Abstract: Investigations of the unimolecular decomposition of
vinyl ethyl ether (VEE), vinyl propyl ether (VPE) and vinyl butyl
ether (VBE) have shown that activation of the molecule of a ether
results in formation of a cyclic construction - the transition state (TS),
which may lead to the displacement of the thermodynamic
equilibrium towards the reaction products. The TS is obtained by
applying energy minimization relative to the ground state of an ether
under the program MM2 when taking into account the hydrogen bond
formation between a hydrogen atom of alkyl residue and the extreme
atom of carbon of the vinyl group. The dissociation of TS up to the
products is studied by energy minimization procedure using the
mathematical program Gaussian. The obtained calculation data for
VEE testify that the decomposition of this ether may be conditioned
by hydrogen bond formation for two possible versions: when α- or β-
hydrogen atoms of the ethyl group are bound to carbon atom of the
vinyl group. Applying the same calculation methods to other ethers
(VPE and VBE) it is shown that only in the case of hydrogen bonding
between α-hydrogen atom of the alkyl residue and the extreme atom
of carbon of the vinyl group (αH---C) results in decay of theses
ethers.
Abstract: Indium-tin oxide films are deposited by low plasma
temperature RF sputtering on highly flexible modification of glycol
polyethyleneterephtalate substrates. The produced layers are
characterized with transparency over 82 % and sheet resistance of
86.9 Ω/square. The film’s conductivity was further improved by
additional UV illumination from light source (365 nm), having power
of 250 W. The influence of the UV exposure dose on the structural
and electro-optical properties of ITO was investigated. It was
established that the optimum time of illumination is 10 minutes and
further UV treatment leads to polymer substrates degradation.
Structural and bonds type analysis show that at longer treatment
carbon atoms release and diffuse into ITO films, which worsen their
electrical behavior. For the optimum UV dose the minimum sheet
resistance was measured to be 19.2 Ω/square, and the maximum
transparency remained almost unchanged – above 82 %.
Abstract: The storage of thermal energy as a latent heat of phase
change material (PCM) has created considerable interest among
researchers in recent times. Here, an attempt is made to carry out
numerical investigations to analyze the performance of latent heat
storage units (LHSU) employing phase change material. The
mathematical model developed is based on an enthalpy formulation.
Freezing time of PCM packed in three different shaped containers
viz. rectangular, cylindrical and cylindrical shell is compared. The
model is validated with the results available in the literature. Results
show that for the same mass of PCM and surface area of heat
transfer, cylindrical shell container takes the least time for freezing
the PCM and this geometric effect is more pronounced with an
increase in the thickness of the shell than that of length of the shell.
Abstract: The fundamental aim of extended expansion concept is
to achieve higher work done which in turn leads to higher thermal
efficiency. This concept is compatible with the application of
turbocharger and LHR engine. The Low Heat Rejection engine was
developed by coating the piston crown, cylinder head inside with
valves and cylinder liner with partially stabilized zirconia coating of
0.5 mm thickness. Extended expansion in diesel engines is termed as
Miller cycle in which the expansion ratio is increased by reducing the
compression ratio by modifying the inlet cam for late inlet valve
closing. The specific fuel consumption reduces to an appreciable level
and the thermal efficiency of the extended expansion turbocharged
LHR engine is improved.
In this work, a thermodynamic model was formulated and
developed to simulate the LHR based extended expansion
turbocharged direct injection diesel engine. It includes a gas flow
model, a heat transfer model, and a two zone combustion model. Gas
exchange model is modified by incorporating the Miller cycle, by
delaying inlet valve closing timing which had resulted in considerable
improvement in thermal efficiency of turbocharged LHR engines. The
heat transfer model, calculates the convective and radiative heat
transfer between the gas and wall by taking into account of the
combustion chamber surface temperature swings. Using the two-zone
combustion model, the combustion parameters and the chemical
equilibrium compositions were determined. The chemical equilibrium
compositions were used to calculate the Nitric oxide formation rate by
assuming a modified Zeldovich mechanism. The accuracy of this
model is scrutinized against actual test results from the engine. The
factors which affect thermal efficiency and exhaust emissions were
deduced and their influences were discussed. In the final analysis it is
seen that there is an excellent agreement in all of these evaluations.
