Abstract: Polyethylene glycol (PEG) is a condensation polymer of ethylene oxide and water. It is soluble in water and in many organic solvents. PEG is used to make emulsifying agents, detergents, soaps, plasticizers, ointments etc. Ethanol (C2H5OH) also known as ethyl alcohol is a well-known organic compound and has wide applications in chemical industry as it is used as a solvent for paint, varnish, in preserving biological specimens, used as a fuel mixed with petrol etc. Though their chemical and physical properties are already studied, still because of their uses in day to day life the authors thought it is better to study some more of their physical properties like ultrasonic velocity and hence adiabatic compressibility, free length, etc. A detailed study of such properties and some excess parameters like excess adiabatic compressibility, excess free volume and few more in the liquid mixtures of these two compounds with PEG as a solute and Ethanol as a solvent at various mole fractions may throw some light on deeper understanding of molecular interaction between the solute and the solvent supported by NMR, IR etc. Hence the present research work is on ultrasonics/allied studies on these two liquid mixtures. Ultrasonic velocity (U), density (ρ) and viscosity (η) at room temperature and at different mole fraction from 0 to 0.055 of ethanol in PEG have been experimentally carried out by the authors. Acoustical parameters such as adiabatic compressibility (β), free volume (Vf), acoustic impedance (Z), internal pressure (πi), intermolecular free length (Lf) and relaxation time (τ) were calculated from the experimental data. We have calculated excess parameters like excess adiabatic compressibility (βE), excess internal pressure (πiE) free length (LfE) and excess acoustic impedance (ZE) etc for these two chosen liquid mixtures. The excess compressibility is positive and maximum around a mole fraction 0.007 and excess internal pressure is negative and maximum at the same mole fraction and longer free length. The results are analyzed and it may be concluded that the molecular interactions between the solute and the solvent is not strong and it may be weak. Appropriate graphs are drawn.
Abstract: Potential synthesis of a series of 3-amino-4-arylazothiophene derivatives from reaction of 2-cyano-2-phenylthiocarbamoyl acetamide and the appropriate α-halogenated reagents, followed by coupling with different aryl diazonium salts (Japp-Klingemann reaction), and another series of 5-arylazo-thiazol-2-ylcarbamoyl-thiophene derivatives from base-catalyzed intramolecular condensation of 5-arylazo-2-(N-chloroacetyl)amino-thiazole with selected b-keto compounds (Thorpe-Ziegler reaction) was performed. The biological activity of the two series was studied in vitro. Their versatility for pharmaceutical purposes was reported, where they displayed remarkable activities against selected pathogenic microorganisms; Bacillus subtilis, Staphylococcus aureus (Gram positive bacteria), Escherichia coli, Pseudomonas aeruginosa (Gram negative bacteria), and Aspergillus flavus, Candida albicans (fungi) with various degrees related to their chemical structures.
Abstract: In order to investigate the properties of coral reef origin secondary aerosol and especially the contribution of secondary organic aerosol, ethanol affinity to atmospheric nucleation mode particles (diameter
Abstract: This work reports on the fabrication of tin nanoclusters by sputtering and inert-gas condensation inside an ultra-high vacuum compatible system. This technique allows to fine tune the size and yield of nanoclusters by controlling the nanocluster source parameters. The produced nanoclusters are deposited on SiO2/Si substrate with pre-formed electrical electrodes to produce a nanocluster device. Those devices can be potentially used for gas sensor applications.
Abstract: A presentation of the design of the Organic Rankine cycle (ORC) with heat regeneration and superheating processes is a subject of this paper. The maximum temperature level in the ORC is considered to be 110°C and the maximum pressure varies up to 2.5MPa. The selection process of the appropriate working fluids, thermal design and calculation of the cycle and its components are described. With respect to the safety, toxicity, flammability, price and thermal cycle efficiency, the working fluid selected is R134a. As a particular example, the thermal design of the condenser used for the ORC engine with a theoretical thermal power of 179 kW was introduced. The minimal heat transfer area for a completed condensation was determined to be approximately 520m2.
Abstract: This work presents results of moist air condensation in heat exchanger. It describes theoretical knowledge and definition of moist air. Model with geometry of square canal was created for better understanding and postprocessing of condensation phenomena. Different approaches were examined on this model to find suitable software and model. Obtained knowledge was applied to geometry of real heat exchanger and results from experiment were compared with numerical results. One of the goals is to solve this issue without creating any user defined function in the applied code. It also contains summary of knowledge and outlook for future work.
