Abstract: Over the last decades, worldwide environmental awareness has grown due to the depletion of raw material resources and global warming. This awareness has prompted the development of new products more environmentally friendly. Among these products are biocomposite materials reinforced with natural fibers. The main challenge in developing the use of biocomposites in exterior applications is the lack of knowledge about their durability and the evolution of their mechanical and physicochemical properties in the long term. The aim of this work is to study the photooxidation of unidirectional (UD) composites based on recycled matrix. For this purpose, UD flax fiber composites based on recycled polypropylene were prepared by thermocompression. An accelerated aging test was carried out using a xenon arc WeatherOmeter. The consequences of UV exposure on the chemical composition and morphology of the surface of composites as well as on their tensile mechanical properties have been reported. The results showed that accelerated aging had a significant effect on the surface of these composites while it had little impact on their mechanical properties.
Abstract: Antioxidant-rich extracts were prepared from pomegranate peels, seeds and juice using methanol and ethanol and their antioxidant activity was evaluated by the 1,1-diphenyl-2-picrylhydrazine (DPPH) radical scavenging and Ferric Reducing Antioxidant Power (FRAP) method. Both analytical methods indicated a higher antioxidant activity in extracts prepared from peels, which was comparable to that of butylated hydroxytoluene (BHT). Furthermore, the antioxidant activity was correlated to the phenolic and flavonoid content of the various extracts. The antioxidant effectiveness of the extracts was also assessed using corn oil as the oxidation substrate. More specifically, preheated corn oil samples stabilized with extracts at a concentration of 250 ppm, 500 ppm or 1,000 ppm were subjected to accelerated aging (100 oC, 10 days) and the extent of oxidative alteration was followed by the measurement of the peroxide, conjugated dienes and trienes, as well as p-aniside value. BHT at its legal limit (200 ppm) served as standard besides the control sample. Results from the different parameters were in agreement with each other suggesting that pomegranate extracts can stabilize corn oil effectively under accelerated conditions, at all concentrations tested. However, the magnitude of oil stabilization depended strongly on the amount of extract added and this was positively correlated with their phenolic content. Pomegranate peel extracts, which exhibited the highest not only phenolic and flavonoid content but also antioxidant activity, were more potent in inhibiting oxidative deterioration. Both methanolic and ethanolic peel extracts at a concentration of 500 ppm exerted a stabilizing effect comparable to that of BHT, while at a concentration of 1000 ppm they exhibited higher stabilization efficiency in comparison to BHT. Finally, heating oil samples resulted in a time dependent decrease in their antioxidant capacity. Samples containing peel extracts appeared to retain their antioxidant capacity for a longer period, indicating that these extracts contained active compounds that offered superior antioxidant protection to corn oil.
Abstract: In this paper, a degradation of the photopolymeric material (PhPM), used as printing plate in the flexography reproduction technique, caused by accelerated aging has been observed. Since the basis process for production of printing plates from the PhPM is a radical cross-linking process caused by exposing to UV wavelengths, the assumption was that improper storage or irregular handling of the PhPM plate can change the surface and structure characteristics of the plates. Results have shown that the aging process causes degradation in the structure and changes in the surface of the PhPM printing plate.
Abstract: Building code-related literature provides
recommendations on normalizing approaches to the calculation of
the dynamic properties of structures. Most building codes make a
distinction among types of structural systems, construction material,
and configuration through a numerical coefficient in the
expression for the fundamental period. The period is then used in
normalized response spectra to compute base shear. The typical
parameter used in simplified code formulas for the fundamental
period is overall building height raised to a power determined from
analytical and experimental results. However, reinforced concrete
buildings which constitute the majority of built space in less
developed countries pose additional challenges to the ones built with
homogeneous material such as steel, or with concrete under stricter
quality control. In the present paper, the particularities of reinforced
concrete buildings are explored and related to current methods of
equivalent static analysis. A comparative study is presented between
the Uniform Building Code, commonly used for buildings within
and outside the USA, and data from the Middle East used to model
151 reinforced concrete buildings of varying number of bays, number
of floors, overall building height, and individual story height. The
fundamental period was calculated using eigenvalue matrix
computation. The results were also used in a separate regression
analysis where the computed period serves as dependent variable,
while five building properties serve as independent variables. The
statistical analysis shed light on important parameters that simplified
code formulas need to account for including individual story height,
overall building height, floor plan, number of bays, and concrete
properties. Such inclusions are important for reinforced concrete
buildings of special conditions due to the level of concrete damage,
aging, or materials quality control during construction.
