Abstract: In countries with hot climates, air-conditioning forms
a large proportion of annual peak electrical demand, requiring
expansion of power plants to meet the peak demand, which goes
unused most of the time. Use of well-designed cool storage can offset
the peak demand to a large extent. In this study, an air conditioning
system with naturally stratified storage tank was designed,
constructed and tested. A new type of diffuser was designed and used
in this study. Factors that influence the performance of chilled water
storage tanks were investigated. The results indicated that stratified
storage tank consistently stratified well without any physical barrier.
Investigation also showed that storage efficiency decreased with
increasing flow rate due to increased mixing of warm and chilled
water. Diffuser design and layout primarily affected the mixing near
the inlet diffuser and the extent of this mixing had primary influence
on the shape of the thermocline. The heat conduction through tank
walls and through the thermocline caused widening of mixed volume.
Thermal efficiency of stratified storage tanks was as high as 90
percent, which indicates that stratified tanks can effectively be used
as a load management technique.
Abstract: Dew harvesting needs only weak investment and
exploits a free, clean and inexhaustible energy. This study aims to
measure the relative contributions of dew and rain water in the
Mediterranean Dalmatian coast and islands of Croatia and determine
whether dew water is potable. Two sites were chosen, an open site on
the coast favourable to dew formation (Zadar) and a less favourable
site in a circus of mountains in Komiža (Vis Island). Between July
1st, 2003 and October 31st, 2006, dew hasbeen daily collected on a 1
m2 tilted (30°) test dew condenser together with ordinary
meteorological data (air temperature and relative humidity, cloud
coverage, windspeed and direction). The mean yearly cumulative
dew yields were found to be 20 mm (Zadar) and 9.3 mm (Komiža ).
During the dry season (May to October), monthly cumulative dew
water yield can represent up to 38% of water collected by rain fall. In
July 2003 and 2006, dew water represented about 120% of the
monthly cumulative rain water. Dew and rain water were analyzed in
Zadar. The corresponding parameters were measured: pH, electrical
conductivity, major anions (HCO3
-, Cl-, SO4
2-
, NO3
-
, ,) and major
cations (NH4
+, Na+, K+, Ca2+, Mg2+. Both dew and rain water are in
conformity with the WHO directives for potability except Mg2+.
Using existing roofs and refurbishing the abandoned impluviums to
permit dew collection could then provide a useful supplementary
amount of water, especially during the dry season.
Abstract: The distillation process in the general sense is a
relatively simple technique from the standpoints of its principles.
When dedicating distillation to water treatment and specifically
producing fresh water from sea, ocean and/ briny waters it is
interesting to notice that distillation has no limitations or domains of
applicability regarding the nature or the type of the feedstock water.
This is not the case however for other techniques that are
technologically quite complex, necessitate bigger capital investments
and are limited in their usability. In a previous paper we have
explored some of the effects of temperature on yield. In this paper,
we continue building onto that knowledge base and focus on the
effects of several additional engineering and design variables on
productivity.
Abstract: The effects of irrigation with dairy factory wastewater
on soil properties were investigated at two sites that had received
irrigation for > 60 years. Two adjoining paired sites that had never
received DFE were also sampled as well as another seven fields from
a wider area around the factory. In comparison with paired sites that
had not received effluent, long-term wastewater irrigation resulted in
an increase in pH, EC, extractable P, exchangeable Na and K and
ESP. These changes were related to the use of phosphoric acid,
NaOH and KOH as cleaning agents in the factory. Soil organic C
content was unaffected by DFE irrigation but the size (microbial
biomass C and N) and activity (basal respiration) of the soil
microbial community were increased. These increases were
attributed to regular inputs of soluble C (e.g. lactose) present as milk
residues in the wastewater. Principal component analysis (PCA) of
the soils data from all 11sites confirmed that the main effects of DFE
irrigation were an increase in exchangeable Na, extractable P and
microbial biomass C, an accumulation of soluble salts and a liming
effect. PCA analysis of soil bacterial community structure, using
PCR-DGGE of 16S rDNA fragments, generally separated individual
sites from one another but did not group them according to irrigation
history. Thus, whilst the size and activity of the soil microbial
community were increased, the structure and diversity of the
bacterial community remained unaffected.
