Abstract: Using ab initio theoretical calculations, we present
analysis of fragmentation process. The analysis is performed in two
steps. The first step is calculation of fragmentation energies by ab
initio calculations. The second step is application of the energies to
kinetic description of process. The energies of fragments are
presented in this paper. The kinetics of fragmentation process can be
described by numerical models. The method for kinetic analysis is
described in this paper. The result - composition of fragmentation
products - will be calculated in future. The results from model can be
compared to the concentrations of fragments from mass spectrum.
Abstract: A new approach is adopted in this paper based
on Turk and Pentland-s eigenface method. It was found that the
probability density function of the distance between the projection
vector of the input face image and the average projection vector of
the subject in the face database, follows Rayleigh distribution. In
order to decrease the false acceptance rate and increase the
recognition rate, the input face image has been recognized using two
thresholds including the acceptance threshold and the rejection
threshold. We also find out that the value of two thresholds will be
close to each other as number of trials increases. During the training,
in order to reduce the number of trials, the projection vectors for each
subject has been averaged. The recognition experiments using the
proposed algorithm show that the recognition rate achieves to
92.875% whilst the average number of judgment is only 2.56 times.
Abstract: Zirconium diamine and triamine complexes can possess biological activities. These complexes were synthesised via the reaction of equimolar quantities of 1,10-phenanthroline {NC3H3(C6H2)NC3H3} (L1) or 4-4-amino phenazone {ONC6H5(NH)CH(NH2} (L2) or diphenyl carbizon {HNNCO(NH)2(C6H5)} (L3) with a Zirconium Salt {ZrOCl2} in a 1:1 ratio to form complexes [{NC3H3(C6H2)NC3H3}ZrOCl2}] [ZrOCl2L1], [{(O2NC6H4(NH)(NH2)}ZrOCl2] [ZrOCl2L2] and [{HNNCO(NH)2(C6H5)ZrOCl2}] [ZrOCl2L3] respectively. They were characterised using Fourier Transform Infrared (FT-IR) and UV-Visible spectroscopy. Also a variable temperature study of these complexes was completed, using UV-Visible spectroscopy to observe electronic transitions under temperature control. Also a DFT study was done on these complexes via the information from FT-IR and UV-Visible spectroscopy.
These complexes were found to show different inhibition to the growth of bacterial strains of Bacillus spp. & Klebsiella spp. & E. coli & Proteus spp. & Pseudomona spp. at different concentrations (0.001, 0.2 and 1M). For better understanding these complexes were examined by using a Density Functional Theory (DFT) calculation.
Abstract: The angular distribution of Compton scattering of two
quanta originating in the annihilation of a positron with an electron
is investigated as a quantum key distribution (QKD) mechanism in
the gamma spectral range. The geometry of coincident Compton
scattering is observed on the two sides as a way to obtain partially
correlated readings on the quantum channel. We derive the noise
probability density function of a conceptually equivalent prepare
and measure quantum channel in order to evaluate the limits of the
concept in terms of the device secrecy capacity and estimate it at
roughly 1.9 bits per 1 000 annihilation events. The high error rate
is well above the tolerable error rates of the common reconciliation
protocols; therefore, the proposed key agreement protocol by public
discussion requires key reconciliation using classical error-correcting
codes. We constructed a prototype device based on the readily
available monolithic detectors in the least complex setup.
Abstract: Constant upgrading of Enterprise Resource Planning
(ERP) systems is necessary, but can cause new defects. This paper
attempts to model the likelihood of defects after completed upgrades
with Weibull defect probability density function (PDF). A case study
is presented analyzing data of recorded defects obtained for one ERP
subsystem. The trends are observed for the value of the parameters
relevant to the proposed statistical Weibull distribution for a given
one year period. As a result, the ability to predict the appearance of
defects after the next upgrade is described.
