Abstract: The chemical and physical characteristics of rainwater
harvested from a typical rooftop were progressively studied. The
samples of rainwater collected were analyzed for pH, major ion
concentrations, TDS, turbidity, conductivity. All the Physicochemical
constituents fell within the WHO guideline limits at some points as
rainfall progresses except the pH. All the components of rainwater
quality measured during the study showed higher concentrations
during the early stages of rainfall and reduce as time progresses.
There was a downward trend in terms of pH as rain progressed, with
18% of the samples recording pH below the WHO limit of 6.5-8.0. It
was observed that iron concentration was above the WHO threshold
value of 0.3 mg/l on occasions of heavy rains. The results revealed
that most of physicochemical characteristics of rainwater samples
were generally below the WHO threshold, as such, the rainwater
characteristics showed satisfactory conditions in terms of
physicochemical constituents.
Abstract: This study investigates how AlGaAs/GaAs thin film
solar cells perform under varying global solar spectrum due to the
changes of environmental parameters such as the air mass and the
atmospheric turbidity. The solar irradiance striking the solar cell is
simulated using the spectral irradiance model SMARTS2 (Simple
Model of the Atmospheric Radiative Transfer of Sunshine) for clear
skies on the site of Setif (Algeria). The results show a reduction in the
short circuit current due to increasing atmospheric turbidity, it is
63.09% under global radiation. However increasing air mass leads to
a reduction in the short circuit current of 81.73%. The efficiency
decreases with increasing atmospheric turbidity and air mass.
Abstract: Pollution of the Klip River has caused
microorganisms inhabiting it to develop protective survival
mechanisms. This study isolated and characterized the heavy metal
resistant bacteria in the Klip River. Water and sediment samples were
collected from six sites along the course of the river. The pH,
turbidity, salinity, temperature and dissolved oxygen were measured
in-situ. The concentrations of six heavy metals (Cd, Cu, Fe, Ni, Pb
and Zn) of the water samples were determined by atomic absorption
spectroscopy. Biochemical and antibiotic profiles of the isolates were
assessed using the API 20E® and Kirby Bauer Method. Growth
studies were carried out using spectrophotometric methods. The
isolates were identified using 16SrDNA sequencing. The uppermost
part of the Klip River with the lowest pH had the highest levels of
heavy metals. Turbidity, salinity and specific conductivity increased
measurably at Site 4 (Henley on Klip Weir). MIC tests showed that
16 isolates exhibited high iron and lead resistance. Antibiotic
susceptibility tests revealed that the isolates exhibited multitolerances
to drugs such as Tetracycline, Ampicillin, and
Amoxicillin.
Abstract: This research aimed to study on the efficiency of wastewater treatment by comparing the different aeration times of surface aerators in Suan Sunandha Rajabhat University. In doing so, the operation of surface aerators was divided into 2 groups which included the groups of 8 hours (8-0/opened-closed) and 4 hours (2-2/opened-closed) of aeration time per day. As a result of the study, it was found that the efficiency of wastewater treatment in the forms of DO, BOD, turbidity and NO2- by 8 hours (8-0/opened-closed) and 4 hours (2-2/opened-closed) of aeration time per day of surface aerators was not statistically different [Sig. = .644, .488, .716 and .054 > α (.05)] while the efficiency in the forms of NO3- and P was significantly different at the statistical level of .01 [Sig. = .001 and .000 < α (.01)].
Abstract: Despite of few research works on municipal sludge, still there is a lack of actual data. Thus, this work was focused on the conditioning and rheology of fresh activated sludge. The effect of cationic polyelectrolyte has been investigated at different concentrations and pH values in a comparative fashion. Yield stress is presented in all results indicating the minimum stress that necessary to reach flow conditions. Connections between particle-particle is the reason for this yield stress, also, the addition of polyelectrolyte causes strong bonds between particles and water resulting in the aggregation of particles which required higher shear stress in order to flow. The results from the experiments indicate that the cationic polyelectrolytes have significant effluence on the sludge characteristic and water quality such as turbidity, SVI, zone settling rate and shear stress.