Abstract: With the long-term objective of Critical Heat Flux (CHF) prediction, a Direct Numerical Simulation (DNS) framework for simulation of subcooled and saturated nucleate pool boiling is developed. One case of saturated, and three cases of subcooled boiling at different subcooling levels are simulated. Grid refinement study is also reported. Both boiling and condensation phenomena can be computed simultaneously in the proposed numerical framework. Computed bubble detachment diameters of the saturated nucleate pool boiling cases agree well with the experiment. The flow structures around the growing bubble are presented and the accompanying physics is described. The relation between heat flux evolution from the heated wall and the bubble growth is studied, along with investigations of temperature distribution and flow field evolutions.
Abstract: There are several ways of improving the performance of a vapor compression refrigeration cycle. Use of an ejector as expansion device is one of the alternative ways. The present paper aims at evaluate the performance improvement of a vapor compression refrigeration cycle under a wide range of operating conditions. A numerical model is developed and a parametric study of important parameters such as condensation (30-50°C) and evaporation temperatures (-20-5°C), nozzle and diffuser efficiencies (0.75-0.95), subcooling and superheating degrees (0-15K) are investigated. The model verification gives a good agreement with the literature data. The simulation results revealed that condensation temperature has the highest effect (129%) on the performance improvement ratio while superheating has the lowest one (6.2%). Among ejector efficiencies, the diffuser efficiency has a significant effect on the COP of ejector expansion refrigeration cycle. The COP improvement percentage decreases from 10.9% to 4.6% as subcooling degrees increases by 15K.
Abstract: The significance of psychology in studying politics
is embedded in philosophical issues as well as behavioural
pursuits. For the former is often associated with Sigmund Freud
and his followers. The latter is inspired by the writings of Harold
Lasswell. Political psychology or psychopolitics has its own
impression on political thought ever since it deciphers the concept
of human nature and political propaganda. More importantly,
psychoanalysis views political thought as a textual content which
needs to explore the latent from the manifest content. In other
words, it reads the text symptomatically and interprets the hidden
truth. This paper explains the paradigm of dream interpretation
applied by Freud. The dream work is a process which has four
successive activities: condensation, displacement, representation
and secondary revision. The texts dealing with political though can
also be interpreted on these principles. Freud's method of dream
interpretation draws its source after the hermeneutic model of
philological research. It provides theoretical perspective and
technical rules for the interpretation of symbolic structures. The
task of interpretation remains a discovery of equivalence of
symbols and actions through perpetual analogies. Psychoanalysis
can help in studying political thought in two ways: to study the text
distortion, Freud's dream interpretation is used as a paradigm
exploring the latent text from its manifest text; and to apply Freud's
psychoanalytic concepts and theories ranging from individual mind
to civilization, religion, war and politics.
Abstract: Novel polystrene-bound Schiff bases and their Pt(IV)
complexes have been prepared from condensation reaction of
polystyrene-A-NH2 with 2-hydroxybenzaldehyde and 5-fluoro-3-
bromo-2-hydroxybenzaldehyde. The structures of Pt(IV) complexes
with polystyrene including Schiff bases have been determined by
elemental analyses, magnetic susceptibility, IR, 1H-NMR, UV-vis,
TG/DTA and AAS. The antibacterial and antifungal activities of the
synthesized compounds have been studied by the well-diffusion
method against some selected microorganisms: (Bacillus cereus spp.,
Listeria monocytogenes 4b, Micrococcus luteus, Staphylococcus
aureus, Staphylococcus epidermis, Brucella abortus, Escherichia
coli, Pseudomonas putida spp., Shigella dysenteria type 10,
Salmonella typhi H).
Abstract: Zinc oxide thin films with various microstructures
were grown on substrates by using HCOOH-sols. The reaction
mechanism of the sol system was investigated by performing an XPS
analysis of as-synthesized films, due to the products of hydrolysis
and condensation in the sol system contributing to the chemical state
of the as-synthesized films. The chemical structures of the assynthesized
films related to the microstructures of the final annealed
films were also studied. The results of the Zn 2p3/2, C 1s and O1s
XPS patterns indicate that the hydrolysis reaction in the sol system is
strongly influenced by the HCOOH agent. The results of XRD and
FE-SEM demonstrated the microstructures of the annealed films are
related to the content of hydrolyzed zinc hydrate (Zn-OH) species
present, and that content of the Zn-OH species in the sol system
increases the HCOOH adding, and these Zn-OH species existing in
the sol phase are responsible for large ZnO crystallites in the final
annealed films.
