Abstract: The elastic properties and fracture of two-dimensional
graphene were calculated purely from the atomic bonding (stretching
and bending) based on molecular mechanics method. Considering the
representative unit cell of graphene under various loading conditions,
the deformations of carbon bonds and the variations of the interlayer
distance could be realized numerically under the geometry constraints
and minimum energy assumption. In elastic region, it was found that
graphene was in-plane isotropic. Meanwhile, the in-plane deformation
of the representative unit cell is not uniform along armchair direction
due to the discrete and non-uniform distributions of the atoms. The
fracture of graphene could be predicted using fracture criteria based on
the critical bond length, over which the bond would break. It was
noticed that the fracture behavior were directional dependent, which
was consistent with molecular dynamics simulation results.
Abstract: Native American communities are struggling with unemployment and depressed economies. A major cause is a lack of business knowledge, education, and cultural desire. And yet, in the history of the American West, Native Americans were considered the best traders and negotiators for everything from furs to weapons to buffalo. To improve these economies, there has been an effort to reintroduce that heritage to todays and tomorrows generation of tribal members, such Crow, Cheyenne, and Blackfeet. Professors at the College of Business Montana State University-Billings (MSUB) teach tribal students in Montana to create business plans. These plans have won national small business plan competitions. The teaching and advising method used at MSUB is uniquely successful as theses business students are now five time national champions. This article reviews the environment and the method of learning to achieve a winning small business plan with Native American students. It discusses the five plans that became national champions. And it discusses the problems and solutions discovered in the process of achieving results. Students who participated in this endeavor have graduated and become CPAs, MBAs, and gainfully employed in their chosen professions. They have also worked to improve the economies of their native lands and homes. By educating members of these communities with business strategy and plan development, they are better able to impact their own economies.
Abstract: This work studies the effect of chemical composition
on the activity and selectivity of γ–alumina supported CuO/
MnO2/Cr2O3 catalysts toward deep oxidation of CO, dimethyl ether
(DME) and methanol. The catalysts were prepared by impregnation
of the support with an aqueous solution of copper nitrate, manganese
nitrate and CrO3 under different conditions. Thermal, XRD and TPR
analysis were performed. The catalytic measurements of single
compounds oxidation were carried out on continuous flow equipment
with a four-channel isothermal stainless steel reactor. Flow-line
equipment with an adiabatic reactor for simultaneous oxidation of all
compounds under the conditions that mimic closely the industrial
ones was used. The reactant and product gases were analyzed by
means of on-line gas chromatographs.
On the basis of XRD analysis it can be concluded that the active
component of the mixed Cu-Mn-Cr/γ–alumina catalysts consists of at
least six compounds – CuO, Cr2O3, MnO2, Cu1.5Mn1.5O4,
Cu1.5Cr1.5O4 and CuCr2O4, depending on the Cu/Mn/Cr molar ratio.
Chemical composition strongly influences catalytic properties, this
influence being quite variable with regards to the different processes.
The rate of CO oxidation rapidly decrease with increasing of
chromium content in the active component while for the DME was
observed the reverse trend. It was concluded that the best
compromise are the catalysts with Cu/(Mn + Cr) molar ratio 1:5 and
Mn/Cr molar ratio from 1:3 to 1:4.
Abstract: Evidence shows that start-ups success is positively
correlated with the launch of the first product. However, new ventures
are seldom able to acquire abundant resources for new product
development (NPD), which means that entrepreneurs may depend on
personal creativity instead of physical investments to achieve and
accelerate innovation speed. This study accentuates the role of
entrepreneurial bricolage, which defined as making do by applying
combinations of the resources at hand to new problems and
opportunities, in the relations of creative self-efficacy and innovation
speed. This study uses the multiple regression analysis to test the
hypotheses in a sample of 203 start-ups operating in various creative
markets in Taiwan. Results reveal that creative self-efficacy is
positively and directly associated with innovation speed, whereas
entrepreneurial bricolage plays a full mediator. These findings offer
important theoretical and practical implications.
