Abstract: For the last few years, release of burned undesirable by-products has become a challenging issue in oil industries. Flaring, as one of the main sources of air contamination, involves detrimental and long-lasting effects on human health and is considered a substantial reason for energy losses worldwide. This research involves studying the implications of two main flare gas recovery methods at three oil refineries, all in Iran as the case I, case II, and case III in which the production capacities are increasing respectively. In the proposed methods, flare gases are converted into more valuable products, before combustion by the flare networks. The first approach involves collecting, compressing and converting the flare gas to smokeless fuel which can be used in the fuel gas system of the refineries. The other scenario includes utilizing the flare gas as a feed into liquefied petroleum gas (LPG) production unit already established in the refineries. The processes of these scenarios are simulated, and the capital investment is calculated for each procedure. The cumulative profits of the scenarios are evaluated using Net Present Value method. Furthermore, the sensitivity analysis based on total propane and butane mole fraction is carried out to make a rational comparison for LPG production approach, and the results are illustrated for different mole fractions of propane and butane. As the mole fraction of propane and butane contained in LPG differs in summer and winter seasons, the results corresponding to LPG scenario are demonstrated for each season. The results of the simulations show that cumulative profit in fuel gas production scenario and LPG production rate increase with the capacity of the refineries. Moreover, the investment return time in LPG production method experiences a decline, followed by a rising trend with an increase in C3 and C4 content. The minimum value of time return occurs at propane and butane sum concentration values of 0.7, 0.6, and 0.7 in case I, II, and III, respectively. Based on comparison of the time of investment return and cumulative profit, fuel gas production is the superior scenario for three case studies.
Abstract: Packed columns of liquefied petroleum gas (LPG) consists of separating the liquid mixture of propane and butane to pure gas components by the distillation phenomenon. The flow of the gas and liquid inside the columns is operated by two ways: The co-current and the counter current operation. Heat, mass and species transfer between phases represent the most important factors that influence the choice between those two operations. In this paper, both processes are discussed using computational CFD simulation through ANSYS-Fluent software. Only 3D half section of the packed column was considered with one packed bed. The packed bed was characterized in our case as a porous media. The simulations were carried out at transient state conditions. A multi-component gas and liquid mixture were used out in the two processes. We utilized the Euler-Lagrange approach in which the gas was treated as a continuum phase and the liquid as a group of dispersed particles. The heat and the mass transfer process was modeled using multi-component droplet evaporation approach. The results show that the counter-current process performs better than the co-current, although such limitations of our approach are noted. This comparison gives accurate results for computations times higher than 2 s, at different gas velocity and at packed bed porosity of 0.9.
Abstract: In the gas refineries of Iran-s South Pars Gas
Complex, Sulfrex demercaptanization process is used to remove
volatile and corrosive mercaptans from liquefied petroleum gases by
caustic solution. This process consists of two steps. Removing low
molecular weight mercaptans and regeneration exhaust caustic. Some
parameters such as LPG feed temperature, caustic concentration and
feed-s mercaptan in extraction step and sodium mercaptide content in
caustic, catalyst concentration, caustic temperature, air injection rate
in regeneration step are effective factors. In this paper was focused on
temperature factor that play key role in mercaptans extraction and
caustic regeneration. The experimental results demonstrated by
optimization of temperature, sodium mercaptide content in caustic
because of good oxidation minimized and sulfur impurities in
product reduced.
Abstract: The present project was conducted with the
circumferential-fuel-jets inverse diffusion flame (CIDF) burner
burning liquefied petroleum gas (LPG) enriched with 50% of
hydrogen fuel (H2). The range of stable operation of the CIDF burner
in terms of Reynolds number (from laminar to turbulent flow regions),
equivalence ratio and fuel jet velocity of LPG of the 50% H2-LPG
mixed fuel was identified. Experiments were also carried out to
investigate the flame structures of the LPG flame and LPG enriched H2
flame. Experimental results obtained from these two flames were
compared to fully explore the influence of hydrogen addition on flame
stability. Flame heights obtained by burning these two kinds of fuels at
various equivalence ratios were compared and correlated with the
Global Momentum Ratio (GMR).
Abstract: Fluid flow in cylinders of elliptic cross-section was investigated. Fluid used is Liquefied petroleum gas (LPG). LPG found in Nigeria contains majorly butane with percentages of propane. Commercial available code FLUENT which uses finite volume method was used to solve fluid flow governing equations. There has been little attention paid to fluid flow in cylindrical elliptic pipes. The present work aims to predict the LPG gas flow in cylindrical pipes of elliptic cross-section. Results of flow parameters of velocity and pressure distributions are presented. Results show that the pressure drop in elliptic pipes is higher than circular pipe of the same cross-sectional area. This is an important result as the pressure drop is related to the pump power needed to drive the flow. Results show that the velocity increases towards centre of the pipe as the flow moves downstream, and also increases towards the outlet of the pipe.