Abstract: 40L of hollow fiber membrane bioreactor with solids retention times (SRT) of 30, 15 and 4 days were setup for treating synthetic wastewater at hydraulic retention times (HRT) of 12, 8 and 4 hours. The objectives of the study were to investigate the effects of SRT and HRT on membrane fouling. A comparative analysis was carried out for physiochemical quality parameters (turbidity, suspended solids, COD, NH3-N and PO43-). Scanning electron microscopy (SEM), energy diffusive X-ray (EDX) analyzer and particle size distribution (PSD) were used to characterize the membrane fouling properties. The influence of SRT on the quality of effluent, activated sludge quality, and membrane fouling were also correlated. Lower membrane fouling and slower rise in trans-membrane pressure (TMP) were noticed at the longest SRT and HRT of 30d and 12h, respectively. Increasing SRT results in noticeable reduction of dissolved organic matters. The best removal efficiencies of COD, TSS, NH3-N and PO43- were 93%, 98%, 80% and 30% respectively. The high HRT with shorter SRT induced faster fouling rate. The main fouling resistance was cake layer. The most severe membrane fouling was observed at SRT and HRT of 4 and 12, respectively with thickness cake layer of 17mm as reflected by higher TMP, lower effluent removal and thick sludge cake layer.
Abstract: This study aimed to evaluated the surface water quality for agriculture and consumption in the Amphawa District. The surface water quality parameters in this study included water temperature, turbidity, conductivity, salinity, pH, dissolved oxygen, BOD, nitrate, suspended solids, phosphorus, total dissolved solids (TDS), iron (Fe), copper (Cu), zinc (Zn), manganese (Mn), lead (Pb) and cadmium (Cd). The water samples were collected from small excavation, Lychee, Pomelo and Coconut orchards for 3 seasons from January to December 2011.
The surface water quality from small excavation, Lychee, pomelo and coconut orchards were met the type III of surface water quality standard. The concentration of heavy metal and did not differ significantly at 0.05 level, except dissolved oxygen.
The surface water was suitable for consumption by the usual sterile and generally improving water quality through the process before and was suitable for agriculture.
Abstract: The effect of polyelectrolytes; cationic and anionic charges and coagulants have been investigated for fresh activated sludge at different concentrations and pH values in a comparative fashion. The results from the experiments indicate that the cationic polyelectrolytes have a significant effluence on the sludge characteristic, degree of flocculation and water quality such as turbidity and SVI. The results show that the cationic CPAM-80 is the most effective polyelectrolyte used corresponding to turbidity and SVI despite of the variations in feed properties of the fresh activated sludge.
Abstract: The study was designed to evaluate the use of low
concentrations of separan flocculent (Less than 3 ppm) on
physicochemical properties of sugar cane juice. Colour, pH, purity,
turbidity, pol, brix, reducing sugars tannins and polyphenols of
crushed cane (green and burned) juice, mixed juice and clarified
juice were studied. The results showed that pol, brix, reducing sugar
and turbidity are higher in crushed cane juice. Clarified burned juice
had low turbidity, reducing sugars, pol and brix but had significantly
lower pH, purity and colour when compared to crushed juice.
Polyphenols of the crushed juice (1.19%) decreased significantly in
the clarified juice to 0.006%. Addition of separan at a concentration
of 0.015 ppm reduced significantly colour, polyphenols and tannins
and reducing sugar compared to the control.
Abstract: The Yasuj city stream named the Beshar supply
water for different usages such as aquaculture farms , drinking,
agricultural and industrial usages. Fish processing plants
,Agricultural farms, waste water of industrial zones and hospitals
waste water which they are generate by human activity produce a
considerable volume of effluent and when they are released in to the
stream they can effect on the water quality and down stream aquatic
systems. This study was conducted to evaluate the effects of outflow
effluent from different human activity and point and non point
pollution sources on the water quality and health of the Beshar
river next to Yasuj. Yasuj is the biggest and most important city in
the Kohkiloye and Boyerahmad province . The Beshar River is one
of the most important aquatic ecosystems in the upstream of the
Karun watershed in south of Iran which is affected by point and non
point pollutant sources . This study was done in order to evaluate the
effects of human activities on the water quality and health of the
Beshar river. This river is approximately 190 km in length and
situated at the geographical positions of 51° 20' to 51° 48' E and 30°
18' to 30° 52' N it is one of the most important aquatic ecosystems of
Kohkiloye and Boyerahmad province in south-west Iran. In this
research project, five study stations were selected to examine water
pollution in the Beshar River systems. Human activity is now one of
the most important factors affecting on hydrology and water quality
of the Beshar river. Humans use large amounts of resources to sustain
various standards of living, although measures of sustainability are
highly variable depending on how sustainability is defined. The
Beshar river ecosystems are particularly sensitive and vulnerable to
human activities. The water samples were analyzed, then some
important water quality parameters such as pH, dissolve oxygen
(DO), Biochemical Oxygen Demand (BOD5), Chemical Oxygen
Demand (COD), Total Suspended Solids (TDS),Turbidity,
Temperature, Nitrates (NO3) and Phosphates (PO4) were estimated
at the two stations. The results show a downward trend in the water
quality at the down stream of the city. The amounts of
BOD5,COD,TSS,T,Turbidity, NO3 and PO4 in the down stream
stations were considerably more than the station 1. By contrast the
amounts of DO in the down stream stations were less than to the
station 1. However when effluent discharge consequence of human
activities are released into the Beshar river near the city, the quality
of river are decreases and the environmental problems of the river
during the next years are predicted to rise.
