Abstract: Polymer-particle interactions can be effectively utilized to produce composites that possess physicochemical properties superior to that of neat polymer. The incorporation of fillers with dimensions comparable to polymer chain size produces composites with extra-ordinary properties owing to very high surface to volume ratio. The dispersion of nanoparticles is achieved by inducing steric repulsion realized by grafting particles with polymeric chains. A comprehensive understanding of the interparticle interaction between these functionalized nanoparticles plays an important role in the synthesis of a stable polymer nanocomposite. With the focus on incorporation of clay sheets in a polymer matrix, we theoretically construct the polymer mediated interparticle potential for two nanosheets grafted with polymeric chains. The self-consistent field theory (SCFT) is employed to obtain the inhomogeneous composition field under equilibrium. Unlike the continuum models, SCFT is built from the microscopic description taking in to account the molecular interactions contributed by both intra- and inter-chain potentials. We present the results of SCFT calculations of the interaction potential curve for two grafted nanosheets immersed in the matrix of polymeric chains of dissimilar chemistry to that of the grafted chains. The interaction potential is repulsive at short separation and shows depletion attraction for moderate separations induced by high grafting density. It is found that the strength of attraction well can be tuned by altering the compatibility between the grafted and the mobile chains. Further, we construct the interaction potential between two nanosheets grafted with diblock copolymers with one of the blocks being chemically identical to the free polymeric chains. The interplay between the enthalpic interaction between the dissimilar species and the entropy of the free chains gives rise to a rich behavior in interaction potential curve obtained for two separate cases of free chains being chemically similar to either the grafted block or the free block of the grafted diblock chains.
Abstract: The development of numerical analysis and its
application to geomechanics problems have provided geotechnical
engineers with extremely powerful tools. One of the most important
problems in geotechnical engineering is the slope stability
assessment. It is a very difficult task due to several aspects such the
nature of the problem, experimental consideration, monitoring,
controlling, and assessment. The main objective of this paper is to
perform a comparative numerical study between the following
methods: The Limit Equilibrium (LEM), Finite Element (FEM),
Limit Analysis (LAM) and Distinct Element (DEM). The comparison
is conducted in terms of the safety factors and the critical slip
surfaces. Through the results, we see the feasibility to analyse slope
stability by many methods.
Abstract: The aim of this work is to present a low cost adsorbent
for removing toxic heavy metals from aqueous solutions. Therefore,
we are interested to investigate the efficiency of natural clay minerals
collected from south Tunisia and their modified form using sulfuric
acid in the removal of toxic metal ions: Zn(II) and Pb(II) from
synthetic waste water solutions. The obtained results indicate that
metal uptake is pH-dependent and maximum removal was detected to
occur at pH 6. Adsorption equilibrium is very rapid and it was
achieved after 90 min for both metal ions studied. The kinetics results
show that the pseudo-second-order model describes the adsorption
and the intraparticle diffusion models are the limiting step. The
treatment of natural clay with sulfuric acid creates more active sites
and increases the surface area, so it showed an increase of the
adsorbed quantities of lead and zinc in single and binary systems. The
competitive adsorption study showed that the uptake of lead was
inhibited in the presence of 10 mg/L of zinc. An antagonistic binary
adsorption mechanism was observed. These results revealed that clay
is an effective natural material for removing lead and zinc in single
and binary systems from aqueous solution.
Abstract: The present study focused on carrying out the creep analysis in an isotropic thick-walled composite cylindrical pressure vessel composed of aluminum matrix reinforced with silicon-carbide in particulate form. The creep behavior of the composite material has been described by the threshold stress based creep law. The values of stress exponent appearing in the creep law were selected as 3, 5 and 8. The constitutive equations were developed using well known von-Mises yield criteria. Models were developed to find out the distributions of creep stress and strain rate in thick-walled composite cylindrical pressure vessels under internal pressure. In order to obtain the stress distributions in the cylinder, the equilibrium equation of the continuum mechanics and the constitutive equations are solved together. It was observed that the radial stress, tangential stress and axial stress increases along with the radial distance. The cross-over was also obtained almost at the middle region of cylindrical vessel for tangential and axial stress for different values of stress exponent. The strain rates were also decreasing in nature along the entire radius.
