Abstract: Extraction of Fe(III) from aqueous solution using Trin-
butyl Phosphate (TBP) as carrier needs a highly acidic medium
(>6N) as it favours formation of chelating complex FeCl3.TBP.
Similarly, stripping of Iron(III) from loaded organic solvents requires
neutral pH or alkaline medium to dissociate the same complex. It is
observed that TBP co-extracts acids along with metal, which causes
reversal of driving force of extraction and iron(III) is re-extracted
back from the strip phase into the feed phase during Liquid Emulsion
Membrane (LEM) pertraction. Therefore, rate of extraction of
different mineral acids (HCl, HNO3, H2SO4) using TBP with and
without presence of metal Fe(III) was examined. It is revealed that in
presence of metal acid extraction is enhanced. Determination of mass
transfer coefficient of both acid and metal extraction was performed
by using Bulk Liquid Membrane (BLM). The average mass transfer
coefficient was obtained by fitting the derived model equation with
experimentally obtained data. The mass transfer coefficient of the
mineral acid extraction is in the order of kHNO3 = 3.3x10-6m/s > kHCl =
6.05x10-7m/s > kH2SO4 = 1.85x10-7m/s. The distribution equilibria of
the above mentioned acids between aqueous feed solution and a
solution of tri-n-butyl-phosphate (TBP) in organic solvents have been
investigated. The stoichiometry of acid extraction reveals the
formation of TBP.2HCl, HNO3.2TBP, and TBP.H2SO4 complexes.
Moreover, extraction of Iron(III) by TBP in HCl aqueous solution
forms complex FeCl3.TBP.2HCl while in HNO3 medium forms
complex 3FeCl3.TBP.2HNO3
Abstract: The absolute Cu atoms density in Cu(2S1/22P1/2)
ground state has been measured by Resonance Optical Absorption
(ROA) technique in a DC magnetron sputtering deposition with
argon. We measured these densities under variety of operation
conditions: pressure from 0.6 μbar to 14 μbar, input power from
10W to 200W and N2 mixture from 0% to 100%. For measuring the
gas temperature, we used the simulation of N2 rotational spectra
with a special computer code. The absolute number density of Cu
atoms decreases with increasing the N2 percentage of buffer gas at
any conditions of this work. But the deposition rate, is not decreased
with the same manner. The deposition rate variation is very small
and in the limit of quartz balance measuring equipment accuracy. So
we conclude that decrease in the absolute number density of Cu
atoms in magnetron plasma has not a big effect on deposition rate,
because the diffusion of Cu atoms to the chamber volume and
deviation of Cu atoms from direct path (towards the substrate)
decreases with increasing of N2 percentage of buffer gas. This is
because of the lower mass of N2 atoms compared to the argon ones.
Abstract: A collaboration among the Hospital S. Giovanni Battista
of Turin, the Politecnico of Turin, and the MUST company is
described. The content of the collaboration has been and is the use of
ICT-s, e-learning, and blended learning for the internal professional
education, training, and keeping up to date of the personnel of the
hospital. A platform for the delivery of the teaching materials has
been built, including an evaluation and self-evaluation tool. The first
on line courses have been developed and delivered and many more
are in preparation. The first results of the monitoring of the efficacy
of the online education have been positive.
Abstract: Many commercial processes are available for the
removal of H2S from gaseous streams. The desulfurization of gas
streams using aqueous ferric sulfate solution as washing liquor is
studied. Apart from sulfur, only H2O is generated in the process, and
consequently, no waste treatment facilities are required. A distinct
advantage of the process is that the reaction of H2S with is so rapid
and complete that there remains no danger of discharging toxic waste
gas. In this study, the reactive absorption of hydrogen sulfide into
aqueous ferric sulfate solution has been studied and design
calculations for equipments have been done and effective operation
parameters on this process considered. Results show that high
temperature and low pressure are suitable for absorption reaction.