Abstract: An HPLC-UV analytical method was developed to
determine ethylenediaminetetraacetic acid (EDTA) in dairy
wastewater and surface water. The optimizing separation was achieved
by reversed–phase ion-pair liquid chromatography on a C18 column
using methanol as mobile phase solvent, tetrabutylammonium bromide
as the ion-pair reagent in pH 3.3 formate buffer solution at a flow rate
of 0.9 mL min-1 with a UV detector at 265 nm. No interference of Ca,
Mg or NO3
- was detected. Method performance was evaluated in terms
of linearity, repeatability and reproducibility. The method detection
limit was 5 μg L-1. The contents of EDTA in dairy effluents were 72 ~
261 μg L-1 at a large dairy site. A change of EDTA concentration was
observed downstream of the dairy effluent discharge, but this was well
under the predicted no effect concentration for aquatic ecosystem.
Abstract: Geopolymer cement was evaluated as wellbore sealing material for carbon dioxide geosequestration application. Curing of cement system in saline water and strength testing in triaxial stress state condition under lateral confinement is relevant to primary cementing in CO2 geosequestration wellbore in saline aquifer. Geopolymer cement was cured in saline water (both at ambient conditions for 28 days and heated (60°C) conditions for 12 hours) and tested for triaxial strength at different levels of lateral confinement. Normal water and few other curing techniques were also studied both for geopolymer and API ‘G’ cement. Results reported were compared to evaluate the suitability of saline water for curing of geopolymer cement. Unconfined compression test results showed higher strength for curing in saline water than normal water. Besides, testing strength under lateral confinement demonstrated the material failure behavior from brittle to plastic.
Abstract: Low carbon deep drawing steel DC 01 according to EN 10130-91 was nitrooxidized in dissociated ammonia at 580°C/45 min and consequently oxidised at 380°C/5 min in vapour of distilled water. Material after nitrooxidation had 54 % increase of yield point, 34 % increase of strength and 10-times increased resistance to atmospheric corrosion in comparison to the material before nitrooxidation. The microstructure of treated material consisted of thin ε-phase layer connected to layer containing precipitated massive needle shaped Fe4N - γ' nitrides. This layer passed to a diffusion layer consisting of fine irregular shaped Fe16N2 - α'' nitrides regularly dispersed in ferritic matrix. Fatigue properties were examined under bending load with frequency of 20 kHz and sinusoidal symmetric cycle. The results confirmed positive influence of nitrooxidation on fatigue properties as fatigue limit of treated material was double in comparison to untreated material.
Abstract: Bottle water is getting very popular all through the
world; especially in the gulf countries as the main source of drinking
water. However, concerns over leaching of toxic chemicals are
increasing. In this study, a health risk assessment was conducted in
accordance with the guidelines indicated by United States
Environmental Protection Agency (USEPA). It is conducted based on
leaching of Diethyl Phthalate (DEP) from Polyethylene terephthalate
(PET). The toxicity and exposure assessment of diethyl phthalate was
conducted to characterize its risk on human health. Risk management
is also discussed.
Abstract: The agriculture lignocellulosic by-products are receiving increased attention, namely in the search for filter materials that retain contaminants from water. These by-products, specifically almond and hazelnut shells are abundant in Portugal once almond and hazelnuts production is a local important activity. Hazelnut and almond shells have as main constituents lignin, cellulose and hemicelluloses, water soluble extractives and tannins. Along the adsorption of heavy metals from contaminated waters, water soluble compounds can leach from shells and have a negative impact in the environment. Usually, the chemical characterization of treated water by itself may not show environmental impact caused by the discharges when parameters obey to legal quality standards for water. Only biological systems can detect the toxic effects of the water constituents. Therefore, the evaluation of toxicity by biological tests is very important when deciding the suitability for safe water discharge or for irrigation applications.
