Abstract: This paper presents a finite element model for a Sandwich Plate containing a piezoelectric core. A sandwich plate with a piezoelectric core is constructed using the shear mode of piezoelectric materials. The orientation of poling vector has a significant effect on deflection and stress induced in the piezo-actuated adaptive sandwich plate. In the present study, the influence of this factor for a clamped-clamped-free-free and simple-simple-free-free square sandwich plate is investigated using Finite Element Method. The study uses ABAQUS (v.6.7) software to derive the finite element model of the sandwich plate. By using this model, the study gives the influences of the poling vector angle on the response of the smart structure and determines the maximum transverse displacement and maximum stress induced.
Abstract: A one-dimensional mathematical model was developed in order to analyze and optimize the latent heat storage wall. The governing equations for energy transport were developed by using the enthalpy method and discretized with volume control scheme. The resulting algebraic equations were next solved iteratively by using TDMA algorithm. A series of numerical investigations were conducted in order to examine the effects of the thickness of the PCM layer on the thermal behavior of the proposed heating system. Results are obtained for thermal gain and temperature fluctuation. The charging discharging process was also presented and analyzed.
Abstract: Cascade refrigeration systems employ series of single stage vapor compression units which are thermally coupled with evaporator/condenser cascades. Different refrigerants are used in each of the circuit depending on the optimum characteristics shown by the refrigerant for a particular application. In the present research study, a steady state thermodynamic model is developed which simulates the working of an actual cascade system. The model provides COP and all other system parameters e.g. total compressor work, temperature, pressure, enthalpy and entropy at different state points. The working fluid in low temperature circuit (LTC) is CO2 (R744) while Ammonia (R717), Propane (R290), Propylene (R1270), R404A and R12 are the refrigerants in high temperature circuit (HTC). The performance curves of Ammonia, Propane, Propylene, and R404A are compared with R12 to find its nearest substitute. Results show that Ammonia is the best substitute of R12.
Abstract: In the present paper, an experimental investigation was conducted to study the thermodynamic of uranium extraction from Tunisian wet phosphoric acid using the synergistic solvent mixture of di-2-ethylhexyl phosphoric acid (DEHPA) and trioctyl phosphine oxid (TOPO) diluted in kerosene. The effect of different factors affecting the extraction process (temperature, TOPO and DEHPA concentrations) has been investigated. The obtained data of temperature effect on the extraction showed that the enthalpy change is -35.8 kJ.mol-1. The slope analysis method was used for determining the stoichiometry of the extracted species.
Abstract: This analysis of Kuosheng nuclear power plant (NPP)
was performed mainly by TRACE, assisted with FRAPTRAN and
FRAPCON. SNAP v2.2.1 and TRACE v5.0p3 are used to develop the
Kuosheng NPP SPU TRACE model which can simulate the turbine
trip without bypass transient. From the analysis of TRACE, the
important parameters such as dome pressure, coolant temperature and
pressure can be determined. Through these parameters, comparing
with the criteria which were formulated by United States Nuclear
Regulatory Commission (U.S. NRC), we can determine whether the
Kuoshengnuclear power plant failed or not in the accident analysis.
However, from the data of TRACE, the fuel rods status cannot be
determined. With the information from TRACE and burn-up analysis
obtained from FRAPCON, FRAPTRAN analyzes more details about
the fuel rods in this transient. Besides, through the SNAP interface, the
data results can be presented as an animation. From the animation, the
TRACE and FRAPTRAN data can be merged together that may be
realized by the readers more easily. In this research, TRACE showed
that the maximum dome pressure of the reactor reaches to 8.32 MPa,
which is lower than the acceptance limit 9.58 MPa. Furthermore,
FRAPTRAN revels that the maximum strain is about 0.00165, which
is below the criteria 0.01. In addition, cladding enthalpy is 52.44 cal/g
which is lower than 170 cal/g specified by the USNRC NUREG-0800
Standard Review Plan.
