Pt(IV) Complexes with Polystrene-bound Schiff Bases as Antimicrobial Agent: Synthesis and Characterization
Novel polystrene-bound Schiff bases and their Pt(IV)
complexes have been prepared from condensation reaction of
polystyrene-A-NH2 with 2-hydroxybenzaldehyde and 5-fluoro-3-
bromo-2-hydroxybenzaldehyde. The structures of Pt(IV) complexes
with polystyrene including Schiff bases have been determined by
elemental analyses, magnetic susceptibility, IR, 1H-NMR, UV-vis,
TG/DTA and AAS. The antibacterial and antifungal activities of the
synthesized compounds have been studied by the well-diffusion
method against some selected microorganisms: (Bacillus cereus spp.,
Listeria monocytogenes 4b, Micrococcus luteus, Staphylococcus
aureus, Staphylococcus epidermis, Brucella abortus, Escherichia
coli, Pseudomonas putida spp., Shigella dysenteria type 10,
Salmonella typhi H).
[1] M. Turky─▒lmaz, M. Kacan, Y. Baran, "Structure, spectroscopic, thermal
properties and catalytic activity of iron(III)-Schiff base complexes,"
Inorg. Chim. Acta, vol. 395 pp. 255-259, January 2013.
[2] M. Shamsipur, A. Soleymanpour, M. Akhond, H. Sharghi, M. Ali
Naseri, "Ioide-selective carbon paste electrodes based on recently
synthesized Schiff base complexes of Fe(III) ," Analyt. Chim. Acta, vol.
450, pp. 37-44, December 2001.
[3] K.C. Gupta, A. K. Sutar, "Catalytic activities of Schiff base transition
metal complexes," Coord. Chem. Rev. vol. 252, pp. 1420-1450,
September 2008.
[4] A. Trzesowska-Kruszynska, "Copper complex of glycine Schiff base: In
situ ligand synthesis, structure, spectral, and thermal properties," J. Mol.
Struct. vol. 1017, pp. 72-78, June 2012.
[5] K. E. Uhrich, S. M. Cannizzaro, R.S. Langer, K. M. Shakesheff,
"Polymeric Systems for Controlled Drug Release," Chem. Rev. vol.
99(11), pp. 3189-3198, November 1999.
[6] Young-Ee Kwan, Kyu-Ja Whang, Young-Ja Park, Kuk Hwan Kim,
"Synthesis, characterization and antitumör activity of novel octahedral
Pt(IV) complexes," Bio. Med. Chem., vol. 11, pp. 1669-1676, January
2003.
[7] K.S. Siddiqi, R.I. Kureshy, N.H. Khan, S. Tabassum, S.A.A. Zaidi,
"Characterization and toxicity of lanthanide complexes with nitrogenand
sulphur-containing Schiff bases," Inorg. Chim. Acta, vol. 151, pp.
95-100, February 1998.
[8] E. Bozkır, N. Sarı, H. Öğütcü, "Polystyrene containing
carbinolamine/Azomethine Potentially Useful as Antimicrobial
Agent:Synthesis and Biological Evaluation," J. Inorg. Organomet.
Polym. vol. 22, pp. 1146-1155, June 2012.
[9] C. Selvi, D. Nartop, "Novel polymer anchored Cr(III) Schiff base
complexes:Synthesis, characterization and antimicrobial properties",
Spec. Chimica. Acta Part A, vol. 95, pp. 165-171, September 2012.
[10] G. Socrates, Infrared and Raman Characteristic Group Frequencies, John
Wiley&Sons Ltd., New York, 2001.
[11] A. M. Ali, A. H. Ahmed, T. A. Mohammed, B. H. Mohammed,
"Geometrical studies on iron(III), palladium(II) and platinum(IV)
complexes of bis-Schiff bases derived from aromatic diammine and
corrosion inhibitions of ligands," J. Appl. Sci. Res., vol. 3, pp. 109-118,
2007.
[12] A. J. Abdul-Ghani, A. M. N. Khaleel, "Synthesis and characterization of
new Schiff bases derived from N (1)-substituted isatin with
dithiooxamide and their Co(II), Ni(II), Cu(II), Pd(II), and Pt(IV)
complexes," Bioinorg Chem Appl., vol. 2009, pp. 12, October 2009.
[13] M. J. Corbel, "Brucellosis: an overview. Emerging Infectious
Diseases," Emerging Infectious Diseases Journal, vol: 3, pp. 213, June
1997.
[14] M. Gloria, R. Diez-Orejas, F. Navarro -Garcia, L. Monteoliva, C. Gill,
M. Sanchez-Perez, C. Nombela, "Candida albicans: genetics,
dimorphism and pathogenicity," Internatl. Microbiol., vol. 1, pp. 95-
106, 1998.
[1] M. Turky─▒lmaz, M. Kacan, Y. Baran, "Structure, spectroscopic, thermal
properties and catalytic activity of iron(III)-Schiff base complexes,"
Inorg. Chim. Acta, vol. 395 pp. 255-259, January 2013.
