Abstract: The world economic crises and budget constraints
have caused authorities, especially those in developing countries, to
rationalize water quality monitoring activities. Rationalization
consists of reducing the number of monitoring sites, the number of
samples, and/or the number of water quality variables measured. The
reduction in water quality variables is usually based on correlation. If
two variables exhibit high correlation, it is an indication that some of
the information produced may be redundant. Consequently, one
variable can be discontinued, and the other continues to be measured.
Later, the ordinary least squares (OLS) regression technique is
employed to reconstitute information about discontinued variable by
using the continuously measured one as an explanatory variable. In
this paper, two record extension techniques are employed to
reconstitute information about discontinued water quality variables,
the OLS and the Line of Organic Correlation (LOC). An empirical
experiment is conducted using water quality records from the Nile
Delta water quality monitoring network in Egypt. The record
extension techniques are compared for their ability to predict
different statistical parameters of the discontinued variables. Results
show that the OLS is better at estimating individual water quality
records. However, results indicate an underestimation of the variance
in the extended records. The LOC technique is superior in preserving
characteristics of the entire distribution and avoids underestimation
of the variance. It is concluded from this study that the OLS can be
used for the substitution of missing values, while LOC is preferable
for inferring statements about the probability distribution.
Abstract: The production of devices in nanoscale with specific
molecular rectifying function is one of the most significant goals in
state-of-art technology. In this work we show by ab initio quantum
mechanics calculations coupled with non-equilibrium Green
function, the design of an organic two-terminal device. These
molecular structures have molecular source and drain with several
bridge length (from five up to 11 double bonds). Our results are
consistent with significant features as a molecular rectifier and can be
raised up as: (a) it can be used as bi-directional symmetrical rectifier;
(b) two devices integrated in one (FET with one operational region,
and Thyristor thiristor); (c) Inherent stability due small intrinsic
capacitance under forward/reverse bias. We utilize a scheme for the
transport mechanism based on previous properties of ¤Ç bonds type
that can be successfully utilized to construct organic nanodevices.
Abstract: The quantitative determination of several trace
elements (Cr, As, Se, Cd, Hg, Pb) existing as inorganic impurities in
some oriental herb-products such as Lingzhi Mushroom capsules,
Philamin powder, etc using ICP-MS has been studied. Various
instrumental parameters such as power, gas flow rate, sample depth, as
well as the concentration of nitric acid and thick background due to
high concentration of possible interferences on the determination of
these above-mentioned elements was investigated and the optimum
working conditions of the sample measurement on ICP-MS
(Agilent-7500a) were reported. Appropriate isotope internal standards
were also used to improve the accuracy of mercury determination.
Optimal parameters for sampling digestion were also investigated. The
recovery of analytical procedure was examined by using a Certified
Reference Material (IAEA-CRM 359). The recommended procedure
was then applied for the quantitative determination of Cr, As, Se, Cd,
Hg, Pb in Lingzhi Mushroom capsule, and Philamine powder samples.
The reproducibility of sample measurement (average value between
94 and 102%) and the uncertainty of analytical data (less than 20%)
are acceptable.
Abstract: In this study Vitaton (an organic supplement which
contains fermentative β-carotene) and synthetic astaxanthin
(CAROPHYLL® Pink) were evaluated as pro-growth factors in
Rainbow trout diet. An 8 week feeding trial was conducted to
determine the effects of Vitaton versus astaxanthin on rearing factors,
survival rate and visual flesh color of Rainbow trout
(Oncorhnchynchus mykiss) with initial weight of 196±5. Four
practical diets were formulated to contain 50 and 80 (ppm) of β-
carotene and astaxanthin and also a control diet was prepared without
any pigment. Each diet was fed to triplicate groups of fish rearing in
fresh water. Fish were fed twice daily. The water temperature
fluctuated from 12 to 15 (C˚) and also dissolved oxygen content was
between 7 to 7.5 (mg/lit) during the experimental period. At the end
of the experiment, growth and food utilization parameters and
survival rate were unaffected by dietary treatments (p>0.05). Also,
there was no significant difference between carcass yield within
treatments (p>0.05). No significant difference recognized between
visual flesh color (SalmoFan score) of fish fed Vitaton-containing
diets. On the contrary, feeding on diets containing 50 and 80 (ppm)
of astaxanthin, increased SalmoFan score (flesh astaxanthin
concentration) from
Abstract: General as well as the MSW management in Thailand is reviewed in this paper. Topics include the MSW generation, sources, composition, and trends. The review, then, moves to sustainable solutions for MSW management, sustainable alternative approaches with an emphasis on an integrated MSW management. Information of waste in Thailand is also given at the beginning of this paper for better understanding of later contents. It is clear that no one single method of MSW disposal can deal with all materials in an environmentally sustainable way. As such, a suitable approach in MSW management should be an integrated approach that could deliver both environmental and economic sustainability. With increasing environmental concerns, the integrated MSW management system has a potential to maximize the useable waste materials as well as produce energy as a by-product. In Thailand, the compositions of waste (86%) are mainly organic waste, paper, plastic, glass, and metal. As a result, the waste in Thailand is suitable for an integrated MSW management. Currently, the Thai national waste management policy starts to encourage the local administrations to gather into clusters to establish central MSW disposal facilities with suitable technologies and reducing the disposal cost based on the amount of MSW generated.