The main purpose of the present work was to assess the potential impacts of waters after been treated for heavy metal removal by hazelnut and almond shells adsorption systems, with short term acute toxicity tests.
To conduct the study, water at pH 6 with 25 mg.L-1 of lead, was treated with 10 g of shell per litre of wastewater, for 24 hours. This procedure was followed for each bark. Afterwards the water was collected for toxicological assays; namely bacterial resistance, seed germination, Lemna minor L. test and plant grow. The effect in isolated bacteria strains was determined by disc diffusion method and the germination index of seed was evaluated using lettuce, with temperature and humidity germination control for 7 days. For aquatic higher organism, Lemnas were used with 4 days contact time with shell solutions, in controlled light and temperature. For terrestrial higher plants, biomass production was evaluated after 14 days of tomato germination had occurred in soil, with controlled humidity, light and temperature.
Toxicity tests of water treated with shells revealed in some extent effects in the tested organisms, with the test assays showing a close behaviour as the control, leading to the conclusion that its further utilization may not be considered to create a serious risk to the environment.
Abstract: Since water resources of desert Naein City are very
limited, a approach which saves water resources and meanwhile
meets the needs of the greenspace for water is to use city-s sewage
wastewater. Proper treatment of Naein-s sewage up to the standards
required for green space uses may solve some of the problems of
green space development of the city. The present paper closely
examines available statistics and information associated with city-s
sewage system, and determines complementary stages of sewage
treatment facilities of the city. In the present paper, population, per
capita water use, and required discharge for various greenspace
pieces including different plants are calculated. Moreover, in order to
facilitate the application of water resources, a Crude water
distribution network apart from drinking water distribution network is
designed, and a plan for mixing municipal wells- water with sewage
wastewater in proposed mixing tanks is suggested. Hence, following
greenspace irrigation reform and complementary plan, per capita
greenspace of the city will be increased from current amount of 13.2
square meters to 32 square meters.
Abstract: The study investigated the hydrophilic to hydrophobic
transition of modified polyacrylamide hydrogel with the inclusion of
N-isopropylacrylamide (NIAM). The modification was done by
mimicking micellar polymerization, which resulted in better
arrangement of NIAM chains in the polyacrylamide network. The
degree of NIAM arrangement is described by NH number. The
hydrophilic to hydrophobic transition was measured through the
partition coefficient, K, of Orange II and Methylene Blue in hydrogel
and in water. These dyes were chosen as a model for solutes with
different degree of hydrophobicity. The study showed that the
hydrogel with higher NH values resulted in better solubility of both
dyes. Moreover, in temperature above the lower critical solution
temperature (LCST) of Poly(N-isopropylacrylamide) (PNIAM)also
caused the collapse of NIPAM chains which results in a more
hydrophobic environment that increases the solubility of Methylene
Blue and decreases the solubility of Orange II in the hydrogels with
NIPAM present.
Abstract: In this study arsenate [As(V)] removal from drinking water by coagulation process was investigated. Ferric chloride (FeCl3.6H2O) and ferrous sulfate (FeSO4.7H2O) were used as coagulant. The effects of major operating variables such as coagulant dose (1–30 mg/L) and pH (5.5–9.5) were investigated. Ferric chloride and ferrous sulfate were found as effective and reliable coagulant due to required dose, residual arsenate and coagulant concentration. Optimum pH values for maximum arsenate removal for ferrous sulfate and ferric chloride were found as 8 and 7.5. The arsenate removal efficiency decreased at neutral and acidic pH values for Fe(II) and at the high acidic and high alkaline pH for Fe(III). It was found that the increase of coagulant dose caused a substantial increase in the arsenate removal. But above a certain ferric chloride and ferrous sulfate dosage, the increase in arsenate removal was not significant. Ferric chloride and ferrous sulfate dose above 8 mg/L slightly increased arsenate removal.
