Abstract: The transesterification of dimethyl malonate (DMM)
with phenol has been studied in vapour phase over cordierite
honeycomb coated with solid acid catalysts such as ZrO2,
Mo(VI)/ZrO2 and SO42-/ZrO2. The catalytic materials were prepared
honeycomb coated, powder forms, and characterized for their total
surface acidity by NH3-TPD and crystalinity by powder XRD
methods. Phenyl methyl malonate (PMM) and diphenyl malonate
(DPM) were obtained as the reaction products. A good conversion of
DMM (up to 82%) of MPM with 95% selectivity was observed when
the reactions were carried out at a catalyst bed temperature of 200 °C
and flow-rate of 10 mL/h in presence of Mo(VI)/ZrO2 as catalyst.
However, over SO4^2-/ZrO2 catalyst, the yield of DPM was found to be
higher. The results have been interpreted based on the variation of
acidic properties and powder XRD phases of zirconia on
incorporation of Mo(VI) or SO42– ions. Transesterification reactions
were also carried out over powder forms of the catalytic materials
and the yield of the desired phenyl ester products were compared
with that of the HC coated catalytic materials. The solid acids were
found to be reusable when used for at least 5 reaction cycles.
Abstract: Considering the challenges of short product life cycles
and growing variant diversity, cost minimization and manufacturing
flexibility increasingly gain importance to maintain a competitive
edge in today’s global and dynamic markets. In this context, an
aerodynamic part feeding system for high-speed industrial assembly
applications has been developed at the Institute of Production
Systems and Logistics (IFA), Leibniz Universitaet Hannover. The
aerodynamic part feeding system outperforms conventional systems
with respect to its process safety, reliability, and operating speed. In
this paper, a multi-objective optimisation of the aerodynamic feeding
system regarding the orientation rate, the feeding velocity, and the
required nozzle pressure is presented.
Abstract: Durian skin is a newly explores natural fibre
potentially reinforced polyolefin for diverse applications. In this
work, investigation on the effect of coupling agent, maleic anhydride
polypropylene (MAPP) on the mechanical, morphological, and
thermal properties of polypropylene (PP) reinforced with durian skin
fibre (DSF) was conducted. The presence of 30 wt% DSF
significantly reduced the tensile strength of PP-DSF composite.
Interestingly, even though the same trend goes to PP-DSF with the
presence of MAPP, the reduction is only about 4% relative to
unreinforced PP and 18% higher than PP-DSF without MAPP
(untreated composite or UTC). The used of MAPP in treated
composite (TC) also increased the tensile modulus, flexural
properties and degradation temperature. The enhanced mechanical
properties are consistent with good interfacial interaction as
evidenced under scanning electron microscopy.
Abstract: Much of the literature on research design has focused
on research conducted in developed, uni-cultural or primarily English
speaking countries. Studies of qualitative case study research, the
challenges, and prospects have been embedded in Western/Eurocentric
society and social theories. Although there have been some
theoretical studies, few empirical studies have been conducted to
explore the nature of the challenges of qualitative case study in
developing countries. These challenges include accessibility to
organizations, conducting interviews in developing countries,
accessing documents and observing official meetings, language and
cultural challenges, the use of consent forms, issues affecting access
to companies, respondent issues, and data analysis. The author, while
conducting qualitative case study research in Libya, faced all these
issues. The discussion in this paper examines these issues in order to
make a contribution toward the literature in this area.
Abstract: We have studied the temporal characteristics of
bistable perception of the stimuli of two types: one involves
alterations in a perceived depth and another one has an ambiguous
content. We used the Necker lattice and lines of shadowed circles
ambiguously perceived either as spheres or holes as stimuli of the
first type. The Winson figure (the Eskimo/Indian picture) was a
stimulus of the second type. We have analyzed how often the
reversals occurred (reversal rate) and for how long each of the two
interpretations, or percepts, was observed during one presentation
(stability durations). For all three ambiguous images the reversal rate
and the stability durations had similar values, which provide another
evidence for a significant role of top-down processes in multistable
perception.
