Abstract: The effects of upflow liquid velocity (ULV) on
performance of expanded granular sludge bed (EGSB) system were
investigated. The EGSB reactor, made from galvanized steel pipe
0.10 m diameter and 5 m height, had been used to treat piggery
wastewater, after passing through acidification tank. It consisted of
39.3 l working volume in reaction zone and 122 l working volume in
sedimentation zone, at the upper part. The reactor was seeded with
anaerobically digested sludge and operated at the ULVs of 4, 8, 12
and 16 m/h, consecutively, corresponding to organic loading rates of
9.6 – 13.0 kg COD/ (m3.d). The average COD concentrations in the
influent were 9,601 – 13,050 mg/l. The COD removal was not
significantly different, i.e. 93.0% - 94.0%, except at ULV 12 m/h where
SS in the influent was exceptionally high so that VSS washout had
occurred, leading to low COD removal. The FCOD and VFA
concentrations in the effluent of all experiments were not much
different, indicating the same range of treatment performance. The
biogas production decreased at higher ULV and ULV of 4 m/h is
suggested as design criterion for EGSB system.
Abstract: Thailand is one of the world-s leaders of rice
producers and exporters. Farmers have to increase the rice cultivation
frequency for serving the national increasing of export-s demand. It
leads to an elimination of rice residues by open burning which is the
quickest and costless management method. The open burning of rice
residue is one of the major causes of air pollutants and greenhouse
gas (GHG) emission. Under ASEAN agreement on trans-boundary
haze, Thailand set the master plan to mitigate air pollutant emission
from open burning of agricultural residues. In this master plan,
residues incorporation is promoted as alternative management
method to open burning. However, the assessment of both options in
term of GHG emission in order to investigate their contribution to
long-term global warming is still scarce or inexistent. In this study, a
method on rice residues assessment was first developed in order to
estimate and compare GHG emissions from rice cultivation under
rice residues open burning and the case with incorporation of the
same amount of rice residues, using 2006 IPCC guidelines for
emission estimation and Life Cycle Analysis technique. The
emission from rice cultivation in different preparing area practice
was also discussed.
Abstract: The effect of varying holding temperature on hatching success, occurrence of deformities and mortality rates were investigated for goldlined seabream eggs. Wild broodstock (600 g) were stocked at a 2:1 male-female ratio in a 2 m3 fiberglass tank supplied with filtered seawater (37 g L-1 salinity, temp. range 24±0.5 oC [day] and 22±1 oC [night], DO2 in excess of 5.0mg L-1). Females were injected with 200 IU kg-1 HCG between 08.00 and 10.00 h and returned to tanks to spawn following which eggs were collected by hand using a 100μm net. Fertilized eggs at the gastrulation stage (120 L-1) were randomly placed into one of 12 experimental 6 L aerated (DO2 5 mg L-1) plastic containers with water temperatures maintained at 24±0.5 oC (ambient), 26±0.5 oC, 28± 0.5 oC and 30±0.5 oC using thermostats. Each treatment was undertaken in triplicate using a 12:12 photophase:scotophase photoperiod. No differences were recorded between eggs reared at 24 and 26 oC with respect to viability, deformity, mortality or unhatched egg rates. Increasing temperature reduced the number of viable eggs with those at 30 oC returning poorest performance (P < 0.05). Mortality levels were lowest for eggs incubated at 24 and 26 oC. The greatest level of deformities recorded was that for eggs reared at 28 oC.
