Abstract: Fibers are extensively used in civil engineering applications for many years. In this study, empty fruit bunch of date palm trees were used to produce cellulose fiber that were used as additives in the asphalt binder. Two sizes (coarse and fine) of cellulose fibers were pre-blended in PG64-22 binder with various contents of 1.5%, 3%, 4.5%, 6%, and 7.5% by weight of asphalt binder. The physical and rheological properties of fiber modified asphalt binders were tested by using conventional tests such as penetration, softening point and viscosity; and SHRP test such as dynamic shear rheometer. The results indicated that the fiber modified asphalt binders were higher in softening point, viscosity, and complex shear modulus, and lower in penetration compared to pure asphalt. The fiber modified binders showed an improvement in rheological properties since it was possible to raise the control binder (pure asphalt) PG from 64 to 70 by adding 6% (by weight) of either fine or coarse fibers. Such improvement in stiffness of fiber modified binder is expected to improve pavement resistance to rutting.
Abstract: We have incorporated the translational rotational (TR)
coupling effects in the framework of three body force shell model
(TSM) to develop an extended TSM (ETSM). The dynamical matrix
of ETSM has been applied to compute the phonon frequencies of
orientationally disordered mixed crystal (ND4Br)x(KBr)1-x in (q00),
(qq0) and (qqq) symmetry directions for compositions 0.10≤x≤0.50
at T=300K.These frequencies are plotted as a function of wave vector
k. An unusual acoustic mode softening is found along symmetry
directions (q00) and (qq0) as a result of translation-rotation coupling.
Abstract: Flexible pavement made with neat asphalt binder is not enough to resist heavy traffic loads as well as harsh environmental condition found in Riyadh region. Therefore, there is a need to modify asphalt binder with polymers to satisfy such conditions. There are several types of polymers that are used to modify asphalt binder. The objective of this paper is to compare the rheological properties of six polymer modified asphalt binders (Lucolast7010, Anglomak2144, Paveflex140, SBS KTR401, EE-2 and Crumb rubber) obtained from asphalt manufacturer plants. The rheological properties of polymer modified asphalt binders were tested using conventional tests such as penetration, softening point and viscosity; and SHRP tests such as dynamic shear rheometer and bending beam rheometer. The results have indicated that the polymer modified asphalt binders have lower penetration and higher softening point than neat asphalt indicating an improvement in stiffness of asphalt binder, and as a result, more resistant to rutting. Moreover, the dynamic shear rheometer results have shown that all modifiers used in this study improved the binder properties and satisfied the Superpave specifications except SBS KTR401 which failed to satisfy the rutting parameter (G*/sinδ).
Abstract: In the process of recovering oil in weak sandstone formations, the strength of sandstones around the wellbore is weakened due to the increase of effective stress/load from the completion activities around the cavity. The weakened and de-bonded sandstone may be eroded away by the produced fluid, which is termed sand production. It is one of the major trending subjects in the petroleum industry because of its significant negative impacts, as well as some observed positive impacts. For efficient sand management therefore, there has been need for a reliable study tool to understand the mechanism of sanding. One method of studying sand production is the use of the widely recognized Discrete Element Method (DEM), Particle Flow Code (PFC3D) which represents sands as granular individual elements bonded together at contact points. However, there is limited knowledge of the particle-scale behavior of the weak sandstone, and the parameters that affect sanding. This paper aims to investigate the reliability of using PFC3D and a simple Darcy flow in understanding the sand production behavior of a weak sandstone. An isotropic tri-axial test on a weak oil sandstone sample was first simulated at a confining stress of 1MPa to calibrate and validate the parallel bond models of PFC3D using a 10m height and 10m diameter solid cylindrical model. The effect of the confining stress on the number of bonds failure was studied using this cylindrical model. With the calibrated data and sample material properties obtained from the tri-axial test, simulations without and with fluid flow were carried out to check on the effect of Darcy flow on bonds failure using the same model geometry. The fluid flow network comprised of every four particles connected with tetrahedral flow pipes with a central pore or flow domain. Parametric studies included the effects of confining stress, and fluid pressure; as well as validating flow rate – permeability relationship to verify Darcy’s fluid flow law. The effect of model size scaling on sanding was also investigated using 4m height, 2m diameter model. The parallel bond model successfully calibrated the sample’s strength of 4.4MPa, showing a sharp peak strength before strain-softening, similar to the behavior of real cemented sandstones. There seems to be an exponential increasing relationship for the bigger model, but a curvilinear shape for the smaller model. The presence of the Darcy flow induced tensile forces and increased the number of broken bonds. For the parametric studies, flow rate has a linear relationship with permeability at constant pressure head. The higher the fluid flow pressure, the higher the number of broken bonds/sanding. The DEM PFC3D is a promising tool to studying the micromechanical behavior of cemented sandstones.
