Abstract: The systematic manipulations of shapes and sizes of
inorganic compounds greatly benefit the various application fields
including optics, magnetic, electronics, catalysis and medicine.
However shape control has been much more difficult to achieve.
Hence exploration of novel method for the preparation of differently
shaped nanoparticles is challenging research area. II-VI group of
semiconductor cadmium sulphide (CdS) nanostructure with different
morphologies (such as, acicular like, mesoporous, spherical shapes)
and of crystallite sizes vary from 11 to 16 nm were successfully
synthesized by chemical aqueous precipitation of Cd2+ ions with
homogeneously released S2- ions from decomposition of cadmium
sulphate (CdSO4) and thioacetamide (CH3CSNH2) by annealing at
different radiations (microwave, ultrasonic and sunlight) with matter
and systematic research has been done for various factors affecting
the controlled growth rate of CdS nanoparticles. The obtained
nanomaterials have been characterized by X-ray Diffraction (XRD),
Fourier Transform Infrared Spectroscopy (FTIR),
Thermogravometric (DSC-TGA) analysis and Scanning Electron
Microscopy (SEM). The result indicates that on increasing the
reaction time particle size increases but on increasing the molar ratios
grain size decreases.
Abstract: Commercial nanocomposite food packaging type nano-silver containers were characterised using scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX). The presence of nanoparticles consistent with the incorporation of 1% nano-silver (Ag) and 0.1% titanium dioxide (TiO2) nanoparticle into polymeric materials formed into food containers was confirmed. Both nanomaterials used in this type of packaging appear to be embedded in a layered configuration within the bulk polymer. The dimensions of the incorporated nanoparticles were investigated using X-ray diffraction (XRD) and determined by calculation using the Scherrer Formula; these were consistent with Ag and TiO2 nanoparticles in the size range 20-70nm both were spherical shape nanoparticles. Antimicrobial assessment of the nanocomposite container has also been performed and the results confirm the antimicrobial activity of Ag and TiO2 nanoparticles in food packaging containers. Migration assessments were performed in a wide range of food matrices to determine the migration of nanoparticles from the packages. The analysis was based upon the relevant European safety Directives and involved the application of inductively coupled plasma mass spectrometry (ICP-MS) to identify the range of migration risk. The data pertain to insignificance levels of migration of Ag and TiO2 nanoparticles into the selected food matrices.
Abstract: Today, biogenic magnetite nanoparticles among
magnetic nanoparticles have unique attracted attention because of
their magnetic characteristics and potential applications in various
fields such as therapeutic and diagnostic. A well known example of
these biogenic nanoparticles is magnetosomes of magnetotactic
bacteria. In this research, we used two different types of technique for
the isolation and purification of magnetosome nanoparticles from the
isolated magnetotactic bacterial cells, heat-alkaline treatment and
sonication. Also we evaluated pyrogen content and sterility of
synthesized the isolated individual magnetosome by the Limulus
Amoebocyte Lysate test and direct impedimetric method
respectively.
Abstract: In the present work, we have developed a symmetric electrochemical capacitor based on the nanostructured iron oxide (Fe3O4)-activated carbon (AC) nanocomposite materials. The physical properties of the nanocomposites were characterized by Scanning Electron Microscopy (SEM) and Brunauer-Emmett-Teller (BET) analysis. The electrochemical performances of the composite electrode in 1.0 M Na2SO3 and 1.0 M Na2SO4 aqueous solutions were evaluated using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The composite electrode with 4 wt% of iron oxide nanomaterials exhibits the highest capacitance of 86 F/g. The experimental results clearly indicate that the incorporation of iron oxide nanomaterials at low concentration to the composite can improve the capacitive performance, mainly attributed to the contribution of the pseudocapacitance charge storage mechanism and the enhancement on the effective surface area of the electrode. Nevertheless, there is an optimum threshold on the amount of iron oxide that needs to be incorporated into the composite system. When this optimum threshold is exceeded, the capacitive performance of the electrode starts to deteriorate, as a result of the undesired particle aggregation, which is clearly indicated in the SEM analysis. The electrochemical performance of the composite electrode is found to be superior when Na2SO3 is used as the electrolyte, if compared to the Na2SO4 solution. It is believed that Fe3O4 nanoparticles can provide favourable surface adsorption sites for sulphite (SO3 2-) anions which act as catalysts for subsequent redox and intercalation reactions.
Abstract: Nanomaterials have attracted considerable attention
during the last two decades, due to their unusual electrical, mechanical
and other physical properties as compared with their bulky
counterparts. The mechanical properties of nanostructured materials
show strong size dependency, which has been explained within the
framework of continuum mechanics by including the effects of surface
stress. The size-dependent deformations of two-dimensional
nanosized structures with surface effects are investigated in the paper
by the finite element method. Truss element is used to evaluate the
contribution of surface stress to the total potential energy and the
Gurtin and Murdoch surface stress model is implemented with
ANSYS through its user programmable features. The proposed
approach is used to investigate size-dependent stress concentration
around a nanosized circular hole and the size-dependent effective
moduli of nanoporous materials. Numerical results are compared with
available analytical results to validate the proposed modeling
approach.
Abstract: Recently, nanomaterials are developed in the form of nano-films, nano-crystals and nano-pores. Lanthanide phosphates as a material find extensive application as laser, ceramic, sensor, phosphor, and also in optoelectronics, medical and biological labels, solar cells and light sources. Among the different kinds of rare-earth orthophosphates, yttrium orthophosphate has been shown to be an efficient host lattice for rare earth activator ions, which have become a research focus because of their important role in the field of light display systems, lasers, and optoelectronic devices. It is in this context that the 4fn- « 4fn-1 5d transitions of rare earth in insulating materials, lying in the UV and VUV, are the aim of large number of studies .Though there has been a few reports on Eu3+, Nd3+, Pr3+,Er3+, Ce3+, Tm3+ doped YPO4. The 4fn- « 4fn-1 5d transitions of the rare earth dependent to the host-matrix, several matrices ions were used to study these transitions, in this work we are suggesting to study on a very specific class of inorganic material that are orthophosphate doped with rare earth ions. This study focused on the effect of Ce3+ concentration on the structural and optical properties of Ce3+ doped YPO4 yttrium orthophosphate with powder form prepared by the Sol Gel method.
Abstract: The aim of our work is to study phase composition,
particle size and magnetic response of Fe2O3/TiO2 nanocomposites
with respect to the final annealing temperature. Those nanomaterials
are considered as smart catalysts, separable from a liquid/gaseous
phase by applied magnetic field. The starting product was obtained
by an ecologically acceptable route, based on heterogeneous
precipitation of the TiO2 on modified g-Fe2O3 nanocrystals dispersed
in water. The precursor was subsequently annealed on air at
temperatures ranging from 200 oC to 900 oC. The samples were
investigated by synchrotron X-ray powder diffraction (S-PXRD),
magnetic measurements and Mössbauer spectroscopy. As evidenced
by S-PXRD and Mössbauer spectroscopy, increasing the annealing
temperature causes evolution of the phase composition from
anatase/maghemite to rutile/hematite, finally above 700 oC the
pseudobrookite (Fe2TiO5) also forms. The apparent particle size of
the various Fe2O3/TiO2 phases has been determined from the highquality
S-PXRD data by using two different approaches: the Rietveld
refinement and the Debye method. Magnetic response of the samples
is discussed in considering the phase composition and the particle
size.