Abstract: Earth pressure balance (EPB) tunnel boring machines are designed for digging in different types of soil, especially clay soils. This operation requires the treatment of soil by lubricants to facilitate the procedure of excavation. A possible use of this soil is limited by the effect of treatment on the hydro-mechanical properties of the soil. This work aims to study the effect of a foaming agent on the hydro-mechanical properties of clay soil. The injection of the foam agent in the soil leads to create a soil matrix in which they are incorporated gas bubbles. The state of the foam in the soil is scalable thanks to the degradation of the gas bubbles in the soil.
Abstract: The manufacture of composite parts is a major issue in many industrial domains. Polymer composite materials are ideal for structural applications where high strength-to-weight and stiffness-to-weight ratios are required. However, exposition to extreme environment conditions (temperature, humidity) affects mechanical properties of organic composite materials and lead to an undesirable degradation. Aging mechanisms in organic matrix are very diverse and vary according to the polymer and the aging conditions such as temperature, humidity etc. This paper studies the hygrothermal aging effect on the mechanical properties of fiber reinforced plastics laminates at 40 °C in different environment exposure. Two composite materials are used to conduct the study (carbon fiber/epoxy and glass fiber/vinyl ester with two stratifications for both the materials [904/04] and [454/04]). The experimental procedure includes a mechanical characterization of the materials in a virgin state and exposition of specimens to two environments (seawater and demineralized water). Absorption kinetics for the two materials and both the stratifications are determined. Three-point bending test is performed on the aged materials in order to determine the hygrothermal effect on the mechanical properties of the materials.
Abstract: This work involves the degradation of plastic waste in the presence of three different nanocatalysts. A thin film of LLDPE was formed with all three nanocatalysts separately in the solvent. Thermo Gravimetric Analysis (TGA) and Differential Scanning Calorimetric (DSC) analysis of polymers suggest that the presence of these catalysts lowers the degradation temperature and the change mechanism of degradation. Gas chromatographic analysis was carried out for two films. In gas chromatography (GC) analysis, it was found that degradation of pure polymer produces only 32% C3/C4 hydrocarbons and 67.6% C5/C9 hydrocarbons. In the presence of these catalysts, more than 80% of polymer by weight was converted into either liquid or gaseous hydrocarbons. Change in the mechanism of degradation of polymer was observed therefore more C3/C4 hydrocarbons along with valuable feedstock are produced. Adjustment of dose of nanocatalyst, use of nano-admixtures and recycling of catalyst can make this catalytic feedstock recycling method a good tool to get sustainable environment. The obtained products can be utilized as fuel or can be transformed into other useful products. In accordance with the principles of sustainable development, chemical recycling i.e. tertiary recycling of polymers along with the reuse (zero order recycling) of plastics can be the most appropriate and promising method in this direction. The tertiary recycling is attracting much attention from the viewpoint of the energy resource.
Abstract: Textile industries cater to varied customer preferences and contribute substantially to the economy. However, these textile industries also produce a considerable amount of effluents. Prominent among these are the azo dyes which impart considerable color and toxicity even at low concentrations. Azo dyes are also used as coloring agents in food and pharmaceutical industry. Despite their applications, azo dyes are also notorious pollutants and carcinogens. Popular techniques like photo-degradation, biodegradation and the use of oxidizing agents are not applicable for all kinds of dyes, as most of them are stable to these techniques. Chemical coagulation produces a large amount of toxic sludge which is undesirable and is also ineffective towards a number of dyes. Most of the azo dyes are stable to UV-visible light irradiation and may even resist aerobic degradation. Adsorption has been the most preferred technique owing to its less cost, high capacity and process efficiency and the possibility of regenerating and recycling the adsorbent. Adsorption is also most preferred because it may produce high quality of the treated effluent and it is able to remove different kinds of dyes. However, the adsorption process is influenced by many variables whose inter-dependence makes it difficult to identify optimum conditions. The variables include stirring speed, temperature, initial concentration and adsorbent dosage. Further, the internal diffusional resistance inside the adsorbent particle leads to slow uptake of the solute within the adsorbent. Hence, it is necessary to identify optimum conditions that lead to high capacity and uptake rate of these pollutants. In this work, commercially available activated carbon was chosen as the adsorbent owing to its high surface area. A typical azo dye found in textile effluent waters, viz. the monoazo Acid Orange 10 dye (CAS: 1936-15-8) has been chosen as the representative pollutant. Adsorption studies were mainly focused at obtaining equilibrium and kinetic data for the batch adsorption process at different process conditions. Studies were conducted at different stirring speed, temperature, adsorbent dosage and initial dye concentration settings. The Full Factorial Design was the chosen statistical design framework for carrying out the experiments and identifying the important factors and their interactions. The optimum conditions identified from the experimental model were validated with actual experiments at the recommended settings. The equilibrium and kinetic data obtained were fitted to different models and the model parameters were estimated. This gives more details about the nature of adsorption taking place. Critical data required to design batch adsorption systems for removal of Acid Orange 10 dye and identification of factors that critically influence the separation efficiency are the key outcomes from this research.