Abstract: Petrol Fuel Station (PFS) has potential hazards to the
people, asset, environment and reputation of an operating company.
Fire hazards, static electricity air pollution evoked by aliphatic and
aromatic organic compounds are major causes of accident/incident
occurrence at fuel station. Activities such as carelessness,
maintenance, housekeeping, slips trips and falls, transportation
hazard, major and minor injuries, robbery and snake bites has a
potential to create unsafe conditions. The level of risk of these
hazards varies according to location and country. The emphasis on
safety considerations by the government is variable all around the
world. Developed countries safety records are much better as
compared to developing countries safety statistics. There is no
significant approach available to highlight the unsafe acts and unsafe
conditions during operation and maintenance of fuel station. Fuel
station is the most commonly available facilities that contain
flammable and hazardous materials. Due to continuous operation of
fuel station they pose various hazards to people, environment and
assets of an organization. To control these hazards, there is a need for
specific approach. PFS operation is unique as compared to other
businesses. For smooth operations it demands an involvement of
operating company, contractor and operator group. This study will
focus to address hazard contributing factors that have a potential to
make PFS operation risky. One year data collected, 902 activities
analyzed, comparisons were made to highlight significant
contributing factors. The study will provide help and assistance to
PFS outlet marketing companies to make their fuel station operation
safer. It will help health safety and environment (HSE) professionals
to arrest the gap available related to safety matters at PFS.
Abstract: Vermiculite was used to develop inorganic
carrier-based formulations of fluorescent pseudomonad strains
R62 and R81. The effect of bio-inoculation of fluorescent
pseudomonad strains R62 and R81 (plant growth promoting
and biocontrol agent) on growth responses of Vigna-mungo
under field condition was enumerated. The combined bioinoculation
of these two organisms in a formuation increased
the pods yield by 300% in comparison to the control crop.
There was also significant increment in the other plant growth
responses such as dry root weight, dry shoot weight, shoot
length and number of branches per plant.
Abstract: Compared to oil production from microorganisms, little work has been performed for mixed culture of microalgae and yeast. In this article it is aimed to show high oil accumulation potential of mixed culture of microalgae Chlorella sp. KKU-S2 and oleaginous yeast Torulaspora maleeae Y30 using sugarcane molasses as substrate. The monoculture of T. maleeae Y30 grew faster than that of microalgae Chlorella sp. KKU-S2. In monoculture of yeast, a biomass of 6.4g/L with specific growth rate (m) of 0.265 (1/d) and lipid yield of 0.466g/L were obtained, while 2.53g/L of biomass with m of 0.133 (1/d) and lipid yield of 0.132g/L were obtained for monoculture of Chlorella sp. KKU-S2. The biomass concentration in the mixed culture of T. maleeae Y30 with Chlorella sp. KKU-S2 increased faster and was higher compared with that in the monoculture and mixed culture of microalgae. In mixed culture of microalgae Chlorella sp. KKU-S2 and C. vulgaris TISTR8580, a biomass of 3.47g/L and lipid yield of 0.123 g/L were obtained. In mixed culture of T. maleeae Y30 with Chlorella sp. KKU-S2, a maximum biomass of 7.33 g/L and lipid yield of 0.808g/L were obtained. Maximum cell yield coefficient (YX/S, 0.229g/L), specific yield of lipid (YP/X, 0.11g lipid/g cells) and volumetric lipid production rate (QP, 0.115 g/L/d) were obtained in mixed culture of yeast and microalgae. Clearly, T. maleeae Y30 and Chlorella sp. KKU-S2 use sugarcane molasses as organic nutrients efficiently in mixed culture under mixotrophic growth. The biomass productivity and lipid yield are notably enhanced in comparison with monoculture.
Abstract: This paper describes the experimental efficiency of a
compact organic Rankine cycle (ORC) system with a compact
rotary-vane-type expander. The compact ORC system can be used for
power generation from low-temperature heat sources such as waste
heat from various small-scale heat engines, fuel cells, electric devices,
and solar thermal energy. The purpose of this study is to develop an
ORC system with a low power output of less than 1 kW with a hot
temperature source ranging from 60°C to 100°C and a cold
temperature source ranging from 10°C to 30°C. The power output of
the system is rather less due to limited heat efficiency. Therefore, the
system should have an economically optimal efficiency. In order to
realize such a system, an efficient and low-cost expander is
indispensable. An experimental ORC system was developed using the
rotary-vane-type expander which is one of possible candidates of the
expander. The experimental results revealed the expander
performance for various rotation speeds, expander efficiencies, and
thermal efficiencies. Approximately 30 W of expander power output
with 48% expander efficiency and 4% thermal efficiency with a
temperature difference between the hot and cold sources of 80°C was
achieved.
