Abstract: Nano fibers produced by electrospinning are of industrial and scientific attention due to their special characteristics such as long length, small diameter and high surface area. Applications of electrospun structures in nanotechnology are included tissue scaffolds, fibers for drug delivery, composite reinforcement, chemical sensing, enzyme immobilization, membrane-based filtration, protective clothing, catalysis, solar cells, electronic devices and others. Many polymer and ceramic precursor nano fibers have been successfully electrospun with diameters in the range from 1 nm to several microns. The process is complex so that fiber diameter is influenced by various material, design and operating parameters. The objective of this work is to apply genetic algorithm on the parameters of electrospinning which have the most significant effect on the nano fiber diameter to determine the optimum parameter values before doing experimental set up. Effective factors including initial polymer concentration, initial jet radius, electrical potential, relaxation time, initial elongation, viscosity and distance between nozzle and collector are considered to determine finest diameter which is selected by user.
Abstract: This paper presents a comparative study on dry and wet grinding through experimental investigation in the grinding of CSM glass fibre reinforced polymer laminates using a pink aluminium oxide wheel. Different sets of experiments were performed to study the effects of the independent grinding parameters such as grinding wheel speed, feed and depth of cut on dependent performance criteria such as cutting forces and surface finish. Experimental conditions were laid out using design of experiment central composite design. An effective coolant was sought in this study to minimise cutting forces and surface roughness for GFRP laminates grinding. Test results showed that the use of coolants reduces surface roughness, although not necessarily the cutting forces. These research findings provide useful economic machining solution in terms of optimized grinding conditions for grinding CSM GFRP.
Abstract: A statistical optimization of the saccharification
process of EFB was studied. The statistical analysis was done by
applying faced centered central composite design (FCCCD) under
response surface methodology (RSM). In this investigation, EFB
dose, enzyme dose and saccharification period was examined, and the
maximum 53.45% (w/w) yield of reducing sugar was found with 4%
(w/v) of EFB, 10% (v/v) of enzyme after 120 hours of incubation. It
can be calculated that the conversion rate of cellulose content of the
substrate is more than 75% (w/w) which can be considered as a
remarkable achievement. All the variables, linear, quadratic and
interaction coefficient, were found to be highly significant, other than
two coefficients, one quadratic and another interaction coefficient.
The coefficient of determination (R2) is 0.9898 that confirms a
satisfactory data and indicated that approximately 98.98% of the
variability in the dependent variable, saccharification of EFB, could
be explained by this model.
Abstract: A novel biomass composite inspired from wood porous
structure was manufactured by impregnating vinyl monomer into
wood cellular structure under vacuum conditions, and initiating the
monomer for in situ polymerization through a thermal treatment. The
vacuum condition was studied, and the mechanical properties of the
composite were also tested. SEM observation shows that polymer
generated in the wood porous structure, and strongly interacted with
wood matrix; and the polymer content increased with vacuum value
increasing. FTIR indicates that polymer grafted onto wood matrix,
resulting chemical complex between them. The rate of monomer
loading increased with increasing vacuum value and time, accordance
with rate of polymer loading. The compression strength and modulus
of elasticity linearly increased with the increasing rate of polymer
loading. Results indicate that the novel biomass composite possesses
good mechanical properties capable of applying in the fields of
construction, traffic and so forth.
Abstract: A statistical optimization was studied to design a media composition to produce optimum cellulolytic enzyme where palm oil mill effluent (POME) as a basal medium and filamentous fungus, Trichoderma reesei RUT-C30 were used in the liquid state bioconversion(LSB). 2% (w/v) total suspended solid, TSS, of the POME supplemented with 1% (w/v) cellulose, 0.5%(w/v) peptone and 0.02% (v/v) Tween 80 was estimated to produce the optimum CMCase activity of 18.53 U/ml through the statistical analysis followed by the faced centered central composite design(FCCCD). The probability values of cellulose (
Abstract: The commercial white tyres are usually used for forklifts in food and medicine industries. Conventionally, silica is used as reinforcement in the tyres. However, the adhesion between silica particles and rubber is remarkably poor. To improve the problem of adhesion and hence enhance wear resistance, modification of silica surface is one of the solutions. In this work, the natural rubber compound blending with polyisoprene-coated silica prepared by admicellar polymerization technique was studied to compare with the natural rubber compound of unmodified silica. The surface characterization of modified silica was also examined by SEM, FTIR, and TGA. The results show that polyisoprene-coated silica/natural rubber compound gave better overall mechanical properties, especially wear resistance with the improvement of the adhesion between silica and natural rubber matrix that can be seen in the SEM micrograph.