[2] M. Shamsipur, A. Soleymanpour, M. Akhond, H. Sharghi, M. Ali
Naseri, "Ioide-selective carbon paste electrodes based on recently
synthesized Schiff base complexes of Fe(III) ," Analyt. Chim. Acta, vol.
450, pp. 37-44, December 2001.
[3] K.C. Gupta, A. K. Sutar, "Catalytic activities of Schiff base transition
metal complexes," Coord. Chem. Rev. vol. 252, pp. 1420-1450,
September 2008.
[4] A. Trzesowska-Kruszynska, "Copper complex of glycine Schiff base: In
situ ligand synthesis, structure, spectral, and thermal properties," J. Mol.
Struct. vol. 1017, pp. 72-78, June 2012.
[5] K. E. Uhrich, S. M. Cannizzaro, R.S. Langer, K. M. Shakesheff,
"Polymeric Systems for Controlled Drug Release," Chem. Rev. vol.
99(11), pp. 3189-3198, November 1999.
[6] Young-Ee Kwan, Kyu-Ja Whang, Young-Ja Park, Kuk Hwan Kim,
"Synthesis, characterization and antitumör activity of novel octahedral
Pt(IV) complexes," Bio. Med. Chem., vol. 11, pp. 1669-1676, January
2003.
[7] K.S. Siddiqi, R.I. Kureshy, N.H. Khan, S. Tabassum, S.A.A. Zaidi,
"Characterization and toxicity of lanthanide complexes with nitrogenand
sulphur-containing Schiff bases," Inorg. Chim. Acta, vol. 151, pp.
95-100, February 1998.
[8] E. Bozkır, N. Sarı, H. Öğütcü, "Polystyrene containing
carbinolamine/Azomethine Potentially Useful as Antimicrobial
Agent:Synthesis and Biological Evaluation," J. Inorg. Organomet.
Polym. vol. 22, pp. 1146-1155, June 2012.
[9] C. Selvi, D. Nartop, "Novel polymer anchored Cr(III) Schiff base
complexes:Synthesis, characterization and antimicrobial properties",
Spec. Chimica. Acta Part A, vol. 95, pp. 165-171, September 2012.
[10] G. Socrates, Infrared and Raman Characteristic Group Frequencies, John
Wiley&Sons Ltd., New York, 2001.
[11] A. M. Ali, A. H. Ahmed, T. A. Mohammed, B. H. Mohammed,
"Geometrical studies on iron(III), palladium(II) and platinum(IV)
complexes of bis-Schiff bases derived from aromatic diammine and
corrosion inhibitions of ligands," J. Appl. Sci. Res., vol. 3, pp. 109-118,
2007.
[12] A. J. Abdul-Ghani, A. M. N. Khaleel, "Synthesis and characterization of
new Schiff bases derived from N (1)-substituted isatin with
dithiooxamide and their Co(II), Ni(II), Cu(II), Pd(II), and Pt(IV)
complexes," Bioinorg Chem Appl., vol. 2009, pp. 12, October 2009.
[13] M. J. Corbel, "Brucellosis: an overview. Emerging Infectious
Diseases," Emerging Infectious Diseases Journal, vol: 3, pp. 213, June
1997.
[14] M. Gloria, R. Diez-Orejas, F. Navarro -Garcia, L. Monteoliva, C. Gill,
M. Sanchez-Perez, C. Nombela, "Candida albicans: genetics,
dimorphism and pathogenicity," Internatl. Microbiol., vol. 1, pp. 95-
106, 1998.
@article{"International Journal of Chemical, Materials and Biomolecular Sciences:63210", author = "Dilek Nartop and Nurşen Sarı and Hatice Öğütçü", title = "Pt(IV) Complexes with Polystrene-bound Schiff Bases as Antimicrobial Agent: Synthesis and Characterization", abstract = "Novel polystrene-bound Schiff bases and their Pt(IV)
complexes have been prepared from condensation reaction of
polystyrene-A-NH2 with 2-hydroxybenzaldehyde and 5-fluoro-3-
bromo-2-hydroxybenzaldehyde. The structures of Pt(IV) complexes
with polystyrene including Schiff bases have been determined by
elemental analyses, magnetic susceptibility, IR, 1H-NMR, UV-vis,
TG/DTA and AAS. The antibacterial and antifungal activities of the
synthesized compounds have been studied by the well-diffusion
method against some selected microorganisms: (Bacillus cereus spp.,
Listeria monocytogenes 4b, Micrococcus luteus, Staphylococcus
aureus, Staphylococcus epidermis, Brucella abortus, Escherichia
coli, Pseudomonas putida spp., Shigella dysenteria type 10,
Salmonella typhi H).", keywords = "Polymer-bound Schiff bases, polystyrene-A-NH2, Pt(IV) complexes, biological activity.", volume = "7", number = "6", pages = "468-4", }