Abstract: In this paper, we present an innovative scheme of
blindly extracting message bits from an image distorted by an attack.
Support Vector Machine (SVM) is used to nonlinearly classify the
bits of the embedded message. Traditionally, a hard decoder is used
with the assumption that the underlying modeling of the Discrete
Cosine Transform (DCT) coefficients does not appreciably change.
In case of an attack, the distribution of the image coefficients is
heavily altered. The distribution of the sufficient statistics at the
receiving end corresponding to the antipodal signals overlap and a
simple hard decoder fails to classify them properly. We are
considering message retrieval of antipodal signal as a binary
classification problem. Machine learning techniques like SVM is
used to retrieve the message, when certain specific class of attacks is
most probable. In order to validate SVM based decoding scheme, we
have taken Gaussian noise as a test case. We generate a data set using
125 images and 25 different keys. Polynomial kernel of SVM has
achieved 100 percent accuracy on test data.
Abstract: This research proposed a new design of helmet-shaped
array transcranial magnetic stimulation coil system. It was constructed
using several sagittal directional wires and several coronal directional
wires. By varying the current direction and strength on each wire, this
array coil system could be constructed into the circular coil and
figure-eight coil of different size. Also, this proposed coil system can
flexibly not only change the stimulation location, range, type and
strength, but also change the shape and the channel number of coil
dynamically.
Abstract: Image compression is one of the most important
applications Digital Image Processing. Advanced medical imaging
requires storage of large quantities of digitized clinical data. Due to
the constrained bandwidth and storage capacity, however, a medical
image must be compressed before transmission and storage. There
are two types of compression methods, lossless and lossy. In Lossless
compression method the original image is retrieved without any
distortion. In lossy compression method, the reconstructed images
contain some distortion. Direct Cosine Transform (DCT) and Fractal
Image Compression (FIC) are types of lossy compression methods.
This work shows that lossy compression methods can be chosen for
medical image compression without significant degradation of the
image quality. In this work DCT and Fractal Compression using
Partitioned Iterated Function Systems (PIFS) are applied on different
modalities of images like CT Scan, Ultrasound, Angiogram, X-ray
and mammogram. Approximately 20 images are considered in each
modality and the average values of compression ratio and Peak
Signal to Noise Ratio (PSNR) are computed and studied. The quality
of the reconstructed image is arrived by the PSNR values. Based on
the results it can be concluded that the DCT has higher PSNR values
and FIC has higher compression ratio. Hence in medical image
compression, DCT can be used wherever picture quality is preferred
and FIC is used wherever compression of images for storage and
transmission is the priority, without loosing picture quality
diagnostically.
Abstract: In this era of technology, fueled by the pervasive usage of the internet, security is a prime concern. The number of new attacks by the so-called “bots", which are automated programs, is increasing at an alarming rate. They are most likely to attack online registration systems. Technology, called “CAPTCHA" (Completely Automated Public Turing test to tell Computers and Humans Apart) do exist, which can differentiate between automated programs and humans and prevent replay attacks. Traditionally CAPTCHA-s have been implemented with the challenge involved in recognizing textual images and reproducing the same. We propose an approach where the visual challenge has to be read out from which randomly selected keywords are used to verify the correctness of spoken text and in turn detect the presence of human. This is supplemented with a speaker recognition system which can identify the speaker also. Thus, this framework fulfills both the objectives – it can determine whether the user is a human or not and if it is a human, it can verify its identity.