Abstract: In this paper, a new design technique for enhancing
bandwidth that improves the performance of a conventional
microstrip patch antenna is proposed. This paper presents a novel
wideband probe fed inverted slotted microstrip patch antenna. The
design adopts contemporary techniques; coaxial probe feeding,
inverted patch structure and slotted patch. The composite effect of
integrating these techniques and by introducing the proposed patch,
offer a low profile, broadband, high gain, and low cross-polarization
level. The results for the VSWR, gain and co-and cross-polarization
patterns are presented. The antenna operating the band of 1.80-2.36
GHz shows an impedance bandwidth (2:1 VSWR) of 27% and a gain
of 10.18 dBi with a gain variation of 1.12 dBi. Good radiation
characteristics, including a cross-polarization level in xz-plane less
than -42 dB, have been obtained.
Abstract: Textile structures are engineered and fabricated to
meet worldwide structural applications. Nevertheless, research
varying textile structure on natural fibre as composite reinforcement
was found to be very limited. Most of the research is focusing on
short fibre and random discontinuous orientation of the reinforcement
structure. Realizing that natural fibre (NF) composite had been
widely developed to be used as synthetic fibre composite
replacement, this research attempted to examine the influence of
woven and cross-ply laminated structure towards its mechanical
performances. Laminated natural fibre composites were developed
using hand lay-up and vacuum bagging technique. Impact and
flexural strength were investigated as a function of fibre type (coir
and kenaf) and reinforcement structure (imbalanced plain woven,
0°/90° cross-ply and +45°/-45° cross-ply). Multi-level full factorial
design of experiment (DOE) and analysis of variance (ANOVA) was
employed to impart data as to how fibre type and reinforcement
structure parameters affect the mechanical properties of the
composites. This systematic experimentation has led to determination
of significant factors that predominant influences the impact and
flexural properties of the textile composites. It was proven that both
fibre type and reinforcement structure demonstrated significant
difference results. Overall results indicated that coir composite and
woven structure exhibited better impact and flexural strength. Yet,
cross-ply composite structure demonstrated better fracture resistance.
Abstract: In this paper a Public Key Cryptosystem is proposed
using the number theoretic transforms (NTT) over a ring of integer
modulo a composite number. The key agreement is similar to
ElGamal public key algorithm. The security of the system is based on
solution of multivariate linear congruence equations and discrete
logarithm problem. In the proposed cryptosystem only fixed numbers
of multiplications are carried out (constant complexity) and hence the
encryption and decryption can be done easily. At the same time, it is
very difficult to attack the cryptosystem, since the cipher text is a
sequence of integers which are interrelated. The system provides
authentication also. Using Mathematica version 5.0 the proposed
algorithm is justified with a numerical example.
Abstract: In this study, the effect of mechanical activation on the synthesis of Fe3Al/Al2O3 nanocomposite has been investigated by using mechanochemical method. For this purpose, Aluminum powder and hematite as precursors, with stoichiometric ratio, have been utilized and other effective parameters in milling process were kept constant. Phase formation analysis, crystallite size measurement and lattice strain were studied by X-ray diffraction (XRD) by using Williamson-Hall method as well as microstructure and morphology were explored by Scanning electron microscopy (SEM). Also, Energy-dispersive X-ray spectroscopy (EDX) analysis was used in order to probe the particle distribution. The results showed that after 30-hour milling, the reaction was started, combustibly done and completed.