Abstract: Haynes 25 alloy (also known as L-605 alloy) is cobalt
based super alloy which has widely applications such as aerospace
industry, turbine and furnace parts, power generators and heat
exchangers and petroleum refining components due to its excellent
characteristics. However, the workability of this alloy is more
difficult compared to normal steels or even stainless. In present work,
an experimental investigation was performed under cryogenic
cooling to determine cutting tool wear patterns and obtain optimal
cutting parameters in turning of cobalt based superalloy Haynes 25.
In experiments, uncoated carbide tool was used and cutting speed (V)
and feed rate (f) were considered as test parameters. Tool wear
(VBmax) were measured for process performance indicators.
Analysis of variance (ANOVA) was performed to determine the
importance of machining parameters.
Abstract: We used live E. coli containing synthetic genetic
oscillators to study how the degree of synchrony between the genetic
circuits of sister cells changes with temperature. We found that both
the mean and the variability of the degree of synchrony between the
fluorescence signals from sister cells are affected by temperature.
Also, while most pairs of sister cells were found to be highly
synchronous in each condition, the number of asynchronous pairs
increased with increasing temperature, which was found to be due to
disruptions in the oscillations. Finally we provide evidence that these
disruptions tend to affect multiple generations as opposed to
individual cells. These findings provide insight in how to design
more robust synthetic circuits and in how cell division can affect their
dynamics.
Abstract: Cyberspace has become a more viable arena for
budding artists to share musical acts through digital forms. The
increasing relevance of online communities has attracted scholars
from various fields demonstrating its influence on social capital. This
paper extends this understanding of social capital among Filipino
music artists belonging to the SoundCloud Philippines Facebook
Group.
The study makes use of various qualitative data obtained from
key-informant interviews and participant observation of online and
physical encounters, analyzed using the case study approach.
Soundcloud Philippines has over seven-hundred members and is
composed of Filipino singers, instrumentalists, composers, arrangers,
producers, multimedia artists and event managers. Group interactions
are a mix of online encounters based on Facebook and SoundCloud
and physical encounters through meet-ups and events. Benefits
reaped from the community are informational, technical,
instrumental, promotional, motivational and social support. Under the
guidance of online group administrators, collaborative activities such
as music productions, concerts and events transpire. Most conflicts
and problems arising are resolved peacefully. Social capital in
SoundCloud Philippines is mobilized through recognition, respect
and reciprocity.
Abstract: Let us consider that the entire universe is composed of
a single hydrogen atom within which the electron is moving around
the proton. In this case, according to classical theories of physics,
radiation, photons respectively, should be absorbed by the electron.
Depending on the number of photons absorbed, the electron radius of
rotation around the proton is established. Until now, the principle of
photons absorption by electrons and the electron transition to a new
energy level, namely to a higher radius of rotation around the proton,
is not clarified in physics. This paper aims to demonstrate that
radiation, photons respectively, have mass and negative electrostatic
charge similar to electrons but infinitely smaller. The experiments
which demonstrate this theory are simple: thermal expansion,
photoelectric effect and thermonuclear reaction.
Abstract: Market is an important factor for start-ups to look into
during decision-making in product development and related areas.
Emerging country markets are more uncertain in terms of information
availability and institutional supports. The literature review of market
uncertainty reveals the need for identifying factors representing the
market uncertainty. This paper identifies factors for market
uncertainty using Exploratory Factor Analysis (EFA) and confirmed
the number of factor retention using an alternative factor retention
criterion ‘Parallel Analysis’. 500 entrepreneurs, engaged in start-ups
from all over India participated in the study. This paper concludes
with the factor structure of ‘market uncertainty’ having dimensions of
uncertainty in industry orientation, uncertainty in customer
orientation and uncertainty in marketing orientation.
Abstract: This paper presents an application of Artificial Neural
Network (ANN) algorithm for improving power system voltage
stability. The training data is obtained by solving several normal and
abnormal conditions using the Linear Programming technique. The
selected objective function gives minimum deviation of the reactive
power control variables, which leads to the maximization of
minimum Eigen value of load flow Jacobian. The considered reactive
power control variables are switchable VAR compensators, OLTC
transformers and excitation of generators. The method has been
implemented on a modified IEEE 30-bus test system. The results
obtain from the test clearly show that the trained neural network is
capable of improving the voltage stability in power system with a
high level of precision and speed.