Abstract: Numerical studies have been carried out using a two
dimensional code to examine the influence of pressure / thrust
transient of solid propellant rockets at liftoff. This code solves
unsteady Reynolds-averaged thin-layer Navier–Stokes equations by
an implicit LU-factorization time-integration method. The results
from the parametric study indicate that when the port is narrow there
is a possibility of increase in pressure / thrust-rise rate due to
relatively high flame spread rate. Parametric studies further reveal
that flame spread rate can be altered by altering the propellant
properties, igniter jet characteristics and nozzle closure burst pressure
without altering the grain configuration and/or the mission
demanding thrust transient. We observed that when the igniter
turbulent intensity is relatively low the vehicle could liftoff early due
to the early flow choking of the rocket nozzle. We concluded that the
high pressurization-rate has structural implications at liftoff in
addition to transient burning effect. Therefore prudent selection of the
port geometry and the igniter, for meeting the mission requirements,
within the given envelop are meaningful objectives for any designer
for the smooth liftoff of solid propellant rockets.
Abstract: Now a days, a significant part of commercial and governmental organisations like museums, cultural organizations, libraries, commercial enterprises, etc. invest intensively in new technologies for image digitization, digital libraries, image archiving and retrieval. Hence image authorization, authentication and security has become prime need. In this paper, we present a semi-fragile watermarking scheme for color images. The method converts the host image into YIQ color space followed by application of orthogonal dual domains of DCT and DWT transforms. The DCT helps to separate relevant from irrelevant image content to generate silent image features. DWT has excellent spatial localisation to help aid in spatial tamper characterisation. Thus image adaptive watermark is generated based of image features which allows the sharp detection of microscopic changes to locate modifications in the image. Further, the scheme utilises the multipurpose watermark consisting of soft authenticator watermark and chrominance watermark. Which has been proved fragile to some predefined processing like intentinal fabrication of the image or forgery and robust to other incidental attacks caused in the communication channel.
Abstract: The volume of XML data exchange is explosively
increasing, and the need for efficient mechanisms of XML data
management is vital. Many XML storage models have been proposed
for storing XML DTD-independent documents in relational database
systems. Benchmarking is the best way to highlight pros and cons of
different approaches. In this study, we use a common benchmarking
scheme, known as XMark to compare the most cited and newly
proposed DTD-independent methods in terms of logical reads,
physical I/O, CPU time and duration. We show the effect of Label
Path, extracting values and storing in another table and type of join
needed for each method-s query answering.
Abstract: This paper presents an application of Artificial Neural Network (ANN) to forecast actual cost of a project based on the earned value management system (EVMS). For this purpose, some projects randomly selected based on the standard data set , and it is produced necessary progress data such as actual cost ,actual percent complete , baseline cost and percent complete for five periods of project. Then an ANN with five inputs and five outputs and one hidden layer is trained to produce forecasted actual costs. The comparison between real and forecasted data show better performance based on the Mean Absolute Percentage Error (MAPE) criterion. This approach could be applicable to better forecasting the project cost and result in decreasing the risk of project cost overrun, and therefore it is beneficial for planning preventive actions.
Abstract: Today, node-disjoint routing becomes inessential
technique in communication of packets among various nodes in
networks. Meanwhile AODV (Ad Hoc On-demand Multipath
Distance Vector) creates single-path route between a pair of source
and destination nodes. Some researches has done so far to make
multipath node-disjoint routing based on AODV protocol. But
however their overhead and end-to-end delay are relatively high,
while the detail of their code is not available too. This paper proposes
a new approach of multipath node-disjoint routing based on AODV
protocol. Then the algorithm of analytical model is presented. The
extensive results of this algorithm will be presented in the next paper.
Abstract: This paper deals with the application of a fuzzy set in
measuring teachers- beliefs about mathematics. The vagueness of
beliefs was transformed into standard mathematical values using a
fuzzy preferences model. The study employed a fuzzy approach
questionnaire which consists of six attributes for measuring
mathematics teachers- beliefs about mathematics. The fuzzy conjoint
analysis approach based on fuzzy set theory was used to analyze the
data from twenty three mathematics teachers from four secondary
schools in Terengganu, Malaysia. Teachers- beliefs were recorded in
form of degrees of similarity and its levels of agreement. The
attribute 'Drills and practice is one of the best ways of learning
mathematics' scored the highest degree of similarity at 0. 79860 with
level of 'strongly agree'. The results showed that the teachers- beliefs
about mathematics were varied. This is shown by different levels of
agreement and degrees of similarity of the measured attributes.