Overall results of the present analysis show that simplified code
formulas for fundamental period and base shear may be applied but
they require revisions to account for multiple parameters. The
conclusion above is confirmed by the analytical model where
fundamental periods were computed using numerical techniques and
eigenvalue solutions. This recommendation is particularly relevant
to code upgrades in less developed countries where it is customary to
adopt, and mildly adapt international codes.
We also note the necessity of further research using empirical data
from buildings in Lebanon that were subjected to severe damage due
to impulse loading or accelerated aging. However, we excluded this
study from the present paper and left it for future research as it has its
own peculiarities and requires a different type of analysis.
Abstract: Overhead electrical insulators form an important link in an electric power system. Along with the traditional insulators (i.e. glass and porcelain, etc) presently the polymeric insulators are also used world widely. These polymeric insulators are very sensitive to various environmental parameters such temperature, environmental pollution, UV-radiations, etc. which seriously effect their electrical, chemical and hydrophobic properties. The UV radiation level in the central region of Saudi Arabia is high as compared to the IEC standard for the accelerated aging of the composite insulators. Commonly used suspension type of composite EPDM (Ethylene Propylene Diene Monomer) insulator was subjected to accelerated stress aging as per modified IEC standard simulating the inland arid deserts atmospheric condition and also as per IEC-61109 standard. The hydrophobic characteristics were studied by measuring the contact angle along the insulator surface before and after the accelerated aging of the samples. It was found that EPDM insulator loses it hydrophobic properties proportional to the intensity of UV irradiations and its rate of recovery is also very low as compared to Silicone Rubber insulator.KeywordsEPDM, composite insulators, accelerated aging, hydrophobicity, contact angle.
Abstract: High voltage generators are being subject to higher
voltage rating and are being designed to operate in harsh conditions.
Stator windings are the main component of generators in which
Electrical, magnetical and thermal stresses remain major failures for
insulation degradation accelerated aging. A large number of
generators failed due to stator winding problems, mainly insulation
deterioration. Insulation degradation assessment plays vital role in the
asset life management. Mostly the stator failure is catastrophic
causing significant damage to the plant. Other than generation loss,
stator failure involves heavy repair or replacement cost. Electro
thermal analysis is the main characteristic for improvement design of
stator slot-s insulation. Dielectric parameters such as insulation
thickness, spacing, material types, geometry of winding and slot are
major design consideration. A very powerful method available to
analyze electro thermal performance is Finite Element Method
(FEM) which is used in this paper. The analysis of various stator coil
and slot configurations are used to design the better dielectric system
to reduce electrical and thermal stresses in order to increase the
power of generator in the same volume of core. This paper describes
the process used to perform classical design and improvement
analysis of stator slot-s insulation.
Abstract: We investigate the ZnO role in the inherent protection
of old manuscripts to protect them against environmental damaging
effect of ultraviolet radiation, pollutant gasses, mold and bacteria. In
this study a cellulosic nanocomposite of ZnO were used as protective
coating on the surface of paper fibers. This layered nanocomposite
can act as a consolidate materials too. Furthermore, to determine how
well paper works screen objects from the damaging effects, two
accelerated aging mechanisms due to light and heat are discussed.
Results show good stability of papers with nanocomposite coating.
Also, a good light stability was shown in the colored paper that
treated with this nanocomposite. Furthermore, to demonstrate the
degree of antifungal and antibacterial properties of coated papers,
papers was treated with four common molds and bacteria and the
good preventive effects of coated paper against molds and bacteria
are described.
Abstract: High voltage generators are being subject to higher
voltage rating and are being designed to operate in harsh conditions.
Stator windings are the main component of generators in which
Electrical, magnetically and thermal stresses remain major failures
for insulation degradation accelerated aging. A large number of
generators failed due to stator winding problems, mainly insulation
deterioration. Insulation degradation assessment plays vital role in the
asset life management. Mostly the stator failure is catastrophic
causing significant damage to the plant. Other than generation loss,
stator failure involves heavy repair or replacement cost. Electro
thermal analysis is the main characteristic for improvement design of
stator slot-s insulation. Dielectric parameters such as insulation
thickness, spacing, material types, geometry of winding and slot are
major design consideration. A very powerful method available to
analyze electro thermal performance is Finite Element Method
(FEM) which is used in this paper. The analysis of various stator coil
and slot configurations are used to design the better dielectric system
to reduce electrical and thermal stresses in order to increase the
power of generator in the same volume of core. This paper describes
the process used to perform classical design and improvement
analysis of stator slot-s insulation.