Abstract: Electrochemical-oxidation of Reactive Black-5 (RB- 5) was conducted for degradation using DSA type Ti/RuO2-SnO2- Sb2O5 electrode. In the study, for electro-oxidation, electrode was indigenously fabricated in laboratory using titanium as substrate. This substrate was coated using different metal oxides RuO2, Sb2O5 and SnO2 by thermal decomposition method. Laboratory scale batch reactor was used for degradation and decolorization studies at pH 2, 7 and 11. Current density (50mA/cm2) and distance between electrodes (8mm) were kept constant for all experiments. Under identical conditions, removal of color, COD and TOC at initial pH 2 was 99.40%, 55% and 37% respectively for initial concentration of 100 mg/L RB-5. Surface morphology and composition of the fabricated electrode coatings were characterized using scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX) respectively. Coating microstructure was analyzed by X-ray diffraction (XRD). Results of this study further revealed that almost 90% of oxidation occurred within 5-10 minutes.
Abstract: The effect of notch depth on the elastic new strainconcentration
factor (SNCF) of rectangular bars with single edge Unotch
under combined loading is studied here. The finite element
method (FEM) and super position technique are used in the current
study. This new SNCF under combined loading of static tension and
pure bending has been defined under triaxial stress state. The
employed specimens have constant gross thickness of 16.7 mm and
net section thickness varied to give net-to-gross thickness ratio ho/Ho
from 0.2 to 0.95. The results indicated that the elastic SNCF for
combined loading increases with increasing notch depth up to ho/Ho =
0.7 and sharply decreases with increasing notch depth. It is also
indicated that the elastic SNCF of combined loading is greater than
that of pure bending and less than that of the static tension for 0.2 ≤
ho/Ho ≤ 0.7. However, the elastic SNCF of combined loading is the
elastic SNCF for static tension and less than that of pure bending for
shallow notches (i.e. 0.8 ≤ ho/Ho ≤ 0.95).
Abstract: We numerically study the three-dimensional
magnetohydrodynamics (MHD) stability of oscillatory natural
convection flow in a rectangular cavity, with free top surface, filled
with a liquid metal, having an aspect ratio equal to A=L/H=5, and
subjected to a transversal temperature gradient and a uniform
magnetic field oriented in x and z directions. The finite volume
method was used in order to solve the equations of continuity,
momentum, energy, and potential. The stability diagram obtained in
this study highlights the dependence of the critical value of the
Grashof number Grcrit , with the increase of the Hartmann number
Ha for two orientations of the magnetic field. This study confirms
the possibility of stabilization of a liquid metal flow in natural
convection by application of a magnetic field and shows that the
flow stability is more important when the direction of magnetic field
is longitudinal than when the direction is transversal.
Abstract: Triglycerides and their derivatives are considered as viable alternatives for diesel fuels. Rice bran oil is used as diesel fuel. Highly viscous rice bran oil can be reduced by blending it with diesel fuel. The present research is aimed to investigate experimentally the performance, exhaust emission and combustion characteristics of a direct injection (DI) diesel engine, typically used in agricultural sector, over the entire load range when fuelled with rice bran oil and diesel fuel blends, RB10 (10% rice bran oil + 90% diesel fuel) to RB50. The performance, emission and combustion parameters of RB20 were found to be very close to neat diesel fuel (ND). The injector opening pressure (IOP) undoubtedly is of prime importance in diesel engine operation. Performance, emission and combustion characteristics with RB30 at enhanced IOPs are better than ND. Improved premixed heat release rate were noticed with RB30 when the IOP is enhanced.
Abstract: Modern building automation needs to deal with very
different types of demands, depending on the use of a building and the
persons acting in it. To meet the requirements of situation awareness
in modern building automation, scenario recognition becomes more
and more important in order to detect sequences of events and to react
to them properly. We present two concepts of scenario recognition
and their implementation, one based on predefined templates and the
other applying an unsupervised learning algorithm using statistical
methods. Implemented applications will be described and their advantages
and disadvantages will be outlined.
