Abstract: In this paper, the exergy analysis of vapor absorption
refrigeration system using LiBr-H2O as working fluid is carried out
with the modified Gouy-Stodola approach rather than the classical
Gouy-Stodola equation and effect of varying input parameters is also
studied on the performance of the system. As the modified approach
uses the concept of effective temperature, the mathematical
expressions for effective temperature have been formulated and
calculated for each component of the system. Various constraints and
equations are used to develop program in EES to solve these
equations. The main aim of this analysis is to determine the
performance of the system and the components having major
irreversible loss. Results show that exergy destruction rate is
considerable in absorber and generator followed by evaporator and
condenser. There is an increase in exergy destruction in generator,
absorber and condenser and decrease in the evaporator by the
modified approach as compared to the conventional approach. The
value of exergy determined by the modified Gouy-Stodola equation
deviates maximum i.e. 26% in the generator as compared to the
exergy calculated by the classical Gouy-Stodola method.
Abstract: This paper introduces an original method for
guaranteed estimation of the accuracy for an ensemble of Lipschitz
classifiers. The solution was obtained as a finite closed set of
alternative hypotheses, which contains an object of classification with
probability of not less than the specified value. Thus, the
classification is represented by a set of hypothetical classes. In this
case, the smaller the cardinality of the discrete set of hypothetical
classes is, the higher is the classification accuracy. Experiments have
shown that if cardinality of the classifiers ensemble is increased then
the cardinality of this set of hypothetical classes is reduced. The
problem of the guaranteed estimation of the accuracy for an ensemble
of Lipschitz classifiers is relevant in multichannel classification of
target events in C-OTDR monitoring systems. Results of suggested
approach practical usage to accuracy control in C-OTDR monitoring
systems are present.
Abstract: Groundwater inflow to the tunnels is one of the most
important problems in tunneling operation. The objective of this
study is the investigation of model dimension effects on tunnel inflow
assessment in discontinuous rock masses using numerical modeling.
In the numerical simulation, the model dimension has an important
role in prediction of water inflow rate. When the model dimension is
very small, due to low distance to the tunnel border, the model
boundary conditions affect the estimated amount of groundwater flow
into the tunnel and results show a very high inflow to tunnel. Hence,
in this study, the two-dimensional universal distinct element code
(UDEC) used and the impact of different model parameters, such as
tunnel radius, joint spacing, horizontal and vertical model domain
extent has been evaluated. Results show that the model domain extent
is a function of the most significant parameters, which are tunnel
radius and joint spacing.
Abstract: Using the first-principles full-potential linearized
augmented plane wave plus local orbital (FP-LAPW+lo) method
based on density functional theory (DFT), we have investigated the
electronic structure and magnetism of full Heusler alloys Co2ZrGe
and Co2NbB. These compounds are predicted to be half-metallic
ferromagnets (HMFs) with a total magnetic moment of 2.000 B per
formula unit, well consistent with the Slater-Pauling rule.
Calculations show that both the alloys have an indirect band gaps, in
the minority-spin channel of density of states (DOS), with values of
0.58 eV and 0.47 eV for Co2ZrGe and Co2NbB, respectively.
Analysis of the DOS and magnetic moments indicates that their
magnetism is mainly related to the d-d hybridization between the Co
and Zr (or Nb) atoms. The half-metallicity is found to be relatively
robust against volume changes. In addition, an atom inside molecule
AIM formalism and an electron localization function ELF were also
adopted to study the bonding properties of these compounds, building
a bridge between their electronic and bonding behavior.
As they have a good crystallographic compatibility with the lattice of
semiconductors used industrially and negative calculated cohesive
energies with considerable absolute values these two alloys could be
promising magnetic materials in the spintronic field.
Abstract: An innovative concept called “Flexy-Energy” is developing at 2iE. This concept aims to produce electricity at lower cost by smartly mix different available energy sources in accordance to the load profile of the region. With a higher solar irradiation and due to the fact that Diesel generator are massively used in sub-Saharan rural areas, PV/Diesel hybrid systems could be a good application of this concept and a good solution to electrify this region, provided they are reliable, cost effective and economically attractive to investors. Presentation of the developed approach is the aims of this paper. The PV/Diesel hybrid system designed consists to produce electricity and/or heat from a coupling between Diesel Diesel generators and PV panels without batteries storage, while ensuring the substitution of gasoil by bio-fuels available in the area where the system will be installed. The optimal design of this system is based on his technical performances; the Life Cycle Cost (LCC) and Levelized Cost of Energy are developed and use as economic criteria. The Net Present Value (NPV), the internal rate of return (IRR) and the discounted payback (DPB) are also evaluated according to dual electricity pricing (in sunny and unsunny hours). The PV/Diesel hybrid system obtained is compared to the standalone Diesel Diesel generators. The approach carried out in this paper has been applied to Siby village in Mali (Latitude 12 ° 23'N 8 ° 20'W) with 295 kWh as daily demand.This approach provides optimal physical characteristics (size of the components, number of component) and dynamical characteristics in real time (number of Diesel generator on, their load rate, fuel specific consumptions, and PV penetration rate) of the system. The system obtained is slightly cost effective; but could be improved with optimized tariffing strategies.