Abstract: Speckled images arise when coherent microwave,
optical, and acoustic imaging techniques are used to image an object, surface or scene. Examples of coherent imaging systems include synthetic aperture radar, laser imaging systems, imaging sonar
systems, and medical ultrasound systems. Speckle noise is a form of object or target induced noise that results when the surface of the object is Rayleigh rough compared to the wavelength of the illuminating radiation. Detection and estimation in images corrupted
by speckle noise is complicated by the nature of the noise and is not
as straightforward as detection and estimation in additive noise. In
this work, we derive stochastic models for speckle noise, with an emphasis on speckle as it arises in medical ultrasound images. The
motivation for this work is the problem of segmentation and tissue classification using ultrasound imaging. Modeling of speckle in this
context involves partially developed speckle model where an underlying Poisson point process modulates a Gram-Charlier series
of Laguerre weighted exponential functions, resulting in a doubly
stochastic filtered Poisson point process. The statistical distribution of partially developed speckle is derived in a closed canonical form.
It is observed that as the mean number of scatterers in a resolution cell is increased, the probability density function approaches an
exponential distribution. This is consistent with fully developed speckle noise as demonstrated by the Central Limit theorem.
Abstract: Wind is among the potential energy resources which
can be harnessed to generate wind energy for conversion into
electrical power. Due to the variability of wind speed with time and
height, it becomes difficult to predict the generated wind energy more
optimally. In this paper, an attempt is made to establish a
probabilistic model fitting the wind speed data recorded at
Makambako site in Tanzania. Wind speeds and direction were
respectively measured using anemometer (type AN1) and wind Vane
(type WD1) both supplied by Delta-T-Devices at a measurement
height of 2 m. Wind speeds were then extrapolated for the height of
10 m using power law equation with an exponent of 0.47. Data were
analysed using MINITAB statistical software to show the variability
of wind speeds with time and height, and to determine the underlying
probability model of the extrapolated wind speed data. The results
show that wind speeds at Makambako site vary cyclically over time;
and they conform to the Weibull probability distribution. From these
results, Weibull probability density function can be used to predict
the wind energy.
Abstract: Given a bivariate normal sample of correlated variables,
(Xi, Yi), i = 1, . . . , n, an alternative estimator of Pearson’s correlation
coefficient is obtained in terms of the ranges, |Xi − Yi|.
An approximate confidence interval for ρX,Y is then derived, and
a simulation study reveals that the resulting coverage probabilities
are in close agreement with the set confidence levels. As well, a
new approximant is provided for the density function of R, the
sample correlation coefficient. A mixture involving the proposed
approximate density of R, denoted by hR(r), and a density function
determined from a known approximation due to R. A. Fisher is shown
to accurately approximate the distribution of R. Finally, nearly exact
density approximants are obtained on adjusting hR(r) by a 7th degree
polynomial.
Abstract: This paper presents a new approach for the prob-ability density function estimation using the Support Vector Ma-chines (SVM) and the Expectation Maximization (EM) algorithms.In the proposed approach, an advanced algorithm for the SVM den-sity estimation which incorporates the Mean Field theory in the learning process is used. Instead of using ad-hoc values for the para-meters of the kernel function which is used by the SVM algorithm,the proposed approach uses the EM algorithm for an automatic optimization of the kernel. Experimental evaluation using simulated data set shows encouraging results.
Abstract: In this paper, four carbazole-based D-D-π-A organic
dyes code as CCT2A, CCT3A, CCT1PA and CCT2PA were reported.