Abstract: Cubic equations of state (EoS), popular due to their simple mathematical form, ease of use, semi-theoretical nature and reasonable accuracy, are normally fitted to vapor-liquid equilibrium P-v-T data. As a result, they often show poor accuracy in the region near and above the critical point. In this study, the performance of the renowned Peng-Robinson (PR) and Patel-Teja (PT) EoS’s around the critical area has been examined against the P-v-T data of water. Both of them display large deviations at critical point. For instance, PR-EoS exhibits discrepancies as high as 47% for the specific volume, 28% for the enthalpy departure and 43% for the entropy departure at critical point. It is shown that incorporating P-v-T data of the supercritical region into the retuning of a cubic EoS can improve its performance at and above the critical point dramatically. Adopting a retuned acentric factor of 0.5491 instead of its genuine value of 0.344 for water in PR-EoS and a new F of 0.8854 instead of its original value of 0.6898 for water in PT-EoS reduces the discrepancies to about one third or less.
Abstract: Activated carbons were produced from olive stones by a chemical process. The activated carbon (AC) were modified by nitric acid and used as adsorbents for the removal of methylene blue dye from aqueous solution. The activated carbons were characterized by nitrogen adsorption and enthalpy of immersion. Batch adsorption experiments were carried out to study the effect of initial different concentrations solution on dye adsorption properties. Isotherms were fitted to Langmuir model, and corresponding parameters were determined. The results showed that the increase of ration of ZnCl2 leads to increase in apparent surface areas and produces activated carbons with pore structure more developed. However, the maximum MB uptakes for all carbons were determined and correlated with activated carbons characteristics.
Abstract: In this study the enthalpies of dissociation for pure
methane and pure carbon dioxide was calculated using a hydrate
equilibrium data obtained in this study. The enthalpy of dissociation
was determined using Clausius-Clapeyron equation. The results were
compared with the values reported in literature obtained using
various techniques.
Abstract: Adsorption of CS2 vapors has been studied on
different types of activated carbons obtained from different source
raw materials. The activated carbons have different surface areas and
are associated with varying amounts of the carbon-oxygen surface
groups. The adsorption of CS2 vapors is not directly related to surface
area, but is considerably influenced by the presence of carbonoxygen
surface groups. The adsorption decreases on increasing the
amount of carbon-oxygen surface groups on oxidation and increases
when these surface groups are eliminated on degassing. The
adsorption is maximum in case of the 950°-degassed carbon sample
which is almost completely free of any associated oxygen. The
kinetic data as analysed by Empirical diffusion model and Linear
driving force mass transfer model indicate that the adsorption does
not involve Fickian diffusion but may be considered as a pseudo first
order mass transfer process. The activation energy of adsorption and
isosteric enthalpies of adsorption indicate that the adsorption does not
involve interaction between CS2 and carbon-oxygen surface groups,
but hydrophobic interactions between CS2 and C-C atoms in the
carbon lattice.
Abstract: The paper presents a numerical investigation on the
rapid gas decompression in pure nitrogen which is made by using the
one-dimensional (1D) and three-dimensional (3D) mathematical
models of transient compressible non-isothermal fluid flow in pipes.
A 1D transient mathematical model of compressible thermal multicomponent
fluid mixture flow in pipes is presented. The set of the
mass, momentum and enthalpy conservation equations for gas phase
is solved in the model. Thermo-physical properties of multicomponent
gas mixture are calculated by solving the Equation of
State (EOS) model. The Soave-Redlich-Kwong (SRK-EOS) model is
chosen. This model is successfully validated on the experimental data
[1] and shows a good agreement with measurements. A 3D transient
mathematical model of compressible thermal single-component gas
flow in pipes, which is built by using the CFD Fluent code (ANSYS),
is presented in the paper. The set of unsteady Reynolds-averaged
conservation equations for gas phase is solved. Thermo-physical
properties of single-component gas are calculated by solving the Real
Gas Equation of State (EOS) model. The simplest case of gas
decompression in pure nitrogen is simulated using both 1D and 3D
models. The ability of both models to simulate the process of rapid
decompression with a high order of agreement with each other is
tested. Both, 1D and 3D numerical results show a good agreement
between each other. The numerical investigation shows that 3D CFD
model is very helpful in order to validate 1D simulation results if the
experimental data is absent or limited.