Abstract: Even its content is rich in antioxidants ϒ-oryzanol, rice bran is not used properly as functional food. This research aims to (1) extract ϒ-oryzanol; (2) determine the solubility of ϒ-oryzanol in supercritical CO2 based on phase equilibrium theory; and (3) study the effect of process variables on solubility. Extraction experiments were carried out for rice bran (5 g) at various extraction pressures, temperatures and reaction times. The flowrate of supercritical fluid through the extraction vessel was 25 g/min. The extracts were collected and analysed with high-pressure liquid chromatography (HPLC). The conclusion based on the experiments are as: (1) The highest experimental solubility was 0.303 mcg/mL RBO at T= 60°C, P= 90 atm, t= 30 min; (2) Solubility of ϒ-oryzanol was influenced by pressure and temperature. As the pressure and temperature increase, the solubility increases; (3) The solubility data of supercritical extraction can be successfully determined using phase equilibrium theory. Meanwhile, tocopherol was found and slightly investigated in this work.
Abstract: In this paper, applying frequency domain approach, a
delayed competitive web-site system is investigated. By choosing
the parameter α as a bifurcation parameter, it is found that Hopf
bifurcation occurs as the bifurcation parameter α passes a critical
values. That is, a family of periodic solutions bifurcate from the
equilibrium when the bifurcation parameter exceeds a critical value.
Some numerical simulations are included to justify the theoretical
analysis results. Finally, main conclusions are given.
Abstract: Textile industries cater to varied customer preferences and contribute substantially to the economy. However, these textile industries also produce a considerable amount of effluents. Prominent among these are the azo dyes which impart considerable color and toxicity even at low concentrations. Azo dyes are also used as coloring agents in food and pharmaceutical industry. Despite their applications, azo dyes are also notorious pollutants and carcinogens. Popular techniques like photo-degradation, biodegradation and the use of oxidizing agents are not applicable for all kinds of dyes, as most of them are stable to these techniques. Chemical coagulation produces a large amount of toxic sludge which is undesirable and is also ineffective towards a number of dyes. Most of the azo dyes are stable to UV-visible light irradiation and may even resist aerobic degradation. Adsorption has been the most preferred technique owing to its less cost, high capacity and process efficiency and the possibility of regenerating and recycling the adsorbent. Adsorption is also most preferred because it may produce high quality of the treated effluent and it is able to remove different kinds of dyes. However, the adsorption process is influenced by many variables whose inter-dependence makes it difficult to identify optimum conditions. The variables include stirring speed, temperature, initial concentration and adsorbent dosage. Further, the internal diffusional resistance inside the adsorbent particle leads to slow uptake of the solute within the adsorbent. Hence, it is necessary to identify optimum conditions that lead to high capacity and uptake rate of these pollutants. In this work, commercially available activated carbon was chosen as the adsorbent owing to its high surface area. A typical azo dye found in textile effluent waters, viz. the monoazo Acid Orange 10 dye (CAS: 1936-15-8) has been chosen as the representative pollutant. Adsorption studies were mainly focused at obtaining equilibrium and kinetic data for the batch adsorption process at different process conditions. Studies were conducted at different stirring speed, temperature, adsorbent dosage and initial dye concentration settings. The Full Factorial Design was the chosen statistical design framework for carrying out the experiments and identifying the important factors and their interactions. The optimum conditions identified from the experimental model were validated with actual experiments at the recommended settings. The equilibrium and kinetic data obtained were fitted to different models and the model parameters were estimated. This gives more details about the nature of adsorption taking place. Critical data required to design batch adsorption systems for removal of Acid Orange 10 dye and identification of factors that critically influence the separation efficiency are the key outcomes from this research.