A series of these organic dyes containing identical donor and
acceptor group but different π-system. The effect of replacing of
thiophene by phenyl thiophene as π-system on the physical
properties has been focused. The structural, energetic properties and
absorption spectra were theoretically investigated by means of
Density Functional Theory (DFT) and Time-Dependent Density
Functional Theory (TD-DFT). The results show that nonplanar
conformation due to steric hindrance in donor part (cabazolecarbazole
unit) of dye molecule can prevent unfavorable dye
aggregation. By means of the TD-DFT method, the absorption
spectra were calculated by B3LYP and BHandHLYP to study the
affect of hybrid functional on the excitation energy (Eg). The results
revealed the increasing of thiophene units not only resulted in
decreasing of Eg, but also found the shifting of absorption spectra to
higher wavelength. TD-DFT/BHandHLYP calculated results are
more strongly agreed with the experimental data than B3LYP
functions. Furthermore, the adsorptions of CCT2A and CCT3A on the
TiO2 anatase (101) surface were carried out by mean of the chemical
periodic calculation. The result exhibit the strong adsorption energy.
The calculated results provide our new organic dyes can be
effectively used as dye for Dye Sensitized Solar Cell (DSC).
Abstract: In this paper, a Dynamic Economic Dispatch (DED) model is developed for the system consisting of both thermal generators and wind turbines. The inclusion of a significant amount of wind energy into power systems has resulted in additional constraints on DED to accommodate the intermittent nature of the output. The probability of stochastic wind power based on the Weibull probability density function is included in the model as a constraint; A Here-and-Now Approach. The Environmental Protection Agency-s hourly emission target, which gives the maximum emission during the day, is used as a constraint to reduce the atmospheric pollution. A 69-bus test system with non-smooth cost function is used to illustrate the effectiveness of the proposed model compared with static economic dispatch model with including the wind power.
Abstract: Real world Speaker Identification (SI) application
differs from ideal or laboratory conditions causing perturbations that
leads to a mismatch between the training and testing environment
and degrade the performance drastically. Many strategies have been
adopted to cope with acoustical degradation; wavelet based Bayesian
marginal model is one of them. But Bayesian marginal models
cannot model the inter-scale statistical dependencies of different
wavelet scales. Simple nonlinear estimators for wavelet based
denoising assume that the wavelet coefficients in different scales are
independent in nature. However wavelet coefficients have significant
inter-scale dependency. This paper enhances this inter-scale
dependency property by a Circularly Symmetric Probability Density
Function (CS-PDF) related to the family of Spherically Invariant
Random Processes (SIRPs) in Log Gabor Wavelet (LGW) domain
and corresponding joint shrinkage estimator is derived by Maximum
a Posteriori (MAP) estimator. A framework is proposed based on
these to denoise speech signal for automatic speaker identification
problems. The robustness of the proposed framework is tested for
Text Independent Speaker Identification application on 100 speakers
of POLYCOST and 100 speakers of YOHO speech database in three
different noise environments. Experimental results show that the
proposed estimator yields a higher improvement in identification
accuracy compared to other estimators on popular Gaussian Mixture
Model (GMM) based speaker model and Mel-Frequency Cepstral
Coefficient (MFCC) features.
Abstract: An inflation–extension test with human vena cava
inferior was performed with the aim to fit a material model. The vein
was modeled as a thick–walled tube loaded by internal pressure and
axial force. The material was assumed to be an incompressible
hyperelastic fiber reinforced continuum. Fibers are supposed to be
arranged in two families of anti–symmetric helices. Considered
anisotropy corresponds to local orthotropy. Used strain energy
density function was based on a concept of limiting strain
extensibility. The pressurization was comprised by four pre–cycles
under physiological venous loading (0 – 4kPa) and four cycles under
nonphysiological loading (0 – 21kPa). Each overloading cycle was
performed with different value of axial weight. Overloading data
were used in regression analysis to fit material model. Considered
model did not fit experimental data so good. Especially predictions
of axial force failed. It was hypothesized that due to
nonphysiological values of loading pressure and different values of
axial weight the material was not preconditioned enough and some
damage occurred inside the wall. A limiting fiber extensibility
parameter Jm was assumed to be in relation to supposed damage.
Each of overloading cycles was fitted separately with different values
of Jm. Other parameters were held the same. This approach turned out
to be successful. Variable value of Jm can describe changes in the
axial force – axial stretch response and satisfy pressure – radius
dependence simultaneously.
