Abstract: This paper studied the synthesis of monoacylglycerol (monolaurin) by glycerolysis of coconut oil and crude glycerol, catalyzed by Carica papaya lipase. Coconut oil obtained from cold pressed extraction method and crude glycerol obtained from the biodiesel plant in Department of Chemistry, Uttaradit Rajabhat University, Thailand which used oils were used as raw materials for biodiesel production through transesterification process catalyzed by sodium hydroxide. The influences of the following variables were studied: (i) type of organic solvent, (ii) molar ratio of substrate, (iii) reaction temperature, (iv) reaction time, (v) lipase dosage, and (vi) initial water activity of enzyme. High yields in monoacylglycerol (58.35%) were obtained with molar ratio of glycerol to oil at 8:1 in ethanol, temperature was controlled at 45oC for 36 hours, the amount of enzyme used was 20 wt% of oil and initial water activity of enzyme at 0.53.
Abstract: This paper describes technological possibilities to
enhance methane productionin the anaerobic stabilization of wastewater treatment plant excess sludge. This objective can be achieved by the addition of waste residues: crude glycerol from biodiesel production and residues from fishery. The addition
ofglycerol in an amount by weight of 2 – 5% causes enhancement of methane production of about 250 – 400%. At the same time the
percentage increase of total solids concentration in the outgoing sludge is ten or more times less. The containment of methane in
biogas is higher in case of admixed substrate.
Abstract: In this study, the transesterification of palm oil with methanol for biodiesel production was studied by using CaO–ZnO as a heterogeneous base catalyst prepared by incipient-wetness impregnation (IWI) and co-precipitation (CP) methods. The reaction parameters considered were molar ratio of methanol to oil, amount of catalyst, reaction temperature, and reaction time. The optimum conditions–15:1 molar ratio of methanol to oil, a catalyst amount of 6 wt%, reaction temperature of 60 °C, and reaction time of 8 h–were observed. The effects of Ca loading, calcination temperature, and catalyst preparation on the catalytic performance were studied. The fresh and spent catalysts were characterized by several techniques, including XRD, TPR, and XRF.
Abstract: In this paper, naturally immobilized lipase, Carica
papaya lipase, catalyzed biodiesel production from fish oil was
studied. The refined fish oil, extracted from the discarded parts of
fish, was used as a starting material for biodiesel production. The
effects of molar ratio of oil: methanol, lipase dosage, initial water
activity of lipase, temperature and solvent were investigated. It was
found that Carica papaya lipase was suitable for methanolysis of fish
oil to produce methyl ester. The maximum yield of methyl ester
could reach up to 83% with the optimal reaction conditions: oil:
methanol molar ratio of 1: 4, 20% (based on oil) of lipase, initial
water activity of lipase at 0.23 and 20% (based on oil) of tert-butanol
at 40oC after 18 h of reaction time. There was negligible loss in
lipase activity even after repeated use for 30 cycles.
Abstract: In this research, CaO-ZnO catalysts (with various
Ca:Zn atomic ratios of 1:5, 1:3, 1:1, and 3:1) prepared by incipientwetness
impregnation (IWI) and co-precipitation (CP) methods were
used as a catalyst in the transesterification of palm oil with methanol
for biodiesel production. The catalysts were characterized by several
techniques, including BET method, CO2-TPD, and Hemmett
Indicator. The effects of precursor concentration, and calcination
temperature on the catalytic performance were studied under reaction
conditions of a 15:1 methanol to oil molar ratio, 6 wt% catalyst,
reaction temperature of 60°C, and reaction time of 8 h. At Ca:Zn
atomic ratio of 1:3 gave the highest FAME value owing to a basic
properties and surface area of the prepared catalyst.
Abstract: Biodiesel is traditionally produced from oleaginous
plants. On the other hand, increasing biodiesel production from these
raw materials could create problems of food supply. Producing
biodiesel from microalgae could help to overcome this difficulty,
because microalgae are rich in lipids and do not compete for arable
lands. However, no studies had compared vegetable and microalgae
oil-based biodiesel in terms of yield, viscosity and heat of
combustion. In the present study, commercial canola and microalgae
oil were therefore transesterified with methanol under a homogenous
alkali catalyst (potassium hydroxide) at 100oC for 1h. The result
showed that microalgae-based oil has a higher yield in biodiesel with
89.7% (g biodiesel/g oil) and a lower kinematic viscosity (22oC) of
4.31 mm/s2 than canola oil.
Abstract: Biodisel is a type of biofuel having similar properties of diesel fuel but lacks substances (undesirable emissions) such as sulfur, nitrogen and aromatic polycyclic. Upon filtration of waste oil, the biodiesel fuel was produced via carrying out transestrification reaction of triglycerides followed by conducting viscosity, density, flash point, cloud point, pour point and copper strip corrosion tests on the samples and comparing with EN14214 and ASTM 6751 standards and all results were found in the permitted limit. The highest yield of biodiesel production reaction was found 46.6435 g when Sodium Hydroxide catalyst in amount of 0.375g was employed, 44.2347 g when Sodium methoxide catalyst in amount of 0.5g was employed and 56.5124 g when acid sulfuric catalyst in amount of 1g was employed and 47.3290 g when two stage reaction was done.