Abstract: Land Use Land Cover (LULC) changes due to human
activities and natural causes have become a major environmental
concern. Assessment of temporal remote sensing data provides
information about LULC impacts on environment. Land Surface
Temperature (LST) is one of the important components for modeling
environmental changes in climatological, hydrological, and
agricultural studies. In this study, LULC changes (September 7, 1984
and July 8, 2014) especially in agricultural lands together with
population changes (1985-2014) and LST status were investigated
using remotely sensed and census data in South Marmara Watershed,
Turkey. LULC changes were determined using Landsat TM and
Landsat OLI data acquired in 1984 and 2014 summers. Six-band TM
and OLI images were classified using supervised classification
method to prepare LULC map including five classes including Forest
(F), Grazing Land (G), Agricultural Land (A), Water Surface (W),
Residential Area-Bare Soil (R-B) classes. The LST image was also
derived from thermal bands of the same dates.
LULC classification results showed that forest areas, agricultural
lands, water surfaces and residential area-bare soils were increased as
65751 ha, 20163 ha, 1924 ha and 20462 ha respectively. In
comparison, a dramatic decrement occurred in grazing land (107985
ha) within three decades. The population increased 29% between
years 1984-2014 in whole study area. Along with the natural causes,
migration also caused this increase since the study area has an
important employment potential. LULC was transformed among the
classes due to the expansion in residential, commercial and industrial
areas as well as political decisions. In the study, results showed that
agricultural lands around the settlement areas transformed to
residential areas in 30 years.
The LST images showed that mean temperatures were ranged
between 26-32°C in 1984 and 27-33°C in 2014. Minimum
temperature of agricultural lands was increased 3°C and reached to
23°C. In contrast, maximum temperature of A class decreased to
41°C from 44°C. Considering temperatures of the 2014 R-B class and
1984 status of same areas, it was seen that mean, min and max
temperatures increased by 2°C.
As a result, the dynamism of population, LULC and LST resulted
in increasing mean and maximum surface temperatures, living
spaces/industrial areas and agricultural lands.
Abstract: The aim of this research was to reveal the link
between mental variables, such as spatial abilities, memory, intellect
and professional experience of drivers.
Participants were allocated to four groups: no experience,
inexperienced, skilled and professionals (total 85 participants). The
level of ability for spatial navigation and indicator of nonverbal
memory grow along the process of accumulation of driving
experience. At high levels of driving experience, this tendency is
especially noticeable. The professionals having personal
achievements in driving (racing) differ from skilled drivers in better
feeling of direction, which is specific for them not just in a short-term
situation of an experimental task, but also in life-size perspective.
The level of ability of mental rotation does not grow with the growth
of driving experience, which confirms the multiple intelligence
theory according to which spatial abilities represent specific, other
than logical intelligence type of intellect. The link between spatial
abilities, memory, intellect and professional experience of drivers
seems to be different relating spatial navigation or mental rotation as
different kinds of spatial abilities.
Abstract: Evapotranspiration is one of the most important
components of the hydrological cycle. Evapotranspiration (ETo) is an
important variable in water and energy balances on the earth’s
surface, and knowledge of the distribution of ET is a key factor in
hydrology, climatology, agronomy and ecology studies. Many
researchers have a valid relationship, which is a function of climate
factors, to estimate the potential evapotranspiration presented to the
plant water stress or water loss, prevent. The FAO-Penman method
(PM) had been recommended as a standard method. This method
requires many data and these data are not available in every area of
world. So, other methods should be evaluated for these conditions.
When sufficient or reliable data to solve the PM equation are not
available then Hargreaves equation can be used. The Hargreaves
equation (HG) requires only daily mean, maximum and minimum air
temperature extraterrestrial radiation .In this study, Hargreaves
method (HG) were evaluated in 12 stations in the North West region
of Iran. Results of HG and M.HG methods were compared with
results of PM method. Statistical analysis of this comparison showed
that calibration process has had significant effect on efficiency of
Hargreaves method.