Variation of hydrogen sulfide concentration and Fe3+ concentration
with time in absorption reaction shown that the reaction of ferric
sulfate and hydrogen sulfide is first order with respect to the both
reactant. At low Fe2(SO4)3 concentration the absorption rate of H2S
increase with increasing the Fe2(SO4)3 concentration. At higher
concentration a decrease in the absorption rate was found. At higher
concentration of Fe2(SO4)3, the ionic strength and viscosity of
solution increase remarkably resulting in a decrease of solubility,
diffusivity and hence absorption rate.
Abstract: α-Pinene is the main component of the most
turpentine oils. The hydration of α-pinene with acid catalysts leads to
a complex mixture of monoterpenes. In order to obtain more valuable
products, the α-pinene in the turpentine can be hydrated in dilute
mineral acid solutions to produce α-terpineol. The design of
separation processes requires information on phase equilibrium and
related thermodynamic properties. This paper reports the results of
study on liquid-liquid equilibrium (LLE) of system containing α-
pinene + water and α-terpineol + water.
Binary LLE for α-pinene + water system, and α-terpineol + water
systems were determined by experiment at 301K and atmospheric
pressure. The two component mixture was stirred for about 30min,
then the mixture was left for about 2h for complete phase separation.
The composition of both phases was analyzed by using a Gas
Chromatograph. The experimental data were correlated by
considering both NRTL and UNIQUAC activity coefficient models.
The LLE data for the system of α-pinene + water and α-terpineol +
water were correlated successfully by the NRTL model. The
experimental data were not satisfactorily fitted by the UNIQUAC
model. The NRTL model (α =0.3) correlates the LLE data for the
system of α-pinene + water at 301K with RMSD of 0.0404%. And
the NRTL model (α =0.61) at 301K with RMSD of 0.0058 %. The
NRTL model (α =0.3) correlates the LLE data for the system of α-
terpineol + water at 301K with RMSD of 0.1487% and the NRTL
model (α =0.6) at 301K with RMSD of 0.0032%, between the
experimental and calculated mole fractions.
Abstract: This study mainly aims at assessing the level of
microbial pollution of the water used in the chair system in dental
clinics. For this purpose 36 samples have been randomly collected
from a number of dental surgeries in the city of Tripoli in Libya.
However, 32 of the samples have tested positive to microbial
pollution including 13 of the samples, which have tested positives to
Pseudomonas aeruginosa. Based on the results of the test a further
investigation of the biofilms incorporated within the dental chair
system has been conducted. The laboratory tests of biofilms with
similar design to those found in dental chairs have proved that
bacterial pollution takes place through saliva of the patients who use
the chairs, and that this saliva is rich with nutrients which provides a
suitable breeding ground for all types of bacteria.
Abstract: System MEMORI automatically detects and recognizes
rotated and/or rescaled versions of the objects of a database within
digital color images with cluttered background. This task is accomplished
by means of a region grouping algorithm guided by heuristic
rules, whose parameters concern some geometrical properties and the
recognition score of the database objects. This paper focuses on the
strategies implemented in MEMORI for the estimation of the heuristic
rule parameters. This estimation, being automatic, makes the system
a self configuring and highly user-friendly tool.
Abstract: Massive use of places with strong tourist attraction
with the consequent possibility of losing place-identity produces
harmful effects on cities and their users. In order to mitigate this risk,
areas close to such places can be identified so as to widen the
visitor-s range of action and offer alternative activities integrated
with the main site. The cultural places and appropriate activities can
be identified using a method of analysis and design able to trace the
identity of the places, their characteristics and potential, and to
provide a sustainable improvement. The aim of this work is to
propose PlaceMaker as a method of urban analysis and design which
both detects elements that do not feature in traditional mapping and
which constitute the contemporary identity of the places, and
identifies appropriate project interventions. Two final complex maps
– the first of analysis and the second of design – respectively
represent the identity of places and project interventions. In order to
illustrate the method-s potential; the results of the experimentation
carried out in the Trevi-Pantheon route in Rome and the appropriate
interventions to decongest the area are illustrated.
Abstract: This paper presents a new growing neural network for
cluster analysis and market segmentation, which optimizes the size
and structure of clusters by iteratively checking them for multivariate
normality. We combine the recently published SGNN approach [8]
with the basic principle underlying the Gaussian-means algorithm
[13] and the Mardia test for multivariate normality [18, 19]. The new
approach distinguishes from existing ones by its holistic design and
its great autonomy regarding the clustering process as a whole. Its
performance is demonstrated by means of synthetic 2D data and by
real lifestyle survey data usable for market segmentation.