Abstract: In this study, a low temperature sensor highly selective to CO in presence of methane is fabricated by using 4 nm SnO2 quantum dots (QDs) prepared by sonication assisted precipitation. SnCl4 aqueous solution was precipitated by ammonia under sonication, which continued for 2 h. A part of the sample was then dried and calcined at 400°C for 1.5 h and characterized by XRD and BET. The average particle size and the specific surface area of the SnO2 QDs as well as their sensing properties were compared with the SnO2 nano-particles which were prepared by conventional sol-gel method. The BET surface area of sonochemically as-prepared product and the one calcined at 400°C after 1.5 hr are 257 m2/gr and 212 m2/gr respectively while the specific surface area for SnO2 nanoparticles prepared by conventional sol-gel method is about 80m2/gr. XRD spectra revealed pure crystalline phase of SnO2 is formed for both as-prepared and calcined samples of SnO2 QDs. However, for the sample prepared by sol-gel method and calcined at 400°C SnO crystals are detected along with those of SnO2. Quantum dots of SnO2 show exceedingly high sensitivity to CO with different concentrations of 100, 300 and 1000 ppm in whole range of temperature (25- 350°C). At 50°C a sensitivity of 27 was obtained for 1000 ppm CO, which increases to a maximum of 147 when the temperature rises to 225°C and then drops off while the maximum sensitivity for the SnO2 sample prepared by the sol-gel method was obtained at 300°C with the amount of 47.2. At the same time no sensitivity to methane is observed in whole range of temperatures for SnO2 QDs. The response and recovery times of the sensor sharply decreases with temperature, while the high selectivity to CO does not deteriorate.
Abstract: The modified Claus process is the major technology
for the recovery of elemental sulfur from hydrogen sulfide. The
chemical reactions that can occur in the reaction furnace are
numerous and many byproducts such as carbon disulfide and carbon
carbonyl sulfide are produced. These compounds can often contribute
from 20 to 50% of the pollutants and therefore, should be hydrolyzed
in the catalytic converter. The inlet temperature of the first catalytic
reactor should be maintained over than 250 °C, to hydrolyze COS
and CS2. In this paper, the various configurations for the first
converter reheating of sulfur recovery unit are investigated. As a
result, the performance of each method is presented for a typical
clause unit. The results show that the hot gas method seems to be
better than the other methods.
Abstract: In this study, the effects of biogas fuels on the performance of an annular micro gas turbine (MGT) were assessed experimentally and numerically. In the experiments, the proposed MGT system was operated successfully under each test condition; minimum composition to the fuel with the biogas was roughly 50% CH4 with 50% CO2. The power output was around 170W at 85,000 RPM as 90% CH4 with 10% CO2 was used and 70W at 65,000 RPM as 70% CH4 with 30% CO2 was used. When a critical limit of 60% CH4 was reached, the power output was extremely low. Furthermore, the theoretical Brayton cycle efficiency and electric efficiency of the MGT were calculated as 23% and 10%, respectively. Following the experiments, the measured data helped us identify the parameters of dynamic model in numerical simulation. Additionally, a numerical analysis of re-designed combustion chamber showed that the performance of MGT could be improved by raising the temperature at turbine inlet. This study presents a novel distributed power supply system that can utilize renewable biogas. The completed micro biogas power supply system is small, low cost, easy to maintain and suited to household use.
Abstract: Partial combustion of biomass in the gasifier generates producer gas that can be used for heating purposes and as supplementary or sole fuel in internal combustion engines. In this study, the virgin biomass obtained from hingan shell is used as the feedstock for gasifier to generate producer gas. The gasifier-engine system is operated on diesel and on esters of vegetable oil of hingan in liquid fuel mode operation and then on liquid fuel and producer gas combination in dual fuel mode operation. The performance and emission characteristics of the CI engine is analyzed by running the engine in liquid fuel mode operation and in dual fuel mode operation at different load conditions with respect to maximum diesel savings in the dual fuel mode operation. It was observed that specific energy consumption in the dual fuel mode of operation is found to be in the higher side at all load conditions. The brake thermal efficiency of the engine using diesel or hingan oil methyl ester (HOME) is higher than that of dual fuel mode operation. A diesel replacement in the tune of 60% in dual fuel mode is possible with the use of hingan shell producer gas. The emissions parameters such CO, HC, NOx, CO2 and smoke are higher in the case of dual fuel mode of operation as compared to that of liquid fuel mode.
Abstract: Although oil-based drilling fluids are of paramount practical and economical interest, they represent a serious source of pollution, once released into the environment as drill cuttings. The aim of this study is to assess the capability of isolated microorganisms to degrade gasoil fuel. The commonly used physicochemical and biodegradation remediation techniques of petroleum contaminated soil were both investigated. The study revealed that natural biodegradation is favorable. Even though, the presence of heavy metals, the moisture level of (8.55%) and nutrient deficiencies put severe constrains on microorganisms- survival ranges inhibiting the biodegradation process. The selected strains were able to degrade the diesel fuel at significantly high rates (around 98%).