Abstract: Concurrent planning of project scheduling and
material ordering has been increasingly addressed within last decades
as an approach to improve the project execution costs. Therefore, we
have taken the problem into consideration in this paper, aiming to
maximize schedules quality robustness, in addition to minimize the
relevant costs. In this regard, a bi-objective mathematical model is
developed to formulate the problem. Moreover, it is possible to
utilize the all-unit discount for materials purchasing. The problem is
then solved by the E-constraint method, and the Pareto front is
obtained for a variety of robustness values. The applicability and
efficiency of the proposed model is tested by different numerical
instances, finally.
Abstract: Production fluids are transported from the platform to
tankers or process facilities through transfer pipelines. Water being
one of the heavier phases tends to settle at the bottom of pipelines
especially at low flow velocities and this has adverse consequences
for pipeline integrity. On restart after a shutdown, this could result in
corrosion and issues for process equipment, thus the need to have the
heavier liquid dispersed into the flowing lighter fluid. This study
looked at the flow regime of low water cut and low flow velocity oil
and water flow using conductive film thickness probes in a large
diameter 4-inch pipe to obtain oil and water interface height and the
interface structural velocity. A wide range of 0.1–1.0 m/s oil and
water mixture velocities was investigated for 0.5–5% water cut. Two
fluid model predictions were used to compare with the experimental
results.
Abstract: Poverty alleviation is one of the most difficult
challenges facing third world countries in their development efforts.
Evidences in Nigeria showed that the number of those in poverty has
continued to increase. This paper is aimed at analyzing the
performance of poverty alleviation measures undertaken by
successive administrations in Nigeria with a view to addressing the
quagmire. The study identified the whole gamut of factors that served
as stumbling blocks to the implementation of each of the strategies
and recommended the involvement of local people in the
identification and design of projects so that sufficient participation
could be achieved.
Abstract: The modelling of physical phenomena, such as the
earth’s free oscillations, the vibration of strings, the interaction of
atomic particles, or the steady state flow in a bar give rise to Sturm-
Liouville (SL) eigenvalue problems. The boundary applications of
some systems like the convection-diffusion equation, electromagnetic
and heat transfer problems requires the combination of Dirichlet and
Neumann boundary conditions. Hence, the incorporation of Robin
boundary condition in the analyses of Sturm-Liouville problem. This
paper deals with the computation of the eigenvalues and
eigenfunction of generalized Sturm-Liouville problems with Robin
boundary condition using the finite element method. Numerical
solution of classical Sturm–Liouville problem is presented. The
results show an agreement with the exact solution. High results
precision is achieved with higher number of elements.
Abstract: The aim of this work is to detect geometrical shape
objects in an image. In this paper, the object is considered to be as a
circle shape. The identification requires find three characteristics,
which are number, size, and location of the object. To achieve the
goal of this work, this paper presents an algorithm that combines
from some of statistical approaches and image analysis techniques.
This algorithm has been implemented to arrive at the major
objectives in this paper. The algorithm has been evaluated by using
simulated data, and yields good results, and then it has been applied
to real data.
Abstract: This research was made during the 2015 growing
periods in the trial filed of "Research Station for Department of Field
Crops, Agricultural Faculty, Selcuk University" according to
“Randomized Blocks Design” with 3 replications. Research material
was the following pea lines; PS16, PS18, PS21, PS23, PS24, PS25,
PS36, PS47, PS49, PS51, PS54, PS58, PS67, PS69, PS71, PS73,
PS83, PS84, PS87 and PSKY and three cultivars and other 2
commercial varieties named as Bolero, Rondo and Ultrello. Some
agronomical characteristics such as plant height (cm) number of pod
per plant number of seed per pod number of seed per plant 100 seed
weight (g) and seed yield (kg ha-1) were determined. The highest seed
yield was obtained 2727.0 kg ha-1 in the PS71 line and the lowest
value was obtained 1238.0 kg ha-1 in the commercial variety of
Bolero. Results of the research implicated that the new developed
lines were superior compared with the control (commercial) varieties
by means of most of the characteristics. Nevertheless, similar
researches should be continued in different locations and years.
