Abstract: This research evaluated and compared the thermodynamic performance of heat pump systems which can be run under two different modes as air to air and air to water by using only one compressor. To achieve this comparison an experimental performance study was made on a traditional vapor compressed heat pump system that can be run air to air mode and air to water mode by help of a valve. The experiments made under different thermal conditions. Thermodynamic performance of the systems are presented and compared with each other for different working conditions.
Abstract: This paper presents the exergy analysis of a
desalination unit using humidification-dehumidification process.
Here, this unit is considered as a thermal system with three main
components, which are the heating unit by using a solar collector, the
evaporator or the humidifier, and the condenser or the dehumidifier.
In these components the exergy is a measure of the quality or grade
of energy and it can be destroyed in them. According to the second
law of thermodynamics this destroyed part is due to irreversibilities
which must be determined to obtain the exergetic efficiency of the
system.
In the current paper a computer program has been developed using
visual basic to determine the exergy destruction and the exergetic
efficiencies of the components of the desalination unit at variable
operation conditions such as feed water temperature, outlet air
temperature, air to feed water mass ratio and salinity, in addition to
cooling water mass flow rate and inlet temperature, as well as
quantity of solar irradiance.
The results obtained indicate that the exergy efficiency of the
humidifier increases by increasing the mass ratio and decreasing the
outlet air temperature. In the other hand the exergy efficiency of the
condenser increases with the increase of this ratio and also with the
increase of the outlet air temperature.
Abstract: Adsorption of Toluidine blue dye from aqueous solutions onto Neem Leaf Powder (NLP) has been investigated. The surface characterization of this natural material was examined by Particle size analysis, Scanning Electron Microscopy (SEM), Fourier Transform Infrared (FTIR) spectroscopy and X-Ray Diffraction (XRD). The effects of process parameters such as initial concentration, pH, temperature and contact duration on the adsorption capacities have been evaluated, in which pH has been found to be most effective parameter among all. The data were analyzed using the Langmuir and Freundlich for explaining the equilibrium characteristics of adsorption. And kinetic models like pseudo first- order, second-order model and Elovich equation were utilized to describe the kinetic data. The experimental data were well fitted with Langmuir adsorption isotherm model and pseudo second order kinetic model. The thermodynamic parameters, such as Free energy of adsorption (AG"), enthalpy change (AH') and entropy change (AS°) were also determined and evaluated.
Abstract: Gas turbine air inlet cooling is a useful method for
increasing output for regions where significant power demand and
highest electricity prices occur during the warm months. Inlet air
cooling increases the power output by taking advantage of the gas
turbine-s feature of higher mass flow rate when the compressor inlet
temperature decreases. Different methods are available for reducing
gas turbine inlet temperature. There are two basic systems currently
available for inlet cooling. The first and most cost-effective system is
evaporative cooling. Evaporative coolers make use of the evaporation
of water to reduce the gas turbine-s inlet air temperature. The second
system employs various ways to chill the inlet air. In this method, the
cooling medium flows through a heat exchanger located in the inlet
duct to remove heat from the inlet air. However, the evaporative
cooling is limited by wet-bulb temperature while the chilling can cool
the inlet air to temperatures that are lower than the wet bulb
temperature. In the present work, a thermodynamic model of a gas
turbine is built to calculate heat rate, power output and thermal
efficiency at different inlet air temperature conditions. Computational
results are compared with ISO conditions herein called "base-case".
Therefore, the two cooling methods are implemented and solved for
different inlet conditions (inlet temperature and relative humidity).
Evaporative cooler and absorption chiller systems results show that
when the ambient temperature is extremely high with low relative
humidity (requiring a large temperature reduction) the chiller is the
more suitable cooling solution. The net increment in the power output
as a function of the temperature decrease for each cooling method is
also obtained.
Abstract: Palm shell obtained from coastal part of southern
India was studied for the removal for the adsorption of Hg (II) ions.
Batch adsorption experiments were carried out as a function of pH,
concentration of Hg (II) ions, time, temperature and adsorbent dose.
Maximum removal was seen in the range pH 4.0- pH 7.0. The palm
shell powder used as adsorbent was characterized for its surface area,
SEM, PXRD, FTIR, ion exchange capacity, moisture content, and
bulk density, soluble content in water and acid and pH. The
experimental results were analyzed using Langmuir I, II, III, IV and
Freundlich adsorption isotherms. The batch sorption kinetics was
studied for the first order reversible reaction, pseudo first order;
pseudo second order reaction and the intra-particle diffusion reaction.