Abstract: International competitiveness receives much attention
nowadays, but up to now its assessment has been heavily based on
manufacturing industry statistics. This paper addresses the need for
competitiveness indicators that cover the service sector and sets out a
multilevel framework for measuring international services trade
competitiveness. The approach undertaken here aims at
comparatively examining the international competitiveness of the
EU-25 (the twenty-five European Union member states before the 1st
of January 2007), Romanian and Bulgarian services trade, as well as
the last two countries- structure of specialization on the EU-25
services market. The primary changes in the international
competitiveness of three major services sectors – transportation,
travel and other services - are analyzed. This research attempts to
determine the ability of the two recent European Union (EU) member
states to contend with the challenges that might arise from the hard
competition within the enlarged EU, in the field of services trade.
Abstract: In this paper we apply an Adaptive Network-Based
Fuzzy Inference System (ANFIS) with one input, the dependent
variable with one lag, for the forecasting of four macroeconomic
variables of US economy, the Gross Domestic Product, the inflation
rate, six monthly treasury bills interest rates and unemployment rate.
We compare the forecasting performance of ANFIS with those of the
widely used linear autoregressive and nonlinear smoothing transition
autoregressive (STAR) models. The results are greatly in favour of
ANFIS indicating that is an effective tool for macroeconomic
forecasting used in academic research and in research and application
by the governmental and other institutions
Abstract: In this paper, a multi-branch power line is modeled using ABCD matrix to show its worth as a communication channel. The model is simulated using MATLAB in an effort to investigate the effects of multiple loading, multipath, and those as a result of load mismatching. The channel transfer function is obtained and investigated using different cable lengths, and different number of bridge taps under given loading conditions.
Abstract: Bacterial molecular chaperone DnaK plays an essential role in protein folding, stress response and transmembrane targeting of proteins. DnaKs from many bacterial species, including Escherichia coli, Salmonella typhimurium and Haemophilus infleunzae are the molecular targets for the insect-derived antimicrobial peptide pyrrhocoricin. Pyrrhocoricin-like peptides bind in the substrate recognition tunnel. Despite the high degree of crossspecies sequence conservation in the substrate-binding tunnel, some bacteria are not sensitive to pyrrhocoricin. This work addresses the molecular mechanism of resistance of Helicobacter pylori DnaK to pyrrhocoricin. Homology modelling, structural and sequence analysis identify a single aminoacid substitution at the interface between the lid and the β-sandwich subdomains of the DnaK substrate-binding domain as the major determinant for its resistance.
Abstract: Buoyancy driven heat transfer of nanofluids in a
cylindrical enclosure used as a control unit in the subsea hydrocarbon
injection wells is investigated in this study. The governing equations
obtained with the Boussinesq approximation are solved using Comsol
Multiphysics finite element analysis and simulation software. The
base fluid is water and CuO is used as nanoparticles. Solution is
obtained for nanoparticle solid volume fraction of 8% and for
Rayleigh number in the range of 105-107. The results show that
nanoparticle usage in the cylindrical electronic control unit has a
significant effect on the flow and heat transfer.
Abstract: In this paper we use the property of co-occurrence
matrix in finding parallel lines in binary pictures for fingerprint
identification. In our proposed algorithm, we reduce the noise by
filtering the fingerprint images and then transfer the fingerprint
images to binary images using a proper threshold. Next, we divide
the binary images into some regions having parallel lines in the same
direction. The lines in each region have a specific angle that can be
used for comparison. This method is simple, performs the
comparison step quickly and has a good resistance in the presence of
the noise.