Abstract: Sodium borosilicate glasses doped with different
content of NdF3 mol % have been prepared by rapid quenching
method. Ultrasonic velocities (both longitudinal and shear)
measurements have been carried out at room temperature and at
ultrasonic frequency of 4 MHz. Elastic moduli, Debye temperature,
softening temperature and Poisson's ratio have been obtained as a
function of NdF3 modifier content. Results showed that the elastic
moduli, Debye temperature, softening temperature and Poisson's ratio
have very slight change with the change of NdF3 mol % content.
Based on FTIR spectroscopy and theoretical (Bond compression)
model, quantitative analysis has been carried out in order to obtain
more information about the structure of these glasses. The study
indicated that the structure of these glasses is mainly composed of
SiO4 units with four bridging oxygens (Q4), and with three bridging
and one nonbridging oxygens (Q3).
Abstract: Promotion of the Fiber Reinforced Concrete (FRC) as a construction material for civil engineering projects has invoked numerous researchers to investigate their mechanical behavior. Even though there is satisfactory information about the effects of fiber type and length, concrete mixture, casting type and other variables on the strength and deformability parameters of FRC, the numerical modeling of such materials still needs research attention. The focus of this study is to investigate the feasibility of Concrete Damaged Plasticity (CDP) model in prediction of Macro-synthetic FRC structures behavior. CDP model requires the tensile behavior of concrete to be well characterized. For this purpose, a series of uniaxial direct tension and four point bending tests were conducted on the notched specimens to define bilinear tension softening (post-peak tension stress-strain) behavior. With these parameters obtained, the flexural behavior of macro-synthetic FRC beams were modeled and the results showed a good agreement with the experimental measurements.
Abstract: Graphene, a single-atom sheet, has been considered as
the most promising material for making future nanoelectromechanical
systems as well as purely electrical switching with graphene
transistors. Graphene-based devices have advantages in scaled-up
device fabrication due to the recent progress in large area graphene
growth and lithographic patterning of graphene nanostructures. Here
we investigated its mechanical responses of circular graphene
nanoflake under the nanoindentation using classical molecular
dynamics simulations. A correlation between the load and the
indentation depth was constructed. The nanoindented force in this
work was applied to the center point of the circular graphene nanoflake
and then, the resonance frequency could be tuned by a nanoindented
depth. We found the hardening or the softening of the graphene
nanoflake during its nanoindented-deflections, and such properties
were recognized by the shift of the resonance frequency. The
calculated mechanical parameters in the force-vs-deflection plot were
in good agreement with previous experimental and theoretical works.
This proposed schematics can detect the pressure via the deflection
change or/and the resonance frequency shift, and also have great
potential for versatile applications in nanoelectromechanical systems.
Abstract: Asphalt concrete pavements have a short life cycle,
failing mainly due to temperature changes, traffic loading and ageing.
Modified asphalt mixtures provide the technology to produce a
bituminous binder with improved viscoelastic properties, which
remain in balance over a wider temperature range and loading
conditions. In this research, 60/70 penetration grade asphalt binder
was modified by adding 2, 4, 6, 8 and 10 percent by weight of asphalt
binder following the wet process and the mineral aggregate was
modified by adding 1, 2, 3, 4 and 5 percent crumb rubber by volume
of the mineral aggregate following the dry process. The LDPE
modified asphalt binder rheological properties were evaluated. The
laboratory results showed an increase in viscosity, softening point
and stiffness of the binder. The modified asphalt was then used in
preparing asphalt mixtures by Marshall Mix design procedure. The
Marshall Stability values for mixes containing 2% crumb rubber and
4% LDPE were found to be 30% higher than the conventional asphalt
concrete mix.
Abstract: The nickel-manganese (Ni-Mn) alloy coating prepared
from DC electrodeposition process in sulphamate bath was studied.
The effects of process parameters, such as current density and
electrolyte composition, on the cathodic current efficiency,
microstructure, internal stress and mechanical properties were
investigated. Because of its crucial effect on the application to the
electroforming of microelectronic components, the development of
low internal stress coating with high leveling power was emphasized.
It was found that both the coating’s manganese content and the
cathodic current efficiency increased with the raise in current density.
In addition, the internal stress of the deposited coating showed
compressive nature at low current densities while changed to tensile
one at higher current densities. Moreover, the metallographic
observation, X-ray diffraction measurement, and polarization curve
measurement were conducted. It was found that the Ni-Mn coating
consisted of nano-sized columnar grains and the maximum hardness of
the coating was associated with (111) preferred orientation in the
microstructure. The grain size was refined along with the increase in
the manganese content of the coating, which accordingly, raised its
hardness and resistance to annealing softening. In summary, the
Ni-Mn coating prepared at lower current density of 1-2 A/dm2 had low
internal stress, high leveling power, and better corrosion resistance.
