Abstract: The present paper discusses the selection of process
parameters for obtaining optimal nanocrystallites size in the CuOZrO2
catalyst. There are some parameters changing the inorganic
structure which have an influence on the role of hydrolysis and
condensation reaction. A statistical design test method is
implemented in order to optimize the experimental conditions of
CuO-ZrO2 nanoparticles preparation. This method is applied for the
experiments and L16 orthogonal array standard. The crystallites size
is considered as an index. This index will be used for the analysis in
the condition where the parameters vary. The effect of pH, H2O/
precursor molar ratio (R), time and temperature of calcination,
chelating agent and alcohol volume are particularity investigated
among all other parameters. In accordance with the results of
Taguchi, it is found that temperature has the greatest impact on the
particle size. The pH and H2O/ precursor molar ratio have low
influences as compared with temperature. The alcohol volume as
well as the time has almost no effect as compared with all other
parameters. Temperature also has an influence on the morphology
and amorphous structure of zirconia. The optimal conditions are
determined by using Taguchi method. The nanocatalyst is studied by
DTA-TG, XRD, EDS, SEM and TEM. The results of this research
indicate that it is possible to vary the structure, morphology and
properties of the sol-gel by controlling the above-mentioned
parameters.
Abstract: Natural gas flow contains undesirable solid particles,
liquid condensation, and/or oil droplets and requires reliable
removing equipment to perform filtration. Recent natural gas
processing applications are demanded compactness and reliability of
process equipment. Since conventional means are sophisticated in
design, poor in efficiency, and continue lacking robust, a supersonic
nozzle has been introduced as an alternative means to meet such
demands.
A 3-D Convergent-Divergent Nozzle is simulated using
commercial Code for pressure ratio (NPR) varies from 1.2 to 2. Six
different shapes of nozzle are numerically examined to illustrate the
position of shock-wave as such spot could be considered as a
benchmark of particle separation. Rectangle, triangle, circular,
elliptical, pentagon, and hexagon nozzles are simulated using Fluent
Code with all have same cross-sectional area.
The simple one-dimensional inviscid theory does not describe the
actual features of fluid flow precisely as it ignores the impact of
nozzle configuration on the flow properties. CFD Simulation results,
however, show that nozzle geometry influences the flow structures
including location of shock wave.
The CFD analysis predicts shock appearance when p01/pa>1.2 for
almost all geometry and locates at the lower area ratio (Ae/At).
Simulation results showed that shock wave in Elliptical nozzle has
the farthest distance from the throat among the others at relatively
small NPR. As NPR increases, hexagon would be the farthest. The
numerical result is compared with available experimental data and
has shown good agreement in terms of shock location and flow
structure.
Abstract: This paper aims to perform the second law analysis of
thermodynamics on the laminar film condensation of pure saturated
vapor flowing in the direction of gravity on an ellipsoid with variable
wall temperature. The analysis provides us understanding how the
geometric parameter- ellipticity and non-isothermal wall temperature
variation amplitude “A." affect entropy generation during film-wise
condensation heat transfer process. To understand of which
irreversibility involved in this condensation process, we derived an
expression for the entropy generation number in terms of ellipticity
and A. The result indicates that entropy generation increases with
ellipticity. Furthermore, the irreversibility due to finite temperature
difference heat transfer dominates over that due to condensate film
flow friction and the local entropy generation rate decreases with
increasing A in the upper half of ellipsoid. Meanwhile, the local
entropy generation rate enhances with A around the rear lower half of
ellipsoid.
Abstract: The thermal, epithermal and fast fluxes were
calculated for three irradiation channels at Egypt Second Research
Reactor (ETRR-2) using CITVAP code. The validity of the
calculations was verified by experimental measurements. There are
some deviations between measurements and calculations. This is due
to approximations in the calculation models used, homogenization of
regions, condensation of energy groups and uncertainty in nuclear
data used. Neutron flux data for the three irradiation channels are
now available. This would enable predicting the irradiation
conditions needed for future radioisotope production.
Abstract: In this study, direct numerical simulation for the bubble condensation in the subcooled boiling flow was performed. The main goal was to develop the CFD modeling for the bubble condensation and to evaluate the accuracy of the VOF model with the developed CFD modeling. CFD modeling for the bubble condensation was developed by modeling the source terms in the governing equations of VOF model using UDF. In the modeling, the amount of condensation was determined using the interfacial heat transfer coefficient obtained from the bubble velocity, liquid temperature and bubble diameter every time step. To evaluate the VOF model using the CFD modeling for the bubble condensation, CFD simulation results were compared with SNU experimental results such as bubble volume and shape, interfacial area, bubble diameter and bubble velocity. Simulation results predicted well the behavior of the actual condensing bubble. Therefore, it can be concluded that the VOF model using the CFD modeling for the bubble condensation will be a useful computational fluid dynamics tool for analyzing the behavior of the condensing bubble in a wide range of the subcooled boiling flow.
Abstract: This paper discuss the separation of the miscible
liquids by means of fractional distillation. For complete separation of
liquids, the process of heating, condensation, separation and storage
is done automatically to achieve the objective. PIC micro-controller
has been used to control each and every process of the work. The
controller also controls the storage process by activating and deactivating
the conveyors. The liquids are heated which on reaching
their respective boiling points evaporate and enter the condensation
chamber where they convert into liquid. The liquids are then directed
to their respective tanks by means of stepper motor which moves in
three directions, each movement into different tank. The tank on
filling sends the signal to controller which then opens the solenoid
valves. The tank is emptied into the beakers below the nozzle. As the
beaker filled, the nozzle closes and the conveyors come into
operation. The filled beaker is replaced by an empty beaker from
behind. The work can be used in oil industries, chemical industries
and paint industries.