Abstract: The paper presents a one-dimensional transient
mathematical model of compressible non-isothermal multicomponent
fluid mixture flow in a pipe. The set of the mass,
momentum and enthalpy conservation equations for gas phase is
solved in the model. Thermo-physical properties of multi-component
gas mixture are calculated by solving the Equation of State (EOS)
model. The Soave-Redlich-Kwong (SRK-EOS) model is chosen. Gas
mixture viscosity is calculated on the basis of the Lee-Gonzales-
Eakin (LGE) correlation. Numerical analysis of rapid gas
decompression process in rich and base natural gases is made on the
basis of the proposed mathematical model. The model is successfully
validated on the experimental data [1]. The proposed mathematical
model shows a very good agreement with the experimental data [1] in
a wide range of pressure values and predicts the decompression in
rich and base gas mixtures much better than analytical and
mathematical models, which are available from the open source
literature.
Abstract: There are three possible effects of Special Theory of
Relativity (STR) on a thermodynamic system. Planck and Einstein
looked upon this process as isobaric; on the other hand Ott saw it as
an adiabatic process. However plenty of logical reasons show that the
process is isotherm. Our phenomenological consideration
demonstrates that the temperature is invariant with Lorenz
transformation. In that case process is isotherm, so volume and
pressure are Lorentz covariant. If the process is isotherm the Boyles
law is Lorentz invariant. Also equilibrium constant and Gibbs energy,
activation energy, enthalpy entropy and extent of the reaction became
Lorentz invariant.
Abstract: The storage of thermal energy as a latent heat of phase
change material (PCM) has created considerable interest among
researchers in recent times. Here, an attempt is made to carry out
numerical investigations to analyze the performance of latent heat
storage units (LHSU) employing phase change material. The
mathematical model developed is based on an enthalpy formulation.
Freezing time of PCM packed in three different shaped containers
viz. rectangular, cylindrical and cylindrical shell is compared. The
model is validated with the results available in the literature. Results
show that for the same mass of PCM and surface area of heat
transfer, cylindrical shell container takes the least time for freezing
the PCM and this geometric effect is more pronounced with an
increase in the thickness of the shell than that of length of the shell.
Abstract: In this paper, the melting of a semi-infinite body as a
result of a moving laser beam has been studied. Because the Fourier
heat transfer equation at short times and large dimensions does not
have sufficient accuracy; a non-Fourier form of heat transfer
equation has been used. Due to the fact that the beam is moving in x
direction, the temperature distribution and the melting pool shape are
not asymmetric. As a result, the problem is a transient threedimensional
problem. Therefore, thermophysical properties such as
heat conductivity coefficient, density and heat capacity are functions
of temperature and material states. The enthalpy technique, used for
the solution of phase change problems, has been used in an explicit
finite volume form for the hyperbolic heat transfer equation. This
technique has been used to calculate the transient temperature
distribution in the semi-infinite body and the growth rate of the melt
pool. In order to validate the numerical results, comparisons were
made with experimental data. Finally, the results of this paper were
compared with similar problem that has used the Fourier theory. The
comparison shows the influence of infinite speed of heat propagation
in Fourier theory on the temperature distribution and the melt pool
size.
Abstract: The paper investigates parallel channel instabilities of
natural circulation boiling water reactor. A thermal-hydraulic model
is developed to simulate two-phase flow behavior in the natural circulation boiling water reactor (NCBWR) with the incorporation of
ex-core components and recirculation loop such as steam separator, down-comer, lower-horizontal section and upper-horizontal section
and then, numerical analysis is carried out for parallel channel
instabilities of the reactor undergoing both in-phase and out-of-phase
modes of oscillations. To analyze the relative effect on stability of the reactor due to inclusion of various ex-core components and
recirculation loop, marginal stable point is obtained at a particular inlet enthalpy of the reactor core without the inclusion of ex-core
components and recirculation loop and then with the inclusion of the
same. Numerical simulations are also conducted to determine the
relative dominance between two modes of oscillations i.e. in-phase and out-of-phase. Simulations are also carried out when the channels
are subjected to asymmetric power distribution keeping the inlet enthalpy same.
