
simulation program. When experimental and simulation results are
compared, it has been found that the fuel saving was reached up the
to 40 percent ratios.
Abstract: This paper presents an optimization of the hull
separation, i.e. transverse clearance. The main objective is to identify
the feasible speed ranges and find the optimum transverse clearance
considering the minimum wave-making resistance. The dimensions
and the weight of hardware systems installed in the catamaran
structured fuel cell powered USV (Unmanned Surface Vehicle) were
considered as constraints. As the CAE (Computer Aided Engineering)
platform FRIENDSHIP-Framework was used. The hull surface
modeling, DoE (Design of Experiment), Tangent search optimization,
tool integration and the process automation were performed by
FRIENDSHIP-Framework. The hydrodynamic result was evaluated
by XPAN the potential solver of SHIPFLOW.
Abstract: The Long-range Energy and Alternatives Planning (LEAP) energy planning system has been developed for South Africa, for the 2005 base year and a limited number of plausible future scenarios that may have significant implications (negative or positive) in terms of environmental impacts. The system quantifies the national energy demand for the domestic, commercial, transport, industry and agriculture sectors, the supply of electricity and liquid fuels, and the resulting emissions. The South African National Energy Research Institute (SANERI) identified the need to develop an environmental assessment tool, based on the LEAP energy planning system, to provide decision-makers and stakeholders with the necessary understanding of the environmental impacts associated with different energy scenarios. A comprehensive analysis of indicators that are used internationally and in South Africa was done and the available data was accessed to select a reasonable number of indicators that could be utilized in energy planning. A consultative process was followed to determine the needs of different stakeholders on the required indicators and also the most suitable form of reporting. This paper demonstrates the application of Energy Environmental Sustainability Indicators (EESIs) as part of the developed tool, which assists with the identification of the environmental consequences of energy generation and use scenarios and thereby promotes sustainability, since environmental considerations can then be integrated into the preparation and adoption of policies, plans, programs and projects. Recommendations are made to refine the tool further for South Africa.
Abstract: Petrol Fuel Station (PFS) has potential hazards to the
people, asset, environment and reputation of an operating company.
Fire hazards, static electricity air pollution evoked by aliphatic and
aromatic organic compounds are major causes of accident/incident
occurrence at fuel station. Activities such as carelessness,
maintenance, housekeeping, slips trips and falls, transportation
hazard, major and minor injuries, robbery and snake bites has a
potential to create unsafe conditions. The level of risk of these
hazards varies according to location and country. The emphasis on
safety considerations by the government is variable all around the
world. Developed countries safety records are much better as
compared to developing countries safety statistics. There is no
significant approach available to highlight the unsafe acts and unsafe
conditions during operation and maintenance of fuel station. Fuel
station is the most commonly available facilities that contain
flammable and hazardous materials. Due to continuous operation of
fuel station they pose various hazards to people, environment and
assets of an organization. To control these hazards, there is a need for
specific approach. PFS operation is unique as compared to other
businesses. For smooth operations it demands an involvement of
operating company, contractor and operator group. This study will
focus to address hazard contributing factors that have a potential to
make PFS operation risky. One year data collected, 902 activities
analyzed, comparisons were made to highlight significant
contributing factors. The study will provide help and assistance to
PFS outlet marketing companies to make their fuel station operation
safer. It will help health safety and environment (HSE) professionals
to arrest the gap available related to safety matters at PFS.
Abstract: This paper describes the experimental efficiency of a
compact organic Rankine cycle (ORC) system with a compact
rotary-vane-type expander. The compact ORC system can be used for
power generation from low-temperature heat sources such as waste
heat from various small-scale heat engines, fuel cells, electric devices,
and solar thermal energy. The purpose of this study is to develop an
ORC system with a low power output of less than 1 kW with a hot
temperature source ranging from 60°C to 100°C and a cold
temperature source ranging from 10°C to 30°C. The power output of
the system is rather less due to limited heat efficiency. Therefore, the
system should have an economically optimal efficiency. In order to
realize such a system, an efficient and low-cost expander is
indispensable. An experimental ORC system was developed using the
rotary-vane-type expander which is one of possible candidates of the
expander. The experimental results revealed the expander
performance for various rotation speeds, expander efficiencies, and
thermal efficiencies. Approximately 30 W of expander power output
with 48% expander efficiency and 4% thermal efficiency with a
temperature difference between the hot and cold sources of 80°C was
achieved.
Abstract: The rapidly increasing costs of power line extensions
and fossil fuel, combined with the desire to reduce carbon dioxide
emissions pushed the development of hybrid power system suited for
remote locations, the purpose in mind being that of autonomous local
power systems. The paper presents the suggested solution for a “high
penetration" hybrid power system, it being determined by the
location of the settlement and its “zero policy" on carbon dioxide
emissions. The paper focuses on the technical solution and the power
flow management algorithm of the system, taking into consideration
local conditions of development.
Abstract: Economic dispatch (ED) is considered to be one of the
key functions in electric power system operation. This paper presents
a new hybrid approach based genetic algorithm (GA) to economic
dispatch problems. GA is most commonly used optimizing algorithm
predicated on principal of natural evolution. Utilization of chaotic
queue with GA generates several neighborhoods of near optimal
solutions to keep solution variation. It could avoid the search process
from becoming pre-mature. For the objective of chaotic queue
generation, utilization of tent equation as opposed to logistic equation
results in improvement of iterative speed. The results of the proposed
approach were compared in terms of fuel cost, with existing
differential evolution and other methods in literature.