Abstract: The tradition competitive newsvendor game assumes decision makers are rational. However, there are behavioral biases when people make decisions, such as loss aversion, mental accounting and overconfidence. Overestimation of a subject’s own performance is one type of overconfidence. The objective of this research is to analyze the impact of the overestimated demand in the newsvendor competitive game with two players. This study builds a competitive newsvendor game model where newsvendors have private information of their demands, which is overestimated. At the same time, demands of each newsvendor forecasted by a third party institution are available. This research shows that the overestimation leads to demand steal effect, which reduces the competitor’s order quantity. However, the overall supply of the product increases due to overestimation. This study illustrates the boundary condition for the overestimated newsvendor to have the equilibrium order drop due to the demand steal effect from the other newsvendor. A newsvendor who has higher critical fractile will see its equilibrium order decrease with the drop of estimation level from the other newsvendor.
Abstract: Ionic liquids are finding a wide range of applications from reaction media to separations and materials processing. In these applications, Vapor–Liquid equilibrium (VLE) is the most important one. VLE for six systems at 353 K and activity coefficients at infinite dilution [(γ)_i^∞] for various solutes (alkanes, alkenes, cycloalkanes, cycloalkenes, aromatics, alcohols, ketones, esters, ethers, and water) in the ionic liquids (1-ethyl-3-methylimidazolium bis (trifluoromethylsulfonyl)imide [EMIM][BTI], 1-hexyl-3-methyl imidazolium bis (trifluoromethylsulfonyl) imide [HMIM][BTI], 1-octyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide [OMIM][BTI], and 1-butyl-1-methylpyrrolidinium bis (trifluoromethylsulfonyl) imide [BMPYR][BTI]) have been used to train neural networks in the temperature range from (303 to 333) K. Densities of the ionic liquids, Hildebrant constant of substances, and temperature were selected as input of neural networks. The networks with different hidden layers were examined. Networks with seven neurons in one hidden layer have minimum error and good agreement with experimental data.
Abstract: Heavy metals have a damaging impact for the environment, animals and humans due to their extreme toxicity and removing them from wastewaters is a very important and interesting task in the field of water pollution control. Biosorption is a relatively new method for treatment of wastewaters and recovery of heavy metals. In this study, a continuous fixed bed study was carried out by using Bacillus thuringiensis as a biosorbent for the removal of Cu and Mn ions from Sarcheshmeh Acid Mine Drainage (AMD). The effect of operating parameters such as flow rate and bed height on the sorption characteristics of B. thuringiensis was investigated at pH 6.0 for each metal ion. The experimental results showed that the breakthrough time decreased with increasing flow rate and decreasing bed height. The data also indicated that the equilibrium uptake of both metals increased with decreasing flow rate and increasing bed height. BDST, Thomas, and Yoon–Nelson models were applied to experimental data to predict the breakthrough curves. All models were found suitable for describing the whole dynamic behavior of the column with respect to flow rate and bed height. In order to regenerate the adsorbent, an elution step was carried out with 1 M HCl and five adsorption-desorption cycles were carried out in continuous manner.
Abstract: Water suspensions of in-organic (metals and oxides)
and organic nano-objects (chitozan and collagen) were subjected to
the treatment of direct and alternative electrical fields. In addition to
quasi-periodical spatial patterning resonance-like performance of
spatial distributions of these suspensions has been found at low
frequencies of alternating electrical field. These resonances are
explained as the result of creation of equilibrium states of groups of
charged nano-objects with opposite signs of charges at the interparticle
distances where the forces of Coulomb attraction are
compensated by the repulsion forces induced by relatively negative
polarization of hydrated regions surrounding the nanoparticles with
respect to pure water. The low frequencies of these resonances are
explained by comparatively big distances between the particles and
their big masses with t\respect to masses of atoms constituting
molecules with high resonance frequencies. These new resonances
open a new approach to detailed modeling and understanding of
mechanisms of the influence of electrical fields on the functioning of
internal organs of living organisms at the level of cells and neurons.
Abstract: In this paper, von Mises and Drucker-Prager yield criteria, as typical ones that consider the effect of intermediate principal stress σ2, have been selected and employed for investigating the influence of σ2 on the solution of a typical stability problem. The bearing capacity factors have been calculated under plane strain condition (strip footing) and axisymmetric condition (circular footing) using the method of stress characteristics together with the criteria mentioned. Different levels of σ2 relative to the other two principal stresses have been considered. While a higher σ2 entry in yield criterion gives a higher bearing capacity; its entry in equilibrium equations (axisymmetric) causes substantial reduction.