Abstract: The new era of digital communication has brought up
many challenges that network operators need to overcome. The high
demand of mobile data rates require improved networks, which is a
challenge for the operators in terms of maintaining the quality of
experience (QoE) for their consumers. In live video transmission,
there is a sheer need for live surveillance of the videos in order to
maintain the quality of the network. For this purpose objective
algorithms are employed to monitor the quality of the videos that are
transmitted over a network. In order to test these objective algorithms,
subjective quality assessment of the streamed videos is required, as the
human eye is the best source of perceptual assessment. In this paper we
have conducted subjective evaluation of videos with varying spatial
and temporal impairments. These videos were impaired with frame
freezing distortions so that the impact of frame freezing on the quality
of experience could be studied. We present subjective Mean Opinion
Score (MOS) for these videos that can be used for fine tuning the
objective algorithms for video quality assessment.
Abstract: Fibre cement plates, often used in construction,
generally are made using quartz as an inert material, cement as a
binder and cellulose as a fibre. This paper, first of all, investigates the
mechanical properties and durability of fibre cement plates when
quartz is both partly and fully replaced with diatomite. Diatomite
does not only have lower density compared to quartz but also has
high pozzolanic activity. The main objective of this paper is the
investigation of the effects of supplementary cementing materials
(SCMs) on the short and long term mechanical properties and
durability characteristics of fibre cement plates prepared using
diatomite. Supplementary cementing materials such as ground
granulated blast furnace slug (GGBS) and fly ash (FA) are used in
this study. Volume proportions of 10, 20, 30 and 40% of GGBS and
FA are used as partial replacement materials to cement. Short and
long term mechanical properties such as compressive and flexural
strengths as well as sorptivity characteristics and mass were
investigated. Consistency and setting time at each replacement levels
of SCMs were also recorded. The effects of using supplementary
cementing materials on the carbonation and sulphate resistance of
fibre cement plates were then experimented. The results, first of all,
show that the use of diatomite as a full or partial replacement to
quartz resulted in a systematic decrease in total mass of the fibre
cement plates. The reduction of mass was largely due to the lower
density and finer particle size of diatomite compared to quartz. The
use of diatomite did not only reduce the mass of these plates but also
increased the compressive strength significantly as a result of its high
pozzolanic activity. The replacement levels of both GGBS and FA
resulted in a systematic decrease in short term compressive strength
with increasing replacement levels. This was essentially expected as
the total rate of hydration is much lower in GGBS and FA than that
of cement. Long term results however, indicated that the compressive
strength of fibre cement plates prepared using both GGBS and FA
increases with time and hence the compressive strength of plates
prepared using SCMs is either equivalent or more than the
compressive strength of plates prepared using cement alone.
Durability characteristics of fibre cement plates prepared using SCMs
were enhanced significantly. Measurements of sopritivty
characteristics were also indicated that the plates prepared using
SCMs has much lower water absorption capacities compared to
plates prepared cement alone. Much higher resistance to carbonation
and sulphate attach were observed with plates prepared using SCMs.
The results presented in this paper show that the use of SCMs does
not only support the production of more sustainable construction
materials but also enhances the mechanical properties and durability
characteristics of fibre cement plates.
Abstract: Continuous upflow filters can combine the nutrient
(nitrogen and phosphate) and suspended solid removal in one unit
process. The contaminant removal could be achieved chemically or
biologically; in both processes the filter removal efficiency depends
on the interaction between the packed filter media and the influent. In
this paper a residence time distribution (RTD) study was carried out
to understand and compare the transfer behaviour of contaminants
through a selected filter media packed in a laboratory-scale
continuous up flow filter; the selected filter media are limestone and
white dolomite. The experimental work was conducted by injecting a
tracer (red drain dye tracer –RDD) into the filtration system and then
measuring the tracer concentration at the outflow as a function of
time; the tracer injection was applied at hydraulic loading rates
(HLRs) (3.8 to 15.2 m h-1). The results were analysed according to
the cumulative distribution function F(t) to estimate the residence
time of the tracer molecules inside the filter media. The mean
residence time (MRT) and variance σ2 are two moments of RTD that
were calculated to compare the RTD characteristics of limestone with
white dolomite. The results showed that the exit-age distribution of
the tracer looks better at HLRs (3.8 to 7.6 m h-1) and (3.8 m h-1) for
limestone and white dolomite respectively. At these HLRs the
cumulative distribution function F(t) revealed that the residence time
of the tracer inside the limestone was longer than in the white
dolomite; whereas all the tracer took 8 minutes to leave the white
dolomite at 3.8 m h-1. On the other hand, the same amount of the
tracer took 10 minutes to leave the limestone at the same HLR. In
conclusion, the determination of the optimal level of hydraulic
loading rate, which achieved the better influent distribution over the
filtration system, helps to identify the applicability of the material as
filter media. Further work will be applied to examine the efficiency
of the limestone and white dolomite for phosphate removal by
pumping a phosphate solution into the filter at HLRs (3.8 to 7.6 m h-1).