Abstract: Synthetic juice clarification was done through spiral
wound ultrafiltration (UF) membrane module. Synthetic juice was
clarified at two different operating conditions, such as, with and
without permeates recycle at turbulent flow regime. The performance
of spiral wound ultrafiltration membrane was analyzed during
clarification of synthetic juice. Synthetic juice was the mixture of
deionized water, sucrose and pectin molecule. The operating
conditions are: feed flowrate of 10 lpm, pressure drop of 413.7 kPa
and Reynolds no of 5000. Permeate sample was analyzed in terms of
volume reduction factor (VRF), viscosity (Pa.s), ⁰Brix, TDS (mg/l),
electrical conductivity (μS) and turbidity (NTU). It was observe that
the permeate flux declined with operating time for both conditions of
with and without permeate recycle due to increase of concentration
polarization and increase of gel layer on membrane surface. For
without permeate recycle, the membrane fouling rate was faster
compared to with permeate recycle. For without permeate recycle,
the VRF rose up to 5 and for with recycle permeate the VRF is 1.9.
The VRF is higher due to adsorption of solute (pectin) molecule on
membrane surface and resulting permeateflux declined with VRF.
With permeate recycle, quality was within acceptable limit. Fouled
membrane was cleaned by applying different processes (e.g.,
deionized water, SDS and EDTA solution). Membrane cleaning was
analyzed in terms of permeability recovery.
Abstract: Dispersions of casein micelles (CM) were studied at a
constant protein concentration of 5 wt % in high NaCl environment
ranging from 0% to 12% by Dynamic light scattering (DLS) and
Fourier Transform Infrared (FTIR). The rehydration profiles obtained
were interpreted in term of wetting, swelling and dispersion stages by
using a turbidity method. Two behaviours were observed depending
on the salt concentration. The first behaviour (low salt concentration)
presents a typical rehydration profile with a significant change
between 3 and 6% NaCl indicating quick wetting, swelling and long
dispersion stage. On the opposite, the dispersion stage of the second
behaviour (high salt concentration) was significantly shortened
indicating a strong modification of the protein backbone. A salt
increase result to a destabilization of the micelle and the formation of
mini-micelles more or less aggregated indicating an average micelles
size ranging from 100 to 200 nm. For the first time, the estimations
of secondary structural elements (irregular, ß-sheet, α-helix and turn)
by the Amide III assignments were correlated with results from
Amide I.
Abstract: The Beshar River is one aquatic ecosystem, which is
located next to the city of Yasuj in southern Iran. The Beshar river
has been contaminated by industrial factories such as effluent of
sugar factory, agricultural and other activities in this region such as,
Imam Sajjad hospital, drainage from agricultural farms, Yasuj urban
surface runoff and effluent of wastewater treatment plants ,specially
Yasuj waste water treatment plant. In order to evaluate the effects of
these pollutants on the quality of the Beshar river, five monitoring
stations were selected along its course. The first station is located
upstream of Yasuj near the Dehnow village; stations 2 to 4 are
located east, south and west of city; and the 5th station is located
downstream of Yasuj. Several water quality parameters were
sampled. These include pH, dissolved oxygen, biological oxygen
demand (BOD), temperature, conductivity, turbidity, total dissolved
solids and discharge or flow measurements. Water samples from the
five stations were collected and analyzed to determine the following
physicochemical parameters: EC, pH, T.D.S, T.H, No2, DO, BOD5,
COD during 2008 to 2010. The study shows that the BOD5 value of
station 1 is at a minimum (1.7 ppm) and increases downstream from
stations 2 to 4 to a maximum (11.6 ppm), and then decreases at
station 5. The DO values of station 1 is a maximum (8.45 ppm),
decreases downstream to stations 2 - 4 which are at a minimum (3.1
ppm), before increasing at station 5. The amount of BOD and TDS
are highest at the 4th station and the amount of DO is lowest at this
station, marking the 4th station as more highly polluted than the
other stations .This study shows average amount of the water quality
parameters in first year of sampling (2008) have had a better quality
relation to third year in 2010 because of recent drought in this region
and pollutant increasing .As the Beshar river path after 5th station
goes through the mountain area with more slope and flow velocity
,so the physicochemical parameters improve at the 5th station due to
pollutant degradation and dilution. Finally the point and nonpoint
pollutant sources of Beshar river were determined and compared to
the monitoring results.