The biomass was successfully used for removal Hg (II) from
synthetic and industrial effluents and the technique appears
industrially applicable and viable.
Abstract: This research deals with techno economic analysis to select the most economic desalination method for Asalouyeh combined cycle power plant . Due to lack of fresh water, desalination of sea water is necessary to provide required DM water of Power Plant. The most common desalination methods are RO, MSF, MED, and MED–TVC. In this research, methods of RO, MED, and MED– TVC have been compared. Simulation results show that recovery of heat of exhaust gas of main stack is optimum case for providing DM water required for injected steam of MED desalination. This subject is very important because of improving thermal efficiency of power plant using extra heat recovery. Also, it has been shown that by adding 3 rows of finned tube to de-aerator evaporator, which is very simple and low cost, required steam for generating 5200 m3/day of desalinated water is obtainable.
Abstract: The purpose of this research is to establish the experimental conditions for removal of Cibacron Brilliant Yellow 3G-P dye (CBY) from aqueous solutions by sorption onto coffee husks as a low-cost sorbent. The effects of various experimental parameters (e.g. initial CBY dye concentration, sorbent mass, pH, temperature) were examined and the optimal experimental conditions were determined. The results indicated that the removal of the dye was pH dependent and at initial pH of 2, the dye was removed effectively. The CBY dye sorption data were fitted to Langmuir, Freundlich, Temkin and Dubinin-Radushkevich equilibrium models. The maximum sorption capacity of CBY dye ions onto coffee husks increased from 24.04 to 35.04 mg g-1 when the temperature was increased from 293 to 313 K. The calculated sorption thermodynamic parameters including ΔG°, ΔH°, and ΔS° indicated that the CBY dye sorption onto coffee husks is a spontaneous, endothermic and mainly physical in nature.
Abstract: The deterministic quantum transfer-matrix (QTM)
technique and its mathematical background are presented. This
important tool in computational physics can be applied to a class of
the real physical low-dimensional magnetic systems described by the
Heisenberg hamiltonian which includes the macroscopic molecularbased
spin chains, small size magnetic clusters embedded in some
supramolecules and other interesting compounds. Using QTM, the
spin degrees of freedom are accurately taken into account, yielding
the thermodynamical functions at finite temperatures.
In order to test the application for the susceptibility calculations to
run in the parallel environment, the speed-up and efficiency of
parallelization are analyzed on our platform SGI Origin 3800 with
p = 128 processor units. Using Message Parallel Interface (MPI)
system libraries we find the efficiency of the code of 94% for
p = 128 that makes our application highly scalable.
Abstract: Isobaric vapor-liquid equilibrium measurements are
reported for the binary mixture of Methyl acetate and
Isopropylbenzene at 97.3 kPa. The measurements have been
performed using a vapor recirculating type (modified Othmer's)
equilibrium still. The mixture shows positive deviation from ideality
and does not form an azeotrope. The activity coefficients have been
calculated taking into consideration the vapor phase nonideality. The
data satisfy the thermodynamic consistency tests of Herington and
Black. The activity coefficients have been satisfactorily correlated by
means of the Margules, NRTL, and Black equations. A comparison
of the values of activity coefficients obtained by experimental data
with the UNIFAC model has been made.
Abstract: ORC (Organic Rankine Cycle) has potential of
reducing consumption of fossil fuels and has many favorable
characteristics to exploit low-temperature heat sources. In this work
thermodynamic performance of ORC with regeneration is
comparatively assessed for various working fluids. Special attention is
paid to the effects of system parameters such as the turbine inlet
pressure on the characteristics of the system such as net work
production, heat input, volumetric flow rate per 1 MW of net work and
quality of the working fluid at turbine exit as well as thermal
efficiency. Results show that for a given source the thermal efficiency
generally increases with increasing of the turbine inlet pressure
however has optimal condition for working fluids of low critical
pressure such as iso-pentane or n-pentane.