Abstract: The underutilization of biomass resources in the
Philippines, combined with its growing population and the rise in
fossil fuel prices confirms demand for alternative energy sources. The
goal of this paper is to provide a comparison of MODIS-based and
Landsat-based agricultural land cover maps when used in the
estimation of rice hull’s available energy potential. Biomass resource
assessment was done using mathematical models and remote sensing
techniques employed in a GIS platform.
Abstract: This research work presents the surface
thermodynamics approach to M-TB/HIV-Human sputum
interactions. This involved the use of the Hamaker coefficient
concept as a surface energetics tool in determining the interaction
processes, with the surface interfacial energies explained using van
der Waals concept of particle interactions. The Lifshitz derivation for
van der Waals forces was applied as an alternative to the contact
angle approach which has been widely used in other biological
systems. The methodology involved taking sputum samples from
twenty infected persons and from twenty uninfected persons for
absorbance measurement using a digital Ultraviolet visible
Spectrophotometer. The variables required for the computations with
the Lifshitz formula were derived from the absorbance data. The
Matlab software tools were used in the mathematical analysis of the
data produced from the experiments (absorbance values). The
Hamaker constants and the combined Hamaker coefficients were
obtained using the values of the dielectric constant together with the
Lifshitz Equation. The absolute combined Hamaker coefficients
A132abs and A131abs on both infected and uninfected sputum samples
gave the values of A132abs = 0.21631x10-21Joule for M-TB infected
sputum and Ã132abs = 0.18825x10-21Joule for M-TB/HIV infected
sputum. The significance of this result is the positive value of the
absolute combined Hamaker coefficient which suggests the existence
of net positive van der waals forces demonstrating an attraction
between the bacteria and the macrophage. This however, implies that
infection can occur. It was also shown that in the presence of HIV,
the interaction energy is reduced by 13% conforming adverse effects
observed in HIV patients suffering from tuberculosis.
Abstract: Education and practical training crisis management
members are a topical issue nowadays. The paper deals with the
perspectives and possibilities of "smart solutions" to education for
crisis management staff. Currently, there is a large number of
simulation tools, which notes that they are suitable for practical
training of crisis management staff. The first part of the paper is focused on the introduction of the
technology simulation tools. The simulators aim is to create a
realistic environment for the practical training of extending units of
crisis staff. The second part of the paper concerns the possibilities of using the
simulation technology to the education process. The aim of this
section is to introduce the practical capabilities and potential of the
simulation programs for practical training of crisis management staff.
Abstract: This study aims to examine the sensory quality of
meatballs made from Balinese beef and buffalo meat after the
addition of smoke powder prior to storage at the temperatures of 2-
5°C for 7 days. This study used meat from Longissimus dorsi muscle
of male Balinese cattle aged 3 years and of male buffalo aged 5 years
as the main raw materials, and smoke powder as a binder and
preservative in making meatballs. The study was based on completely
randomized design (CRD) of factorial pattern of 2 x 3 x 2 where
factors 1, 2 and 3 included the types of meat (cattle and buffalo),
types of smoke powder (oven dried, freeze dried and spray dried)
with a level of 2% of the weight of the meat (w/w), and storage
duration (0 and 7 days) with three replications, respectively. The
parameters measured were the meatball sensory quality (scores of
tenderness, firmness, chewing residue, and intensity of flavor). The
results of this study show that each type of meat has produced
different sensory characteristics. The meatballs made from buffalo
meat have higher tenderness and elasticity scores than the Balinese
beef. Meanwhile, the buffalo meatballs have a lower residue
mastication score than the Balinese beef. Each type of smoke
powders has produced a relatively similar sensory quality of
meatballs. It can be concluded that the smoke powder of 2% of the
weight of the meat (w/w) could maintain the sensory quality of the
meatballs for 7 days of storage.