Abstract: Since dealing with high dimensional data is
computationally complex and sometimes even intractable, recently
several feature reductions methods have been developed to reduce
the dimensionality of the data in order to simplify the calculation
analysis in various applications such as text categorization, signal
processing, image retrieval, gene expressions and etc. Among feature
reduction techniques, feature selection is one the most popular
methods due to the preservation of the original features.
In this paper, we propose a new unsupervised feature selection
method which will remove redundant features from the original
feature space by the use of probability density functions of various
features. To show the effectiveness of the proposed method, popular
feature selection methods have been implemented and compared.
Experimental results on the several datasets derived from UCI
repository database, illustrate the effectiveness of our proposed
methods in comparison with the other compared methods in terms of
both classification accuracy and the number of selected features.
Abstract: This paper reports the feasibility of the ARMA model
to describe a bursty video source transmitting over a AAL5 ATM link
(VBR traffic). The traffic represents the activity of the action movie
"Lethal Weapon 3" transmitted over the ATM network using the Fore
System AVA-200 ATM video codec with a peak rate of 100 Mbps
and a frame rate of 25. The model parameters were estimated for a
single video source and independently multiplexed video sources. It
was found that the model ARMA (2, 4) is well-suited for the real data
in terms of average rate traffic profile, probability density function,
autocorrelation function, burstiness measure, and the pole-zero
distribution of the filter model.
Abstract: Density functional theory (DFT) calculations were performed to calculate aluminum-27, boron-11, and nitrogen-14 quadrupole coupling constant (CQ) in the representative considered model of (6, 0) boron nitride-aluminum nitride nanotube junction (BN-AlNNT) for the first time. To this aim, 1.3 nm length of BNAlN consisting of 18 Al, 18 B, and 36 N atoms was selected where the end atoms capped by hydrogen atoms. The calculated CQ values for optimized BN-AlNNT system reveal different electrostatic environment in the mentioned system. The calculations were performed using the Gaussian 98 package of program.
Abstract: Performance of a dual maximal ratio combining
receiver has been analyzed for M-ary coherent and non-coherent
modulations over correlated Nakagami-m fading channels with nonidentical
and arbitrary fading parameter. The classical probability
density function (PDF) based approach is used for analysis.
Expressions for outage probability and average symbol error
performance for M-ary coherent and non-coherent modulations have
been obtained. The obtained results are verified against the special
case published results and found to be matching. The effect of the
unequal fading parameters, branch correlation and unequal input
average SNR on the receiver performance has been studied.
Abstract: This manuscript presents a method for the numerical solution of the Cauchy type singular integral equations of the first kind, over a finite segment which is bounded at the end points of the finite segment. The Chebyshev polynomials of the second kind with the corresponding weight function have been used to approximate the density function. The force function is approximated by using the Chebyshev polynomials of the first kind. It is shown that the numerical solution of characteristic singular integral equation is identical with the exact solution, when the force function is a cubic function. Moreover, it also shown that this numerical method gives exact solution for other singular integral equations with degenerate kernels.
Abstract: The bonding configuration and the heat of adsorption
of a furfural molecule on the Pd(111) surface were determined by ab
initio density-functional-theory calculations. The dynamics of pure
liquid water, the liquid-solid interface formed by liquid water and the
Pd(111) surface, as well as furfural at the water-Pd interface, were
investigated by ab initio molecular dynamics simulations at finite
temperatures. Calculations and simulations suggest that the bonding
configurations at the water-Pd interface promote decarbonylation of
furfural.
Abstract: Relay based communication has gained considerable importance in the recent years. In this paper we find the end-toend statistics of a two hop non-regenerative relay branch, each hop being Nakagami-m faded. Closed form expressions for the probability density functions of the signal envelope at the output of a selection combiner and a maximal ratio combiner at the destination node are also derived and analytical formulations are verified through computer simulation. These density functions are useful in evaluating the system performance in terms of bit error rate and outage probability.