Abstract: To reduce the carbon dioxide emission into the
atmosphere, adsorption is believed to be one of the most attractive
methods for post-combustion treatment of flue gas. In this work,
activated carbon (AC) was modified by polyethylenimine (PEI) via
impregnation in order to enhance CO2 adsorption capacity. The
adsorbents were produced at 0.04, 0.16, 0.22, 0.25, and 0.28 wt%
PEI/AC. The adsorption was carried out at a temperature range from
30 °C to 75 °C and five different gas pressures up to 1 atm. TG-DTA,
FT-IR, UV-visible spectrometer, and BET were used to characterize
the adsorbents. Effects of PEI loading on the AC for the CO2
adsorption were investigated. Effectiveness of the adsorbents on the
CO2 adsorption including CO2 adsorption capacity and adsorption
temperature was also investigated. Adsorption capacities of CO2 were
enhanced with the increase in the amount of PEI from 0.04 to 0.22
wt% PEI before the capacities decreased onwards from0.25 wt% PEI
at 30 °C. The 0.22 wt% PEI/AC showed higher adsorption capacity
than the AC for adsorption at 50 °C to 75 °C.
Abstract: Due to the environmental and price issues of current
energy crisis, scientists and technologists around the globe are
intensively searching for new environmentally less-impact form of
clean energy that will reduce the high dependency on fossil fuel.
Particularly hydrogen can be produced from biomass via thermochemical
processes including pyrolysis and gasification due to the
economic advantage and can be further enhanced through in-situ
carbon dioxide removal using calcium oxide. This work focuses on
the synthesis and development of the flowsheet for the enhanced
biomass gasification process in PETRONAS-s iCON process
simulation software. This hydrogen prediction model is conducted at
operating temperature between 600 to 1000oC at atmospheric
pressure. Effects of temperature, steam-to-biomass ratio and
adsorbent-to-biomass ratio were studied and 0.85 mol fraction of
hydrogen is predicted in the product gas. Comparisons of the results
are also made with experimental data from literature. The
preliminary economic potential of developed system is RM 12.57 x
106 which equivalent to USD 3.77 x 106 annually shows economic
viability of this process.
Abstract: This paper attempts to establish the fact that Multi
State Network Classification is essential for performance
enhancement of Transport protocols over Satellite based Networks. A
model to classify Multi State network condition taking into
consideration both congestion and channel error is evolved. In order
to arrive at such a model an analysis of the impact of congestion and
channel error on RTT values has been carried out using ns2. The
analysis results are also reported in the paper. The inference drawn
from this analysis is used to develop a novel statistical RTT based
model for multi state network classification.
An Adaptive Multi State Proactive Transport Protocol consisting
of Proactive Slow Start, State based Error Recovery, Timeout Action
and Proactive Reduction is proposed which uses the multi state
network state classification model. This paper also confirms through
detail simulation and analysis that a prior knowledge about the
overall characteristics of the network helps in enhancing the
performance of the protocol over satellite channel which is
significantly affected due to channel noise and congestion.
The necessary augmentation of ns2 simulator is done for
simulating the multi state network classification logic. This
simulation has been used in detail evaluation of the protocol under
varied levels of congestion and channel noise. The performance
enhancement of this protocol with reference to established protocols
namely TCP SACK and Vegas has been discussed. The results as
discussed in this paper clearly reveal that the proposed protocol
always outperforms its peers and show a significant improvement in
very high error conditions as envisaged in the design of the protocol.
Abstract: Fixed-bed slow pyrolysis experiments of rice husk
have been conducted to determine the effect of pyrolysis
temperature, heating rate, particle size and reactor length on the
pyrolysis product yields. Pyrolysis experiments were performed at
pyrolysis temperature between 400 and 600°C with a constant
heating rate of 60°C/min and particle sizes of 0.60-1.18 mm. The
optimum process conditions for maximum liquid yield from the rice
husk pyrolysis in a fixed bed reactor were also identified. The highest
liquid yield was obtained at a pyrolysis temperature of 500°C,
particle size of
1.18-1.80 mm, with a heating rate of 60°C/min in a 300 mm length
reactor. The obtained yield of, liquid, gas and solid were found be in
the range of 22.57-31.78 %, 27.75-42.26 % and 34.17-42.52 % (all
weight basics) respectively at different pyrolysis conditions. The
results indicate that the effects of pyrolysis temperature and particle
size on the pyrolysis yield are more significant than that of heating
rate and reactor length. The functional groups and chemical
compositions present in the liquid obtained at optimum conditions
were identified by Fourier Transform-Infrared (FT-IR) spectroscopy
and Gas Chromatography/ Mass Spectroscopy (GC/MS) analysis
respectively.