Abstract: Biodiesel is widely investigated to solve the twin
problem of depletion of fossil fuel and environmental degradation.
The main objective of the present work is to compare performance,
emissions, and combustion characteristics of biodiesel derived from
cotton seed oil in a diesel engine with the baseline results of
petrodiesel fuel. Tests have been conducted on a single cylinder, four
stroke CIDI diesel engine with a speed of 1500 rpm and a fixed
compression ratio of 17.5 at different load conditions. The
performance parameters evaluated include brake thermal efficiency,
brake specific fuel consumption, brake power, indicated mean
effective pressure, mechanical efficiency, and exhaust gas
temperature. Regarding combustion study, cylinder pressure, rate of
pressure rise, net heat release rate, cumulative heat release, mean gas
temperature, mass fraction burned, and fuel line pressure were
evaluated. The emission parameters such as carbon monoxide, carbon
dioxide, un-burnt hydrocarbon, oxides of nitrogen, and smoke
opacity were also measured by a smoke meter and an exhaust gas
analyzer and compared with baseline results. The brake thermal
efficiency of cotton seed oil methyl ester (CSOME) was lower than
that of petrodiesel and brake specific fuel consumption was found to
be higher. However, biodiesel resulted in the reduction of carbon
dioxide, un-burnt hydrocarbon, and smoke opacity at the expense of
nitrogen oxides. Carbon monoxide emissions for biodiesel was higher
at maximum output power. It has been found that the combustion
characteristics of cotton seed oil methyl ester closely followed those
of standard petrodiesel. The experimental results suggested that
biodiesel derived from cotton seed oil could be used as a good
substitute to petrodiesel fuel in a conventional diesel without any
modification.
Abstract: Monitoring the conditions of rotating machinery, such
as bearings, is important in order to improve the stability of work.
Acoustic Emission (AE) and vibration analysis are some of the most
accomplished techniques used for this purpose. Acoustic emission
has the ability to detect the initial phase of component degradation.
Moreover, it has been observed that vibration analysis is not as
successful at low rotational speeds (below 100 rpm). This because the
energy generated within this speed region is not detectable using
conventional vibration. From this perspective, this paper has
presented a brief review of using acoustic emission techniques for
monitoring bearing conditions.
Abstract: The development of composite materials and the
related design and manufacturing technologies is one of the most
important advances in the history of materials. Composites are
multifunctional materials having unprecedented mechanical and
physical properties that can be tailored to meet the requirements of a
particular application. Some composites also exhibit great resistance
to high-temperature corrosion, oxidation, and wear. Polymers are
widely used indoors and outdoors, therefore they are exposed to a
chemical environment which may include atmospheric oxygen, acidic
fumes, acidic rain, moisture heat and thermal shock, ultra-violet light,
high energy radiation, etc. Different polymers are affected differently
by these factors even though the amorphous polymers are more
sensitive. Ageing is also important and it is defined as the process of
deterioration of engineering materials resulting from the combined
effects of atmospheric radiation, heat, oxygen, water, microorganisms
and other atmospheric factors.