Abstract: In this article, a high vacuum system for the evaporation of organic semiconductors is introduced and a mathematical model is given. Based on the exact input output linearization a deposition rate controller is designed and tested with different evaporation materials.
Abstract: Environmental contamination is a common problem in ex-industrial and industrial sites. This article gives a brief description of general applied environmental investigation methodologies and possible remediation applications in Latvia. Most of contaminated areas are situated in former and active industrial, military areas and ports. Industrial and logistic activities very often have been with great impact for more than hundred years thus the contamination level with heavy metals, hydrocarbons, pesticides, persistent organic pollutants is high and is threatening health and environment in general. 242 territories now are numbered as contaminated and fixed in the National Register of contaminated territories in Latvia. Research and remediation of contamination in densely populated areas are of important environmental policy domain. Four different investigation case studies of contaminated areas are given describing the history of use, environmental quality assessment as well as planned environmental management actions. All four case study locations are situated in Riga - the capital of the Republic of Latvia. The aim of this paper is to analyze the situation and problems with management of contaminated areas in Latvia, give description of field research methods and recommendations for remediation industry based on scientific data and innovations.
Abstract: This paper discusses the development of a qualitative
simulator (abbreviated QRiOM) for predicting the behaviour of
organic chemical reactions. The simulation technique is based on the
qualitative process theory (QPT) ontology. The modelling constructs
of QPT embody notions of causality which can be used to explain the
behaviour of a chemical system. The major theme of this work is
that, in a qualitative simulation environment, students are able to
articulate his/her knowledge through the inspection of explanations
generated by software. The implementation languages are Java and
Prolog. The software produces explanation in various forms that
stresses on the causal theories in the chemical system which can be
effectively used to support learning.
Abstract: The hybrid membranes containing inorganic materials in polymer matrix are identified as a remarkable family of proton conducting hybrid electrolytes. In this work, the proton conducting inorganic/organic hybrid membranes for proton exchange membrane fuel cells (PEMFCs) were prepared using polyvinyl alcohol (PVA), tetraethoxyorthosilane (TEOS) and heteropolyacid (HPA). The synthesized hybrid membranes were characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction spectroscopy (XRD), Scanning electron microscopy (SEM) and Thermogravimetry analysis (TGA). The effects of heteropolyacid incorporation on membrane properties, including morphology and thermal stability were extensively investigated.
Abstract: Smoke from domestic wood burning has been
identified as a major contributor to air pollution, motivating detailed
emission measurements under controlled conditions. A series of
experiments was performed to characterise the emissions from wood
combustion in a fireplace and in a woodstove of two common species
of trees grown in Spain: Pyrenean oak (Quercus pyrenaica) and
black poplar (Populus nigra). Volatile organic compounds (VOCs) in
the exhaust emissions were collected in Tedlar bags, re-sampled in
sorbent tubes and analysed by thermal desorption-gas
chromatography-flame ionisation detection. Pyrenean oak presented
substantially higher emissions in the woodstove than in the fireplace,
for the majority of compounds. The opposite was observed for
poplar. Among the 45 identified species, benzene and benzenerelated
compounds represent the most abundant group, followed by
oxygenated VOCs and aliphatics. Emission factors obtained in this
study are generally of the same order than those reported for
residential experiments in the USA.
Abstract: Aiming at most of the aviation products are facing the problem of fatigue fracture in vibration environment, we makes use of the testing result of a bracket, analysis for the structure with ANSYS-Workbench, predict the life of the bracket by different ways, and compared with the testing result. With the research on analysis methods, make an organic combination of simulation analysis and testing, Not only ensure the accuracy of simulation analysis and life predict, but also make a dynamic supervision of product life process, promote the application of finite element simulation analysis in engineering practice.
Abstract: The soil moisture content is an important property of
the soil. The results of mean weekly gravimetric soil moisture
content, measured for the three soil layers within the A horizon,
showed that it was higher for the top 5 cm over the whole period of
monitoring (15/7/2004 up to 10/11/05) with the variation becoming
greater during winter time. This reflects the pattern of rainfall in
Ireland which is spread over the whole year and shows that light
rainfall events during summer time were compensated by loss
through evapotranspiration, but only in the top 5 cm of soil. This
layer had the highest porosity and highest moisture holding capacity
due to the high content of organic matter. The gravimetric soil
moisture contents of the top 5 cm and the underlying 5-15 and 15-25
cm layers show that bottom site of the Hill Field had higher soil
moisture content than the middle and top sites during the whole
period of monitoring.