Abstract: Predicting the collapse potential of a structure during
earthquakes is an important issue in earthquake engineering. Many
researchers proposed different methods to assess the collapse
potential of structures under the effect of strong ground motions.
However most of them did not consider degradation and softening
effect in hysteretic behavior. In this study, collapse potential of
SDOF systems caused by dynamic instability with stiffness and
strength degradation has been investigated. An equation was
proposed for the estimation of collapse period of SDOF system which
is a limit value of period for dynamic instability. If period of the
considered SDOF system is shorter than the collapse period then the
relevant system exhibits dynamic instability and collapse occurs.
Abstract: Food is widely packaged with plastic materials to
prevent microbial contamination and spoilage. Ionizing radiation is
widely used to sterilize the food-packaging materials. Sterilization by
γ-radiation causes degradation such as embrittlement, stiffening,
softening, discoloration, odour generation, and decrease in molecular
weight. Many antioxidants can prevent γ-degradation but most of
them are toxic. The migration of antioxidants to its environment
gives rise to major concerns in case of food packaging plastics. In
this attempt, we have aimed to utilize synergistic mixtures of
stabilizers which are approved for food-contact applications.
Ethylene-propylene-diene terpolymer has been melt-mixed with
hindered amine stabilizers (HAS), phenolic antioxidants and organophosphites
(hydroperoxide decomposer). Results were discussed by
comparing the stabilizing efficiency of mixtures with and without
phenol system. Among phenol containing systems where we mostly
observed discoloration due to the oxidation of hindered phenol, the
combination of secondary HAS, tertiary HAS, organo-phosphite and
hindered phenol exhibited improved stabilization efficiency than
single or binary additive systems. The mixture of secondary HAS and
tertiary HAS, has shown antagonistic effect of stabilization.
However, the combination of organo-phosphite with secondary HAS,
tertiary HAS and phenol antioxidants have been found to give
synergistic even at higher doses of Gamma-irradiation. The effects
have been explained through the interaction between the stabilizers.
After γ-irradiation, the consumption of oligomeric stabilizer
significantly depends on the components of stabilization mixture. The
effect of the organo-phosphite antioxidant on the overall stability has
been discussed.
Abstract: The rate of natural gas dissociation from the Coal
Matrix depends on depressurization of reservoir through removing of
the cleat water from the coal seam. These waters are similar to brine
and aged of very long years. For improving the connectivity through
fracking /fracturing, high pressure liquids are pumped off inside the
coal body. A significant quantity of accumulated water, a combined
mixture of cleat water and fracking fluids (back flow water) is
pumped out through gas well. In Queensland, Australia Coal Seam
Gas (CSG) industry is in booming state and estimated of 30,000 wells
would be active for CSG production forecasting life span of 30 years.
Integrated water management along with water softening programs is
practiced for subsequent treatment and later on discharge to nearby
surface water catchment. Water treatment is an important part of the
CSG industry. A case study on a CSG site and review on the test
results are discussed for assessing the Standards & Practices for
management of CSG by-product water and their subsequent disposal
activities. This study was directed toward (i) water management and
softening process in Spring Gully CSG field, (ii) Comparative
analysis on experimental study and standards and (iii) Disposal of the
treated water. This study also aimed for alternative usages and their
impact on vegetation, living species as well as long term effects.
Abstract: Numerous amounts of metallurgical dusts and sludge containing iron as well as some other valuable elements such as Zn, Pb and C are annually produced in the steelmaking industry. These alternative iron ore resources (fines) with unsatisfying physical and metallurgical properties are difficult to recycle. However, agglomerating these fines to be further used as a feed stock for existing iron and steelmaking processes is practiced successfully at several plants but for limited extent.
In the present study, briquettes of integrated steelmaking industry waste materials (namely, BF-dust and sludge, BOF-dust and sludge) were used as feed stock to produce direct reduced iron (DRI). Physical and metallurgical properties of produced briquettes were investigated by means of TGA/DTA/QMS in combination with XRD. Swelling, softening and melting behavior were also studied using heating microscope.
Abstract: This paper shows the advantages of the material failure process simulation by improve finite elements with embedded discontinuities, using a new definition of traction vector, dependent on the discontinuity length and the angle. Particularly, two families of this kind of elements are compared: kinematically optimal symmetric and statically and kinematically optimal non-symmetric. The constitutive model to describe the behavior of the material in the symmetric formulation is a traction-displacement jump relationship equipped with softening after reaching the failure surface.