Abstract: Direct conversion of methane to methanol by partial oxidation in a thermal reactor has a poor yield of about 2% which is less than the expected economical yield of about 10%. Conventional thermal catalytic reactors have been proposed to be superseded by plasma reactors as a promising approach, due to strength of the electrical energy which can break C-H bonds of methane. Among the plasma techniques, non-thermal dielectric barrier discharge (DBD) plasma chemical process is one of the most future promising technologies in synthesizing methanol. The purpose of this paper is presenting a brief review of CH4 oxidation with O2 in DBD plasma reactors based on the recent investigations. For this reason, the effect of various parameters of reactor configuration, feed ratio, applied voltage, residence time (gas flow rate), type of applied catalyst, pressure and reactor wall temperature on methane conversion and methanol selectivity are discussed.
Abstract: Contamination of aromatic compounds in water can
cause severe long-lasting effects not only for biotic organism but also
on human health. Several alternative technologies for remediation of
polluted water have been attempted. One of these is adsorption
process of aromatic compounds by using organic modified clay
mineral. Porous structure of clay is potential properties for molecular
adsorptivity and it can be increased by immobilizing hydrophobic
structure to attract organic compounds. In this work natural
montmorillonite were modified with cetyltrimethylammonium
(CTMA+) and was evaluated for use as adsorbents of aromatic
compounds: benzene, toluene, and 2-chloro phenol in its single and
multicomponent solution by ethanol:water solvent. Preparation of
CTMA-montmorillonite was conducted by simple ion exchange
procedure and characterization was conducted by using x-day
diffraction (XRD), Fourier-transform infra red (FTIR) and gas
sorption analysis. The influence of structural modification of
montmorillonite on its adsorption capacity and adsorption affinity of
organic compound were studied. It was shown that adsorptivity of
montmorillonite was increased by modification associated with
arrangements of CTMA+ in the structure even the specific surface
area of modified montmorillonite was lower than raw
montmorillonite. Adsorption rate indicated that material has affinity
to adsorb compound by following order: benzene> toluene > 2-chloro
phenol. The adsorption isotherms of benzene and toluene showed 1st
order adsorption kinetic indicating a partition phenomenon of
compounds between the aqueous and organophilic CTMAmontmorillonite.
Abstract: An interesting method to produce calcium carbonate is based in a gas-liquid reaction between carbon dioxide and aqueous solutions of calcium hydroxide. The design parameters for gas-liquid phase are flow regime, individual mass transfer, gas-liquid specific interfacial area. Most studies on gas-liquid phase were devoted to the experimental determination of some of these parameters, and more specifically, of the mass transfer coefficient, kLa which depends fundamentally on the superficial gas velocity and on the physical properties of absorption phase. The principle investigation was directed to study the effect of the vibration on the mass transfer coefficient kLa in gas-liquid phase during absorption of CO2 in the in aqueous solution of calcium hydroxide. The vibration with a higher frequency increase the mass transfer coefficient kLa, but vibration with lower frequency didn-t improve it, the mass transfer coefficient kLa increase with increase the superficial gas velocity.
Abstract: Role of acoustic driving pressure on the
translational-radial dynamics of a moving single bubble
sonoluminescence (m-SBSL) has been numerically
investigated. The results indicate that increase in the
amplitude of the driving pressure leads to increase in the
bubble peak temperature. The length and the shape of the
trajectory of the bubble depends on the acoustic pressure and
because of the spatially dependence of the radial dynamics of
the moving bubble, its peak temperature varies during the
acoustical pulses. The results are in good agreement with the
experimental reports on m-SBSL.
Abstract: Air pollution is a major environmental health
problem, affecting developed and developing countries around the
world. Increasing amounts of potentially harmful gases and
particulate matter are being emitted into the atmosphere on a global
scale, resulting in damage to human health and the environment.