Abstract: Tea is a widely consumed beverage that contains many components. Caffeine belongs to this group of components called alkaloids contain nitrogen. In this study caffeine contents of three types of Turkish teas are determined by using extraction method. After condensation process, residue of caffeine and oil are obtained with evaporation. The oil which is in the residue is removed by hot water. Extraction process performed by using chloroform and the crude caffeine is obtained. From the results of experiments, caffeine contents are found in black tea, green tea and earl grey tea as 3.57±0.43%, 3.11±0.02%, 4.29±0.27%, respectively. Caffeine contents which are found in 1, 5 and 10 cups of tea are calculated. Furthermore, the daily intake of caffeine from black teas that affects human health is investigated.
Abstract: Bubble generation was observed using a high-speed
camera in subcooled flow boiling at low void fraction. Constant heat
flux was applied on one side of an upward rectangular channel to
make heated test channel. Water as a working fluid from high
subcooling to near saturation temperature was injected step by step to
investigate bubble behavior during void development. Experiments
were performed in two different pressures condition close to 2bar and
4bar. It was observed that in high subcooling when boiling was
commenced, bubble after nucleation departed its origin and slid
beside heated surface. In an observation window mean release
frequency of bubble fb,mean, nucleation site Ns and mean bubble
volume Vb,mean in each step of experiments were measured to
investigate wall vaporization rate. It was found that in proximity of
PNVG vaporization rate was increased significantly in compare with
condensation rate which remained in low value.
Abstract: Two-phase frictional pressure drop data were
obtained for condensation of carbon dioxide in single horizontal
micro tube of inner diameter ranged from 0.6 mm up to 1.6 mm over
mass flow rates from 2.5*10-5 to 17*10-5 kg/s and vapor qualities
from 0.0 to 1.0. The inlet condensing pressure is changed from 33.5
to 45 bars. The saturation temperature ranged from -1.5 oC up to 10
oC. These data have then been compared against three (two-phase)
frictional pressure drop prediction methods. The first method is by
Muller-Steinhagen and Heck (Muller-Steinhagen H, Heck K. A
simple friction pressure drop correlation for two-phase flow in pipes.
Chem. Eng. Process 1986;20:297–308) and that by Gronnerud R.
Investigation of liquid hold-up, flow-resistance and heat transfer in
circulation type evaporators, part IV: two-phase flow resistance in
boiling refrigerants, Annexe 1972. Then the method used by
FriedelL. Improved friction pressures drop in horizontal and vertical
two-phase pipe flow. European Two-Phase Flow Group Meeting,
Paper E2; 1979 June, Ispra, Italy. The methods are used by M.B Ould
Didi et al (2001) “Prediction of two-phase pressure gradients of
refrigerant in horizontal tubes". Int.J.of Refrigeration 25(2002) 935-
947. The best available method for annular flow was that of Muller-
Steinhagen and Heck. It was observed that the peak in the two-phase
frictional pressure gradient is at high vapor qualities.
Abstract: In this work, the condensation fraction and transition
temperature of neutral many bosonic system are studied within the
static fluctuation approximation (SFA). The effect of the potential
parameters such as the strength and range on the condensate fraction
was investigated. A model potential consisting of a repulsive step
potential and an attractive potential well was used. As the potential
strength or the core radius of the repulsive part increases, the
condensation fraction is found to be decreased at the same
temperature. Also, as the potential depth or the range of the attractive
part increases, the condensation fraction is found to be increased. The
transition temperature is decreased as the potential strength or the
core radius of the repulsive part increases, and it increases as the
potential depth or the range of the attractive part increases.
