Abstract: The current study investigated the effect of catalyst ratio and methanol to oil ratio on biodiesel production by using central composite design. Biodiesel was produced by transesterification using sodium hydroxide as a homogeneous catalyst, a laboratory scale reactor consisting of flat bottom flask mounts with a reflux condenser, and a heating plate was used to produce biodiesel. Key parameters, including time, temperature, and mixing rate was kept constant at 60 minutes, 60 oC and 600 RPM, respectively. From the results obtained, it was observed that the biodiesel yield depends on catalyst ratio and methanol to oil ratio. The highest yield of 50.65% was obtained at catalyst ratio of 0.5 wt.% and methanol to oil mole ratio 10.5. The analysis of variances of biodiesel yield showed the R Squared value of 0.8387. A quadratic mathematical model was developed to predict the biodiesel yield in the specified parameters ranges.
Abstract: Biofuel production especially that of biodiesel has gained tremendous attention during the last decade due to environmental concerns and shortage in petroleum oil reservoir. This research aims to investigate the influences of operating parameters, such as the alcohol-to-oil molar ratio (4:1, 6:1, and 9:1) and the amount of catalyst (1, 1.5, and 2 wt.%) on the trans esterification of refined palm oil (RPO) in a medium-scale oscillatory baffle reactor. It has been shown that an increase in the methanol-to-oil ratio resulted in an increase in fatty acid methyl esters (FAMEs) content. The amount of catalyst has an insignificant effect on the FAMEs content. Engine testing was performed on B0 (100 v/v% diesel) and blended fuel or B50 (50 v/v% diesel). Combustion of B50 was found to give lower torque compared to pure diesel. Exhaust gas from B50 was found to contain lower concentration of CO and CO2.
Abstract: The current study investigated the effect of catalyst ratio and methanol to oil ratio on biodiesel production by using central composite design. Biodiesel was produced by transesterification using sodium hydroxide as a homogeneous catalyst, a laboratory scale reactor consisting of flat bottom flask mounts with a reflux condenser and a heating plate was used to produce biodiesel. Key parameters, including, time, temperature and mixing rate were kept constant at 60 minutes, 60 oC and 600 RPM, respectively. From the results obtained, it was observed that the biodiesel yield depends on catalyst ratio and methanol to oil ratio. The highest yield of 50.65% was obtained at catalyst ratio of 0.5 wt.% and methanol to oil mole ratio 10.5. The analysis of variances of biodiesel yield showed the R Squared value of 0.8387. A quadratic mathematical model was developed to predict the biodiesel yield in the specified parameters ranges.
Abstract: This study was initiated to evaluate and optimize the conversion of animal fat from tannery wastes into methyl ester. In the pre-treatment stage, animal fats feedstock was hydrolysed and esterified through solid state fermentation (SSF) using Microbacterium species immobilized onto sand silica matrix. After 72 hours of fermentation, predominant esters in the animal fats were found to be with 83.9% conversion rate. Later, esterified animal fats were transesterified at 3 hour reaction time with 1% NaOH (w/v %), 6% methanol to oil ratio (w/v %) to produce 89% conversion rate. C13 NMR revealed long carbon chain in fatty acid methyl esters at 22.2817-31.9727 ppm. Methyl esters of palmitic, stearic, oleic represented the major components in biodiesel.
Abstract: Sesame is one of the oldest and most important oil
crops as main crop and second crop agriculture. This study was
carried out to determine the effects of different inter- and intra-row
spacings on the yield and yield components on second crop sesame;
was set up in Antalya West Mediterranean Agricultural Research
Institue in 2009. Muganlı 57 sesame cultivar was used as plant
material. The field experiment was set up in a split plot design and
row spacings (30, 40, 50, 60 and 70 cm) were assigned to the main
plots and and intra-row spacings (5, 10, 20 and 30 cm) were assigned
to the subplots. Seed yield, oil ratio, oil yield, protein ratio and
protein yield were investigated. In general, wided inter row spacings
and intra-row spacings, resulted in decreased seed yield, oil yield and
protein yield. The highest seed yield, oil yield and protein yield
(respectively, 1115.0 kg ha-1, 551.3 kg ha-1, 224.7 kg ha-1) were
obtained from 30x5 cm plant density while the lowest seed yield, oil
yield and protein yield (respectively, 677.0 kg ha-1, 327.0 kg ha-1,
130.0 kg ha-1) were recorded from 70x30 cm plant density. As a
result, in terms of oil yield for second crop sesame agriculture, 30 cm
row spacing, and 5 cm intra row spacing are the most suitable plant
densities.
Abstract: Transesterification of candlenut (aleurites moluccana)
oil with methanol using potassium hydroxide as catalyst was
studied. The objective of the present investigation was to produce
the methyl ester for use as biodiesel. The operation variables
employed were methanol to oil molar ratio (3:1 – 9:1), catalyst
concentration (0.50 – 1.5 %) and temperature (303 – 343K). Oil
volume of 150 mL, reaction time of 75 min were fixed as common
parameters in all the experiments. The concentration of methyl ester
was evaluated by mass balance of free glycerol formed which was
analyzed by using periodic acid. The optimal triglyceride conversion
was attained by using methanol to oil ratio of 6:1, potassium
hydroxide as catalyst was of 1%, at room temperature. Methyl ester
formed was characterized by its density, viscosity, cloud and pour
points. The biodiesel properties had properties similar to those of
diesel oil, except for the viscosity that was higher.