Abstract: The first and basic cause of the failure of concrete is repeated freezing (thawing) of moisture contained in the pores, microcracks, and cavities of the concrete. On transition to ice, water existing in the free state in cracks increases in volume, expanding the recess in which freezing occurs. A reduction in strength below the initial value is to be expected and further cycle of freezing and thawing have a further marked effect. By using some experimental parameters like nuclear magnetic resonance variation (NMR), enthalpy-temperature (or heat capacity) variation, we can resolve between the various water states and their effect on concrete properties during cooling through the freezing transition temperature range. The main objective of this paper is to describe the principal type of water responsible for the reduction in strength and structural damage (frost damage) of concrete following repeated freeze –thaw cycles. Some experimental work was carried out at the institute of cryogenics to determine what happens to water in concrete during the freezing transition.
Abstract: CTMA-bentonite and BTEA-Bentonite prepared by Na-bentonite cation exchanged with cetyltrimethylammonium(CTMA) and benzyltriethylammonium (BTEA). Products were characterized by XRD and IR techniques.The d001 spacing value of CTMA-bentonite and BTEA-bentonite are 7.54Å and 3.50Å larger than that of Na-bentonite at 100% cation exchange capacity, respectively. The IR spectrum showed that the intensities of OH stretching and bending vibrations of the two organoclays decreased greatly comparing to untreated Na-bentonite. Batch experiments were carried out at 303 K, 318 K and 333 K to obtain the sorption isotherms of Crystal violet onto the two organoclays. The results show that the sorption isothermal data could be well described by Freundlich model. The dynamical data for the two organoclays fit well with pseudo-second-order kinetic model. The adsorption capacity of CTMA-bentonite was found higher than that of BTEA-Bentonite. Thermodynamic parameters such as changes in the free energy (ΔG°), the enthalpy (ΔH°) and the entropy (ΔS°) were also evaluated. The overall adsorption process of Crystal violet onto the two organoclays were spontaneous, endothermic physisorption. The CTMA-bentonite and BTEA-Bentonite could be employed as low-cost alternatives to activated carbon in wastewater treatment for the removal of color which comes from textile dyes.
Abstract: Saturated two-phase fluid flows are often subject to
pressure induced oscillations. Due to compressibility the vapor
bubbles act as a spring with an asymmetric non-linear characteristic.
The volume of the vapor bubbles increases or decreases differently if
the pressure fluctuations are compressing or expanding;
consequently, compressing pressure fluctuations in a two-phase pipe
flow cause less displacement in the direction of the pipe flow than
expanding pressure fluctuations. The displacement depends on the
ratio of liquid to vapor, the ratio of pressure fluctuations over average
pressure and on the exciting frequency of the pressure fluctuations.
In addition, pressure fluctuations in saturated vapor bubbles cause
condensation and evaporation within the bubbles and change
periodically the ratio between liquid to vapor, and influence the
dynamical parameters for the oscillation. The oscillations are
conforming to an isenthalpic process at constant enthalpy with no
heat transfer and no exchange of work.
The paper describes the governing non-linear equation for twophase
fluid oscillations with condensation and evaporation, and
presents steady state approximate solutions for free and for pressure
induced oscillations. Resonance criteria and stability are discussed.
Abstract: Aggregation behavior of sodium salicylate and sodium cumene sulfonate was studied in aqueous solution at different temperature. Specific conductivity and relative viscosity were measured at different temperature to find minimum hydrotropic concentration. The thermodynamic parameters (free energy, enthalpy and entropy) were evaluated in the temperature range of 30°C-70°C. The free energy decreased with increase in temperature. The aggregation was found to be exothermic in nature and favored by positive value of entropy.
Abstract: Batch adsorption of recalcitrant melanoidin using the abundantly available coal fly ash was carried out. It had low specific surface area (SBET) of 1.7287 m2/g and pore volume of 0.002245 cm3/g while qualitative evaluation of the predominant phases in it was done by XRD analysis. Colour removal efficiency was found to be dependent on various factors studied. Maximum colour removal was achieved around pH 6, whereas increasing sorbent mass from 10g/L to 200 g/L enhanced colour reduction from 25% to 86% at 298 K. Spontaneity of the process was suggested by negative Gibbs free energy while positive values for enthalpy change showed endothermic nature of the process. Non-linear optimization of error functions resulted in Freundlich and Redlich-Peterson isotherms describing sorption equilibrium data best. The coal fly ash had maximum sorption capacity of 53 mg/g and could thus be used as a low cost adsorbent in melanoidin removal.