Abstract: Corrosion of concrete sewer pipes induced by sulfuric
acid is an acknowledged problem and a ticking time-bomb to sewer
operators. Whilst the chemical reaction of the corrosion process is
well-understood, the indirect roles of other parameters in the
corrosion process which are found in sewer environment are not
highly reflected on. This paper reports on a field studies undertaken
in Austria and United Kingdom, where the parameters of
temperature, pH, H2S and CO2 were monitored over a period of time.
The study establishes that (i) effluent temperature and pH have
similar daily pattern and peak times, when examined in minutes
scale; (ii) H2S and CO2 have an identical hourly pattern; (iii) H2S
instant or shifted relation to effluent temperature is governed by the
root mean square value of CO2.
Abstract: Real bronchial tree is very complicated piping system.
Analysis of flow and pressure losses in this system is very difficult.
Due to the complex geometry and the very small size in the lower
generations is examination by CFD possible only in the central part
of bronchial tree. For specify the pressure losses of lower generations
is necessary to provide a mathematical equation. Determination of
mathematical formulas for calculation of pressure losses in the real
lungs is time consuming and inefficient process due to its complexity
and diversity. For these calculations is necessary to slightly simplify
the geometry of lungs (same cross-section over the length of
individual generation) or use one of the idealized models of lungs
(Horsfield, Weibel). The article compares the values of pressure
losses obtained from CFD simulation of air flow in the central part of
the real bronchial tree with the values calculated in a slightly
simplified real lungs by using a mathematical relationship derived
from the Bernoulli and continuity equations. The aim of the article is
to analyse the accuracy of the analytical method and its possibility of
use for the calculation of pressure losses in lower generations, which
is difficult to solve by numerical method due to the small geometry.
Abstract: In urban context, urban nodes such as amenity or
hazard will certainly affect house price, while classic hedonic analysis
will employ distance variables measured from each urban nodes.
However, effects from distances to facilities on house prices generally
do not represent the true price of the property. Distance variables
measured on the same surface are suffering a problem called
multicollinearity, which is usually presented as magnitude variance
and mean value in regression, errors caused by instability. In this paper,
we provided a theoretical framework to identify and gather the data
with less bias, and also provided specific sampling method on locating
the sample region to avoid the spatial multicollinerity problem in three
distance variable’s case.
Abstract: Generating random numbers are mainly used to create
secret keys or random sequences. It can be carried out by various
techniques. In this paper we present a very simple and efficient
pseudo random number generator (PRNG) based on chaotic maps
and S-Box tables. This technique adopted two main operations one to
generate chaotic values using two logistic maps and the second to
transform them into binary words using random S-Box tables.
The simulation analysis indicates that our PRNG possessing
excellent statistical and cryptographic properties.
Abstract: We have been grouping and developing various kinds
of practical, promising sensing applied systems concerning
agricultural advancement and technical tradition (guidance). These
include advanced devices to secure real-time data related to worker
motion, and we analyze by methods of various advanced statistics and
human dynamics (e.g. primary component analysis, Ward system
based cluster analysis, and mapping). What is more, we have been
considering worker daily health and safety issues. Targeted fields are
mainly common farms, meadows, and gardens. After then, we
observed and discussed time-line style, changing data. And, we made
some suggestions. The entire plan makes it possible to improve both
the aforementioned applied systems and farms.
Abstract: This paper shortly describes various types of biomass
and a growing number of facilities utilizing the biomass in the Czech
Republic. The considerable part of this paper deals with energy
parameters of the most frequently used types of biomass and results
of their gasification testing. Sixteen most used "Czech" woody plants
and grasses were selected; raw, element and biochemical analyses
were performed and basic calorimetric values, ash composition, and
ash characteristic temperatures were identified. Later, each biofuel
was tested in a fluidized bed gasifier. The essential part of this paper
provides results of the gasification of selected biomass types.