To show the validity of this symmetric formulation, representative numerical examples illustrating the performance of the proposed formulation are presented. It is shown that the non-symmetric family may over or underestimate the energy required to create a discontinuity, as this effect is related with the total length of the discontinuity, fact that is not noticed when the discontinuity path is a straight line.
Abstract: The effect of gamma irradiation on micro-hardness of polymer blends of poly (ethyl methacrylate)(PEMA) and poly (ethylene oxide) (PEO) has been investigated to detect the radiation induced crosslinking. The blend system comprises a noncrystallizable polymer, PEMA and a crystallizable polymer, PEO. On irradiation, the overall hardness of the blend specimens for different dose levels infers occurrence of a crosslinking process. The radiation-induced crosslinking was greater for blends having lower concentration of PEO. However, increase in radiation dose causes softening of blend system due to radiation induced scissioning of the chains
Abstract: The relationships between Proteolysis and soluble
calcium levels with hardness of cheese texture were investigated in
Iranian UF white cheese during 90 d ripening. Cheeses were sampled
in interior and exterior. Results showed that levels of proteolysis,
soluble calcium and hardness of cheese texture changed significantly
(p< 0.05) over ripening. Levels of proteolysis and hardness were
significantly (p< 0.05) different in interior and exterior zones of
cheeses. External zones of cheeses became softer and had higher
levels of proteolysis compared to internal zones during ripening. The
highest correlation coefficient (r2= 0.979; p
Abstract: This paper presents a part of research on the
rheological properties of bitumen modified by thermoplastic namely
linear low density polyethylene (LLDPE), high density polyethylene
(HDPE) and polypropylene (PP) and its interaction with 80 pen base
bitumen. As it is known that the modification of bitumen by the use
of polymers enhances its performance characteristics but at the same
time significantly alters its rheological properties. The rheological
study of polymer modified bitumen (PMB) was made through
penetration, ring & ball softening point and viscosity test. The results
were then related to the changes in the rheological properties of
polymer modified bitumen. It was observed that thermoplastic
copolymer shows profound effect on penetration rather than
softening point. The viscoelastic behavior of polymer modified
bitumen depend on the concentration of polymer, mixing
temperature, mixing technique, solvating power of base bitumen and
molecular structure of polymer used. PP offer better blend in
comparison to HDPE and LLDPE. The viscosity of base bitumen was
also enhanced with the addition of polymer. The pseudoplastic
behavior was more prominent for HDPE and LLDPE than PP. Best
results were obtained when polymer concentration was kept below
3%
Abstract: Nonlinear finite element method with eight noded
isoparametric quadrilateral element is used for prediction of loaddeformation
behavior including bearing capacity of foundations.
Modified generalized plasticity model with non-associated flow rule
is applied for analysis of soil-footing system. Also Von Mises and
Tresca criterions are used for simulation of soil behavior. Modified
generalized plasticity model is able to simulate load-deformation
including softening behavior. Localization phenomena are considered
by different meshes. Localization phenomena have not been seen in
the examples. Predictions by modified generalized plasticity model
show good agreement with laboratory data and theoretical prediction
in comparison the other models.
Abstract: This study has applied the L16 orthogonal array of the
Taguchi method to determine the optimized polymeric
Nanocomposite asphalt binder. Three control factors are defined as
polypropylene plastomer (PP), styrene-butadiene-styrene elastomer
(SBS) and Nanoclay. Four level of concentration contents are
introduced for prepared asphalt binder samples. all samples were
prepared with 4.5% of bitumen 60/70 content. Compressive strength
tests were carried out for defining the optimized sample via
QUALITEK-4 software. SBS with 3%, PP with 5 % and Nanoclay
with 1.5% of concentrations are defined as the optimized
Nanocomposite asphalt binders. The confirmation compressive
strength and also softening point tests showed that modification of
asphalt binders with this method, improved the compressive strength
and softening points of asphalt binders up to 55%.
Abstract: Prickly pear fruit (Opuntia ficus indica L. Miller) belongs to the Cactaceae family. This species is very sensitive to low storage temperatures (< 5°C) which cause damages. The fruits can be peeled, suitably packaged and successfully commercialized as a ready-to-eat product. The main limit to the extension of the shelf life is the production of off-flavors due to different factors, the growth of microorganisms and the action of endogenous enzymes. Lipoxygenase (LOX) and Pectinesterase (PE) are involved in fruit degradation. In particular, LOX pathway is directly responsible for lipid oxidation, and the subsequent production of off-flavours, while PE causes the softening of fruit during maturation. They act on the texture and shelf-life of post-harvest, packaged fruits, as a function of the the grown of microorganisms and packaging technologies used. The aim of this work is to compare the effect of different packaging technologies on the shelf life extension of ready-to-eat prickly pear fruits with regards for the enzymes activities.