Abstract: Global temperature had increased by about 0.5oC over
the past century, increasing temperature leads to a loss or a decrease
of soil organic matter (SOM). Whereas soil organic matter in many
tropical soils is less stable than that of temperate soils, and it will be
easily affected by climate change. Therefore, conservation of soil
organic matter is urgent issue nowadays. This paper presents the
effect of different doses (5%, 15%) of Ca-type zeolite in conjunction
with organic manure, applied to soil samples from Philippines,
Paraguay and Japan, on the decomposition resistance of soil organic
matter under high temperature. Results showed that a remain or
slightly increase the C/N ratio of soil. There are an increase in
percent of humic acid (PQ) that extracted with Na4P2O7. A decrease
of percent of free humus (fH) after incubation was determined. A
larger the relative color intensity (RF) value and a lower the color
coefficient (6logK) value following increasing zeolite rates leading
to a higher degrees of humification. The increase in the aromatic
condensation of humic acid (HA) after incubation, as indicates by the
decrease of H/C and O/C ratios of HA. This finding indicates that the
use of zeolite could be beneficial with respect to SOM conservation
under global warming condition.
Abstract: An experimental study is realized in order to verify the
Mini Heat Pipe (MHP) concept for cooling high power dissipation
electronic components and determines the potential advantages of
constructing mini channels as an integrated part of a flat heat pipe. A
Flat Mini Heat Pipe (FMHP) prototype including a capillary structure
composed of parallel rectangular microchannels is manufactured and
a filling apparatus is developed in order to charge the FMHP. The
heat transfer improvement obtained by comparing the heat pipe
thermal resistance to the heat conduction thermal resistance of a
copper plate having the same dimensions as the tested FMHP is
demonstrated for different heat input flux rates. Moreover, the heat
transfer in the evaporator and condenser sections are analyzed, and
heat transfer laws are proposed. In the theoretical part of this work, a
detailed mathematical model of a FMHP with axial microchannels is
developed in which the fluid flow is considered along with the heat
and mass transfer processes during evaporation and condensation.
The model is based on the equations for the mass, momentum and
energy conservation, which are written for the evaporator, adiabatic,
and condenser zones. The model, which permits to simulate several
shapes of microchannels, can predict the maximum heat transfer
capacity of FMHP, the optimal fluid mass, and the flow and thermal
parameters along the FMHP. The comparison between experimental
and model results shows the good ability of the numerical model to
predict the axial temperature distribution along the FMHP.
Abstract: Saturated two-phase fluid flows are often subject to
pressure induced oscillations. Due to compressibility the vapor
bubbles act as a spring with an asymmetric non-linear characteristic.
The volume of the vapor bubbles increases or decreases differently if
the pressure fluctuations are compressing or expanding;
consequently, compressing pressure fluctuations in a two-phase pipe
flow cause less displacement in the direction of the pipe flow than
expanding pressure fluctuations. The displacement depends on the
ratio of liquid to vapor, the ratio of pressure fluctuations over average
pressure and on the exciting frequency of the pressure fluctuations.
In addition, pressure fluctuations in saturated vapor bubbles cause
condensation and evaporation within the bubbles and change
periodically the ratio between liquid to vapor, and influence the
dynamical parameters for the oscillation. The oscillations are
conforming to an isenthalpic process at constant enthalpy with no
heat transfer and no exchange of work.
The paper describes the governing non-linear equation for twophase
fluid oscillations with condensation and evaporation, and
presents steady state approximate solutions for free and for pressure
induced oscillations. Resonance criteria and stability are discussed.
Abstract: The purpose of this work is to establish the theoretical
foundations for calculating and designing the sublimationcondensation
processes in chemical apparatuses which are intended
for production of ultrafine powders of crystalline and amorphous
materials with controlled fractional composition. Theoretic analysis
of the primary processes of nucleation and growth kinetics of the
clusters according to the degree of super-saturation and the
homogeneous or heterogeneous nature of nucleation has been carried
out. The engineering design procedures of desublimation processes
have been offered and tested for modification of the Claus process.
Abstract: Support vector machines (SVMs) are considered to be
the best machine learning algorithms for minimizing the predictive
probability of misclassification. However, their drawback is that for
large data sets the computation of the optimal decision boundary is a
time consuming function of the size of the training set. Hence several
methods have been proposed to speed up the SVM algorithm. Here
three methods used to speed up the computation of the SVM
classifiers are compared experimentally using a musical genre
classification problem. The simplest method pre-selects a random
sample of the data before the application of the SVM algorithm. Two
additional methods use proximity graphs to pre-select data that are
near the decision boundary. One uses k-Nearest Neighbor graphs and
the other Relative Neighborhood Graphs to accomplish the task.