Abstract: Silver-exchanged zeolites and clays are used in
polymer composites to confer broad-spectrum antimicrobial
properties on a range of functional materials. Tobermorite is a layer
lattice mineral whose potential as a carrier for Ag+ ions in
antibacterial composites has not yet been investigated. Accordingly,
in this study, synthetic tobermorite was ion-exchanged with 10 wt%
silver ions and the resulting material was incorporated into a
composite film with chitosan. Chitosan is a biocompatible,
biodegradable derivative of chitin, a polysaccharide obtained from
the shells of crustaceans. The solvent-cast Ag+-exchanged
tobermorite-chitosan films were found to exhibit antimicrobial action
against Staphylococcus aureus, Escherichia coli and Pseudomonas
aeruginosa.
Abstract: TiO2/Ag composite films were prepared by
incorporating Ag in the pores of mesoporous TiO2 films using a
photoreduction method. The Ag nanoparticle sizes were in a range of
3.66-38.56 nm. The TiO2/Ag composite films were characterized by
X-ray diffraction (XRD), scanning electron microscopy (SEM) and
transmission electron microscropy (TEM). The TiO2 films and
TiO2/Ag composite films were immersed in a 0.3 mM N719 dye
solution and characterized by UV-Vis spectrophotometer. The
TiO2/Ag/N719 composite film showed that an optimal size of Ag
nanoparticles was 19.12 nm and, hence, gave the maximum optical
absorption spectra. The improved absorption was due to surface
plasmon resonance induced by the Ag nanoparticles to enhance the
absorption coefficient of the dye.
Abstract: The objective of this research was to investigate biodegradation of water hyacinth (Eichhornia crassipes) to produce bioethanol using dilute-acid pretreatment (1% sulfuric acid) results in high hemicellulose decomposition and using yeast (Pachysolen tannophilus) as bioethanol producing strain. A maximum ethanol yield of 1.14g/L with coefficient, 0.24g g-1; productivity, 0.015g l-1h-1 was comparable to predicted value 32.05g/L obtained by Central Composite Design (CCD). Maximum ethanol yield coefficient was comparable to those obtained through enzymatic saccharification and fermentation of acid hydrolysate using fully equipped fermentor. Although maximum ethanol concentration was low in lab scale, the improvement of lignocellulosic ethanol yield is necessary for large scale production.
Abstract: The paper discusses optimising work on a method of processing ceramic / metal composite coatings for various applications and is based on preliminary work on processing anodes for solid oxide fuel cells (SOFCs). The composite coating is manufactured by the electroless co-deposition of nickel and yttria stabilised zirconia (YSZ) simultaneously on to a ceramic substrate. The effect on coating characteristics of substrate surface treatments and electroless nickel bath parameters such as pH and agitation methods are also investigated. Characterisation of the resulting deposit by scanning electron microscopy (SEM) and energy dispersive X-ray analysis (EDXA) is also discussed.
Abstract: This paper introduces a novel design for boring bar with enhanced damping capability. The principle followed in the design phase was to enhance the damping capability minimizing the loss in static stiffness through implementation of composite material interfaces. The newly designed tool has been compared to a conventional tool. The evaluation criteria were the dynamic characteristics, frequency and damping ratio, of the machining system, as well as the surface roughness of the machined workpieces. The use of composite material in the design of damped tool has been demonstrated effective. Furthermore, the autoregressive moving average (ARMA) models presented in this paper take into consideration the interaction between the elastic structure of the machine tool and the cutting process and can therefore be used to characterize the machining system in operational conditions.
Abstract: Composite pins of rubber dust collected from tyre
retreading centres of trucks, cars and buses etc.and epoxy with
weight percentages of 10. 15, and 20 % of rubber (weight fractions of
9, 13 and 17 % respectively) have been prepared in house with the
help of a split wooden mould. The pins were tested in a pin-on-disc
wear monitor to determine the co-efficient of friction and weight
losses with varying speeds, loads and time. The wear volume and
wear rates have also been found out for all these three specimens.. It
is observed that all the specimens have exhibited very low coefficient
of friction and low wear rates under dry sliding condition. Out of the
above three samples tested, the specimen with 10 % rubber dust by
weight has shown lowest wear rates. However a peculiar result i.e
decreasing trend has been obtained with 20% reinforcement of rubber
in epoxy while rubbed against steel at varying speeds. This might
have occurred due to high surface finish of the disc and formation of
a thin transfer layer from the composite
Abstract: The “conveyor belt" as a product represents a
complex high performance component with a wide range of different
applications. Further development of these highly complex
components demands an integration of new technologies and new
enhanced materials. In this context nanostructured fillers appear to
have a more promising effect on the performance of the conveyor
belt composite than conventional micro-scaled fillers.