Abstract: In the present communication, stochastic comparison
of a series (parallel) system having heterogeneous components with
random lifetimes and series (parallel) system having homogeneous
exponential components with random lifetimes has been studied.
Further, conditions under which such a comparison is possible has
been established.
Abstract: Eight steel reinforced concrete beams (SRC), were
fabricated and tested under earthquake type cyclic loading. The
effectiveness of intermediate stiffeners, such as mid-span stiffener and
plastic hinge zone stiffeners, in enhancing composite action and
ductility of SRC beams was investigated. The effectiveness of
strengthened beam-to-column (SBC) and weakened beam-to-column
(WBC) connections in enhancing beam ductility was also studied. It
was found that: (1) All the specimens possessed fairly high flexural
ductility and were found adequate for structures in high seismic zones.
(2) WBC connections induced stress concentration which caused extra
damage to concrete near the flange tapering zone. This extra damage
inhibited the flexural strength development and the ductility of the
specimens with WBC connections to some extent. (3) Specimens with
SBC connections demonstrated higher flexural strength and ductility
compared to specimens with WBC connections. (4) The intermediate
stiffeners, especially combination of plastic hinge zone stiffener and
mid span stiffeners, have an obvious effect in enhancing the ductility
of the beams with SBC connection.
Abstract: The efficacy of the separate mixing of four tropical spicy and medicinal plant products: Dennettia tripetala Baker (pepper fruit), Eugenia aromatica Hook (clove), Piper guineense (Schum and Thonn) (black pepper) and Monodora myristica (Dunal) (African nut-meg) with a household vegetable oil was evaluated under tropical storage conditions for the control and reproductive performance of Dermestes maculatus (De Geer) (hide beetle) and Necroba rufipes (De Geer) (copra beetle) on African catfish, Clarias gariepinus (Burchell). Each of the plant materials was pulverized into powder and applied as a mix of 1ml of oil and plant powder at 2.5, 5.0, 7.5 and 10.0g per 100g of dried fish, and allowed to dry for 6h. Each of the four oil-mixed powder treatments evoked significant (P < 05) mortalities of the two insects compared with the control (oil only) at 1, 3 and 7 days post treatment. The oil-powder mixture dosages did not prevent insect egg hatchability but while the emergent larvae on the treated samples died, the emergent larvae in the control survived into adults. The application of oil-mixed powders effectively suppressed the emergence of the larvae of the beetles. Similarly, each of the oil-powder mixtures significantly reduced weight loss in smoked fish that were exposed to D. maculatus and N. rufipes when compared to the control (P < 05). The results of this study suggest that the plant powders rather than the domestic oil demonstrated protective ability against the fish beetles and confirm the efficacy of the plant products as pest control agents.
Abstract: Solar sunspot rotation, latitudinal bands are studied based on intelligent computation methods. A combination of image fusion method with together tree decomposition is used to obtain quantitative values about the latitudes of trajectories on sun surface that sunspots rotate around them. Daily solar images taken with SOlar and Heliospheric (SOHO) satellite are fused for each month separately .The result of fused image is decomposed with Quad Tree decomposition method in order to achieve the precise information about latitudes of sunspot trajectories. Such analysis is useful for gathering information about the regions on sun surface and coordinates in space that is more expose to solar geomagnetic storms, tremendous flares and hot plasma gases permeate interplanetary space and help human to serve their technical systems. Here sunspot images in September, November and October in 2001 are used for studying the magnetic behavior of sun.
Abstract: Mega urban transport projects (MUTPs) are
increasingly being used in urban environments to ameliorate the
problem of congestion. However, a number of problems with regard
to mega projects have been identified. In particular the seemingly
institutionalised over estimation of economic benefits and persistent
cost over runs, could mean that the wrong projects are selected, and
that the projects that are selected cost more than they should. Studies
to date have produced a number of solutions to these problems,
perhaps most notably, the various methods for the inclusion of the
private sector in project provision. However the problems have
shown significant intractability in the face of these solutions. This
paper provides a detailed examination of some of the problems
facing mega projects and then examines Foucault-s theory of
'governmentality' as a possible frame of analysis which might shed
light on the intractability of the problems that have been identified,
through an identification of the art of government in which MUTPs
occur.
