Abstract: A study concerning the photocatalytic decolourization
of Congo red (CR) dye, over artificial UV irradiation is presented.
Photocatalysts based on a commercial titanium dioxide (TiO2)
modified with transition metals (Ni, Cu and Zn) were used. The
dopage method used was wet impregnation. A TiO2 sample without
salt was subjected to the same hydrothermal treatment to be used as
reference. Congo red solutions to several pH conditions (natural and
basic) were used to evaluate photocatalytic performance of each
doped catalysts. Photodecolourization percentage was measured
spectrofotrometically after 3 h of treatment to 499 nm as response
variable. Kinetics investigations of photodegradation indicated that
reactions obey to Langmuir-Hinshelwood model and pseudo–first
order law. The rate constant studies of photocatalytic decolourization
reactions for Zn–TiO2 and Cu–TiO2 photocatalysts indicated that in
all cases the rate constant of the reaction was higher than that of TiO2
undoped. These results show that nature of the metal modifying the
TiO2 influence on the efficiency of the photocatalyst evaluated in
process. Ni does not present an additional effect compared with TiO2,
while Zn enhances the photoactivity due to its electronic properties.
Abstract: The accelerated sonophotocatalytic degradation of
Reactive Red (RR) 120 dye under visible light using dye sensitized
TiO2 activated by ultrasound has been carried out. The effect of
sonolysis, photocatalysis and sonophotocatalysis under visible light
has been examined to study the influence on the degradation rates by
varying the initial substrate concentration, pH and catalyst loading to
ascertain the synergistic effect on the degradation techniques.
Ultrasonic activation contributes degradation through cavitation
leading to the splitting of H2O2 produced by both photocatalysis and
sonolysis. This results in the formation of oxidative species, such as
singlet oxygen (1O2) and superoxide (O2
-●) radicals in the presence of
oxygen. The increase in the amount of reactive radical species which
induce faster oxidation of the substrate and degradation of
intermediates and also the deaggregation of the photocatalyst are
responsible for the synergy observed under sonication. A
comparative study of photocatalysis and sonophotocatalysis using
TiO2, Hombikat UV 100 and ZnO was also carried out.
Abstract: The fine structure of supercavitation in the wake of a
symmetrical cylinder is studied with high-speed video cameras. The
flow is observed in a cavitation tunnel at the speed of 8m/sec when the
sidewall and the wake are partially filled with the massive cavitation
bubbles. The present experiment observed that a two-dimensional
ripple wave with a wave length of 0.3mm is propagated in a
downstream direction, and then abruptly increases to a thicker
three-dimensional layer. IR-photography recorded that the wakes
originated from the horseshoe vortexes alongside the cylinder. The
wake was developed to inside the dead water zone, which absorbed the
bubbly wake propelled from the separated vortices at the center of the
cylinder. A remote sensing classification technique (maximum most
likelihood) determined that the surface porosity was 0.2, and the mean
speed in the mixed wake was 7m/sec. To confirm the existence of
two-dimensional wave motions in the interface, the experiments were
conducted at a very low frequency, and showed similar gravity waves
in both the upper and lower interfaces.
Abstract: PARIS (Personal Archiving and Retrieving Image
System) is an experiment personal photograph library, which includes
more than 80,000 of consumer photographs accumulated within a
duration of approximately five years, metadata based on our proposed
MPEG-7 annotation architecture, Dozen Dimensional Digital Content
(DDDC), and a relational database structure. The DDDC architecture
is specially designed for facilitating the managing, browsing and
retrieving of personal digital photograph collections. In annotating
process, we also utilize a proposed Spatial and Temporal Ontology
(STO) designed based on the general characteristic of personal
photograph collections. This paper explains PRAIS system.
Abstract: Lighting upgrades involve relatively lower costs which
allow the benefits to be spread more widely than is possible with any
other energy efficiency measure. In order to popularize the adoption of
CFL in Taiwan, the authority proposes to implement a new energy efficient lamp comparative label system. The current study was
accordingly undertaken to investigate the factors affecting the performance and the deviation of actual and labeled performance of
commercially available integrated CFLs. In this paper, standard test
methods to determine the electrical and photometric performances of
CFL were developed based on CIE 84-1989 and CIE 60901-1987,
then 55 selected CFLs from market were tested. The results show that
with higher color temperature of CFLs lower efficacy are achieved. It
was noticed that the most packaging of CFL often lack the information of Color Rendering Index. Also, there was no correlation between
price and performance of the CFLs was indicated in this work. The results of this paper might help consumers to make more informed
CFL-purchasing decisions.