Abstract: This study presents the improvement of thermal
performance of heat pipe using copper nanofluid with aqueous
solution of n-Butanol. The nanofluids kept in the suspension of
conventional fluids have the potential of superior heat transfer
capability than the conventional fluids due to their improved thermal
conductivity. In this work, the copper nanofluid which has a 40 nm
size with a concentration of 100 mg/lit is kept in the suspension of
the de-ionized (DI) water and an aqueous solution of n-Butanol and
these fluids are used as a working medium in the heat pipe. The study
discusses about the effect of heat pipe inclination, type of working
fluid and heat input on the thermal efficiency and thermal resistance.
The experimental results are evaluated in terms of its performance
metrics and are compared with that of DI water.
Abstract: Basic ingredients of concrete are cement, fine aggregate, coarse aggregate and water. To produce a concrete of certain specific properties, optimum proportion of these ingredients are mixed. The important factors which govern the mix design are grade of concrete, type of cement and size, shape and grading of aggregates. Concrete mix design method is based on experimentally evolved empirical relationship between the factors in the choice of mix design. Basic draw backs of this method are that it does not produce desired strength, calculations are cumbersome and a number of tables are to be referred for arriving at trial mix proportion moreover, the variation in attainment of desired strength is uncertain below the target strength and may even fail. To solve this problem, a lot of cubes of standard grades were prepared and attained 28 days strength determined for different combination of cement, fine aggregate, coarse aggregate and water. An artificial neural network (ANN) was prepared using these data. The input of ANN were grade of concrete, type of cement, size, shape and grading of aggregates and output were proportions of various ingredients. With the help of these inputs and outputs, ANN was trained using feed forward back proportion model. Finally trained ANN was validated, it was seen that it gave the result with/ error of maximum 4 to 5%. Hence, specific type of concrete can be prepared from given material properties and proportions of these materials can be quickly evaluated using the proposed ANN.
Abstract: A robust AUSM+ upwind discretisation scheme has been developed to simulate multiphase flow using consistent spatial discretisation schemes and a modified low-Mach number diffusion term. The impact of the selection of an interfacial pressure model has also been investigated. Three representative test cases have been simulated to evaluate the accuracy of the commonly-used stiffenedgas equation of state with respect to the IAPWS-IF97 equation of state for water. The algorithm demonstrates a combination of robustness and accuracy over a range of flow conditions, with the stiffened-gas equation tending to overestimate liquid temperature and density profiles.
Abstract: A mathematical model for the hydrodynamics of a
surface water treatment pilot plant was developed and validated by
the determination of the residence time distribution (RTD) for the
main equipments of the unit. The well known models of ideal/real
mixing, ideal displacement (plug flow) and (one-dimensional axial)
dispersion model were combined in order to identify the structure
that gives the best fitting of the experimental data for each equipment
of the pilot plant. RTD experimental results have shown that pilot
plant hydrodynamics can be quite well approximated by a
combination of simple mathematical models, structure which is
suitable for engineering applications. Validated hydrodynamic
models will be further used in the evaluation and selection of the
most suitable coagulation-flocculation reagents, optimum operating
conditions (injection point, reaction times, etc.), in order to improve
the quality of the drinking water.
Abstract: Membrane distillation (MD) is a rising technology for
seawater or brine desalination process. In this work, an air gap
membrane distillation (AGMD) performance was investigated for
aqueous NaCl solution along with natural ground water and seawater.
In order to enhance the performance of the AGMD process in
desalination, that is, to get more flux, it is necessary to study the
effect of operating parameters on the yield of distillate water. The
influence of operational parameters such as feed flow rate, feed
temperature, feed salt concentration, coolant temperature and air gap
thickness on the membrane distillation (MD) permeation flux have
been investigated for low and high salt solution. the natural
application of ground water and seawater over 90 h continuous
operation, scale deposits observed on the membrane surface and
reduction in flux represents 23% for ground water and 60% for
seawater, in 90 h. This reduction was eliminated (less than 14 %) by
acidification of feed water. Hence, promote the research attention in
apply of AGMD for the ground water as well as seawater
desalination over today-s conventional RO operation.