Operating conditions are described in detail with a focus on
individual fuels properties. Gas composition and impurities content
are also identified. In terms of operating conditions and gas quality,
the essential difference occurred mainly between woody plants and
grasses. The woody plants were evaluated as more suitable fuels for
fluidized bed gasifiers. Testing results significantly help with a
decision-making process regarding suitability of energy plants for
growing and with a selection of optimal biomass-treatment
technology.
Abstract: Modeling and forecasting dynamics of rainfall
occurrences constitute one of the major topics, which have been
largely treated by statisticians, hydrologists, climatologists and many
other groups of scientists. In the same issue, we propose, in the
present paper, a new hybrid method, which combines Extreme
Values and fractal theories. We illustrate the use of our methodology
for transformed Emberger Index series, constructed basing on data
recorded in Oujda (Morocco).
The index is treated at first by Peaks Over Threshold (POT)
approach, to identify excess observations over an optimal threshold u.
In the second step, we consider the resulting excess as a fractal object
included in one dimensional space of time. We identify fractal
dimension by the box counting. We discuss the prospect descriptions
of rainfall data sets under Generalized Pareto Distribution, assured by
Extreme Values Theory (EVT). We show that, despite of the
appropriateness of return periods given by POT approach, the
introduction of fractal dimension provides accurate interpretation
results, which can ameliorate apprehension of rainfall occurrences.
Abstract: Machining of hard materials is a recent technology for
direct production of work-pieces. The primary challenge in
machining these materials is selection of cutting tool inserts which
facilitates an extended tool life and high-precision machining of the
component. These materials are widely for making precision parts for
the aerospace industry. Nickel-based alloys are typically used in
extreme environment applications where a combination of strength,
corrosion resistance and oxidation resistance material characteristics
are required. The present paper reports the theoretical and
experimental investigations carried out to understand the influence of
machining parameters on the response parameters. Considering the
basic machining parameters (speed, feed and depth of cut) a study has
been conducted to observe their influence on material removal rate,
surface roughness, cutting forces and corresponding tool wear.
Experiments are designed and conducted with the help of Central
Composite Rotatable Design technique. The results reveals that for a
given range of process parameters, material removal rate is favorable
for higher depths of cut and low feed rate for cutting forces. Low feed
rates and high values of rotational speeds are suitable for better finish
and higher tool life.
Abstract: The effect of transition metal doping on Pt/Al2O3
catalyst used in propane dehydrogenation reaction at 500°C was
studied. The preparation methods investigated were sequential
impregnation (Pt followed by the 2nd metal or the 2nd metal followed
by Pt) and co-impregnation. The metal contents of these catalysts
were fixed as the weight ratio of Pt per the 2nd metal of around 0.075.
These catalysts were characterized by N2-physisorption, TPR, COchemisorption
and NH3-TPD. It was found that the impregnated 2nd
metal had an effect upon reducibility of Pt due to its interaction with
transition metal-containing structure. This was in agreement with the
CO-chemisorption result that the presence of Pt metal, which is a
result from Pt species reduction, was decreased. The total acidity of
bimetallic catalysts is decreased but the strong acidity is slightly
increased. It was found that the stability of bimetallic catalysts
prepared by co-impregnation and sequential impregnation where the
2nd metal was impregnated before Pt were better than that of
monometallic catalyst (undoped Pt one) due to the forming of Pt sites
located on the transition metal-oxide modified surface. Among all
preparation methods, the sequential impregnation method- having Pt
impregnated before the 2nd metal gave the worst stability because this
catalyst lacked the modified Pt sites and some fraction of Pt sites was
covered by the 2nd metal.
Abstract: In the present work, the dielectric properties of
Epoxy/MWCNT-muscovite HYBRID and MIXED composites based
on a ratio 30:70 were studied. The multi-wall carbon nanotubes
(MWCNT) were prepared using two methods: (a) MWCNTmuscovite
hybrids were synthesised by chemical vapour deposition
(CVD) and (b) physically mixing muscovite with MWCNT. The
effects of different preparation of the composites and filler loading
were evaluated. It was revealed that the dielectric constants of
HYBRID epoxy composites are slightly higher than MIXED epoxy
composites. It was also indicated that the dielectric constant increased
by increasing the MWCNT filler loading.