Abstract: Measurement of the COD of a spent caustic solution involves firstly digestion of a test sample with dichromate solution and secondly measurement of dichromate remained by titration by ferrous ammonium sulfate [FAS] to an end point. In this paper we study by a potentiometric end point with Ag/AgCl reference electrode and gold rode electrode. The potentiometric end point is sharp and easily identified especially for the samples with high turbidity and color that other methods such as colorimetric in this type of sample do not result in high precision. Because interim of titration responds quickly to potential changes within the [Cr+6/Cr+3& Fe+2/Fe+3] solution producing stable readings that is lead to accurate COD measurement. Finally results are compared with data determined using colorimetric method for standard samples. It is shown that the potentiometric end point titration with gold rode electrode can be used with equal or better facility
Abstract: The present study focuses on the discussion over the
parameter of Artificial Neural Network (ANN). Sensitivity analysis is
applied to assess the effect of the parameters of ANN on the prediction
of turbidity of raw water in the water treatment plant. The result shows
that transfer function of hidden layer is a critical parameter of ANN.
When the transfer function changes, the reliability of prediction of
water turbidity is greatly different. Moreover, the estimated water
turbidity is less sensitive to training times and learning velocity than
the number of neurons in the hidden layer. Therefore, it is important to
select an appropriate transfer function and suitable number of neurons
in the hidden layer in the process of parameter training and validation.
Abstract: Coagulation of water involves the use of coagulating
agents to bring the suspended matter in the raw water together for
settling and the filtration stage. Present study is aimed to examine the
effects of aluminum sulfate as coagulant in conjunction with Moringa
Oleifera Coagulant Protein as coagulant aid on turbidity, hardness,
and bacteria in turbid water. A conventional jar test apparatus was
employed for the tests. The best removal was observed at a pH of 7
to 7.5 for all turbidities. Turbidity removal efficiency was resulted
between % 80 to % 99 by Moringa Oleifera Coagulant Protein as
coagulant aid. Dosage of coagulant and coagulant aid decreased with
increasing turbidity. In addition, Moringa Oleifera Coagulant Protein
significantly has reduced the required dosage of primary coagulant.
Residual Al+3 in treated water were less than 0.2 mg/l and meets the
environmental protection agency guidelines. The results showed that
turbidity reduction of % 85.9- % 98 paralleled by a primary
Escherichia coli reduction of 1-3 log units (99.2 – 99.97%) was
obtained within the first 1 to 2 h of treatment. In conclusions,
Moringa Oleifera Coagulant Protein as coagulant aid can be used for
drinking water treatment without the risk of organic or nutrient
release. We demonstrated that optimal design method is an efficient
approach for optimization of coagulation-flocculation process and
appropriate for raw water treatment.
Abstract: The present study is aim to prepare and evaluate the selfnanoemulsifying drug delivery (SNEDDS) system of a poorly water soluble drug valsartan in order to achieve a better dissolution rate which would further help in enhancing oral bioavailability. The present research work describes a SNEDDS of valsartan using labrafil M 1944 CS, Tween 80 and Transcutol HP. The pseudoternary phase diagrams with presence and absence of drug were plotted to check for the emulsification range and also to evaluate the effect of valsartan on the emulsification behavior of the phases. The mixtures consisting of oil (labrafil M 1944 CS) with surfactant (tween 80), co-surfactant (Transcutol HP) were found to be optimum formulations. Prepared formulations were evaluated for its particle size distribution, nanoemulsifying properties, robustness to dilution, self emulsication time, turbidity measurement, drug content and invitro dissolution. The optimized formulations are further evaluated for heating cooling cycle, centrifugation studies, freeze thaw cycling, particle size distribution and zeta potential were carried out to confirm the stability of the formed SNEDDS formulations. The prepared formulation revealed t a significant improvement in terms of the drug solubility as compared with marketed tablet and pure drug.