Abstract: The sea waves carry thousands of GWs of power
globally. Although there are a number of different approaches to
harness offshore energy, they are likely to be expensive, practically
challenging, and vulnerable to storms. Therefore, this paper considers
using the near shore waves for generating mechanical and electrical
power. It introduces two new approaches, the wave manipulation and
using a variable duct turbine, for intercepting very wide wave fronts
and coping with the fluctuations of the wave height and the sea level,
respectively. The first approach effectively allows capturing much
more energy yet with a much narrower turbine rotor. The second
approach allows using a rotor with a smaller radius but captures
energy of higher wave fronts at higher sea levels yet preventing it
from totally submerging. To illustrate the effectiveness of the first
approach, the paper contains a description and the simulation results
of a scale model of a wave manipulator. Then, it includes the results
of testing a physical model of the manipulator and a single duct, axial
flow turbine in a wave flume in the laboratory. The paper also
includes comparisons of theoretical predictions, simulation results,
and wave flume tests with respect to the incident energy, loss in wave
manipulation, minimal loss, brake torque, and the angular velocity.
Abstract: In this paper a new methodology for vendor selection
and supply quotas determination (VSSQD) is proposed. The problem
of VSSQD is solved by the model that combines revised weighting
method for determining the objective function coefficients, and a
multiple objective linear programming (MOLP) method based on the
cooperative game theory for VSSQD. The criteria used for VSSQD
are: (1) purchase costs and (2) product quality supplied by individual
vendors. The proposed methodology has been tested on the example
of flour purchase for a bakery with two decision makers.
Abstract: Socio-economic development, which is seen around
the world today, has contributed to the emergence of new problems
of a social nature. Different political, historical, geographical or
economic conditions cause that, in addition to global issues of social
policy such as an aging population, unemployment, migration,
countries, regions, there are also specific new problems that require
diagnosis, individualized approach and efficient, planned solutions.
These should include, among others, digital addiction, peer violence,
obesity among children, the problem of ‘legal highs’, stress,
depression, diseases associated with environmental pollution etc. The
central authorities, selected most often with the tools specific to
representative democracy, that is, the general election, for many
reasons, inter alia, organizational, communication, are not able to
effectively diagnose their intensity, territorial distribution, and thus to
effectively fight them. This article aims to show how in Poland,
citizens influence solving problems related to the broader social
policy implemented at the local government level and indicates the
possibilities of improving those solutions. The conclusions of
theoretical analysis have been supported by empirical studies, which
tested the use of instruments of participatory democracy in the
planning and creation of communal strategies for solving social
problems in one of the Polish voivodeships.
Abstract: In this paper, we proposed a novel SCR (Silicon Controlled
Rectifier) - based ESD (Electrostatic Discharge) protection device for I/O
and power clamp. The proposed device has a higher holding voltage
characteristic than conventional SCR. These characteristics enable to have
latch-up immunity under normal operating conditions as well as superior full
chip ESD protection. The proposed device was analyzed to figure out
electrical characteristics and tolerance robustness in term of individual
design parameters (D1, D2, D3). They are investigated by using the
Synopsys TCAD simulator. As a result of simulation, holding voltage
increased with different design parameters. The holding voltage of the
proposed device changes from 3.3V to 7.9V. Also, N-Stack structure ESD
device with the high holding voltage is proposed. In the simulation results,
2-stack has holding voltage of 6.8V and 3-stack has holding voltage of
10.5V. The simulation results show that holding voltage of stacking
structure can be larger than the operation voltage of high-voltage
application.