Abstract: Industrial robots become useless without end-effectors
that for many instances are in the form of friction grippers.
Commonly friction grippers apply frictional forces to different
objects on the basis of programmers- experiences. This puts a
limitation on the effectiveness of gripping force that may result in
damaging the object. This paper describes various stages of design
and development of a low cost sensor-based robotic gripper that
would facilitate the task of applying right gripping forces to different
objects. The gripper is also equipped with range sensors in order to
avoid collisions of the gripper with objects. It is a fully functional
automated pick and place gripper which can be used in many
industrial applications. Yet it can also be altered or further developed
in order to suit a larger number of industrial activities. The current
design of gripper could lead to designing completely automated robot
grippers able to improve the efficiency and productivity of industrial
robots.
Abstract: In this paper, applying frequency domain approach, a delayed predator-prey fishery model with prey reserve is investigated. By choosing the delay τ as a bifurcation parameter, It is found that Hopf bifurcation occurs as the bifurcation parameter τ passes a sequence of critical values. That is, a family of periodic solutions bifurcate from the equilibrium when the bifurcation parameter exceeds a critical value. The length of delay which preserves the stability of the positive equilibrium is calculated. Some numerical simulations are included to justify the theoretical analysis results. Finally, main conclusions are given.
Abstract: The search for factors that influence user behavior has remained an important theme for both the academic and practitioner Information Systems Communities. In this paper we examine relevant user behaviors in the phase after adoption and investigate two factors that are expected to influence such behaviors, namely User Involvement (UI) and Personal Innovativeness in IT (PIIT). We conduct a field study to examine how these factors influence postadoption behavior and how they are interrelated. Building on theoretical premises and prior empirical findings, we propose and test two alternative models of the relationship between these factors. Our results reveal that the best explanation of post-adoption behavior is provided by the model where UI and PIIT independently influence post-adoption behavior. Our findings have important implications for research and practice. To that end, we offer directions for future research.
Abstract: This paper introduces an isolated and unique ancient language Burushaski, spoken in Hunza, Nagar, Yasin and parts of Gilgit in the Northern Areas of Pakistan. It explains the working mechanism of Multi Language Text Editor for Urdu and Burushaski. It is developed under the use of ISO/IEC 10646 Unicode standards for Urdu and Burushaski open-type fonts. It gives an ample opportunity to this regional ancient language to have a modern Information technology for its promotion and preservation. The main objective of this research paper is to help preserve the heritage of such rare languages and give smart way of automation. It also facilitates to those who are interested in undertaking research on Burushaski or keen to trace fonatic relationship between the national Urdu language and Burushaski. Since this editor covers both Burushaski and Urdu so it can play an important role to introduce Burusho linguistic culture to the world at large. Precisely, as a result of this research paper, Burushaski publication through IT means would be possible.
Abstract: This article proposes a current-mode square-rooting
circuit using current follower transconductance amplifier (CTFA).
The amplitude of the output current can be electronically controlled
via input bias current with wide input dynamic range. The proposed
circuit consists of only single CFTA. Without any matching
conditions and external passive elements, the circuit is then
appropriate for an IC architecture. The magnitude of the output signal
is temperature-insensitive. The PSpice simulation results are
depicted, and the given results agree well with the theoretical
anticipation. The power consumption is approximately 1.96mW at
±1.5V supply voltages.
Abstract: The amount and heterogeneity of data in biomedical research, notably in interdisciplinary research, requires new methods for the collection, presentation and analysis of information. Important data from laboratory experiments as well as patient trials are available but come out of distributed resources. The Charite Medical School in Berlin has established together with the German Research Foundation (DFG) a new information service center for kidney diseases and transplantation (Open European Nephrology Science Centre - OpEN.SC). The system is based on a service-oriented architecture (SOA) with main and auxiliary modules arranged in four layers. To improve the reuse and efficient arrangement of the services the functionalities are described as business processes using the standardised Business Process Execution Language (BPEL).
