Abstract: As a by-product of the biodiesel industries, glycerol
has been vastly generated which surpasses the market demand. It is
imperative to develop an efficient glycerol valorization processes in
minimizing the net energy requirement and intensifying the biodiesel
production. In this study, base-catalyzed transesterification of
glycerol with dimethyl carbonate using microwave irradiation as
heating method to produce glycerol carbonate was conducted by
varying grades of glycerol, i.e. 70%, 86% and 99% purity, that is
obtained from biodiesel plant. Metal oxide catalysts were used with
varying operating parameters including reaction time, DMC/glycerol
molar ratio, catalyst weight %, temperature and stirring speed. From
the study on the effect of different operating parameters it was found
that the type of catalyst used has the most significant effect on the
transesterification reaction. Amidst the metal oxide catalysts
examined, CaO gave the best performance. This study indicates the
feasibility of producing glycerol carbonate using different grade of
glycerol in both conventional thermal activation and microwave
irradiation with CaO as catalyst. Microwave assisted
transesterification (MAT) of glycerol into glycerol carbonate has
demonstrated itself as an energy efficient route by achieving 94.2%
yield of GC at 65°C, 5 minutes reaction time, 1 wt% CaO and
DMC/glycerol molar ratio of 2. The advantages of MAT
transesterification route has made the direct utilization of bioglycerol
from biodiesel production without the need of purification. This has
marked a more economical and less-energy intensive glycerol
carbonate synthesis route.
Abstract: This paper presents a novel algorithm for modeling
photovoltaic based distributed generators for the purpose of optimal
planning of distribution networks. The proposed algorithm utilizes
sequential Monte Carlo method in order to accurately consider the
stochastic nature of photovoltaic based distributed generators. The
proposed algorithm is implemented in MATLAB environment and
the results obtained are presented and discussed.
Abstract: The present work is aimed at examining carbon steel
oil pipelines corrosion using three natural extracts (Eruca Sativa,
Rosell and Mango peels) that are used as inhibitors of different
concentrations ranging from 0.05-0.1wt. %. Two sulphur compounds
are used as corrosion mediums. Weight loss method was used for
measuring the corrosion rate of the carbon steel specimens immersed
in technical white oil at 100ºC at various time intervals in absence
and presence of the two sulphur compounds. The corroded specimens
are examined using the chemical wear test, scratch test and hardness
test. The scratch test is carried out using scratch loads from 0.5 Kg to
2.0 Kg. The scratch width is obtained at various scratch load and test
conditions. The Brinell hardness test is carried out and investigated
for both corroded and inhibited specimens. The results showed that
three natural extracts can be used as environmentally friendly
corrosion inhibitors.
Abstract: In order to help the expert to validate association rules
extracted from data, some quality measures are proposed in the
literature. We distinguish two categories: objective and subjective
measures. The first one depends on a fixed threshold and on data
quality from which the rules are extracted. The second one consists
on providing to the expert some tools in the objective to explore and
visualize rules during the evaluation step. However, the number of
extracted rules to validate remains high. Thus, the manually mining
rules task is very hard. To solve this problem, we propose, in this
paper, a semi-automatic method to assist the expert during the
association rule's validation. Our method uses rule-based
classification as follow: (i) We transform association rules into
classification rules (classifiers), (ii) We use the generated classifiers
for data classification. (iii) We visualize association rules with their
quality classification to give an idea to the expert and to assist him
during validation process.
Abstract: Background: Muscle Energy Techniques (MET) have
been widely used by manual therapists over the past years, but still
limited research validated its use and there was limited evidence to
substantiate the theories used to explain its effects. Objective: To
investigate the effect of Muscle Energy Technique (MET) on anterior
pelvic tilt in patients with lumbar spondylosis. Design: Randomized
controlled trial. Subjects: Thirty patients with anterior pelvic tilt from
both sexes were involved, aged between 35 to 50 years old and they
were divided into MET and control groups with 15 patients in each.