Abstract: Abstract–Indoor air (VOCs) samples were collected
simultaneously from variety of indoors (e.g. living rooms, baby-s
rooms) and outdoor environments which were voluntarily selected
from the houses in which pregnant residents live throughout Ankara.
This is the first comprehensive study done in Turkey starting from
prenatal period and continued till the babies had one year old. VOCs
levels were measured over 76 homes. Air samples were collected in
Tenax TA sorbent filled tubes with active sampling method and
analyzed with Thermal Desorber and Gas Chromatography/Mass
spectrometry (TD-GC/MS). At the first sampling period in the baby-s
rooms maximum concentration of toluene was measured about
240.77μg.m-3 and in the living rooms maximum concentration of
naphthalene was 180.24μg.m-3. At the second sampling period in the
baby-s rooms maximum concentration of toluene was measured
about 144.97μg.m-3 and in the living rooms maximum concentration
of naphthalene was 247.89μg.m-3. Concentration of TVOCs in the
first period was generally higher than the second period.
Abstract: The rangelands, as one of the largest dynamic biomes
in the world, have very capabilities. Regulation of greenhouse gases
in the Earth's atmosphere, particularly carbon dioxide as the main
these gases, is one of these cases. The attention to rangeland, as
cheep and reachable resources to sequestrate the carbon dioxide,
increases after the Industrial Revolution. Rangelands comprise the
large parts of Iran as a steppic area. Rudshur (Saveh), as area index of
steppic area, was selected under three sites include long-term
exclosure, medium-term exclosure, and grazable area in order to the
capable of carbon dioxide’s sequestration of dominated species.
Canopy cover’s percentage of two dominated species (Artemisia
sieberi Besser & Stipa barbata Desf) was determined via establishing
of random 1 square meter plot. The sampling of above and below
ground biomass style was obtained by complete random. After
determination of ash percentage in the laboratory; conversion ratio of
plant biomass to organic carbon was calculated by ignition method.
Results of the paired t-test showed that the amount of carbon
sequestration in above ground and underground biomass of Artemisia
sieberi Besser & Stipa barbata Desf is different in three regions. It,
of course, hasn’t any difference between under and surface ground’s
biomass of Artemisia sieberi Besser in long-term exclosure. The
independent t-test results indicate differences between underground
biomass corresponding each other in the studied sites. Carbon
sequestration in the Stipa barbata Desf was totally more than
Artemisia sieberi Besser. Altogether, the average sequestration of the
long-term exclosure was 5.842gr/m², the medium-term exclosure was
4.115gr/m², and grazable area was 5.975gr/m² so that there isn’t
valuable statistical difference in term of total amount of carbon
sequestration to three sites.
Abstract: Land degradation is of concern in many countries. People more and more must address the problems associated with the degradation of soil properties due to man. Increasingly, organic soil amendments, such as compost are being examined for their potential use in soil restoration and for preventing soil erosion. In the Czech Republic, compost is the most used to improve soil structure and increase the content of soil organic matter. Land reclamation / restoration is one of the ways to evaluate industrially produced compost because Czech farmers are not willing to use compost as organic fertilizer. The most common use of reclamation substrates in the Czech Republic is for the rehabilitation of landfills and contaminated sites.
This paper deals with the influence of reclamation substrates (RS) with different proportions of compost and sand on selected soil properties–chemical characteristics, nitrogen bioavailability, leaching of mineral nitrogen, respiration activity and plant biomass production. Chemical properties vary proportionally with addition of compost and sand to the control variant (topsoil). The highest differences between the variants were recorded in leaching of mineral nitrogen (varies from 1.36mg dm-3 in C to 9.09mg dm-3). Addition of compost to soil improves conditions for plant growth in comparison with soil alone. However, too high addition of compost may have adverse effects on plant growth. In addition, high proportion of compost increases leaching of mineral N. Therefore, mixture of 70% of soil with 10% of compost and 20% of sand may be recommended as optimal composition of RS.
Abstract: The aim of this study was to investigate the
effectiveness of anaerobic digestion for the treatment of wool
scouring wastes. The experiments design comprised three ratios of
waste (W) to seed(S) (W:S) of 25:75, 50:50 and 75:25, corresponding
to 1.9. 1.7 and 1.5g tCOD/g TS, respectively, with or without
chemicals addition. NH4Cl was added to the reactors as a source for
nitrogen to achieve C:N:P of 420:14:3. A cationic flocculent was
added at 0.5 and 0.75% to enhance flocculation of sludge. The results
showed that the reactors that received W:S at a ratio of 25:75
produced the largest volume of biogas. The final soluble COD
(sCOD) was below the limits for discharge to the sewer system.