Abstract: Carbon dioxide capture process has been simulated
and studied under different process conditions. It has been shown
that several process parameters such as lean amine temperature,
number of adsorber stages, number of stripper stages and stripper
pressure affect different process conditions and outputs such as
carbon dioxide removal and reboiler duty. It may be concluded that
the simulation of carbon dioxide capture process can help to estimate
the best process conditions.
Abstract: The performance of modified Fenton (MF) treatment
to promote PAH oxidation in artificially contaminated soil was
investigated in packed soil column with a hydrogen peroxide (H2O2)
delivery system simulating in situ injection. Soil samples were spiked
with phenanthrene (low molecular weight PAH) and fluoranthene
(high molecular weight PAH) to an initial concentration of 500
mg/kg dried soil each. The effectiveness of process parameters
H2O2/soil, iron/soil, chelating agent/soil weight ratios and reaction
time were studied using a 24 three level factorial design experiments.
Statistically significant quadratic models were developed using
Response Surface Methodology (RSM) for degrading PAHs from the
soil samples. Optimum operating condition was achieved at mild
range of H2O2/soil, iron/soil and chelating agent/soil weight ratios,
indicating cost efficient method for treating highly contaminated
lands.
Abstract: Few studies have been conducted on polymeric strip
and the behavior of soil retaining walls. This paper will present the
effect of frequency on the dynamic behavior of reinforced soil
retaining walls with polymeric strips. The frequency content
describes how the amplitude of a ground motion is distributed among
different frequencies. Since the frequency content of an earthquake
motion will strongly influence the effects of that motion, the
characterization of the motion cannot be completed without the
consideration of its frequency content. The maximum axial force of
reinforcements and horizontal displacement of the reinforced walls
are focused in this research. To clarify the dynamic behavior of
reinforced soil retaining walls with polymeric strips, a numerical
modeling using Finite Difference Method is benefited. As the results
indicate, the frequency of input base acceleration has an important
effect on the behavior of these structures. Because of resonant in the
system, where the frequency of the input dynamic load is equal to the
natural frequency of the system, the maximum horizontal
displacement and the maximum axial forces in polymeric strips is
occurred. Moreover, they were to increase the structure flexibility
because of the main advantages of polymeric strips; i.e. being simple
method of construction, having a homogeneous behavior with soils,
and possessing long durability, which are of great importance in
dynamic analysis.
Abstract: The aim of this paper is to study the internal
stabilization of the Bernoulli-Euler equation numerically. For this,
we consider a square plate subjected to a feedback/damping force
distributed only in a subdomain. An algorithm for obtaining an
approximate solution to this problem was proposed and implemented.
The numerical method used was the Finite Difference Method.
Numerical simulations were performed and showed the behavior of
the solution, confirming the theoretical results that have already been
proved in the literature. In addition, we studied the validation of the
numerical scheme proposed, followed by an analysis of the numerical
error; and we conducted a study on the decay of the energy associated.
Abstract: The Ni/α-Al2O3 catalysts with different amounts of La
as promoter from 0 to 4 wt % were prepared, characterized and their
catalytic activity was investigated in syngas methanation reaction.
Effects of reaction temperature and lanthanum loading on carbon
oxides conversion and methane selectivity were also studied. Adding
certain amount of lanthanum to 10Ni /α-Al2O3 catalysts can decrease
the average NiO crystallite diameter which leads to higher activity and
stability while excessive addition would cause deactivation quickly.
Stability on stream towards deactivation was observed up to 800 min
at 500 °C, 0.1MPa and 600000 mL·g-1·h-1.