Abstract: In internet of things (IoT) system, the communication
scheme with reliability and low power is required to connect a
terminal. Cooperative communication can achieve reliability and
lower power than multiple-input multiple-output (MIMO) system.
Cooperative communication increases the reliability with low
power, but decreases a throughput. It has a weak point that the
communication throughput is decreased. In this paper, a novel scheme
is proposed to increase the communication throughput. The novel
scheme is a transmission structure that increases transmission rate.
A decoding scheme according to the novel transmission structure is
proposed. Simulation results show that the proposed scheme increases
the throughput without bit error rate (BER) performance degradation.
Abstract: Indonesia has experienced annual forest fires that have
rapidly destroyed and degraded its forests. Fires in the peat swamp
forests of Riau Province, have set the stage for problems to worsen,
this being the ecosystem most prone to fires (which are also the most
difficult, to extinguish). Despite various efforts to curb deforestation,
and forest degradation processes, severe forest fires are still
occurring. To find an effective solution, the basic causes of the
problems must be identified. It is therefore critical to have an indepth
understanding of the underlying causal factors that have
contributed to deforestation and forest degradation as a whole, in
order to attain reductions in their rates. An assessment of the drivers of deforestation and forest
degradation was carried out, in order to design and implement
measures that could slow these destructive processes. Research was
conducted in Giam Siak Kecil–Bukit Batu Biosphere Reserve
(GSKBB BR), in the Riau Province of Sumatera, Indonesia. A
biosphere reserve was selected as the study site because such reserves
aim to reconcile conservation with sustainable development. A
biosphere reserve should promote a range of local human activities,
together with development values that are in line spatially and
economically with the area conservation values, through use of a
zoning system. Moreover, GSKBB BR is an area with vast peatlands,
and is experiencing forest fires annually. Various factors were
analysed to assess the drivers of deforestation and forest degradation
in GSKBB BR; data were collected from focus group discussions
with stakeholders, key informant interviews with key stakeholders,
field observation and a literature review. Landsat satellite imagery was used to map forest-cover changes
for various periods. Analysis of landsat images, taken during the
period 2010-2014, revealed that within the non-protected area of core
zone, there was a trend towards decreasing peat swamp forest areas,
increasing land clearance, and increasing areas of community oilpalm
and rubber plantations. Fire was used for land clearing and most
of the forest fires occurred in the most populous area (the transition
area). The study found a relationship between the deforested/
degraded areas, and certain distance variables, i.e. distance from
roads, villages and the borders between the core area and the buffer
zone. The further the distance from the core area of the reserve, the
higher was the degree of deforestation and forest degradation. Research findings suggested that agricultural expansion may be
the direct cause of deforestation and forest degradation in the reserve,
whereas socio-economic factors were the underlying driver of forest
cover changes; such factors consisting of a combination of sociocultural,
infrastructural, technological, institutional (policy and governance), demographic (population pressure) and economic
(market demand) considerations. These findings indicated that local
factors/problems were the critical causes of deforestation and
degradation in GSKBB BR. This research therefore concluded that
reductions in deforestation and forest degradation in GSKBB BR
could be achieved through ‘local actor’-tailored approaches such as
community empowerment.
Abstract: Aurèsregion is one of the arid and semi-arid areas that
have suffered climate crises and overexploitation of natural resources
they have led to significant land degradation. The use of remote sensing data allowed us to analyze the land and
its spatiotemporal changes in the Aurès between 1987 and 2013, for
this work, we adopted a method of analysis based on the exploitation
of the images satellite Landsat TM 1987 and Landsat OLI 2013, from
the supervised classification likelihood coupled with field surveys of
the mission of May and September of 2013. Using ENVI EX software by the superposition of the ground cover
maps from 1987 and 2013, one can extract a spatial map change of
different land cover units. The results show that between 1987 and
2013 vegetation has suffered negative changes are the significant
degradation of forests and steppe rangelands, and sandy soils and
bare land recorded a considerable increase. The spatial change map land cover units between 1987 and 2013
allows us to understand the extensive or regressive orientation of
vegetation and soil, this map shows that dense forests give his place
to clear forests and steppe vegetation develops from a degraded forest
vegetation and bare, sandy soils earn big steppe surfaces that explain
its remarkable extension.