Abstract: The Beshar River is one aquatic ecosystem,which is
affected by pollutants. This study was conducted to evaluate the
effects of human activities on the water quality of the Beshar river.
This river is approximately 190 km in length and situated at the
geographical positions of 51° 20' to 51° 48' E and 30° 18' to 30° 52'
N it is one of the most important aquatic ecosystems of Kohkiloye
and Boyerahmad province next to the city of Yasuj in southern Iran.
The Beshar river has been contaminated by industrial, agricultural
and other activities in this region such as factories, hospitals,
agricultural farms, urban surface runoff and effluent of wastewater
treatment plants. In order to evaluate the effects of these pollutants
on the quality of the Beshar river, five monitoring stations were
selected along its course. The first station is located upstream of
Yasuj near the Dehnow village; stations 2 to 4 are located east, south
and west of city; and the 5th station is located downstream of Yasuj.
Several water quality parameters were sampled. These include pH,
dissolved oxygen, biological oxygen demand (BOD), temperature,
conductivity, turbidity, total dissolved solids and discharge or flow
measurements. Water samples from the five stations were collected
and analysed to determine the following physicochemical
parameters: EC, pH, T.D.S, T.H, No2, DO, BOD5, COD during 2008
to 2009. The study shows that the BOD5 value of station 1 is at a
minimum (1.5 ppm) and increases downstream from stations 2 to 4 to
a maximum (7.2 ppm), and then decreases at station 5. The DO
values of station 1 is a maximum (9.55 ppm), decreases downstream
to stations 2 - 4 which are at a minimum (3.4 ppm), before increasing
at station 5. The amount of BOD and TDS are highest at the 4th
station and the amount of DO is lowest at this station, marking the
4th station as more highly polluted than the other stations. The
physicochemical parameters improve at the 5th station due to
pollutant degradation and dilution. Finally the point and nonpoint
pollutant sources of Beshar river were determined and compared to
the monitoring results.
Abstract: The principal objective of a water treatment plant is to
produce water that satisfies a set of drinking water quality standards
at a reasonable price to the consumers. The gravel-bed flocculator
provide a simple and inexpensive design for flocculation in small
water treatment plants (less than 5000 m3/day capacity). The packed
bed of gravel provides ideal conditions for the formation of compact
settleable flocs because of continuous recontact provided by the
sinuous flow of water through the interstices formed by the gravel.
The field data which were obtained from the operation of the
water supply treatment unit cover the physical, chemical and
biological water qualities of the raw and settled water as obtained by
the operation of the treatment unit. The experiments were carried out
with the aim of assessing the efficiency of the gravel filter in
removing the turbidity, pathogenic bacteria, from the raw water. The
water treatment plant, which was constructed for the treatment of
river water, was in principle a rapid sand filter.
The results show that the average value of the turbidity level of
the settled water was 4.83 NTU with a standard deviation of turbidity
2.893 NTU. This indicated that the removal efficiency of the
sedimentation tank (gravel filter) was about 67.8 %. for pH values
fluctuated between 7.75 and 8.15, indicating the alkaline nature of
the raw water of the river Shatt Al-Hilla, as expected. Raw water pH
is depressed slightly following alum coagulation. The pH of the
settled water ranged from 7.75 to a maximum of 8.05.
The bacteriological tests which were carried out on the water
samples were: total coliform test, E-coli test, and the plate count test.
In each test the procedure used was as outlined in the Standard
Methods for the Examination of Water and Wastewater (APHA,
AWWA, and WPCF, 1985). The gravel filter exhibit a low
performance in removing bacterial load. The percentage bacterial
removal, which is maximum for total plate count (19%) and
minimum for total coliform (16.82%).
Abstract: An experiment was conducted using two aeration
methods (water-into-air and air-into-water) and followed by filtration
processes using manganese greensand material. The properties of
groundwater such as pH, dissolved oxygen, turbidity and heavy metal
concentration (iron and manganese) will be assessed. The objectives
of this study are i) to determine the effective aeration method and ii)
to assess the effectiveness of manganese greensand as filter media in
removing iron and manganese concentration in groundwater. Results
showed that final pH for all samples after treatment are in range from
7.40 and 8.40. Both aeration methods increased the dissolved oxygen
content. Final turbidity for groundwater samples are between 3 NTU
to 29 NTU. Only three out of eight samples achieved iron
concentration of 0.3mg/L and less and all samples reach manganese
concentration of 0.1mg/L and less. Air-into-water aeration method
gives higher percentage of iron and manganese removal compare to
water-into-air method.