Methods: All patients received 3sessions/week for 4 weeks where the
study group received MET, Ultrasound and Infrared, and the control
group received U.S and I.R only. Pelvic angle was measured by
palpation meter, pain severity by the visual analogue scale and
functional disabilities by the Oswestry disability index. Results: Both
groups showed significant improvement in all measured variables.
The MET group was significantly better than the control group in
pelvic angle, pain severity, and functional disability as p-value were
(0.001, 0.0001, 0.0001) respectively. Conclusion and implication: the
study group fulfilled greater improvement in all measured variables
than the control group which implies that application of MET in
combination with U.S and I.R were more effective in improving
pelvic tilting angle, pain severity and functional disabilities than
using electrotherapy only.
Abstract: Significant attention has recently been paid to the
cross-cultural negotiations due to the growth of international
businesses. Despite the substantial body of literature examining the
influence of National Culture (NC) dimensions on negotiations, there
is a lack of studies comparing the influence of NC in Latin America
with a Western European countries, In particular, an extensive review
of the literature revealed that a contribution to knowledge would be
derived from the comparison of the influence of NC dimensions on
negotiations in UK and Venezuela. The primary data was collected
through qualitative interviews, to obtain an insight about the
perceptions and beliefs of Venezuelan and British business managers
about their negotiating styles. The findings of this study indicated
that NC has a great influence on the negotiating styles. In particular,
Venezuelan and British managers demonstrated to have opposed
negotiating styles, affecting the way they communicate, approach
people and their willingness to take risks.
Abstract: Lead time is a critical measure of a supply chain's
performance. It impacts both the customer satisfactions as well as the
total cost of inventory. This paper presents the result of a study on the
analysis of the customer order lead-time for a multinational company.
In the study, the lead time was divided into three stages respectively:
order entry, order fulfillment, and order delivery. A sample of size 2,425 order lines was extracted from the
company's records to use for this study. The sample data entails
information regarding customer orders from the time of order entry
until order delivery. Data regarding the lead time of each stage for
different orders were also provided. Summary statistics on lead time
data reveals that about 30% of the orders were delivered later than the
scheduled due date. The result of the multiple linear regression
analysis technique revealed that component type, logistics parameter,
order size and the customer type have significant impacts on lead
time. Data analysis on the stages of lead time indicates that stage 2
consumed over 50% of the lead time. Pareto analysis was made to
study the reasons for the customer order delay in each stage.
Recommendation was given to resolve the problem.
Abstract: This paper presents a state-of-the-art survey of the
operations research models developed for internal audit planning.
Two alternative approaches have been followed in the literature for
audit planning: (1) identifying the optimal audit frequency; and (2)
determining the optimal audit resource allocation. The first approach
identifies the elapsed time between two successive audits, which can
be presented as the optimal number of audits in a given planning
horizon, or the optimal number of transactions after which an audit
should be performed. It also includes the optimal audit schedule. The
second approach determines the optimal allocation of audit frequency
among all auditable units in the firm. In our review, we discuss both
the deterministic and probabilistic models developed for audit
planning. In addition, game theory models are reviewed to find the
optimal auditing strategy based on the interactions between the
auditors and the clients.
Abstract: Background: The change in foot posture can possibly
generate changes in the pelvic alignment. There is still a lack of
evidence about the effects of bilateral and unilateral flatfoot on
possible changes in pelvic alignment. The purpose of this study was
to investigate the effect of flatfoot on the sagittal and frontal planes of
pelvic postures. Materials and Methods: 56 subjects, aged 18–40
years, were assigned into three groups: 20 healthy subjects, 19
subjects with bilateral flexible second-degree flat foot, and 17
subjects with unilateral flexible second-degree flat foot. 3D
assessment of the pelvis using the formetric-II device was used to
evaluate pelvic alignment in the frontal and sagittal planes by
measuring pelvic inclination and pelvic tilt angles. Results: ANOVA
test with LSD test were used for statistical analysis. Both Unilateral
and bilateral second degree flatfoot produced significant (P
Abstract: The environmental, cultural, social, and technological
changes have led higher education institutes to question their
traditional roles. Many declarations and frameworks highlight the
importance of fulfilling social responsibility of higher education
institutes. The study aims at developing a framework of university
social responsibility and sustainability (USR&S) with focus on South
Valley University (SVU) as a case study of Egyptian Universities.