The analysis of remote sensing data highlights the profound
changes in our environment over time and quantitative monitoring of
the risk of desertification.
Abstract: In the present study, the kinetics of thermal
degradation of a phenolic and lignin reinforced phenolic foams, and
the lignin used as reinforcement were studied and the activation
energies of their degradation processes were obtained by a DAEM
model. The average values for five heating rates of the mean
activation energies obtained were: 99.1, 128.2, and 144.0 kJ.mol-1 for
the phenolic foam; 109.5, 113.3, and 153.0 kJ.mol-1 for the lignin
reinforcement; and 82.1, 106.9, and 124.4 kJ.mol-1 for the lignin
reinforced phenolic foam. The standard deviation ranges calculated
for each sample were 1.27-8.85, 2.22-12.82, and 3.17-8.11 kJ.mol-1
for the phenolic foam, lignin and the reinforced foam, respectively.
The DAEM model showed low mean square errors (
Abstract: Fungal mutant strains have produced cellulase and
xylanase enzymes, and have induced high hydrolysis with enhanced
of rice straw. The mutants were obtained by exposing Penicillium
strain to UV-light treatments. Screening and selection after treatment
with UV-light were carried out using cellulolytic and xylanolytic
clear zones method to select the hypercellulolytic and
hyperxylanolytic mutants. These mutants were evaluated for their
cellulase and xylanase enzyme production as well as their abilities for
biodegradation of rice straw. The mutant 12 UV/1 produced 306.21%
and 209.91% cellulase and xylanase, respectively, as compared with
the original wild type strain. This mutant showed high capacity of
rice straw degradation. The effectiveness of tested mutant strain and
that of wild strain was compared in relation to enhancing the
composting process of rice straw and animal manures mixture. The
results obtained showed that the compost product of inoculated
mixture with mutant strain (12 UV/1) was the best compared to the
wild strain and un-inoculated mixture. Analysis of the composted
materials showed that the characteristics of the produced compost
were close to those of the high quality standard compost. The results
obtained in the present work suggest that the combination between
rice straw and animal manure could be used for enhancing the
composting process of rice straw and particularly when applied with
fungal decomposer accelerating the composting process.
Abstract: Epidermal Growth Factor (EGF, Mw=6,045) has been
reported to have high efficiency of wound repair and anti-wrinkle
effect. However, the half-life of EGF in the body is too short to exert
the biological activity effectively when applied in free form. Growth
Factors can be stabilized by immobilization with carbohydrates from
thermal and proteolytic degradation. Low molecular weight chitosan
(LMCS) and its derivate prepared by hydrogen peroxide has high
solubility. LM6A6DC was successfully prepared as a reactive
carbohydrate for the stabilization of EGF by the reactions of LMCS
with alkalization, tosylation, azidation and reduction. The structure of
LM6A6DC was confirmed by FT-IR, 1H NMR and elementary
analysis. For enhancing the stability of free EGF, EGF was attached
with LM6A6DC by using water-soluble carbodiimide.
EGF-LM6A6DC conjugates did not show any cytotoxicity on the
Normal Human Dermal Fibroblast (NHDF) 3T3 proliferation at least
under 100 μg/ml. In the result, it was considered that LM6A6DC is
suitable to immobilize of growth factor.
Abstract: Worldwide, most PILC MV underground cables in use
are approaching the end of their design life; hence, failures are likely
to increase. This paper studies the electric field and potential
distributions within the PILC insulted cable containing common
void-defect. The finite element model of the performance of the
belted PILC MV underground cable is presented. The variation of the
electric field stress within the cable using the Finite Element Method
(FEM) is concentrated. The effects of the void-defect within the
insulation are given. Outcomes will lead to deeper understanding of
the modeling of Paper Insulated Lead Covered (PILC) and electric
field response of belted PILC insulted cable containing void defect.