Within the project “DotTrans" nanostructured fillers, for example
silicon dioxide, are used to optimize performance parameters of
conveyor belt systems. The objective of the project includes
operating parameters like energy consumption or friction
characteristics as well as adaptive parameters like cut or wear
resistance.
Abstract: An attempt has been made to investigate the
machinability of zirconia toughened alumina (ZTA) inserts while
turning AISI 4340 steel. The insert was prepared by powder
metallurgy process route and the machining experiments were
performed based on Response Surface Methodology (RSM) design
called Central Composite Design (CCD). The mathematical model of
flank wear, cutting force and surface roughness have been developed
using second order regression analysis. The adequacy of model has
been carried out based on Analysis of variance (ANOVA) techniques.
It can be concluded that cutting speed and feed rate are the two most
influential factor for flank wear and cutting force prediction. For
surface roughness determination, the cutting speed & depth of cut
both have significant contribution. Key parameters effect on each
response has also been presented in graphical contours for choosing
the operating parameter preciously. 83% desirability level has been
achieved using this optimized condition.
Abstract: It is important to remove manganese from water
because of its effects on human and the environment. Human
activities are one of the biggest contributors for excessive manganese
concentration in the environment. The proposed method to remove
manganese in aqueous solution by using adsorption as in carbon
nanotubes (CNT) at different parameters: The parameters are CNT
dosage, pH, agitation speed and contact time. Different pHs are pH
6.0, pH 6.5, pH 7.0, pH 7.5 and pH 8.0, CNT dosages are 5mg,
6.25mg, 7.5mg, 8.75mg or 10mg, contact time are 10 min, 32.5 min,
55 min, 87.5 min and 120 min while the agitation speeds are 100rpm,
150rpm, 200rpm, 250rpm and 300rpm. The parameters chosen for
experiments are based on experimental design done by using Central
Composite Design, Design Expert 6.0 with 4 parameters, 5 levels and
2 replications. Based on the results, condition set at pH 7.0, agitation
speed of 300 rpm, 7.5mg and contact time 55 minutes gives the
highest removal with 75.5%. From ANOVA analysis in Design
Expert 6.0, the residual concentration will be very much affected by
pH and CNT dosage. Initial manganese concentration is 1.2mg/L
while the lowest residual concentration achieved is 0.294mg/L,
which almost satisfy DOE Malaysia Standard B requirement.
Therefore, further experiments must be done to remove manganese
from model water to the required standard (0.2 mg/L) with the initial
concentration set to 0.294 mg/L.
Abstract: This paper deals with the design of a periodic output
feedback controller for a flexible beam structure modeled with
Timoshenko beam theory, Finite Element Method, State space
methods and embedded piezoelectrics concept. The first 3 modes are
considered in modeling the beam. The main objective of this work is
to control the vibrations of the beam when subjected to an external
force. Shear piezoelectric sensors and actuators are embedded into
the top and bottom layers of a flexible aluminum beam structure, thus
making it intelligent and self-adaptive. The composite beam is
divided into 5 finite elements and the control actuator is placed at
finite element position 1, whereas the sensor is varied from position 2
to 5, i.e., from the nearby fixed end to the free end. 4 state space
SISO models are thus developed. Periodic Output Feedback (POF)
Controllers are designed for the 4 SISO models of the same plant to
control the flexural vibrations. The effect of placing the sensor at
different locations on the beam is observed and the performance of
the controller is evaluated for vibration control. Conclusions are
finally drawn.