Abstract: Finding the optimal 3D path of an aerial vehicle under
flight mechanics constraints is a major challenge, especially when
the algorithm has to produce real time results in flight. Kinematics
models and Pythagorian Hodograph curves have been widely used
in mobile robotics to solve this problematic. The level of difficulty
is mainly driven by the number of constraints to be saturated at the
same time while minimizing the total length of the path. In this paper,
we suggest a pragmatic algorithm capable of saturating at the same
time most of dimensioning helicopter 3D trajectories’ constraints
like: curvature, curvature derivative, torsion, torsion derivative, climb
angle, climb angle derivative, positions. The trajectories generation
algorithm is able to generate versatile complex 3D motion primitives
feasible by a helicopter with parameterization of the curvature and the
climb angle. An upper ”motion primitives’ concatenation” algorithm
is presented based. In this article we introduce a new way of designing
three-dimensional trajectories based on what we call the ”Dubins
gliding symmetry conjecture”. This extremely performing algorithm
will be soon integrated to a real-time decisional system dealing with
inflight safety issues.
Abstract: The photovoltaic and the semiconductor industries are
in growth and it is necessary to supply a large amount of silicon to
maintain this growth. Since silicon is still the best material for the
manufacturing of solar cells and semiconductor components so the
pure silicon like solar grade and semiconductor grade materials are
demanded. There are two main routes for silicon production:
metallurgical and chemical. In this article, we reviewed the
electrotecnological installations and systems for semiconductor
manufacturing. The main task is to design the installation which can
produce SOG Silicon from river sand by one work unit.
Abstract: In Algeria, the conditioning units of dates, generate
significant quantities of waste arising from sorting deviations. This
biomass, until then considered as a waste with high impact on the
environment can be transformed into high value added product. It is
possible to develop common dates of low commercial value, and put
on the local and international market a new generation of products
with high added values such as bio ethanol. Besides its use in
chemical synthesis, bio ethanol can be blended with gasoline to
produce a clean fuel while improving the octane.
Abstract: A number of studies have been conducted recently to
investigate the influence of randomly oriented fibers on some
engineering properties of cohesive and cohesionless soils. However,
few studies have been carried out on freezing-thawing behavior of
fine-grained soils modified with discrete fiber inclusions and additive
materials. This experimental study was performed to investigate the
effect of randomly distributed polypropylene fibers (PP) and some
additive materials [e.g.., borogypsum (BG), fly ash (FA) and cement
(C)] on freezing-thawing durability (mass losses) of a fine-grained
soil for 6, 12, and 18 cycles. The Taguchi method was applied to the
experiments and a standard L9 orthogonal array (OA) with four
factors and three levels were chosen. A series of freezing-thawing
tests were conducted on each specimen. 0-20% BG, 0-20% FA, 0-
0.25% PP and 0-3% of C by total dry weight of mixture were used in
the preparation of specimens. Experimental results showed that the
most effective materials for the freezing-thawing durability (mass
losses) of the samples were borogypsum and fly ash. The values of
mass losses for 6, 12 and 18 cycles in optimum conditions were
16.1%, 5.1% and 3.6%, respectively.
Abstract: Geological and tectonic framework indicates that
Bangladesh is one of the most seismically active regions in the world.
The Bengal Basin is at the junction of three major interacting plates:
the Indian, Eurasian, and Burma Plates. Besides there are many
active faults within the region, e.g. the large Dauki fault in the north.
The country has experienced a number of destructive earthquakes due
to the movement of these active faults. Current seismic provisions of
Bangladesh are mostly based on earthquake data prior to the 1990.
Given the record of earthquakes post 1990, there is a need to revisit
the design provisions of the code. This paper compares the base shear
demand of three major cities in Bangladesh: Dhaka (the capital city),
Sylhet, and Chittagong for earthquake scenarios of magnitudes
7.0MW, 7.5MW, 8.0MW, and 8.5MW using a stochastic model. In
particular, the stochastic model allows the flexibility to input region
specific parameters such as shear wave velocity profile (that were
developed from Global Crustal Model CRUST2.0) and include the
effects of attenuation as individual components. Effects of soil
amplification were analysed using the Extended Component
Attenuation Model (ECAM). Results show that the estimated base
shear demand is higher in comparison with code provisions leading to
the suggestion of additional seismic design consideration in the study
regions.