Abstract: The development of active and stable catalysts
without noble metals for low temperature oxidation of exhaust gases
remains a significant challenge. The purpose of this study is to
determine the influence of the preparation method on the catalytic
activity of the supported copper-manganese mixed oxides in terms of
VOCs oxidation. The catalysts were prepared by impregnation of γ-
Al2O3 with copper and manganese nitrates and acetates and the
possibilities for CO, CH3OH and dimethyl ether (DME) oxidation
were evaluated using continuous flow equipment with a four-channel
isothermal stainless steel reactor. Effect of the support, Cu/Mn mole
ratio, heat treatment of the precursor and active component loading
were investigated. Highly active alumina supported Cu-Mn catalysts
for CO and VOCs oxidation were synthesized. The effect of
preparation conditions on the activity behavior of the catalysts was
discussed.
The synergetic interaction between copper and manganese species
increases the activity for complete oxidation over mixed catalysts.
Type of support, calcination temperature and active component
loading along with catalyst composition are important factors,
determining catalytic activity. Cu/Mn molar ratio of 1:5, heat
treatment at 450oC and 20 % active component loading are the best
compromise for production of active catalyst for simultaneous
combustion of CO, CH3OH and DME.
Abstract: Considering palm oil as non-drying oil owing to its
low iodine value, an attempt was taken to increase the unsaturation in
the fatty acid chains of palm oil for the preparation of alkyds. To
increase the unsaturation in the palm oil, sulphuric acid (SA) and
para-toluene sulphonic acid (PTSA) was used prior to alcoholysis for
the dehydration process. The iodine number of the oil samples was
checked for the unsaturation measurement by Wijs method. Alkyd
resin was prepared using the dehydrated palm oil by following
alcoholysis and esterification reaction. To improve the film properties
0.5wt.% multi-wall carbon nano tubes (MWCNTs) were used to
manufacture polymeric film. The properties of the resins were
characterized by various physico-chemical properties such as density,
viscosity, iodine value, saponification value, etc. Structural
elucidation was confirmed by Fourier transform of infrared
spectroscopy and proton nuclear magnetic resonance; surfaces of the
films were examined by field-emission scanning electron microscope.
In addition, pencil hardness and chemical resistivity was also
measured by using standard methods. The effect of enhancement of
the unsaturation in the fatty acid chain found significant and
motivational. The resin prepared with dehydrated palm oil showed
improved properties regarding hardness and chemical resistivity
testing. The incorporation of MWCNTs enhanced the thermal
stability and hardness of the films as well.
Abstract: Peace education supports a holistic appreciation for
the value of life and the interdependence of all living systems. Peace
education aims to build a culture of peace. One way of building a
culture of peace is through environmental stewardship. This study
sought to find out the environmental stewardship practices in selected
Higher Education Institutions (HEIs) in the Philippines and how
these environmental stewardship practices lead to building a culture
of peace. The findings revealed that there is still room for
improvement in implementing environmental stewardship in schools
through academic service learning. In addition, the following
manifestations are implemented very satisfactorily in schools: 1)
waste reduction, reuse, and recycling, 2) community service, and 3)
clean and green surroundings. Administrators of schools in the study
lead their staff and students in implementing environmental
stewardship. It could be concluded that those involved in
environmental stewardship display an acceptable culture of peace,
particularly solidarity, respect for persons, and inner peace.
Abstract: Paraffinic oils were submitted to microbial action. The
microorganisms consisted of bacteria of the genera Pseudomonas sp.
and Bacillus lincheniforms. The alterations in interfacial tension were
determined using a tensometer and applying the hanging drop
technique at room temperature (299 K ±275 K). The alteration in the
constitution of the paraffins was evaluated by means of gas
chromatography. The microbial activity was observed to reduce
interfacial tension by 54 to 78%, as well as consuming the paraffins
C19 to C29 and producing paraffins C36 to C44. The LIFirr technique
made it possible to determine the microbial action quickly.
Abstract: The value co-creation has gained much attention in
sales research, but less is known about how salespeople and
customers interact in the authentic business to business (B2B) sales
meetings. The study presented in this paper empirically contributes to
existing research by presenting authentic B2B sales meetings that
were video recorded and analyzed using observation and qualitative
content analysis methods. This paper aims to study key elements of
successful sales interactions between salespeople and customers/
buyers. This study points out that salespeople are selling value rather
than the products or services themselves, which are only enablers in
realizing business benefits. Therefore, our findings suggest that
promoting and easing open discourse is an essential part of a
successful sales encounter. A better understanding of how
salespeople and customers successfully interact would help
salespeople to develop their interpersonal sales skills.