Abstract: Von Willebrand-s disease is the most common
inherited bleeding disorder in humans, it
caused by qualitative abnormalities of the von Willebrand factor
(vWF). Our objective is to determine the prevalence of this disease at
part of the Algerian population in the East and the South by a
biological diagnosis based on specific biological tests (automated
platelet count, the bleeding time (TS), the time of cephalin + activator
(TCA), measure of the prothrombin rate (TP), vWF rate and factor
VIII rate, Molecular electrophoresis of vWF multimers in agarose gel
in the presence of SDS). Four patients of type III or severe
Willebrand-s disease were found on 200 suspect cases. All cases are
showed a deficit in vWF rate (< 5%), and factor VIII (P
Abstract: The purpose of this study was to explore the
demographic differences of international tourists according to three
main factors, including the value of time, shopping behavior and
shopping motivation. The Chatuchak Weekend Market is known as
one of the biggest weekend markets in the world. Too little academic
studies had been conducted in this area of weekend market, despite its
growth and continuous development. In general, both domestic
visitors and international tourists are attracted to the perception of
cheap and bargaining prices the weekend market. However, systematic
research study can provide reliable understanding of the perception of
the visitors.
This study focused on the group of international tourists who visited
the market and aimed to provide better insights based on the
differences in their demographic factors. Findings indicated that
several differences in value of time, shopping behavior, and shopping
motivation were identified by gender, income and age. Research
implications and directions for further studies were discussed.
Abstract: A study concerning the photocatalytic decolourization
of Congo red (CR) dye, over artificial UV irradiation is presented.
Photocatalysts based on a commercial titanium dioxide (TiO2)
modified with transition metals (Ni, Cu and Zn) were used. The
dopage method used was wet impregnation. A TiO2 sample without
salt was subjected to the same hydrothermal treatment to be used as
reference. Congo red solutions to several pH conditions (natural and
basic) were used to evaluate photocatalytic performance of each
doped catalysts. Photodecolourization percentage was measured
spectrofotrometically after 3 h of treatment to 499 nm as response
variable. Kinetics investigations of photodegradation indicated that
reactions obey to Langmuir-Hinshelwood model and pseudo–first
order law. The rate constant studies of photocatalytic decolourization
reactions for Zn–TiO2 and Cu–TiO2 photocatalysts indicated that in
all cases the rate constant of the reaction was higher than that of TiO2
undoped. These results show that nature of the metal modifying the
TiO2 influence on the efficiency of the photocatalyst evaluated in
process. Ni does not present an additional effect compared with TiO2,
while Zn enhances the photoactivity due to its electronic properties.
Abstract: In this study, cometabolic biodegradation of
chloroform was experimented with mixed cultures in the presence of
various organic solvents like methanol, ethanol, isopropanol, acetone,
acetonitrile and toluene as these are predominant discharges in
pharmaceutical industries. Toluene and acetone showed higher
specific chloroform degradation rate when compared to other
compounds. Cometabolic degradation of chloroform was further
confirmed by observation of free chloride ions in the medium. An
extended Haldane model, incorporating the inhibition due to
chloroform and the competitive inhibition between primary
substrates, was developed to predict the biodegradation of primary
substrates, cometabolic degradation of chloroform and the biomass
growth. The proposed model is based on the use of biokinetic
parameters obtained from single substrate degradation studies. The
model was able to satisfactorily predict the experimental results of
ternary and quaternary mixtures. The proposed model can be used for
predicting the performance of bioreactors treating discharges from
pharmaceutical industries.
Abstract: With continuous rise of oil price, how to develop alternative energy source has become a hot topic around the world. This study discussed the dynamic characteristics of an island power system operating under random wind speed lower than nominal wind
speeds of wind turbines. The system primarily consists of three diesel engine power generation systems, three constant-speed variable-pitch wind turbines, a small hydraulic induction generation system, and lumped static loads. Detailed models based on Matlab/Simulink were developed to cater for the dynamic behavior of the system. The results suggested this island power system can operate stably in this operational mode. This study can serve as an important reference for planning, operation, and further expansion of island power systems.