Abstract: The customers use the best compromise criterion
between price and quality of service (QoS) to select or change
their Service Provider (SP). The SPs share the same market and
are competing to attract more customers to gain more profit. Due
to the divergence of SPs interests, we believe that this situation is a
non-cooperative game of price and QoS. The game converges to an
equilibrium position known Nash Equilibrium (NE). In this work, we
formulate a game theoretic framework for the dynamical behaviors
of SPs. We use Genetic Algorithms (GAs) to find the price and
QoS strategies that maximize the profit for each SP and illustrate
the corresponding strategy in NE. In order to quantify how this NE
point is performant, we perform a detailed analysis of the price of
anarchy induced by the NE solution. Finally, we provide an extensive
numerical study to point out the importance of considering price and
QoS as a joint decision parameter.
Abstract: To study the dynamic mechanics response of asphalt
pavement under the temperature load and vehicle loading, asphalt
pavement was regarded as multilayered elastic half-space system, and
theory analysis was conducted by regarding dynamic modulus of
asphalt mixture as the parameter. Firstly, based on the dynamic
modulus test of asphalt mixture, function relationship between the
dynamic modulus of representative asphalt mixture and temperature
was obtained. In addition, the analytical solution for thermal stress in
single layer was derived by using Laplace integral transformation and
Hankel integral transformation respectively by using thermal
equations of equilibrium. The analytical solution of calculation model
of thermal stress in asphalt pavement was derived by transfer matrix
of thermal stress in multilayer elastic system. Finally, the variation of
thermal stress in pavement structure was analyzed. The result shows
that there is obvious difference between the thermal stress based on
dynamic modulus and the solution based on static modulus. So the
dynamic change of parameter in asphalt mixture should be taken into
consideration when theoretical analysis is taken out.
Abstract: Hydrogels are three-dimensional, hydrophilic,
polymeric networks composed of homopolymers or copolymers and
are insoluble in water due to the presence of chemical or physical
cross-links. When hydrogels come in contact with aqueous solutions,
they can effectively sorb and retain the dissolved substances,
depending on the nature of the monomeric units comprising the
hydrogel. For this reason, hydrogels have been proposed in several
studies as water purification agents. At the present work anionic
hydrogels bearing negatively charged –COO- groups were prepared
and investigated. These gels are based on sodium acrylate (ANa),
either homopolymerized (poly(sodiumacrylate), PANa) or
copolymerized (P(DMAM-co-ANa)) with N,N Dimethylacrylamide
(DMAM). The hydrogels were used to extract some model organic
dyes from water. It is found that cationic dyes are strongly sorbed and
retained by the hydrogels, while sorption of anionic dyes was
negligible. In all cases it was found that both maximum sorption
capacity and equilibrium binding constant varied from one dye to the
other depending on the chemical structure of the dye, the presence of
functional chemical groups and the hydrophobic-hydrophilic balance.
Finally, the nonionic hydrogel of the homopolymer poly(N,Ndimethylacrylamide),
PDMAM, was also used for reasons of
comparison.
Abstract: This study, tries to suggest a design method based on
displacement using finite difference numerical modeling in
reinforcing soil retaining wall with steel strip. In this case, dynamic
loading characteristics such as duration, frequency, peak ground
acceleration, geometrical characteristics of reinforced soil structure
and type of the site are considered to correct the pseudo static method
and finally introduce the pseudo static coefficient as a function of
seismic performance level and peak ground acceleration. For this
purpose, the influence of dynamic loading characteristics,
reinforcement length, height of reinforced system and type of the site
are investigated on seismic behavior of reinforcing soil retaining wall
with steel strip. Numerical results illustrate that the seismic response
of this type of wall is highly dependent to cumulative absolute
velocity, maximum acceleration, and height and reinforcement length
so that the reinforcement length can be introduced as the main factor
in shape of failure. Considering the loading parameters, geometric parameters of the
wall and type of the site showed that the used method in this study
leads to efficient designs in comparison with other methods, which
are usually based on limit-equilibrium concept. The outputs show the
over-estimation of equilibrium design methods in comparison with
proposed displacement based methods here.