Abstract: Transesterification of candlenut (aleurites moluccana)
oil with methanol using potassium hydroxide as catalyst was
studied. The objective of the present investigation was to produce
the methyl ester for use as biodiesel. The operation variables
employed were methanol to oil molar ratio (3:1 – 9:1), catalyst
concentration (0.50 – 1.5 %) and temperature (303 – 343K). Oil
volume of 150 mL, reaction time of 75 min were fixed as common
parameters in all the experiments. The concentration of methyl ester
was evaluated by mass balance of free glycerol formed which was
analyzed by using periodic acid. The optimal triglyceride conversion
was attained by using methanol to oil ratio of 6:1, potassium
hydroxide as catalyst was of 1%, at room temperature. Methyl ester
formed was characterized by its density, viscosity, cloud and pour
points. The biodiesel properties had properties similar to those of
diesel oil, except for the viscosity that was higher.
Abstract: Biodiesel production with used frying by
transesterification reaction with methanol, using a commercial
kaolinite thermally-activated solid acid catalyst was investigated.
The surface area, the average pore diameter and pore volume of the
kaolinite catalyst were 10 m2/g, 13.0 nm and 30 mm3/g, respectively.
The optimal conditions for the transesterification reaction were
determined to be oil/methanol, in a molar ratio 1:31, temperature 160
ºC and catalyst concentration of 3% (w/w). The yield of fatty acids
methyl esters (FAME) was 92.4% after 2 h of reaction. This method
of preparation of biodiesel can be a positive alternative for utilizing
used frying corn oil for feedstock of biodiesel combined with the
inexpensive catalyst.
Abstract: Nano MgO has been synthesized by hydration and
dehydration method by modifies the commercial MgO. The prepared
MgO had been investigated as a heterogeneous base catalyst for
transesterification process for biodiesel production using palm oil.
TGA, FT-IR and XRD results obtained from this study lie each other
and proved in the formation of nano MgO from decomposition of
Mg(OH)2. This study proved that the prepared nano MgO was a
better base transesterification catalyst compared to commercial MgO.
The nano MgO calcined at 600ºC had gives the highest conversion of
51.3% of palm oil to biodiesel.
Abstract: Chicken fat was employed as a feedstock for
producing of biodiesel by trasesterification reaction with methanol
and alkali catalyst (KOH). In this study chicken fat biodiesel with
1.4% free fatty acid, methanol and various amount of potassium
hydroxide for 2 hour were studied. The progression of reaction and
conversion of triglycerides to methyl ester were checked by IR
spectrum method.
Abstract: The objective of this work is to produce heterotrophic
microalgal lipid in flask-batch fermentation. Chlorella sp. KKU-S2
supported maximum values of 0.374 g/L/d, 0.478 g lipid/g cells, and
0.112 g/L/d for volumetric lipid production rate, and specific yield of
lipid, and specific rate of lipid production, respectively when culture
was performed on BG-11 medium supplemented with 50g/L glucose.
Among the carbon sources tested, maximum cell yield coefficient
(YX/S, g/L), maximum specific yield of lipid (YP/X, g lipid/g cells) and
volumetric lipid production rate (QP, g/L/d) were found of 0.728,
0.237, and 0.619, respectively, using sugarcane molasses as carbon
source. The main components of fatty acid from extracted lipid were
palmitic acid, stearic acid, oleic acid and linoleic acid which similar
to vegetable oils and suitable for biodiesel production.
Abstract: Biodiesel production results in glycerol production as
the main by-product in biodiesel industry.One of the utilizations of
glycerol obtained from biodiesel production is as a cement grinding
aid (CGA). Results showed that crude glycerol content was 40.19%
whereas pure glycerol content was 82.15%. BSS value of the cement
with CGA supplementation was higher than that of nonsupplemented
cement (blank) indicating that CGA-supplemented
cement had higher fineness than the non-supplemented one. It was
also found that pure glycerol 95% and TEA 5% at 80ºC was the
optimum CGA used to result in finest cement with BSS value of
4.836 cm2/g. Residue test showed that the smallest percent residue
value (0.11%) was obtained in cement with supplementation of pure
glycerol 95% and TEA 5%. Results of residue test confirmed those of
BSS test showing that cement with supplementation of pure glycerol
95% and TEA 5% had the finest particle size.
Abstract: TiO2 supported nano-ZnO catalyst was prepared by
deposition-precipitation and tested for the trans-esterification
reaction of soybean oil to biodiesel. The TiO2 support stabilized the
nano-ZnO in a dispersed form with limited crystallite size compared
to the unsupported ZnO. The final ZnO dispersion and crystallite size
and the material transfer resistance in the catalyst significantly
influenced the supported nano-ZnO catalyst performance.