The study used meetings with 12 vice deans of community services
and environmental affairs on social responsibility and environmental
issues. The proposed framework integrates social responsibility with
strategic management through the establishment and maintenance of
the vision, mission, values, goals and management systems;
elaboration of policies; provision of actions; evaluation of services
and development of social collaboration with stakeholders to meet
current and future needs of the community and environment. The
framework links between different stakeholders internally and
externally using communication and reporting tools. The results show
that SVU integrates social responsibility and sustainability in its
strategic plans. It has policies and actions however fragmented and
lack of appropriate structure and budgeting. The proposed framework
could be valuable for researchers and decision makers of the
Egyptian Universities. The study proposed recommendations and
highlighted building on the results and conducting future research.
Abstract: Background: Delayed onset muscle soreness (DOMS)
is the most common symptom when ordinary individuals and athletes
are exposed to unaccustomed physical activity, especially eccentric
contraction which impairs athletic performance, ordinary people
work ability and physical functioning. Multitudes of methods have
been investigated to reduce DOMS. One of the valuable methods to
control DOMS is repeated bout effect (RBE) as a prophylactic
method. Purpose: To compare the repeated bout effect of
submaximal eccentric with maximal isometric contraction on induced
DOMS. Methods: Sixty normal male volunteers were assigned
randomly into three equal groups: Group A (first study group): 20
subjects received submaximal eccentric contraction on non-dominant
elbow flexors as a prophylactic exercise. Group B (second study
group): 20 subjects received maximal isometric contraction on nondominant
elbow flexors as a prophylactic exercise. Group C (control
group): 20 subjects did not receive any prophylactic exercises.
Maximal isometric peak torque of elbow flexors and patient related
elbow evaluation (PREE) scale were measured for each subject 3
times before, immediately after, and 48 hours after induction of
DOMS. Results: Post-hoc test for maximal isometric peak torque and
PREE scale immediately and 48 hours after induction of DOMS
revealed that group (A) and group (B) resulted in significant decrease
in maximal isometric strength loss and elbow pain and disability
rather than control group (C), but submaximal eccentric group (A)
was more effective than maximal isometric group (B) as it showed
more rapid recovery of functional strength and less degrees of elbow
pain and disability. Conclusion: Both submaximal eccentric
contraction and maximal isometric contraction were effective in
prevention of DOMS but submaximal eccentric contraction produced
a greater protective effect against muscle damage induced by
maximal eccentric exercise performed 2 days later.
Abstract: This study aimed to determine the possible protective effects of L‐carnitine against gentamicin‐induced nephrotoxicity. Forty male albino rats were divided into 4 groups (10 rats each); Group 1: normal control, group 2: induced nephrotoxicity (gentamicin 50 mg/kg/day S.C; 8 days), group 3: treated with L‐ carnitine (40 mg/kg/d SC for 12 days) and group 4: treated with L‐ carnitine 4 days before and for 8 days in concomitant with gentamicin. Gentamicin‐induced nephrotoxicity (group 2): caused significant increase in serum urea, creatinine, urinary N‐acetyl‐B‐D‐ glucosaminidase (NAG), gamma glutamyl transpeptidase (GGT), urinary total protein and kidney tissue malondialdehyde (MDA) with significant decrease in serum superoxide dismutase (SOD), serum catalase and creatinine clearance and marked tubular necrosis in the proximal convoluted tubules with interruption in the basement membrane around the necrotic tubule compared to the normal control group. L‐carnitine 4 days before and for 8 days in concomitant with gentamicin (group 4) offered marked decrease in serum urea, serum creatinine, urinary NAG, urinary GGT, urinary proteins and kidney tissue MDA, with marked increase in serum SOD, serum catalase and creatinine clearance with marked improvement in the tubular damage compared to gentamicin‐induced nephrotoxicity group. L‐carnitine administered for 12 days produced no change in the parameters mentioned above as compared to the normal control group. In conclusion: L‐carnitine could reduce most of the biochemical parameters and also improve the histopathological features of kidney asscociated with gentamicin induced‐nephrotoxicity.