Petroleum-related air pollutants can have a wide variety of adverse
environmental impacts. In the crude oil production sectors, there is a
strong need for a thorough knowledge of gaseous emissions resulting
from the flaring of associated gas of known composition on daily
basis through combustion activities under several operating
conditions. This can help in the control of gaseous emission from
flares and thus in the protection of their immediate and distant
surrounding against environmental degradation.
The impacts of methane and non-methane hydrocarbons emissions
from flaring activities at oil production facilities at Kuwait Oilfields
have been assessed through a screening study using records of flaring
operations taken at the gas and oil production sites, and by analyzing
available meteorological and air quality data measured at stations
located near anthropogenic sources. In the present study the
Industrial Source Complex (ISCST3) Dispersion Model is used to
calculate the ground level concentrations of methane and nonmethane
hydrocarbons emitted due to flaring in all over Kuwait
Oilfields.
The simulation of real hourly air quality in and around oil
production facilities in the State of Kuwait for the year 2006,
inserting the respective source emission data into the ISCST3
software indicates that the levels of non-methane hydrocarbons from
the flaring activities exceed the allowable ambient air standard set by
Kuwait EPA. So, there is a strong need to address this acute problem
to minimize the impact of methane and non-methane hydrocarbons
released from flaring activities over the urban area of Kuwait.
Abstract: Performance of a cobalt doped sol-gel derived silica (Co/SiO2) catalyst for Fischer–Tropsch synthesis (FTS) in slurryphase reactor was studied using paraffin wax as initial liquid media. The reactive mixed gas, hydrogen (H2) and carbon monoxide (CO) in a molar ratio of 2:1, was flowed at 50 ml/min. Braunauer-Emmett- Teller (BET) surface area and X-ray diffraction (XRD) techniques were employed to characterize both the specific surface area and crystallinity of the catalyst, respectively. The reduction behavior of Co/SiO2 catalyst was investigated using the Temperature Programmmed Reduction (TPR) method. Operating temperatures were varied from 493 to 533K to find the optimum conditions to maximize liquid fuels production, gasoline and diesel.
Abstract: Novel acrylated epoxidized hemp oil (AEHO) based
bioresins were successfully synthesised, characterized and applied to
biocomposites reinforced with woven jute fibre. Characterisation of
the synthesised AEHO consisted of acid number titrations and FTIR
spectroscopy to assess the success of the acrylation reaction. Three
different matrices were produced (vinylester (VE), 50/50 blend of
AEHO/VE and 100% AEHO) and reinforced with jute fibre to form
three different types of biocomposite samples. Mechanical properties
in the form of flexural and interlaminar shear strength (ILSS) were
investigated and compared for the different samples. Results from the
mechanical tests showed that AEHO and 50/50 based neat bioresins
displayed lower flexural properties compared with the VE samples.
However when applied to biocomposites and compared with VE
based samples, AEHO biocomposites demonstrated comparable
flexural performance and improved ILSS. These results are attributed
to improved fibre-matrix interfacial adhesion due to surface-chemical
compatibility between the natural fibres and bioresin.
Abstract: The aim of our work is to study phase composition,
particle size and magnetic response of Fe2O3/TiO2 nanocomposites
with respect to the final annealing temperature. Those nanomaterials
are considered as smart catalysts, separable from a liquid/gaseous
phase by applied magnetic field. The starting product was obtained
by an ecologically acceptable route, based on heterogeneous
precipitation of the TiO2 on modified g-Fe2O3 nanocrystals dispersed
in water. The precursor was subsequently annealed on air at
temperatures ranging from 200 oC to 900 oC. The samples were
investigated by synchrotron X-ray powder diffraction (S-PXRD),
magnetic measurements and Mössbauer spectroscopy. As evidenced
by S-PXRD and Mössbauer spectroscopy, increasing the annealing
temperature causes evolution of the phase composition from
anatase/maghemite to rutile/hematite, finally above 700 oC the
pseudobrookite (Fe2TiO5) also forms. The apparent particle size of
the various Fe2O3/TiO2 phases has been determined from the highquality
S-PXRD data by using two different approaches: the Rietveld
refinement and the Debye method. Magnetic response of the samples
is discussed in considering the phase composition and the particle
size.