Abstract: This paper investigates the application of large scale (LS-PV) two-axis tracking photovoltaic power plant in Al-Jagbob, Libya. A 50MW PV-grid connected (two-axis tracking) power plant design in Al-Jagbob, Libya has been carried out presently. A hetero-junction with intrinsic thin layer (HIT) type PV module has been selected and modeled. A Microsoft Excel-VBA program has been constructed to compute slope radiation, dew-point, sky temperature, and then cell temperature, maximum power output and module efficiency for this system, for tracking system. The results for energy production show that the total energy output is 128.5 GWh/year. The average module efficiency is 16.6%. The electricity generation capacity factor (CF) and solar capacity factor (SCF) were found to be 29.3% and 70.4% respectively. A 50MW two axis tracking power plant with a total energy output of 128.5 GWh/year would reduce CO2 pollution by 85,581 tonnes of each year. The payback time for the proposed LS-PV photovoltaic power plant was found to be 4 years.
Abstract: In a world of climate change and limited fossil fuel resources, renewable energy sources are playing an increasingly important role. Due to industrializations and population growth our economy and technologies today largely depend upon natural resources, which are not replaceable. Approximately 90% of our energy consumption comes from fossil fuels (viz. coal, oil and natural gas). The irony is that these resources are depleting. Also, the huge consumption of fossil fuels has caused visible damage to the environment in various forms viz. global warming, acid rains etc.
Abstract: A simple and dexterous in situ method was introduced to load CdS nanocrystals into organofunctionalized mesoporous, which used an ion-exchange method. The products were extensively characterized by combined spectroscopic methods. X- ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM) demonstrated both the maintenance of pore symmetry (space group p6mm) of SBA-15 and the presence of CdS nanocrystals with uniform sizes of about 6 - 8 nm inside the functionalized SBA-15 channels. These mesoporous silica-supported CdS composites showed room temperature photoluminescence properties with a blue shift, indicating the quantum size effect of nanocrystalline CdS.
Abstract: Topical photodynamic therapy (PDT) with
5-aminolevulinic acid (ALA) is an alternative therapy for treating
superficial cancer, especially for skin or oral cancer. ALA, a precursor
of the photosensitizer protoporphyrin IX (PpIX), is present as
zwitterions and hydrophilic property which make the low permeability
through the cell membrane. Collagen is a traditional carrier; its
molecular composed various amino acids which bear positive charge
and negative charge. In order to utilize the ion-pairs with ALA and
collagen, the study employed various pH values adjusting the net
charge. The aim of this study was to compare a series collagen form,
including solution, gel and sponge to investigate the topical delivery
behavior of ALA. The in vivo confocal laser scanning microscopy
(CLSM) study demonstrated that PpIX generation ability was different
pattern after apply for 6 h. Gel type could generate high PpIX, and
archived more deep of skin depth.
Abstract: A spectrophotometric method was developed for simultaneous quantification of pseudoephedrine hydrochloride (PSE) triprolidine hydrochloride (TRI) using second derivative method (zero-crossing technique). The second derivative amplitudes of PSE and TRI were measured at 271 and 321 nm, respectively. The calibration curves were linear in the range of 200 to 1,000 g/ml for PSE and 10 to 50 g/ml for TRI. The method was validated for specificity, accuracy, precision, limit of detection and limit of quantitation. The proposed method was applied to the assaying and dissolution of PSE and TRI in commercial tablets without any chemical separation. The results were compared with those obtained by the official USP31 method and statistical tests showed that there is no significant between the methods at 95% confidence level. The proposed method is simple, rapid and suitable for the routine quality control application. KeywordsTriprolidine, Pseudoephedrine, Derivative spectrophotometry, Dissolution testing.
Abstract: A hybrid Photovoltaic/Thermal (PV/T) solar system integrates photovoltaic and solar thermal technologies into one single solar energy device, with dual generation of electricity and heat energy. The aim of the present study is to evaluate the potential for introduction of the PV/T technology into Northern China. For this purpose, outdoor experiments were conducted on a prototype of a PV/T water-heating system. The annual thermal and electrical performances were investigated under the climatic conditions of Beijing. An economic analysis of the system was then carried out, followed by a sensitivity study. The analysis revealed that the hybrid system is not economically attractive with the current market and energy prices. However, considering the continuous commitment of the Chinese government towards policy development in the renewable energy sector, and technological improvements like the increasing cost-effectiveness of PV cells, PV/Thermal technology may become economically viable in the near future.
Abstract: Artifact free photoplethysmographic (PPG) signals are
necessary for non-invasive estimation of oxygen saturation (SpO2) in
arterial blood. Movement of a patient corrupts the PPGs with motion
artifacts, resulting in large errors in the computation of Sp02. This
paper presents a study on using Kalman Filter in an innovative way
by modeling both the Artillery Blood Pressure (ABP) and the
unwanted signal, additive motion artifact, to reduce motion artifacts
from corrupted PPG signals. Simulation results show acceptable
performance regarding LMS and variable step LMS, thus
establishing the efficacy of the proposed method.