Abstract: The purpose of this study is to determine whether paper assessment especially in the subject mathematics will ever be completely replaced by online assessment using Learning Management System and Content Management System such as blackboard. Testing students has moved from the traditional scribbling and sketching on paper towards working online on a screen and keyboard. It is found that online assessment by using selective types of questions like multiple choices, true or false and final answer questions don’t reflect the actual understanding of students in solving the problems and teachers can’t determine the weakness points of students. In addition, it is showed that OBMCQs are a very good tool for self-assessment and when teachers are testing for knowledge and facts. But when it comes to the skills, OBMCQs are poor tools for measuring the ability to apply knowledge to complex math problem.
Abstract: Al6061 alloy base matrix, reinforced with particles of
silicon carbide (10 wt %) and Graphite powder (1wt%), known as
hybrid composites have been fabricated by liquid metallurgy route
(stir casting technique) and optimized at different parameters like
applied load, sliding speed and sliding distance by taguchi method. A
plan of experiment generated through taguchi technique was used to
perform experiments based on L27 orthogonal array. The developed
ANOVA and regression equations are used to find the optimum
coefficient of friction and wear under the influence of applied load,
sliding speed and sliding distance. On the basis of “smaller the best”
the dry sliding wear resistance was analysed and finally confirmation
tests were carried out to verify the experimental results.
Abstract: The capability of exploiting the electronic charge and
spin properties simultaneously in a single material has made diluted
magnetic semiconductors (DMS) remarkable in the field of
spintronics. We report the designing of DMS based on zinc-blend
ZnO doped with Cr impurity. The full potential linearized augmented
plane wave plus local orbital FP-L(APW+lo) method in density
functional theory (DFT) has been adapted to carry out these
investigations. For treatment of exchange and correlation energy,
generalized gradient approximations have been used. Introducing Cr
atoms in the matrix of ZnO has induced strong magnetic moment
with ferromagnetic ordering at stable ground state. Cr:ZnO was found
to favor the short range magnetic interaction that
reflect tendency of Cr clustering. The electronic structure of ZnO is
strongly influenced in the presence of Cr impurity atoms where
impurity bands appear in the band gap.
Abstract: In this paper, the effects of fiber types and elevated
temperatures on compressive strength, modulus of rapture and the
bond characteristics of fiber reinforced concretes (FRC) are
presented. By using the three different types of fibers (steel fiber-SF,
polypropylene-PPF and polyvinyl alcohol-PVA), FRC specimens
were produced and exposed to elevated temperatures up to 800 ºC for
1.5 hours. In addition, a plain concrete (without fiber) was produced
and used as a control. Test results obtained showed that the steel fiber
reinforced concrete (SFRC) had the highest compressive strength,
modulus of rapture and bond stress values at room temperatures, the
residual bond, flexural and compressive strengths of both FRC and
plain concrete dropped sharply after exposure to high temperatures.
The results also indicated that the reduction of bond, flexural and
compressive strengths with increasing the exposed temperature was
relatively less for SFRC than for plain, and FRC with PPF and PVA.