Abstract: A self-association model has been used to understand
the concentration dependence of free energy of mixing (GM), heat of
mixing (HM), entropy of mixing (SM), activity (a) and microscopic
structures, such as concentration fluctuation in long wavelength limit
(Scc(0)) and Warren-Cowley short range order parameter ( 1
α )for Cu-
Tl molten alloys at 1573K. A comparative study of surface tension of
the alloys in the liquid state at that temperature has also been carried
out theoretically as function of composition in the light of Butler-s
model, Prasad-s model and quasi-chemical approach. Most of the
computed thermodynamic properties have been found in agreement
with the experimental values. The analysis reveals that the Cu-Tl
molten alloys at 1573K represent a segregating system at all
concentrations with moderate interaction. Surface tensions computed
from different approaches have been found to be comparable to each
other showing increment with the composition of copper.
Abstract: The present work deals with thermodynamic analysis
of cascade refrigeration system using ozone friendly refrigerants pair
R507A and R23. R507A is azeotropic mixture composed of HFC
refrigerants R125/R143a (50%/50% wt.). R23 is a single component
HFC refrigerant used as replacement to CFC refrigerant R13 in low
temperature applications. These refrigerants have zero ozone
depletion potential and are non-flammable and as R507A an
azeotropic mixture there is no problem of temperature glide. This
study thermodynamically analyzed R507A-R23 cascade refrigeration
system to optimize the design and operating parameters of the
system. The design and operating parameters include: Condensing,
evaporating, subcooling and superheating temperatures in the high
temperature circuit, temperature difference in the cascade heat
exchanger, Condensing, evaporating, subcooling and superheating
temperatures in the low temperature circuit.
Abstract: Group contribution methods such as the UNIFAC are
of major interest to researchers and engineers involved synthesis,
feasibility studies, design and optimization of separation processes as
well as other applications of industrial use. Reliable knowledge of
the phase equilibrium behavior is crucial for the prediction of the fate
of the chemical in the environment and other applications. The
objective of this study was to predict the solubility of selected
volatile organic compounds (VOCs) in glycol polymers and
biodiesel. Measurements can be expensive and time consuming,
hence the need for thermodynamic models. The results obtained in
this study for the infinite dilution activity coefficients compare very
well those published in literature obtained through measurements. It
is suggested that in preliminary design or feasibility studies of
absorption systems for the abatement of volatile organic compounds,
prediction procedures should be implemented while accurate fluid
phase equilibrium data should be obtained from experiment.
Abstract: In recent years, the underground water sources in
southern Taiwan have become salinized because of saltwater
intrusions. This study explores the adsorption characteristics of
activated carbon on salinizing inorganic salts using isothermal
adsorption experiments and provides a model analysis. The
temperature range for the isothermal adsorption experiments ranged
between 5 to 45 ℃, and the amount adsorbed varied between 28.21 to
33.87 mg/g. All experimental data of adsorption can be fitted to both
the Langmuir and the Freundlich models. The thermodynamic
parameters for per chlorate onto granular activated carbon were
calculated as -0.99 to -1.11 kcal/mol for DG°, -0.6 kcal/mol for DH°,
and 1.21 to 1.84 kcal/mol for DS°. This shows that the adsorption
process of granular activated carbon is spontaneously exothermic. The
observation of adsorption behaviors under low ionic strength, low pH
values, and low temperatures is beneficial to the adsorption removal of
perchlorate with granular activated carbon.
Abstract: Gas condensate Reservoirs show complicated thermodynamic behavior when their pressure reduces to under dew point pressure. Condensate blockage around the producing well cause significant reduction of production rate as well bottom-hole pressure drops below saturation pressure. The main objective of this work was to examine the well test analysis of naturally fractured lean gas condensate reservoir and investigate the effect of condensate formed around the well-bore on behavior of single phase pseudo pressure and its derivative curves. In this work a naturally fractured lean gas condensate reservoir is simulated with compositional simulator. Different sensitivity analysis done on Corry parameters and result of simulator is feed to analytical well testing software. For consideration of these phenomena eighteen compositional models with Capillary number effect are constructed. Matrix relative permeability obeys Corry relative permeability and relative permeability in fracture is linear. Well testing behavior of these models are studied and interpreted. Results show different sensitivity analysis on relative permeability of matrix does not have strong effect on well testing behavior even most part of the matrix around the well is occupied with condensate.