Abstract: The present study was conducted to evaluate the
potential applicability of biological trickling filter system for the
treatment of simulated textile wastewater containing reactive azo
dyes with bacterial consortium under non-sterile conditions. The
percentage decolorization for the treatment of wastewater containing
structurally different dyes was found to be higher than 95% in all
trials. The stable bacterial count of the biofilm on stone media of the
trickling filter during the treatment confirmed the presence,
proliferation, dominance and involvement of the added microbial
consortium in the treatment of textile wastewater. Results of
physicochemical parameters revealed the reduction in chemical
oxygen demand (58.5-75.1%), sulphates (18.9-36.5%), and
phosphates (63.6-73.0%). UV-Visible and FTIR spectroscopy
confirmed decolorization of dye containing wastewater was ultimate
consequence of biodegradation. Toxicological studies revealed the
nontoxic nature of degradative metabolites.
Abstract: This paper present the experimental work of double
unit tunnel form building (TFB) subjected to in-plane lateral cyclic
loading. A one third scale of 3-storey double unit of TFB is tested
until its strength degradation. Then, the TFB is repaired and
retrofitted using additional shear wall, steel angle and CFRP sheet.
The crack patterns, lateral strength, stiffness, ductility and equivalent
viscous damping (EVD) were analyzed and compared before and
after repair and retrofit. The result indicates that the lateral strength
increases by 22% in pushing and 27% in pulling direction. Moreover,
the stiffness and ductility obtained before and after retrofit increase
tremendously by 87.87% and 39.66%, respectively. Meanwhile, the
energy absorption measured by equivalent viscous damping obtained
after retrofit increase by 12.34% in pulling direction. It can be
concluded that the proposed retrofit method is capable to increase the
lateral strength capacity, stiffness and energy absorption of double
unit TFB.
Abstract: In this paper, we present a new maintenance model
for a partially observable system subject to two failure modes,
namely a catastrophic failure and a failure due to the system
degradation. The system is subject to condition monitoring and the
degradation process is described by a hidden Markov model. A
cost-optimal Bayesian control policy is developed for maintaining
the system. The control problem is formulated in the semi-Markov
decision process framework. An effective computational algorithm is
developed, illustrated by a numerical example.
Abstract: In this paper, we investigate the residual life prediction
problem for a partially observable system subject to two failure
modes, namely a catastrophic failure and a failure due to the system
degradation. The system is subject to condition monitoring and the
degradation process is described by a hidden Markov model with
unknown parameters. The parameter estimation procedure based on
an EM algorithm is developed and the formulas for the conditional
reliability function and the mean residual life are derived, illustrated
by a numerical example.
Abstract: Composting is a controlled technology to enhance the
natural aerobic process of organic wastes degradation. The resulting
product is a humified material that is principally recyclable for
agricultural purpose. The composting process is one of the most
important tools for waste management, by the European Community
legislation. In recent years composting has been increasingly used as
a remediation technology to remove biodegradable contaminants
from soil, and to modulate heavy metals bioavailability in
phytoremediation strategies. An optimization in the recovery of
resources from wastes through composting could enhance soil
fertility and promote its use in the remediation biotechnologies of
contaminated soils.
Abstract: The mechanism for extraction bioactive compounds
from plant matrix is essential for optimizing the extraction process. As
a benchmark technique, a soxhlet extraction has been utilized for
discussing the mechanism and compared with an accelerated water
extraction. The trends of both techniques show that the process
involves extraction and degradation. The highest yields of 6-, 8-,
10-gingerols and 6-shogaol in soxhlet extraction were 13.948, 7.12,
10.312 and 2.306 mg/g, respectively. The optimum 6-, 8-,
10-gingerols and 6-shogaol extracted by the accelerated water
extraction at 140oC were 68.97±3.95 mg/g at 3min, 18.98±3.04 mg/g
at 5min, 5.167±2.35 mg/g at 3min and 14.57±6.27 mg/g at 3min,
respectively. The effect of temperature at 3mins shows that the
concentration of 6-shogaol increased rapidly as decreasing the
recovery of 6-gingerol.