Abstract: Depositional environment and source potential of the
different organic-rich levels of Devonian age (up to 990m thick) from
the onshore EC-1 well (Southern Tunisia) were investigated based on
the analysis of more than 130 cutting samples by different
geochemical techniques (Rock-Eval pyrolysis, GC-MS). The
obtained results including Rock Eval Pyrolysis data and biomarker
distribution (terpanes, steranes and aromatics) have been used to
describe the depositional environment and to assess the thermal
maturity of the Devonian organic matter. These results show that the
Emsian deposits exhibit poor to fair TOC contents. The associated
organic matter is composed of mixed kerogen (type II/III), as
indicated by the predominance of C29 steranes over C27 and C28
homologous, that was deposited in a slightly reduced environment
favoring organic matter preservation. Thermal maturity assessed from
Tmax, TNR and MPI-1 values shows a mature stage of organic
matter. The Middle Devonian (Eifelian) shales are rich in type II
organic matter that was deposited in an open marine depositional
environment. The TOC values are high and vary between 2 and 7%
indicating good to excellent source rock. The relatively high HI
values (reaching 547 mg HC/g TOC) and the low values of t19/t23
tricyclic terpane ratio (< 0.2) confirm the marine origin of the organic
matter (type II). During the Upper Devonian, the organic matter was
deposited under variable redox conditions, oxic to suboxic which is
clearly indicated by the low C35/C34 hopanes ratio, immature to
marginally mature with the vitrinite reflectance ranging from 0.5 to
0.7 Ro and Tmax value of 426°C-436 °C and the TOC values range
between 0.8% to 4%.
Abstract: Experimental study of natural convection heat transfer
inside smooth and rough surfaces of vertical and inclined equilateral
triangular channels of different inclination angles with a uniformly
heated surface are performed. The inclination angle is changed from
15º to 90º. Smooth and rough surface of average roughness (0.02mm)
are used and their effect on the heat transfer characteristics are
studied. The local and average heat transfer coefficients and Nusselt
number are obtained for smooth and rough channels at different heat
flux values, different inclination angles and different Rayleigh
numbers (Ra) 6.48 × 105 ≤ Ra ≤ 4.78 × 106. The results show that
the local Nusselt number decreases with increase of axial distance
from the lower end of the triangular channel to a point near the upper
end of channel, and then, it slightly increases. Higher values of local
Nusselt number for rough channel along the axial distance compared
with the smooth channel. The average Nusselt number of rough
channel is higher than that of smooth channel by about 8.1% for
inclined case at θ = 45o and 10% for vertical case. The results
obtained are correlated using dimensionless groups for both rough
and smooth surfaces of the inclined and vertical triangular channels.
Abstract: The introduction of degradable plastic materials into
agricultural sectors has represented a promising alternative to
promote green agriculture and environmental friendly of modern
farming practices. Major challenges of developing degradable
agricultural films are to identify the most feasible types of
degradation mechanisms, composition of degradable polymers and
related processing techniques. The incorrect choice of degradable
mechanisms to be applied during the degradation process will cause
premature losses of mechanical performance and strength. In order to
achieve controlled process of agricultural film degradation, the
compositions of degradable agricultural film also important in order
to stimulate degradation reaction at required interval of time and to
achieve sustainability of the modern agricultural practices. A set of
photodegradable polyethylene based agricultural film was developed
and produced, following the selective optimization of processing
parameters of the agricultural film manufacturing system. Example of
agricultural films application for oil palm seedlings cultivation is
presented.
Abstract: Rice husk and kenaf filled with calcium carbonate
(CaCO3) and high density polyethylene (HDPE) composite were
prepared separately using twin-screw extruder at 50rpm. Different
filler loading up to 30 parts of rice husk particulate and kenaf fiber
were mixed with the fixed 30% amount of CaCO3 mineral filler to
produce rice husk/CaCO3/HDPE and kenaf/CaCO3/HDPE hybrid
composites. In this study, the effects of natural fiber for both rice
husk and kenaf in CaCO3/HDPE composite on physical, mechanical
and morphology properties were investigated. Field Emission
Scanning Microscope (FeSEM) was used to investigate the impact
fracture surfaces of the hybrid composite. The property analyses
showed that water absorption increased with the presence of kenaf
and rice husk fillers. Natural fibers in composite significantly
influence water absorption properties due to natural characters of
fibers which contain cellulose, hemicellulose and lignin structures.
The result showed that 10% of additional natural fibers into hybrid
composite had caused decreased flexural strength, however additional
of high natural fiber (>10%) filler loading has proved to increase its
flexural strength.