Abstract: The rheological properties of light crude oil and its mixture with water were investigated experimentally. These rheological properties include steady flow behavior, yield stress, transient flow behavior, and viscoelastic behavior. A RheoStress RS600 rheometer was employed in all of the rheological examination tests. The light crude oil exhibits a Newtonian and for emulsion exhibits a non-Newtonian shear thinning behavior over the examined shear rate range of 0.1–120 s-1. In first time, a series of samples of crude oil from the Algerian Sahara has been tested and the results expressed in terms of τ=f(γ) have demonstrated their Newtonian character for the temperature included in [20°C, 70°C]. In second time and at T=20°C, the oil-water emulsions (30%, 50% and 70%) by volume of water), thermodynamically stable, have demonstrated a non-Newtonian rheological behavior that is to say, Herschel-Bulkley and Bingham types. For each type of crude oil-water emulsion, the rheological parameters are calculated by numerical treatment of results.
Abstract: The equilibrium, thermodynamics and kinetics of the
biosorption of Cd (II) and Pb(II) by a Spore Forming Bacillus (MGL
75) were investigated at different experimental conditions. The
Langmuir and Freundlich, and Dubinin-Radushkevich (D-R)
equilibrium adsorption models were applied to describe the
biosorption of the metal ions by MGL 75 biomass. The Langmuir
model fitted the equilibrium data better than the other models.
Maximum adsorption capacities q max for lead (II) and cadmium (II)
were found equal to 158.73mg/g and 91.74 mg/g by Langmuir model.
The values of the mean free energy determined with the D-R equation
showed that adsorption process is a physiosorption process. The
thermodynamic parameters Gibbs free energy (ΔG°), enthalpy (ΔH°),
and entropy (ΔS°) changes were also calculated, and the values
indicated that the biosorption process was exothermic and
spontaneous. Experiment data were also used to study biosorption
kinetics using pseudo-first-order and pseudo-second-order kinetic
models. Kinetic parameters, rate constants, equilibrium sorption
capacities and related correlation coefficients were calculated and
discussed. The results showed that the biosorption processes of both
metal ions followed well pseudo-second-order kinetics.
Abstract: In this study thermodynamic performance analysis of a
combined organic Rankine cycle and ejector refrigeration cycle is
carried out for use of low-grade heat source in the form of sensible
energy. Special attention is paid to the effects of system parameters
including the turbine inlet temperature and turbine inlet pressure on the
characteristics of the system such as ratios of mass flow rate, net work
production, and refrigeration capacity as well as the coefficient of
performance and exergy efficiency of the system. Results show that
for a given source the coefficient of performance increases with
increasing of the turbine inlet pressure. However, the exergy
efficiency has an optimal condition with respect to the turbine inlet
pressure.
Abstract: Heat powered solid sorption is a feasible alternative to
electrical vapor compression refrigeration systems. In this paper,
activated carbon (powder type Maxsorb and fiber type ACF-A10)-
CO2 based adsorption cooling cycles are studied using the pressuretemperature-
concentration (P-T-W) diagram. The specific cooling
effect (SCE) and the coefficient of performance (COP) of these two
cooling systems are simulated for the driving heat source
temperatures ranging from 30 ºC to 90 ºC in terms of different
cooling load temperatures with a cooling source temperature of 25
ºC. It is found from the present analysis that Maxsorb-CO2 couple
shows higher cooling capacity and COP. The maximum COPs of
Maxsorb-CO2 and ACF(A10)-CO2 based cooling systems are found
to be 0.15 and 0.083, respectively. The main innovative feature of
this cooling cycle is the ability to utilize low temperature waste heat
or solar energy using CO2 as the refrigerant, which is one of the best
alternative for applications where flammability and toxicity are not
allowed.
Abstract: Considering non-ideal behavior of fluids and its effects on hydrodynamic and mass transfer in multiphase flow is very essential. Simulations were performed that takes into account the effects of mass transfer and mixture non-ideality on hydrodynamics reported by Irani et al. In this paper, by assuming the density of phases to be constant and Raullt-s law instead of using EOS and fugacity coefficient definition, respectively for both the liquid and gas phases, the importance of non-ideality effects on mass transfer and hydrodynamic behavior was studied. The results for a system of octane/propane (T=323 K, P =445 kpa) also indicated that the assumption of constant density in simulation had major role to diverse from experimental data. Furthermore, comparison between obtained results and the previous report indicated significant differences between experimental data and simulation results with more ideal assumptions.