Abstract: Automatic face detection is a complex problem in
image processing. Many methods exist to solve this problem such as
template matching, Fisher Linear Discriminate, Neural Networks,
SVM, and MRC. Success has been achieved with each method to
varying degrees and complexities. In proposed algorithm we used
upright, frontal faces for single gray scale images with decent
resolution and under good lighting condition. In the field of face
recognition technique the single face is matched with single face
from the training dataset. The author proposed a neural network
based face detection algorithm from the photographs as well as if any
test data appears it check from the online scanned training dataset.
Experimental result shows that the algorithm detected up to 95%
accuracy for any image.
Abstract: In this research the level of mercury is analyzed in
muscle tissue of Otolithes ruber retailed in Hamedan, Iran were
determined by flame atomic absorption spectrometry after wet
digestion. Analysis of mercury was carried out by
spectrophotometrically. The average concentration of Hg in muscle
tissue of Otolithes ruber was 0.030±0.026 -g/g so lower than to
compare with the Maximum Allowable Concentration determined by
FAO/WHO Codex Alimentarius Commission.
Abstract: Photovoltaic power generation forecasting is an
important task in renewable energy power system planning and
operating. This paper explores the application of neural networks
(NN) to study the design of photovoltaic power generation
forecasting systems for one week ahead using weather databases
include the global irradiance, and temperature of Ghardaia city
(south of Algeria) using a data acquisition system. Simulations were
run and the results are discussed showing that neural networks
Technique is capable to decrease the photovoltaic power generation
forecasting error.
Abstract: In this paper, we have proposed two novel plasmonic demultiplexing structures based on metal-insulator-metal surfaces which, beside their compact size, have a very good transmission spectrum. The impact of the key internal parameters on the transmission spectrum is numerically analyzed by using the twodimensional (2D) finite difference time domain (FDTD) method. The proposed structures could be used to develop ultra-compact photonic wavelength demultiplexing devices for large-scale photonic integration.
Abstract: This purpose of this paper is to develop and validate a
model to accurately predict the cell temperature of a PV module that
adapts to various mounting configurations, mounting locations, and
climates while only requiring readily available data from the module
manufacturer. Results from this model are also compared to results
from published cell temperature models. The models were used to
predict real-time performance from a PV water pumping systems in
the desert of Medenine, south of Tunisia using 60-min intervals of
measured performance data during one complete year. Statistical
analysis of the predicted results and measured data highlight possible
sources of errors and the limitations and/or adequacy of existing
models, to describe the temperature and efficiency of PV-cells and
consequently, the accuracy of performance of PV water pumping
systems prediction models.
Abstract: Nanophotocatalysts such as titanium (TiO2), zinc (ZnO), and iron (Fe2O3) oxides can be used in organic pollutants oxidation, and in many other applications. But among the challenges for technological application (scale-up) of the nanotechnology scientific developments two aspects are still little explored: research on environmental risk of the nanomaterials preparation methods, and the study of nanomaterials properties and/or performance variability. The environmental analysis was performed for six different methods of ZnO nanoparticles synthesis, and showed that it is possible to identify the more environmentally compatible process even at laboratory scale research. The obtained ZnO nanoparticles were tested as photocatalysts, and increased the degradation rate of the Rhodamine B dye up to 30 times.
Abstract: We propose the use of magneto-optic Kerr effect (MOKE) to realize single-qubit quantum gates. We consider longitudinal and polar MOKE in reflection geometry in which the magnetic field is parallel to both the plane of incidence and surface of the film. MOKE couples incident TE and TM polarized photons and the Hamiltonian that represents this interaction is isomorphic to that of a canonical two-level quantum system. By varying the phase and amplitude of the magnetic field, we can realize Hadamard, NOT, and arbitrary phase-shift single-qubit quantum gates. The principal advantage is operation with magnetically non-transparent materials.
Abstract: In this paper, in order to investigate the effects of
photovoltaic system introduction to detached houses in Japan, two
kinds of works were done. Firstly, the hourly generation amount of a
4.2kW photovoltaic system were simulated in 46 cities to investigate
the potential of the system in different regions in Japan using a
simulation model of photovoltaic system. Secondly, based on the
simulated electricity generation amount, the energy saving, the
environmental and the economic effect of the photovoltaic system
were examined from hourly to annual timescales, based upon
calculations of typical electricity, heating, cooling and hot water
supply load profiles for Japanese dwellings. The above analysis was
carried out using a standard year-s hourly weather data for the
different city provided by the Expanded AMeDAS Weather Data
issued by AIJ (Architectural Institute of Japan).