Abstract: Nowadays, precipitation prediction is required for proper planning and management of water resources. Prediction with neural network models has received increasing interest in various research and application domains. However, it is difficult to determine the best neural network architecture for prediction since it is not immediately obvious how many input or hidden nodes are used in the model. In this paper, neural network model is used as a forecasting tool. The major aim is to evaluate a suitable neural network model for monthly precipitation mapping of Myanmar. Using 3-layerd neural network models, 100 cases are tested by changing the number of input and hidden nodes from 1 to 10 nodes, respectively, and only one outputnode used. The optimum model with the suitable number of nodes is selected in accordance with the minimum forecast error. In measuring network performance using Root Mean Square Error (RMSE), experimental results significantly show that 3 inputs-10 hiddens-1 output architecture model gives the best prediction result for monthly precipitation in Myanmar.
Abstract: A fast settling multipath CMOS OTA for high speed
switched capacitor applications is presented here. With the basic
topology similar to folded-cascode, bandwidth and DC gain of the
OTA are enhanced by adding extra paths for signal from input to
output. Designed circuit is simulated with HSPICE using level 49
parameters (BSIM 3v3) in 0.35mm standard CMOS technology. DC
gain achieved is 56.7dB and Unity Gain Bandwidth (UGB) obtained
is 1.15GHz. These results confirm that adding extra paths for signal
can improve DC gain and UGB of folded-cascode significantly.
Abstract: Pretreatment is an essential step in the conversion of
lignocellulosic biomass to fermentable sugar that used for biobutanol
production. Among pretreatment processes, microwave is considered
to improve pretreatment efficiency due to its high heating efficiency,
easy operation, and easily to combine with chemical reaction. The
main objectives of this work are to investigate the feasibility of
microwave pretreatment to enhance enzymatic hydrolysis of
corncobs and to determine the optimal conditions using response
surface methodology. Corncobs were pretreated via two-stage
pretreatment in dilute sodium hydroxide (2 %) followed by dilute
sulfuric acid 1 %. Pretreated corncobs were subjected to enzymatic
hydrolysis to produce reducing sugar. Statistical experimental design
was used to optimize pretreatment parameters including temperature,
residence time and solid-to-liquid ratio to achieve the highest amount
of glucose. The results revealed that solid-to-liquid ratio and
temperature had a significant effect on the amount of glucose.
Abstract: One of the most important secrets of succesful companies is the fact that cooperation with NGOs will create a good reputation for them so that they can be immunized to economic crisis. The performance of the most admired companies in the world based on the ratings of Forbes and Fortune show us that most of these firms also have close relationships with their NGOs. Today, if companies do something wrong this information spreads very quickly to do the society. If people do not like the activities of a company, it can find itself in public relations nightmare that can threaten its repuation. Since the cost of communication has dropped dramatically due to the vast use of internet, the increase in communication among stakeholders via internet makes companies more visible. These multiple and interdependent interactions among the network of stakeholders is called as the network relationships. NGOs play the role of catalyst among the stakeholders of a firm to enhance the awareness. Succesful firms are aware of this fact that NGOs have a central role in today-s business world. Firms are also aware of the fact that they can enhance their corporate reputation via cooperation with the NGOs. This fact will be illustrated in this paper by examining some of the actions of the most succesful companies in terms of their cooperations with the NGOs.
Abstract: The ability to predict an accurate temperature
distribution requires the knowledge of the losses, the thermal
characteristics of the materials, and the cooling conditions, all of
which are very difficult to quantify. In this paper, the impact of the
effects of iron and copper losses are investigated separately and
their effects on the heating in various points of the stator of an
induction motor, is highlighted by using two simple tests. In addition,
the effect of a defect, such as an open circuit in a phase of the stator,
on the heating is also obtained by a no-load test.
The squirrel cage induction motor is rated at 2.2 kW; 380 V; 5.2
A; Δ connected; 50 Hz; 1420 rpm and the class of insulation F, has
been thermally tested under several load conditions. Several
thermocouples were placed in strategic points of the stator.