Abstract: Cholera is a disease that is predominately common in
developing countries due to poor sanitation and overcrowding
population. In this paper, a deterministic model for the dynamics of
cholera is developed and control measures such as health educational
message, therapeutic treatment, and vaccination are incorporated in
the model. The effective reproduction number is computed in terms
of the model parameters. The existence and stability of the
equilibrium states, disease free and endemic equilibrium states are
established and showed to be locally and globally asymptotically
stable when R0 < 1 and R0 > 1 respectively. The existence of
backward bifurcation of the model is investigated. Furthermore,
numerical simulation of the model developed is carried out to show
the impact of the control measures and the result indicates that
combined control measures will help to reduce the spread of cholera
in the population.
Abstract: This paper studies a mathematical model based on the
integral equations for dynamic analyzes numerical investigations of a
non-uniform or multi-material composite beam. The beam is
subjected to a sub-tangential follower force and elastic foundation.
The boundary conditions are represented by generalized
parameterized fixations by the linear and rotary springs. A
mathematical formula based on Euler-Bernoulli beam theory is
presented for beams with variable cross-sections. The non-uniform
section introduces non-uniformity in the rigidity and inertia of beams
and consequently, more complicated equilibrium who governs the
equation. Using the boundary element method and radial basis
functions, the equation of motion is reduced to an algebro-differential
system related to internal and boundary unknowns. A generalized
formula for the deflection, the slope, the moment and the shear force
are presented. The free vibration of non-uniform loaded beams is
formulated in a compact matrix form and all needed matrices are
explicitly given. The dynamic stability analysis of slender beam is
illustrated numerically based on the coalescence criterion. A realistic
case related to an industrial chimney is investigated.
Abstract: This paper addresses the issue of resource allocation
in the emerging cognitive technology. Focusing the Quality of
Service (QoS) of Primary Users (PU), a novel method is proposed for
the resource allocation of Secondary Users (SU). In this paper, we
propose the unique Utility Function in the game theoretic model of
Cognitive Radio which can be maximized to increase the capacity of
the Cognitive Radio Network (CRN) and to minimize the
interference scenario. Utility function is formulated to cater the need
of PUs by observing Signal to Noise ratio. Existence of Nash
Equilibrium for the postulated game is established.
Abstract: This work explores the inter-region investment
behaviors of Integrated Circuit (IC) design industry from Taiwan to
China using the amount of foreign direct investment (FDI). According
to the mutual dependence among different IC design industrial
locations, Lotka-Volterra model is utilized to explore the FDI
interactions between South and East China. Effects of inter-regional
collaborations on FDI flows into China are considered. The analysis
results show that FDIs into South China for IC design industry
significantly inspire the subsequent FDIs into East China, while FDIs
into East China for Taiwan’s IC design industry significantly hinder
the subsequent FDIs into South China. Because the supply chain along
IC industry includes upstream IC design, midstream manufacturing, as
well as downstream packing and testing enterprises, IC design industry
has to cooperate with IC manufacturing, packaging and testing
industries in the same area to form a strong IC industrial cluster.
Taiwan’s IC design industry implement the largest FDI amount into
East China and the second largest FDI amount into South China
among the four regions: North, East, Mid-West and South China. If IC
design houses undertake more FDIs in South China, those in East
China are urged to incrementally implement more FDIs into East
China to maintain the competitive advantages of the IC supply chain in
East China. On the other hand, as the FDIs in East China rise, the FDIs
in South China will successively decline since capitals have
concentrated in East China. In addition, this investigation proves that
the prediction of Lotka-Volterra model in FDI trends is accurate
because the industrial interactions between the two regions are
included. Finally, this work confirms that the FDI flows cannot reach a
stable equilibrium point, so the FDI inflows into East and South China
will expand in the future.