Abstract: Sedimentation is a hydraulic phenomenon that is
emerging as a serious challenge in river engineering. When the flow
reaches a certain state that gather potential energy, it shifts the
sediment load along channel bed. The transport of such materials can
be in the form of suspended and bed loads. The movement of these
along the river course and channels and the ways in which this could
influence the water intakes is considered as the major challenges for
sustainable O&M of hydraulic structures. This could be very serious
in arid and semi-arid regions like Iran, where inappropriate watershed
management could lead to shifting a great deal of sediments into the
reservoirs and irrigation systems. This paper aims to investigate
sedimentation in the Western Canal of Dez Diversion Weir in Iran,
identifying factors which influence the process and provide ways in
which to mitigate its detrimental effects by using the SHARC
Software.
For the purpose of this paper, data from the Dezful water authority
and Dezful Hydrometric Station pertinent to a river course of about 6
Km were used.
Results estimated sand and silt bed loads concentrations to be 193
ppm and 827ppm respectively. Given the available data on average
annual bed loads and average suspended sediment loads of 165ppm
and 837ppm, there was a significant statistical difference (16%)
between the sand grains, whereas no significant difference (1.2%)
was find in the silt grain sizes. One explanation for such finding
being that along the 6 Km river course there was considerable
meandering effects which explains recent shift in the hydraulic
behavior along the stream course under investigation. The sand
concentration in downstream relative to present state of the canal
showed a steep descending curve. Sediment trapping on the other
hand indicated a steep ascending curve. These occurred because the
diversion weir was not considered in the simulation model.
Abstract: The paper reports the preparation and photocatalytic
activity of ZnO/SnO2 and SnO2 nanoparticles. These nanoparticles
were synthesized by hydrothermal method. The products were
characterized by X-ray diffraction (XRD) and scanning electron
microscopy (SEM). Their grain sizes are about 50-100 nm. The
photocatalytic activities of these materials were investigated for
congo red removal from aqueous solution under UV light irradiation.
It was shown that the use of ZnO/SnO2 as photocatalyst have better
photocatalytic activity for degradation of congo red than SnO2 or
TiO2 (anatase, particle size: 30nm) alone.
Abstract: Determination of nano particle size is substantial since
the nano particle size exerts a significant effect on various properties
of nano materials. Accordingly, proposing non-destructive, accurate
and rapid techniques for this aim is of high interest. There are some
conventional techniques to investigate the morphology and grain size
of nano particles such as scanning electron microscopy (SEM),
atomic force microscopy (AFM) and X-ray diffractometry (XRD).
Vibrational spectroscopy is utilized to characterize different
compounds and applied for evaluation of the average particle size
based on relationship between particle size and near infrared spectra
[1,4] , but it has never been applied in quantitative morphological
analysis of nano materials. So far, the potential application of nearinfrared
(NIR) spectroscopy with its ability in rapid analysis of
powdered materials with minimal sample preparation, has been
suggested for particle size determination of powdered
pharmaceuticals. The relationship between particle size and diffuse
reflectance (DR) spectra in near infrared region has been applied to
introduce a method for estimation of particle size. Back propagation
artificial neural network (BP-ANN) as a nonlinear model was applied
to estimate average particle size based on near infrared diffuse
reflectance spectra. Thirty five different nano TiO2 samples with
different particle size were analyzed by DR-FTNIR spectrometry and
the obtained data were processed by BP- ANN.
Abstract: Two short sediment cores collected from mangrove
areas of Manori and Thane creeks along Mumbai coast were analysed
for sediment composition and metals (Fe, Mn, Cu, Pb, Co, Ni, Zn, Cr
and V). The statistical analysis of Pearson correlation matrix proved
that there is a significant relationship between metal concentration
and finer grain size in Manori creek while poor correlation was
observed in Thane creek. Based on the enrichment factor, the present
metal to background metal ratios clearly reflected maximum
enrichment of Cu and Pb in Manori creek and Mn in Thane creek.
Geoaccumulation index calculated indicate that the study area is
unpolluted with respect to Fe, Mn, Co, Ni, Zn and Cr in both the
cores while moderately polluted with Cu and Pb in Manori creek.
Based on contamination degree, both the core sediments were found
to be considerably contaminated with metals.