Abstract: 17α-ethinylestradiol (EE2) is a recalcitrant micropollutant which is found in small amounts in municipal wastewater. But these small amounts still adversely affect for the reproductive function of aquatic organisms. Evidence in the past suggested that full-scale WWTPs equipped with nitrification process enhanced the removal of EE2 in the municipal wastewater. EE2 has been proven to be able to be transformed by ammonia oxidizing bacteria (AOB) via co-metabolism. This research aims to clarify the EE2 degradation pattern by different consortium of ammonia oxidizing microorganism (AOM) including AOA (ammonia oxidizing archaea) and investigate contribution between the existing ammonia monooxygenase (AMO) and new synthesized AOM. The result showed that AOA or AOB of N. oligotropha cluster in enriched nitrifying activated sludge (NAS) from 2mM and 5mM, commonly found in municipal WWTPs, could degrade EE2 in wastewater via co-metabolism. Moreover, the investigation of the contribution between the existing ammonia monooxygenase (AMO) and new synthesized AOM demonstrated that the new synthesized AMO enzyme may perform ammonia oxidation rather than the existing AMO enzyme or the existing AMO enzyme may has a small amount to oxidize ammonia.
Abstract: A water reuse system in wetland paddy was simulated
to supply water for industrial in this paper. A two-tank model was employed to represent the return flow of the wetland paddy.Historical data were performed for parameter estimation and model verification. With parameters estimated from the data, the model was then used to simulate a reasonable return flow rate from the wetland
paddy. The simulation results show that the return flow ratio was 11.56% in the first crop season and 35.66% in the second crop
season individually; the difference may result from the heavy rainfall in the second crop season. Under the existent pond with surplus
active capacity, the water reuse ratio was 17.14%, and the water supplementary ratio was 21.56%. However, the pattern of rainfall, the
active capacity of the pond, and the rate of water treatment limit the
volume of reuse water. Increasing the irrigation water, dredging the
depth of pond before rainy season and enlarging the scale of module are help to develop water reuse system to support for the industrial
water use around wetland paddy.
Abstract: A laboratory study on the influence of compactive
effort on expansive black cotton specimens treated with up to 8%
ordinary Portland cement (OPC) admixed with up to 8% bagasse ash
(BA) by dry weight of soil and compacted using the energies of the
standard Proctor (SP), West African Standard (WAS) or
“intermediate” and modified Proctor (MP) were undertaken. The
expansive black cotton soil was classified as A-7-6 (16) or CL using
the American Association of Highway and Transportation Officials
(AASHTO) and Unified Soil Classification System (USCS),
respectively. The 7day unconfined compressive strength (UCS)
values of the natural soil for SP, WAS and MP compactive efforts are
286, 401 and 515kN/m2 respectively, while peak values of 1019,
1328 and 1420kN/m2 recorded at 8% OPC/ 6% BA, 8% OPC/ 2% BA
and 6% OPC/ 4% BA treatments, respectively were less than the
UCS value of 1710kN/m2 conventionally used as criterion for
adequate cement stabilization. The soaked California bearing ratio
(CBR) values of the OPC/BA stabilized soil increased with higher
energy level from 2, 4 and 10% for the natural soil to Peak values of
55, 18 and 8% were recorded at 8% OPC/4% BA 8% OPC/2% BA
and 8% OPC/4% BA, treatments when SP, WAS and MP compactive
effort were used, respectively. The durability of specimens was
determined by immersion in water. Soils treatment at 8% OPC/ 4%
BA blend gave a value of 50% resistance to loss in strength value
which is acceptable because of the harsh test condition of 7 days
soaking period specimens were subjected instead of the 4 days
soaking period that specified a minimum resistance to loss in strength
of 80%. Finally An optimal blend of is 8% OPC/ 4% BA is
recommended for treatment of expansive black cotton soil for use as
a sub-base material.